Highly selective photocatalytic CO_(2) reduction to ethylene in pure water by Nb_(2)O_(5) nanoparticles with enriched surface –OH groups under simulated solar illumination

Photocatalytic CO_(2) reduction to valuable chemical compounds could be a promising approach for carbon-neutral practice.In this work,a simple and robust thermal decomposition process was developed with ammonium carbonate((NH4)2CO3)as both precipitation agent and sacrificial template to produce fine Nb_(2)O_(5) nanoparticles with the rich existence of surface hydroxyl(–OH)groups.It was found by density functional theory(DFT)calculations and experiments that the rich existence of the surface–OH groups enhanced the adsorption of both reactants(CO_(2) and H_(2)O molecules)for the photocatalytic CO_(2) reduction on these fine Nb_(2)O_(5) nanoparticles,and the highly selective conversion of CO_(2) to the high-value chemical compound of ethylene(C_(2)H_(4),~68μmol·g^(−1)·h^(−1) with~100%product selectivity)was achieved under simulated solar illumination without usage of any sacrificial agents or noble metal cocatalysts.This synthesis process may also be readily applied as a surface engineering method to enrich the existence of the surface–OH groups on various metal oxide-based photocatalysts for a broad range of technical applications.

Effect of non-uniform illumination on performance of solar thermoelectric generators

Solar thermoelectric generators （STEGs） are heat engines which can generate electricity from concentrated sunlight. The non-uniform illumination caused by the optical concentrator may affect the performance of solar thermoelectric generators. In this paper, a three- dimensional finite element model of solar thermoelectric generators is established. The two-dimensional Gaussian distribution is employed to modify the illumination profiles incident on the thermoelectric generator. Six non-uniformities of solar illumination are investigated while keeping the total energy constant. The influences of non-uniform illumination on the temperature distribution, the voltage distribution, and the maximum output power are respectively discussed. Three thermoelectric generators with 32, 18 and 8 pairs of thermocouples are compared to investigate their capability under non-uniform solar radiation. The result shows that the non-uniformity of the solar illumination has a great effect on the temperature distribution and the voltage distribution. Central thermoelectric legs can achieve a larger temperature difference and generate a larger voltage than peripheral ones. The non-uniform solar illumination will weaken the capability of the TE generator, and the maximum output power decrease by 1.4% among the range of non-uniformity studied in this paper. Reducing the number of the thermoelectric legs for non-uniform solar illumination can greatly increase the performance of the thermoelectric generator.

Vertical structure of longitudinal differences in electron densities at mid-latitudes

By using Constellation Observing System for Meteorology, Ionosphere, and Climate satellite observa- tions, and Global Ionosphere and Thermosphere Model simulations, the altitudinal dependences of the longitudinal differences in electron densities Ne were studied at mid- latitudes for the first time. Distinct altitudinal dependences were revealed： （1） In the northern （southern） hemisphere, there were wave-1 variations mainly in the daytime in the altitudes below 180 km, but wave-2 （wave-l） variations over a whole day above 220 km; （2） a transition （or sep- aration） layer occurred mainly in the daytime within 180 and 220 km, showing reversed longitudinal variation from that at lower altitudes. Solar illumination was one of the plausible mechanisms for the zonal difference of Ne at lower altitudes. At higher altitudes, both neutral winds and solar illumination played important roles. The neutral winds effects accounted for the longitudinal differences in Ne in the European-Asian sector. Neutral composition changes and neutral wind effects both contributed to the formation of the transition layer.

Photocatalytic activity of TiO2 containing anatase nanoparticles and rutile nanoflower structure consisting of nanorods

A series of TiO2 with different crystal phases and morphologies was synthesized via a facile hydrothermal process using titanium nbutoxide and concentrated hydrochloric acid as raw materials. The photocatalytic activity of the samples was evaluated by degradation of Methyl Orange in aqueous solution under UV-Visible light irradiation. On the basis of detailed analysis of the characterizing results of high-resolution transmission electron microscopy, X-ray powder diffraction measurements, X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller measurement, it was concluded that the photo-activity of the catalyst is related directly to the 3D morphology and the crystal phase composition. An excellent catalyst should have both a futile 3D flower-like structure and anatase granulous particles. The 3D flower-like structure could enhance light harvesting, as well as the transfer of reactant molecules from bulk solution to the reactive sites on TiO2. In addition, the optimum anatase/rutile phase ratio was found to be 80：20, which is beneficial to the effective separation of the photogenerated electron-hole pairs.