The aim of this study was to provide a simple, easy-to-use incubation system for small-scale rural poultry farmers far from the electricity grid. To this end, a naturally ventilated solar thermal incubator was built a...The aim of this study was to provide a simple, easy-to-use incubation system for small-scale rural poultry farmers far from the electricity grid. To this end, a naturally ventilated solar thermal incubator was built and experimentally tested. A U-shaped evacuated tube collector and a wooden crate holding 50 eggs were used to build the solar thermal incubator. Water was used as the heat transfer fluid, and an EPCM was integrated into the incubation chamber for operation at night or when the sun was hidden. The heat generated by the solar collector and stored in the heat transfer fluid is transported to the incubation chamber by thermosiphon to heat the chamber. Temperature and humidity probes powered by a solar panel were placed at various locations to monitor the thermo-hygrometric efficiency of the incubation system. The incubator, heated by natural convection, proved to function normally, and the incubation chamber was maintained throughout the incubation period within a temperature range of 35.53˚C to 39.53˚C and relative humidity averaging 49.4% to 68.5%. The experiment was carried out by introducing 30 eggs and the results of the experimental study showed that the incubator’s efficiency was 87%. The performance tests gave a fertility rate of 93% and a hatching rate of 93%, i.e. 28 fertile eggs and 26 hatched eggs, respectively.展开更多
Titanium tetrachloride (TiCl4) treatment was employed to TiO2 coating deposited on fluoride-doped tin oxide (FTO) conducting glass and indium oxide doped tin oxide (ITO) conducting glass, respectively. The nano-crysta...Titanium tetrachloride (TiCl4) treatment was employed to TiO2 coating deposited on fluoride-doped tin oxide (FTO) conducting glass and indium oxide doped tin oxide (ITO) conducting glass, respectively. The nano-crystalline TiO2 coating was deposited using a composite powder composed of polyethylene glycol (PEG) and 25 nm TiO2 particles by vacuum cold spraying (VCS) process. A commercial N-719 dye was used to adsorb on the surface of TiO2 coating to prepare TiO2 electrode, which was applied to assemble dye-sensitized solar cell (DSC). The cell performance was measured under simulated solar light at an intensity of 100 mW·cm-2. Results show that with an FTO substrate the DSC composed of a VCS TiO2 electrode untreated by TiCl4 gives a short-circuit current density of 13.1 mA·cm-2 and an open circuit voltage of 0.60 V corresponding to an overall conversion efficiency of 4.4%. It is found that after TiCl4 treatment to the VCS TiO2 electrode with an FTO substrate, the short circuit current density of the cell increases by 31%, the open-circuit voltage increases by 60 mV and a higher conversion yield of 6.5% was obtained. However, when an ITO substrate is used to deposit TiO2 coating by VCS, after TiCl4 treatment, the conversion efficiency of the assembled cell reduces slightly due to corrosion of the conducting layer on the ITO glass by TiCl4.展开更多
Highly crystalline and transparent CdS films are grown by utilizing the vacuum thermal evaporation (VTE) method. The structural, surface morphological, and optical properties of the films are studied and compared wi...Highly crystalline and transparent CdS films are grown by utilizing the vacuum thermal evaporation (VTE) method. The structural, surface morphological, and optical properties of the films are studied and compared with those prepared by chemical bath deposition (CBD). It is found that the films deposited at a high substrate temperature (200 ℃) have a preferential orientation along (002) which is consistent with CBD-grown films. Absorption spectra reveal that the films are highly transparent and the optical band gap values are found to be in a range of 2.44 eV-2.56 eV. Culnl_xGaxSe2 (CIGS) solar cells with in-situ VTE-grown CdS films exhibit higher values of Voc together with smaller values of Jsc than those from CBD. Eventually the conversion efficiency and fill factor become slightly better than those from the CBD method. Our work suggests that the in-situ thermal evaporation method can be a competitive alternative to the CBD method, particularly in the physical- and vacuum-based CIGS technology.展开更多
