A detailed investigation on Pb-Ca-Sn alloys was made in order to choose suitable grid alloys materials for thin plate lead-acid batteries. The electrochemical performances of alloys were investigated by electrochemica...A detailed investigation on Pb-Ca-Sn alloys was made in order to choose suitable grid alloys materials for thin plate lead-acid batteries. The electrochemical performances of alloys were investigated by electrochemical corrosion experiment, scanning electron microscope (SEM), and cyclic voltammetry (CV) test. The results indicate that Pb-Ca-Sn-Bi-Cu alloys can be used to make the grids used for thin grid lead-acid batteries, the content of bismuth has primary effects on the corrosion resistance of grid alloys, the composition of alloys plays an important role on batteries performance, and appropriate scale of elements can be choosed to obtain optimal electrochemical performance. The lead-acid batteries using this kind of grid show good performance by cycle life test.展开更多
The basic theory of the fast charge and several charge methods are introduced. In order to heighten charge efficiency of valve-regulated lead-acid battery and shorten the charge time, five charge methods are investiga...The basic theory of the fast charge and several charge methods are introduced. In order to heighten charge efficiency of valve-regulated lead-acid battery and shorten the charge time, five charge methods are investigated with experiments done on the Digatron BNT 400-050 test bench. Battery current, terminal voltage, capacity, energy and terminal pole temperature during battery experiment were recorded, and corresponding curves were depicted. Battery capacity-time ratio, energy efficiency and energy-temperature ratio are put forward to be the appraising criteria of lead-acid battery on electric vehicle （EV）. According to the appraising criteria and the battery curves, multistage-current/negative-pulse charge method is recommended to charge lead-acid EV battery.展开更多
The possibility of using Pb-electroplated reticulated SiC as the positive current collector for lead-acid batteries was investigated. Reticulated SiC with two aperture sizes (3 and 2mm) were tested as the substrate of...The possibility of using Pb-electroplated reticulated SiC as the positive current collector for lead-acid batteries was investigated. Reticulated SiC with two aperture sizes (3 and 2mm) were tested as the substrate of positive electrode. It was found that the reticulated SiC has an excellent corrosion resistance in H2SO4 solution, and the Pb layer electroplated on reticulated SiC showed analogous electrochemical behavior to metal Pb. Preliminary test of the battery performance indicated that the utilization efficiency of the positive active mass of new designed batteries are improved compared with the conventional batteries. The improvement could be ascribed to the high specific surface area of the reticulated structured positive current collector, which was further supported by the even better performance of the battery made from a smaller aperture size (2mm) reticulated SiC as the substrate of the positive electrode.展开更多
This paper presents Mathematical Model and Experiment of Temperature effect on Charge and Discharge of Lead-Acid Battery performance in PV system power supply. To test temperature effect on battery discharge cycles, a...This paper presents Mathematical Model and Experiment of Temperature effect on Charge and Discharge of Lead-Acid Battery performance in PV system power supply. To test temperature effect on battery discharge cycles, a temperature range of tropical area from 25 - 60 degrees Celsius in a simulator is set up for testing. This temperature range is normally practical for battery usage. This allows the battery to determine the parameters of the battery quickly and high accurate. A Mathematical Model with MATLAB Program is written and constructed as block diagram using the equations of battery the parameters. By running program, the effects of various parameters are investigated. The results showed that time of discharge the battery is longer. Then, the experiment is set up by battery VRLA 12 V 20 AH. The results confirmed the mathematical model simulations.展开更多