A systematic experimental investigation to understand the effect of heat loss and the thermoelectric aspect ratio (cross sectional area and length) on a flat plate solar thermoelectric system performance was carried o...A systematic experimental investigation to understand the effect of heat loss and the thermoelectric aspect ratio (cross sectional area and length) on a flat plate solar thermoelectric system performance was carried out. The investigation involved a series of experiments on systems with 4 different sizes of thermoelectric generators, and it was tested in 5 different vacuum levels during the steady-state. The detailed experimental investigation provided a substantial amount of data, which revealed that the system performance of both heat and electricity power were improved when the heat lost was minimised. The system’s performance strongly depended on the aspect ratio of the thermoelectric generators. This finding might have a significant impact on the cost of the system by saving the user’s and the manufacturer’s time in examining different TEGs with different aspect ratios in order to get the optimum size optimisation of the hybrid system, as well as reduce the manufacturing cost.展开更多
A novel vacuum ice slurry producing system with jet-pumps was proposed to deal with the problems of high energy consumption and ice blockage.In this novel system,one steam driven by a jet-pump was used to create vacuu...A novel vacuum ice slurry producing system with jet-pumps was proposed to deal with the problems of high energy consumption and ice blockage.In this novel system,one steam driven by a jet-pump was used to create vacuum in a hermetic vessel where water was sprayed through a nozzle to produce ice slurry,while the other steam was used to provide enough cold energy to make the left vapor in the hermetic vessel condense.Mathematical models of this novel system were established and theoretical simulation on the performance characteristics was also implemented based on the MATLAB program.Results show that the novel system is feasible and practicable,and the system performance is affected by many factors,such as the temperature of the generators,condensing temperature,evaporation temperature,and the cooling load of the refrigerator sub-system.The findings are helpful to improve the performance of ice slurry producing system.展开更多
Background: We referred to nearly 40 years of development and application progress of solar dryer in China literature, especially its application in the field of Chinese herbal medicine drying. Objective: We explored ...Background: We referred to nearly 40 years of development and application progress of solar dryer in China literature, especially its application in the field of Chinese herbal medicine drying. Objective: We explored the development direction of China’s development and application of solar dryers, especially focusing on its development and application in traditional Chinese medicine drying. Method: Five types of solar dryers including the greenhouse type solar dryer, the collector type solar dryer, the collector-greenhouse type hybrid solar dryer, the integrated solar dryer and the focusing type solar dryer accounted for the development and application of solar dryers up to 95% in China. The first three types of solar dryers are low temperature dryer (less than or equal to 70°C), while the latter two kinds of solar dryers are high temperature dryer (more than 70°C). In this paper, we respectively introduced and compared the structure, working principle, applications, advantages and disadvantages, and the research status of these five dryer. Results: The integrated solar dryer and the focusing type solar dryer belong to the high temperature dryer types are the future direction of development. Among them, the integrated solar dryer is relatively simple structure and has more promotion prospects. These two kinds of key drying device used in the dryer is the development direction of high efficient vacuum tube. On the other hand, because of their low cost, simple structure and the dry material requirements etc., the three types of low temperature dryers at low temperature for drying materials are also indispensable in the practical application. In contrast, the collector-greenhouse type hybrid solar dryer has more advantages, is the development direction of low temperature drying category. Conclusion: The collector tube which is the key element of the dryer was the core technology of solar dryer. Our country develops more successful of the all-glass vacuum solar thermal collectors and heat pipe-glass vacuum tube. Efficient vacuum tube collector technology is the future developed direction and is equally important to improve the quality of traditional Chinese medicine and dried.展开更多
The removal of impurity phosphorus from metallurgical grade silicon is one of the major problems on purification of metallurgical grade silicon for solar grade silicon preparation. The thermodynamics on vacuum refinin...The removal of impurity phosphorus from metallurgical grade silicon is one of the major problems on purification of metallurgical grade silicon for solar grade silicon preparation. The thermodynamics on vacuum refining process of the metallurgical grade silicon was studied via separation coefficient of impurity phosphorus in the metallurgical grade silicon and vapor-liquid equilibrium composition diagram of Si-P binary alloy at different temperatures. The behaviors of impurity phosphorus in the vacuum distillation process were examined. The results show that the vacuum distillation should be taken to obtain silicon with less than 10-7 P,and the impurity phosphorus is volatilized easily by vacuum distillation in thermodynamics. Phosphorus is distilled from the molten silicon and concentrated in vapor phase.展开更多
The kinetics on vacuum refining process of metallurgical grade silicon was studied using maximum evaporation rate,critical pressure and mean free path of phosphorus in the metallurgical grade silicon at different temp...The kinetics on vacuum refining process of metallurgical grade silicon was studied using maximum evaporation rate,critical pressure and mean free path of phosphorus in the metallurgical grade silicon at different temperatures. The behaviors of impurity phosphorus in the vacuum distillation process were examined in detail. The results show that the fractional vacuum distillation should be taken to obtain silicon with high purity. Impurity phosphorus volatilize with the maximum evaporation rate of 1.150×105- 1.585×106 g/(cm2·min) in the temperature range of 1 073-2 173 K and the pressure below 2.1 Pa. Because the value of ωmax,P is at least 108 times of ωmax,Si,Si hardly evaporates and remains in the residual,which indicates that phosphorus can be removed from metallurgical grade silicon(MG-Si) completely.展开更多
A bonding process for space solar cells implemented by an automated coating and bonding system was theoretically investigated for future parametric studies to achieve better bonding quality. First, the mechanical prop...A bonding process for space solar cells implemented by an automated coating and bonding system was theoretically investigated for future parametric studies to achieve better bonding quality. First, the mechanical properties of silicone adhesive and the vacuum suction cup were experimentally analyzed. Based on the constitutive relationship of four parts in the bonding process, the dynamic bonding process was modeled systematically, and numerically simulated by a commercial finite element analysis code, Adina. The final bonding edge-alignment error and the thickness and uniformity of the adhesive layer were obtained from simulation and validated by experiments. A simulation platform was created for predicting the final bonding quality via adjusting bonding parameters when dimensions of the solar cells and adhesive were changed.展开更多
Solar energy is very useful in the process of desalination especially for areas that suffer from a lack of clean water resources. In recent years, many people have been using solar still. Therefore the raising of the ...Solar energy is very useful in the process of desalination especially for areas that suffer from a lack of clean water resources. In recent years, many people have been using solar still. Therefore the raising of the productivity and efficiency of solar still represents the most important problems that need further research. The present work aims to study the effect of preheating the water entering to still and the effect of reducing pressure inside the still on the productivity of the solar still. Therefore in present work two identical single basin typical double slope solar stills of the inner basin dimensions for each still 2 m × 1 m × 0.08 m, have been designed and fabricated with mild steel plate. One of them is conventional solar still and the other is modified with flat plate collector and vacuum pump to study the effect of preheating and vacuum on the performance of solar still. The experimental measurements are made to enhance the solar still productivity by firstly preheating the water entering the still using flat plate collector and secondly by integrating the still basin with vacuum pump. The results show that preheating the water entering the still increases the water productivity by amount about 27.7% - 29.3%. The results also show that decreasing pressure inside the still using vacuum pump improves the solar still water productivety by amount about 21.8% - 23.9%.展开更多