This paper reports the performance investigation of a newly developed Latent Heat Thermal Battery(LHTB)integrated with a solar collector as the main source of heat.The LHTB is a new solution in the field of thermal st...This paper reports the performance investigation of a newly developed Latent Heat Thermal Battery(LHTB)integrated with a solar collector as the main source of heat.The LHTB is a new solution in the field of thermal storage and developed based on the battery concept in terms of recharge ability,portability and usability as a standalone device.It is fabricated based on the thermal battery storage concept and consists of a plate-fin and tube heat exchanger located inside the battery casing and paraffin wax which is used as a latent heat storage material.Solar thermal energy is absorbed by solar collector and transferred to the LHTB using water as Heat Transfer Fluid(HTF).Charging experiments have been conducted with a HTF at three different temperatures of 68°C,88°C and 108°C and three different flow rates of 30,60 and 120 l/h.It is followed by discharging experiments on fully charged LHTB at three different temperatures of 68°C,88°C and 108°C using HTF at three different flow rates of 30,60 and 120 l/h.It is found that both higher HTF inlet temperature and flow rate have a positive impact on stored thermal energy.However,charging efficiency was decreased by increasing the HTF flow rate.The highest charging efficiency of 29%was achieved using HTF of 108°C at a flow rate of 30 l/h.Most of paraffin melted in this case,while part of the paraffin remained solid in other experiments.On the other hand,the results from discharging experiments revealed that both recovered thermal energy and recovery efficiency increased by either increasing the LHTB temperature or HTF flow rate.Highest recovered thermal energy of 5,825 KJ at 35%recovery efficiency achieved at LHTB of 108°C using 120 l/h of HTF.展开更多
Measurement of state-of-charge of lead-acid batteries using potentiometric sensors would be convenient;however, most of the electrochemical couples are either soluble or are unstable in the battery electrolyte. This p...Measurement of state-of-charge of lead-acid batteries using potentiometric sensors would be convenient;however, most of the electrochemical couples are either soluble or are unstable in the battery electrolyte. This paper describes the results of an investigation of poly (divinylferrocene) (PDVF) and Poly(diethynylanthraquinone) (PAQ) couples in sulfuric acid with the view to developing a potentiometric sensor for lead-acid batteries. These compounds were both found to be quite stable and undergo reversible reduction/oxidation in sulfuric acid media. Their redox potential difference varied linearly with sulfuric acid concentration in the range of 1 M - 5 M (i.e. simulated lead-acid electrolyte during battery charge/discharge cycles). A sensor based on these compounds has been investigated.展开更多
This study presents the implementation of a desulphurization process for lead recycling under different chemical and physical conditions using pyro-metallurgical processes. Desulphurization was done using a hydrometal...This study presents the implementation of a desulphurization process for lead recycling under different chemical and physical conditions using pyro-metallurgical processes. Desulphurization was done using a hydrometallurgical process using sodium carbonate as a desulphurization agent and different lead-bearing loads compositions. Waste characterization included: SO2 concentrations in the stack emissions, total lead content in the furnace ash, the total lead content in the slag, and the toxicity characteristic leaching procedure (TCLP). A significant reduction in SO2 emissions was achieved (~55% reduction) where mean SO2 concentrations changed from 2193 ± 135 ppm to 1006 ± 62 ppm after the implementation of the modified processes. The desulfurized lead paste (i.e. the metallic fraction lead of the battery) of the modified process exhibited an improvement in the concentration of the lead in the TCLP test, with an average value of 1.5 ppm which is below US EPA limit of 5 ppm. The traditional process TCLP mean value for the TCLP was 54.2 ppm. The total lead content in the bag house ashes shows not significant variations, when comparing the desulphurization (67.6% m/m) and non-desulphurization process (64.9% m/m). The total lead mean content in the slag was higher in the desulphurization process (2.49% m/m) than the traditional process (1.91% m/m). Overall, the implementation of a new desulphurization method would potentially increase the operation costs in 10.3%. At the light of these results, a combination of hydrometallurgical and pyro-metallurgical processes in the recycling of lead-acid batteries can be used to reduce the environmental impact of these industries but would increase the operational costs of small lead recyclers.展开更多
Solar cells hold a function of photovoltaic conversion,while rechargeable metal batteries have an advantage of high energy storage.The conventional charge mode of batteries is made based on complete utilization of ele...Solar cells hold a function of photovoltaic conversion,while rechargeable metal batteries have an advantage of high energy storage.The conventional charge mode of batteries is made based on complete utilization of electric energy.The combination of solar cells and rechargeable metal batteries brings a new opportunity for the development of photo-assisted rechargeable batteries,in which the solar energy can be utilized to partially achieve photo-charging with or without external electrical bias.This review highlights the working mechanism and structure design of photo-assisted rechargeable metal batteries according to the characteristics of rechargeable metal batteries and advantage of the photovoltaic technology.In particular,the recent advances are introduced for photo-assisted rechargeable batteries based on light-weight metal anodes,including metal lithium,metal sodium,and metal zinc.The working features of the integrated devices are also discussed for energy saving under photo-assisted charging mode.Finally,a future outlook is provided for further improving the performance of photoassisted rechargeable metal batteries.展开更多
文摘A detailed investigation on Pb-Ca-Sn alloys was made in order to choose suitable grid alloys materials for thin plate lead-acid batteries. The electrochemical performances of alloys were investigated by electrochemical corrosion experiment, scanning electron microscope (SEM), and cyclic voltammetry (CV) test. The results indicate that Pb-Ca-Sn-Bi-Cu alloys can be used to make the grids used for thin grid lead-acid batteries, the content of bismuth has primary effects on the corrosion resistance of grid alloys, the composition of alloys plays an important role on batteries performance, and appropriate scale of elements can be choosed to obtain optimal electrochemical performance. The lead-acid batteries using this kind of grid show good performance by cycle life test.
基金the National "863" Program Project (2004AA501970)
文摘The basic theory of the fast charge and several charge methods are introduced. In order to heighten charge efficiency of valve-regulated lead-acid battery and shorten the charge time, five charge methods are investigated with experiments done on the Digatron BNT 400-050 test bench. Battery current, terminal voltage, capacity, energy and terminal pole temperature during battery experiment were recorded, and corresponding curves were depicted. Battery capacity-time ratio, energy efficiency and energy-temperature ratio are put forward to be the appraising criteria of lead-acid battery on electric vehicle （EV）. According to the appraising criteria and the battery curves, multistage-current/negative-pulse charge method is recommended to charge lead-acid EV battery.
文摘The possibility of using Pb-electroplated reticulated SiC as the positive current collector for lead-acid batteries was investigated. Reticulated SiC with two aperture sizes (3 and 2mm) were tested as the substrate of positive electrode. It was found that the reticulated SiC has an excellent corrosion resistance in H2SO4 solution, and the Pb layer electroplated on reticulated SiC showed analogous electrochemical behavior to metal Pb. Preliminary test of the battery performance indicated that the utilization efficiency of the positive active mass of new designed batteries are improved compared with the conventional batteries. The improvement could be ascribed to the high specific surface area of the reticulated structured positive current collector, which was further supported by the even better performance of the battery made from a smaller aperture size (2mm) reticulated SiC as the substrate of the positive electrode.
文摘This paper presents Mathematical Model and Experiment of Temperature effect on Charge and Discharge of Lead-Acid Battery performance in PV system power supply. To test temperature effect on battery discharge cycles, a temperature range of tropical area from 25 - 60 degrees Celsius in a simulator is set up for testing. This temperature range is normally practical for battery usage. This allows the battery to determine the parameters of the battery quickly and high accurate. A Mathematical Model with MATLAB Program is written and constructed as block diagram using the equations of battery the parameters. By running program, the effects of various parameters are investigated. The results showed that time of discharge the battery is longer. Then, the experiment is set up by battery VRLA 12 V 20 AH. The results confirmed the mathematical model simulations.
基金the University of Malaya,Faculty of Engineering,Faculty Research Grant No.GPF023A-2019.