The allure of high efficiency and low-temperature solution-processed organic-inorganic hybrid perovskite solar cells(PSCs)are inspiring scientists to seek for its commercialization.Interface passivation engineering ha...The allure of high efficiency and low-temperature solution-processed organic-inorganic hybrid perovskite solar cells(PSCs)are inspiring scientists to seek for its commercialization.Interface passivation engineering has become an effective way to further enhance the efficiency and stability of PSCs by defect passivation,reduces the charge recombination and ion migration initiation and hysteresis control,etc.Herein,we have summarized the effects and recent research progress of interface passivation engineering in PSCs.Interface passivation layers can be realized by using the solution and/or vacuum evaporation processes which are very adaptable to varied materials with different properties and fabrication processes for enhanced photovoltaic performance and stability.展开更多
Organic photovoltaic cells using polymer belonging to the aniline-heteroaryl family as electron donor have been achieved by thermal evaporation. We show that the properties of the polymer film, morphology, molecule or...Organic photovoltaic cells using polymer belonging to the aniline-heteroaryl family as electron donor have been achieved by thermal evaporation. We show that the properties of the polymer film, morphology, molecule order and conductivity depend strongly on the bottom anode buffer layer. While cells without anode buffer layer or with MoO3 or CuI anode buffer layer have been probed, we show that CuI allows improving strongly the cells efficiency through an improvement of the morphology and conductivity of the polymer film. This shows that although it is necessary a good band matching at the interface, this is not sufficient, because the templating effect of CuI on the polymer film is primordial for photovoltaic cells improvement.展开更多
The films of two x-shape oligo(thiophene)s, 3, 4-dibithienyl-2, 5-dithienylthiophene (7T) and 2, 5-dibithienyl-3, 4- ditrithienylthiophene (11T), which are prepared by vacuum evaporation, have been investigated ...The films of two x-shape oligo(thiophene)s, 3, 4-dibithienyl-2, 5-dithienylthiophene (7T) and 2, 5-dibithienyl-3, 4- ditrithienylthiophene (11T), which are prepared by vacuum evaporation, have been investigated as novel electron donor layers in two-layer photovoltaic cells. UV-Vis absorptions show red-shifted and broadened absorptions of the vacuumevaporated films as compared with those of the corresponding solutions and spin-coating films, which is beneficial for photovoltaic properties. X-ray diffraction (XRD) and differential scanning calorimetry (DSC) measurements show that the vacuum-evaporated films are almost amorphous. Two-layer photovoltaic cells have been realized by the thermal evaporation of 7T and llT as donors and N, N′-bis(1-ethylpropyl)-3, 4:9,10-perylene bis(tetracarboxyl diimide) (EP- PTC) as an acceptor. An energy conversion efficiency (ECE) of 0.18% of the cell based on 7T with an irradiation of white light at 100 mw/cm^2 has been demonstrated by the measurements of current (I)- voltage (V) curves of the cells to be higher than the ECE of the reference system based on donor dihexylterthienyl (H3T) that is linear and without α, β linkage.展开更多
文摘The aim of this study was to provide a simple, easy-to-use incubation system for small-scale rural poultry farmers far from the electricity grid. To this end, a naturally ventilated solar thermal incubator was built and experimentally tested. A U-shaped evacuated tube collector and a wooden crate holding 50 eggs were used to build the solar thermal incubator. Water was used as the heat transfer fluid, and an EPCM was integrated into the incubation chamber for operation at night or when the sun was hidden. The heat generated by the solar collector and stored in the heat transfer fluid is transported to the incubation chamber by thermosiphon to heat the chamber. Temperature and humidity probes powered by a solar panel were placed at various locations to monitor the thermo-hygrometric efficiency of the incubation system. The incubator, heated by natural convection, proved to function normally, and the incubation chamber was maintained throughout the incubation period within a temperature range of 35.53˚C to 39.53˚C and relative humidity averaging 49.4% to 68.5%. The experiment was carried out by introducing 30 eggs and the results of the experimental study showed that the incubator’s efficiency was 87%. The performance tests gave a fertility rate of 93% and a hatching rate of 93%, i.e. 28 fertile eggs and 26 hatched eggs, respectively.