文摘This paper reports the performance investigation of a newly developed Latent Heat Thermal Battery(LHTB)integrated with a solar collector as the main source of heat.The LHTB is a new solution in the field of thermal storage and developed based on the battery concept in terms of recharge ability,portability and usability as a standalone device.It is fabricated based on the thermal battery storage concept and consists of a plate-fin and tube heat exchanger located inside the battery casing and paraffin wax which is used as a latent heat storage material.Solar thermal energy is absorbed by solar collector and transferred to the LHTB using water as Heat Transfer Fluid(HTF).Charging experiments have been conducted with a HTF at three different temperatures of 68°C,88°C and 108°C and three different flow rates of 30,60 and 120 l/h.It is followed by discharging experiments on fully charged LHTB at three different temperatures of 68°C,88°C and 108°C using HTF at three different flow rates of 30,60 and 120 l/h.It is found that both higher HTF inlet temperature and flow rate have a positive impact on stored thermal energy.However,charging efficiency was decreased by increasing the HTF flow rate.The highest charging efficiency of 29%was achieved using HTF of 108°C at a flow rate of 30 l/h.Most of paraffin melted in this case,while part of the paraffin remained solid in other experiments.On the other hand,the results from discharging experiments revealed that both recovered thermal energy and recovery efficiency increased by either increasing the LHTB temperature or HTF flow rate.Highest recovered thermal energy of 5,825 KJ at 35%recovery efficiency achieved at LHTB of 108°C using 120 l/h of HTF.
文摘Measurement of state-of-charge of lead-acid batteries using potentiometric sensors would be convenient;however, most of the electrochemical couples are either soluble or are unstable in the battery electrolyte. This paper describes the results of an investigation of poly (divinylferrocene) (PDVF) and Poly(diethynylanthraquinone) (PAQ) couples in sulfuric acid with the view to developing a potentiometric sensor for lead-acid batteries. These compounds were both found to be quite stable and undergo reversible reduction/oxidation in sulfuric acid media. Their redox potential difference varied linearly with sulfuric acid concentration in the range of 1 M - 5 M (i.e. simulated lead-acid electrolyte during battery charge/discharge cycles). A sensor based on these compounds has been investigated.
文摘This study presents the implementation of a desulphurization process for lead recycling under different chemical and physical conditions using pyro-metallurgical processes. Desulphurization was done using a hydrometallurgical process using sodium carbonate as a desulphurization agent and different lead-bearing loads compositions. Waste characterization included: SO2 concentrations in the stack emissions, total lead content in the furnace ash, the total lead content in the slag, and the toxicity characteristic leaching procedure (TCLP). A significant reduction in SO2 emissions was achieved (~55% reduction) where mean SO2 concentrations changed from 2193 ± 135 ppm to 1006 ± 62 ppm after the implementation of the modified processes. The desulfurized lead paste (i.e. the metallic fraction lead of the battery) of the modified process exhibited an improvement in the concentration of the lead in the TCLP test, with an average value of 1.5 ppm which is below US EPA limit of 5 ppm. The traditional process TCLP mean value for the TCLP was 54.2 ppm. The total lead content in the bag house ashes shows not significant variations, when comparing the desulphurization (67.6% m/m) and non-desulphurization process (64.9% m/m). The total lead mean content in the slag was higher in the desulphurization process (2.49% m/m) than the traditional process (1.91% m/m). Overall, the implementation of a new desulphurization method would potentially increase the operation costs in 10.3%. At the light of these results, a combination of hydrometallurgical and pyro-metallurgical processes in the recycling of lead-acid batteries can be used to reduce the environmental impact of these industries but would increase the operational costs of small lead recyclers.
基金Financial supports from National Natural Science Foundation(21875123)of Chinathe project of Jiangxi Academy of Sciences(2020-YZD-3)are gratefully acknowledged.
文摘Solar cells hold a function of photovoltaic conversion,while rechargeable metal batteries have an advantage of high energy storage.The conventional charge mode of batteries is made based on complete utilization of electric energy.The combination of solar cells and rechargeable metal batteries brings a new opportunity for the development of photo-assisted rechargeable batteries,in which the solar energy can be utilized to partially achieve photo-charging with or without external electrical bias.This review highlights the working mechanism and structure design of photo-assisted rechargeable metal batteries according to the characteristics of rechargeable metal batteries and advantage of the photovoltaic technology.In particular,the recent advances are introduced for photo-assisted rechargeable batteries based on light-weight metal anodes,including metal lithium,metal sodium,and metal zinc.The working features of the integrated devices are also discussed for energy saving under photo-assisted charging mode.Finally,a future outlook is provided for further improving the performance of photoassisted rechargeable metal batteries.