文摘Titanium tetrachloride (TiCl4) treatment was employed to TiO2 coating deposited on fluoride-doped tin oxide (FTO) conducting glass and indium oxide doped tin oxide (ITO) conducting glass, respectively. The nano-crystalline TiO2 coating was deposited using a composite powder composed of polyethylene glycol (PEG) and 25 nm TiO2 particles by vacuum cold spraying (VCS) process. A commercial N-719 dye was used to adsorb on the surface of TiO2 coating to prepare TiO2 electrode, which was applied to assemble dye-sensitized solar cell (DSC). The cell performance was measured under simulated solar light at an intensity of 100 mW·cm-2. Results show that with an FTO substrate the DSC composed of a VCS TiO2 electrode untreated by TiCl4 gives a short-circuit current density of 13.1 mA·cm-2 and an open circuit voltage of 0.60 V corresponding to an overall conversion efficiency of 4.4%. It is found that after TiCl4 treatment to the VCS TiO2 electrode with an FTO substrate, the short circuit current density of the cell increases by 31%, the open-circuit voltage increases by 60 mV and a higher conversion yield of 6.5% was obtained. However, when an ITO substrate is used to deposit TiO2 coating by VCS, after TiCl4 treatment, the conversion efficiency of the assembled cell reduces slightly due to corrosion of the conducting layer on the ITO glass by TiCl4.
基金Project supported by the Natural Science Foundation of Shanghai (Grant No.13ZR1428200)
文摘Highly crystalline and transparent CdS films are grown by utilizing the vacuum thermal evaporation (VTE) method. The structural, surface morphological, and optical properties of the films are studied and compared with those prepared by chemical bath deposition (CBD). It is found that the films deposited at a high substrate temperature (200 ℃) have a preferential orientation along (002) which is consistent with CBD-grown films. Absorption spectra reveal that the films are highly transparent and the optical band gap values are found to be in a range of 2.44 eV-2.56 eV. Culnl_xGaxSe2 (CIGS) solar cells with in-situ VTE-grown CdS films exhibit higher values of Voc together with smaller values of Jsc than those from CBD. Eventually the conversion efficiency and fill factor become slightly better than those from the CBD method. Our work suggests that the in-situ thermal evaporation method can be a competitive alternative to the CBD method, particularly in the physical- and vacuum-based CIGS technology.
文摘A systematic experimental investigation to understand the effect of heat loss and the thermoelectric aspect ratio (cross sectional area and length) on a flat plate solar thermoelectric system performance was carried out. The investigation involved a series of experiments on systems with 4 different sizes of thermoelectric generators, and it was tested in 5 different vacuum levels during the steady-state. The detailed experimental investigation provided a substantial amount of data, which revealed that the system performance of both heat and electricity power were improved when the heat lost was minimised. The system’s performance strongly depended on the aspect ratio of the thermoelectric generators. This finding might have a significant impact on the cost of the system by saving the user’s and the manufacturer’s time in examining different TEGs with different aspect ratios in order to get the optimum size optimisation of the hybrid system, as well as reduce the manufacturing cost.
基金Project(51376198)supported by the National Natural Science Foundation of ChinaProject(11JJ22029)supported by the Hunan Provincial Natural Science Foundation of China
文摘A novel vacuum ice slurry producing system with jet-pumps was proposed to deal with the problems of high energy consumption and ice blockage.In this novel system,one steam driven by a jet-pump was used to create vacuum in a hermetic vessel where water was sprayed through a nozzle to produce ice slurry,while the other steam was used to provide enough cold energy to make the left vapor in the hermetic vessel condense.Mathematical models of this novel system were established and theoretical simulation on the performance characteristics was also implemented based on the MATLAB program.Results show that the novel system is feasible and practicable,and the system performance is affected by many factors,such as the temperature of the generators,condensing temperature,evaporation temperature,and the cooling load of the refrigerator sub-system.The findings are helpful to improve the performance of ice slurry producing system.
文摘Background: We referred to nearly 40 years of development and application progress of solar dryer in China literature, especially its application in the field of Chinese herbal medicine drying. Objective: We explored the development direction of China’s development and application of solar dryers, especially focusing on its development and application in traditional Chinese medicine drying. Method: Five types of solar dryers including the greenhouse type solar dryer, the collector type solar dryer, the collector-greenhouse type hybrid solar dryer, the integrated solar dryer and the focusing type solar dryer accounted for the development and application of solar dryers up to 95% in China. The first three types of solar dryers are low temperature dryer (less than or equal to 70°C), while the latter two kinds of solar dryers are high temperature dryer (more than 70°C). In this paper, we respectively introduced and compared the structure, working principle, applications, advantages and disadvantages, and the research status of these five dryer. Results: The integrated solar dryer and the focusing type solar dryer belong to the high temperature dryer types are the future direction of development. Among them, the integrated solar dryer is relatively simple structure and has more promotion prospects. These two kinds of key drying device used in the dryer is the development direction of high efficient vacuum tube. On the other hand, because of their low cost, simple structure and the dry material requirements etc., the three types of low temperature dryers at low temperature for drying materials are also indispensable in the practical application. In contrast, the collector-greenhouse type hybrid solar dryer has more advantages, is the development direction of low temperature drying category. Conclusion: The collector tube which is the key element of the dryer was the core technology of solar dryer. Our country develops more successful of the all-glass vacuum solar thermal collectors and heat pipe-glass vacuum tube. Efficient vacuum tube collector technology is the future developed direction and is equally important to improve the quality of traditional Chinese medicine and dried.
基金Project(50674050) supported by the National Natural Science Foundation of ChinaProject(2006BAE01B08) supported by Sustentation Project of Science and Technology of ChinaProject(20060674004) supported by the Doctorial Programs Foundation of Ministry of Education of China.
文摘The removal of impurity phosphorus from metallurgical grade silicon is one of the major problems on purification of metallurgical grade silicon for solar grade silicon preparation. The thermodynamics on vacuum refining process of the metallurgical grade silicon was studied via separation coefficient of impurity phosphorus in the metallurgical grade silicon and vapor-liquid equilibrium composition diagram of Si-P binary alloy at different temperatures. The behaviors of impurity phosphorus in the vacuum distillation process were examined. The results show that the vacuum distillation should be taken to obtain silicon with less than 10-7 P,and the impurity phosphorus is volatilized easily by vacuum distillation in thermodynamics. Phosphorus is distilled from the molten silicon and concentrated in vapor phase.
基金Project(50674050) supported by the National Natural Science Foundation of ChinaProject(2006BAE01B08) supported by the Sustentation Project of Science and Technology of ChinaProject(20060674004) supported by Doctorial Programs Foundation of Ministry of Education of China.
文摘The kinetics on vacuum refining process of metallurgical grade silicon was studied using maximum evaporation rate,critical pressure and mean free path of phosphorus in the metallurgical grade silicon at different temperatures. The behaviors of impurity phosphorus in the vacuum distillation process were examined in detail. The results show that the fractional vacuum distillation should be taken to obtain silicon with high purity. Impurity phosphorus volatilize with the maximum evaporation rate of 1.150×105- 1.585×106 g/(cm2·min) in the temperature range of 1 073-2 173 K and the pressure below 2.1 Pa. Because the value of ωmax,P is at least 108 times of ωmax,Si,Si hardly evaporates and remains in the residual,which indicates that phosphorus can be removed from metallurgical grade silicon(MG-Si) completely.
基金the National Natural Science Foundation of China(60675040)the Specialized Researth Fund for the Doctoral Program of Higher Education(20070248021)
文摘A bonding process for space solar cells implemented by an automated coating and bonding system was theoretically investigated for future parametric studies to achieve better bonding quality. First, the mechanical properties of silicone adhesive and the vacuum suction cup were experimentally analyzed. Based on the constitutive relationship of four parts in the bonding process, the dynamic bonding process was modeled systematically, and numerically simulated by a commercial finite element analysis code, Adina. The final bonding edge-alignment error and the thickness and uniformity of the adhesive layer were obtained from simulation and validated by experiments. A simulation platform was created for predicting the final bonding quality via adjusting bonding parameters when dimensions of the solar cells and adhesive were changed.
文摘Solar energy is very useful in the process of desalination especially for areas that suffer from a lack of clean water resources. In recent years, many people have been using solar still. Therefore the raising of the productivity and efficiency of solar still represents the most important problems that need further research. The present work aims to study the effect of preheating the water entering to still and the effect of reducing pressure inside the still on the productivity of the solar still. Therefore in present work two identical single basin typical double slope solar stills of the inner basin dimensions for each still 2 m × 1 m × 0.08 m, have been designed and fabricated with mild steel plate. One of them is conventional solar still and the other is modified with flat plate collector and vacuum pump to study the effect of preheating and vacuum on the performance of solar still. The experimental measurements are made to enhance the solar still productivity by firstly preheating the water entering the still using flat plate collector and secondly by integrating the still basin with vacuum pump. The results show that preheating the water entering the still increases the water productivity by amount about 27.7% - 29.3%. The results also show that decreasing pressure inside the still using vacuum pump improves the solar still water productivety by amount about 21.8% - 23.9%.
基金the National Key Research and Development Plan(2017YFE0131900,2019YFE0107200)National Natural Science Foundation of China(52072284)+2 种基金the Fundamental Research Funds for the Central Universities(WUT:202443004)the Technological Innovation Key Project of Hubei Province(2018AAA048).J.Z.thanks the support the“Chutian Scholar Program”of Hubei Province,China.
文摘The allure of high efficiency and low-temperature solution-processed organic-inorganic hybrid perovskite solar cells(PSCs)are inspiring scientists to seek for its commercialization.Interface passivation engineering has become an effective way to further enhance the efficiency and stability of PSCs by defect passivation,reduces the charge recombination and ion migration initiation and hysteresis control,etc.Herein,we have summarized the effects and recent research progress of interface passivation engineering in PSCs.Interface passivation layers can be realized by using the solution and/or vacuum evaporation processes which are very adaptable to varied materials with different properties and fabrication processes for enhanced photovoltaic performance and stability.
文摘Organic photovoltaic cells using polymer belonging to the aniline-heteroaryl family as electron donor have been achieved by thermal evaporation. We show that the properties of the polymer film, morphology, molecule order and conductivity depend strongly on the bottom anode buffer layer. While cells without anode buffer layer or with MoO3 or CuI anode buffer layer have been probed, we show that CuI allows improving strongly the cells efficiency through an improvement of the morphology and conductivity of the polymer film. This shows that although it is necessary a good band matching at the interface, this is not sufficient, because the templating effect of CuI on the polymer film is primordial for photovoltaic cells improvement.
基金Project supported by the State Key Development Program for Basic Research of China (Grant No 2002CB613401)the National Natural Science Foundation of China (Grant Nos 20474023 and 50673035)+2 种基金the Cooperation Research Project of National Natural Science Foundation of China and Korea Science and Engineering Foundation (Grant No 20611140613)the Research Project of Jilin Province (Grant Nos 20050504 and 20060702)the Research Project of Changchun City (Grant No 06GH03)
文摘The films of two x-shape oligo(thiophene)s, 3, 4-dibithienyl-2, 5-dithienylthiophene (7T) and 2, 5-dibithienyl-3, 4- ditrithienylthiophene (11T), which are prepared by vacuum evaporation, have been investigated as novel electron donor layers in two-layer photovoltaic cells. UV-Vis absorptions show red-shifted and broadened absorptions of the vacuumevaporated films as compared with those of the corresponding solutions and spin-coating films, which is beneficial for photovoltaic properties. X-ray diffraction (XRD) and differential scanning calorimetry (DSC) measurements show that the vacuum-evaporated films are almost amorphous. Two-layer photovoltaic cells have been realized by the thermal evaporation of 7T and llT as donors and N, N′-bis(1-ethylpropyl)-3, 4:9,10-perylene bis(tetracarboxyl diimide) (EP- PTC) as an acceptor. An energy conversion efficiency (ECE) of 0.18% of the cell based on 7T with an irradiation of white light at 100 mw/cm^2 has been demonstrated by the measurements of current (I)- voltage (V) curves of the cells to be higher than the ECE of the reference system based on donor dihexylterthienyl (H3T) that is linear and without α, β linkage.