In this paper,we present the general design methods and parameter measurements of a 1-k W solidstate radio frequency(RF) power amplifier at 2856 MHz,for the soft X-ray free electron laser facility.Three-stage amplific...In this paper,we present the general design methods and parameter measurements of a 1-k W solidstate radio frequency(RF) power amplifier at 2856 MHz,for the soft X-ray free electron laser facility.Three-stage amplification with a 4-way combination is used.An RF switch module is integrated with the solid-state RF power amplifier to convert the continuous wave(CW) signal into pulse signal,with adjustable pulse width.The power gain is measured at 57.7 d B at 60 d Bm output.The RF phase noise,which is measured by the low-level RF system,is\0.015 degree(RMS),while the pulse frontier jitter is\5 ns.展开更多
One new ternary europium gallium sulfide, Eu2Ga2S5, has been synthesized by a facile solid-state route with boron as the reducing reagent. It crystallizes in the orthorhombic space group Pbca, with a = 11.976(1), b ...One new ternary europium gallium sulfide, Eu2Ga2S5, has been synthesized by a facile solid-state route with boron as the reducing reagent. It crystallizes in the orthorhombic space group Pbca, with a = 11.976(1), b = 11.074(1), c = 17.446(1)A^°, V = 1650.6(3)A^°^3, and Z = 8. Its 3-D structure is built by the connection between EuS 7 monocapped trigonal prisms and GaS 4 tetrahedra, and the latter connect with each other to form layer-like slabs. Its optical energy gap is determined to be 2.17 eV, which is also verified by the electronic band structure calculation.展开更多
The electronic structures of cubic structure of ABX3(A=CH3NH3, Cs; B=Sn, Pb; X=Cl, Br, I) are analyzed by den- sity functional theory using the Perdew-Burke-Ernzerhof exchange-correlation functional and using the He...The electronic structures of cubic structure of ABX3(A=CH3NH3, Cs; B=Sn, Pb; X=Cl, Br, I) are analyzed by den- sity functional theory using the Perdew-Burke-Ernzerhof exchange-correlation functional and using the Heyd-Scuseria- Ernzerhof hybrid functional. The valence band maximum (VBM) is found to be made up by an antibonding hybridization of B s and X p states, whereas bands made up by the π antibonding of B p and X p states dominates the conduction band minimum (CBM). The changes of VBM, CBM, and band gap with ion B and X are then systematically summarized. The natural band offsets of ABX3 are partly given. We also found for all the ABX3 perovskite materials in this study, the bandgap increases with an increasing lattice parameter. This phenomenon has good consistency with the experimental results.展开更多
Two new quaternary sulfides, KSmSiS4 (1) and KYbSiS4 (2), have been synthesized by high-temperature solid-state reaction. Single,crystal X-ray diffraction analyses indicate that both compounds crystallize in the s...Two new quaternary sulfides, KSmSiS4 (1) and KYbSiS4 (2), have been synthesized by high-temperature solid-state reaction. Single,crystal X-ray diffraction analyses indicate that both compounds crystallize in the space group P21/m, and the crystal data are as follows: a = 6.426(11), b = 6.582(11), c = 8.602(15)A, β= 107.90(13)°, Z = 2, V= 346.2(10) A^3, Dc = 3.317 g/cm^3, F(000) = 318,μ(MoKα) = 10.334 mm^-1, the final R = 0.0559 and wR = 0.1370 for 1; and α= 6.3244(10), b = 6.5552(10), c = 8.5701(15)A, β= 108.001(13)°, Z = 2, V = 337.91(9) A^3, De= 3.621 g/cm^3, F(000) = 334, μ(MoKα) = 15.737 mm^-1, the final R = 0.0422 and wR = 0.0960 for 2. The KLnSiS4 (Ln = Sm, Yb) structure consists of corrugated ∞^2 [LnSiS4]^- layers which are formed by edge-sharing LnS8 bicapped trigonal prisms and SiS4 tetrahedra. The K^+ cations are located in the cavities defined by S2 anions between the ∞^2[LnSiS4]^- layers. Band-gap analyses show that compounds 1 and 2 are semiconductors with optical band-gaps of 2.40 and 2.34 eV, respectively.展开更多
A complete solid solutions with monophasic zircon-type structure of vanadates of formula GdxBio.95-xVO4:0.05Eu3+ (x = 04).95) are synthesized by combined method of co-precipitation and hydrothermal synthesis. The...A complete solid solutions with monophasic zircon-type structure of vanadates of formula GdxBio.95-xVO4:0.05Eu3+ (x = 04).95) are synthesized by combined method of co-precipitation and hydrothermal synthesis. Their microstructures and morphologies are characterized by X-ray powder diffraction and transmission electronic microscope, and the results show that each of all the samples has a monophasic zircon-type structure. The absorption spectrum of the prepared phosphor shows a blue-shift of the fundamental absorption band edge with increasing the gadolinium content. Under UV-light and visible-light excitation, all the prepared phosphors show the typical luminescence properties of Eu3+ in the zircon-type structure. The emission intensity of GdxBi0.95-xVO4:0.05Eu3+ (x = 0.55) is strongest in all samples under UV-light and visible-light excitations. Finally, the mechanisms of luminescence of Eu3+ in the GdxBi0.95-xVO4:0.05Eu3+ (x = 0-0.95) solid solutions are analyzed and discussed.展开更多
Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. The P-type semiconductor of copper oxide is an important functional material ...Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. The P-type semiconductor of copper oxide is an important functional material used for photovoltaic cells. Cu O is attractive as a selective solar absorber since it has high solar absorbance and a low thermal emittance. The present work describes the synthesis and characterization of semiconducting Cu O nanoparticles via one-step, solid-state reaction in the presence of Polyethylene glycol400 as size controlling agent for the preparation of Cu O nanoparticles at different temperatures. Solid-state mechanochemical processing, which is not only a physical size reduction process in conventional milling but also a chemical reaction, is mechanically activated at the nanoscale during grinding. The present method is a simple and efficient method of preparing nanoparticles with high yield at low cost. The structural and chemical composition of the nanoparticles were analyzed by X-ray diffraction, field emission scanning electron microscopy and energy-dispersive spectrometer, respectively. Optical properties and band gap of Cu O nanoparticles were studied by UV-Vis spectroscopy. These results showed that the band gap energy decreased with increase of annealing temperature, which can be attributed to the improvement in grain size of the samples.展开更多
Electrophysical properties of multicomponent system Zn2TiO4–Zn2ZrO4–ZnFe2O4 were investigated. The electrical conductivity, band gap, dielectric permittivity, and molar polarizability of formed solid solutions –Zn2...Electrophysical properties of multicomponent system Zn2TiO4–Zn2ZrO4–ZnFe2O4 were investigated. The electrical conductivity, band gap, dielectric permittivity, and molar polarizability of formed solid solutions –Zn2-x(TiaZrb)1-xFe2xO4 (x = 0 - 1.0 are defined;Δх = 0.05;a + b = 1;a:b = 1:5;1:4;1:3;1:2;1:1;2:1;3:1;4:1) were defined. Electrophysical properties of samples are in linear dependence on their composition. All the synthesized samples are semiconductors with high electrical resistivity. Was confirmed the formation of two phases of variable composition with a wide homogeneity range.展开更多
A mercury pnictide halide semiconductor Hg19As10Br18(1) has been prepared by the solid-state reaction and structurally characterized by single-crystal X-ray diffraction analysis.Compound 1 crystallizes in triclinic,...A mercury pnictide halide semiconductor Hg19As10Br18(1) has been prepared by the solid-state reaction and structurally characterized by single-crystal X-ray diffraction analysis.Compound 1 crystallizes in triclinic,space group P with a = 11.262(4),b = 11.352(4),c = 12.309(5) ,α = 105.724(2),β = 105.788(4),γ = 109.0780(10)° and V = 1314.3(8) 3.The structure of 1 is composed of parallel perovskite-like layers bridged by the linearly coordinated Br atoms to form a three-dimensional framework.The optical properties were investigated in terms of the diffuse reflectance spectrum.The electronic band structure along with density of states(DOS) calculated by DFT method indicates that compound 1 is a semiconductor with an indirect band gap,and that the optical absorption is mainly originated from the charge transitions from Br-4p and As-4p to the Hg-6s states.展开更多
文摘In this paper,we present the general design methods and parameter measurements of a 1-k W solidstate radio frequency(RF) power amplifier at 2856 MHz,for the soft X-ray free electron laser facility.Three-stage amplification with a 4-way combination is used.An RF switch module is integrated with the solid-state RF power amplifier to convert the continuous wave(CW) signal into pulse signal,with adjustable pulse width.The power gain is measured at 57.7 d B at 60 d Bm output.The RF phase noise,which is measured by the low-level RF system,is\0.015 degree(RMS),while the pulse frontier jitter is\5 ns.
基金supported by Yangzhou Engineering Technology Research Center of Petrochemical New Materials(YZM2015086)Yangzhou Science and Technology Bureau(YZ2016269)
文摘One new ternary europium gallium sulfide, Eu2Ga2S5, has been synthesized by a facile solid-state route with boron as the reducing reagent. It crystallizes in the orthorhombic space group Pbca, with a = 11.976(1), b = 11.074(1), c = 17.446(1)A^°, V = 1650.6(3)A^°^3, and Z = 8. Its 3-D structure is built by the connection between EuS 7 monocapped trigonal prisms and GaS 4 tetrahedra, and the latter connect with each other to form layer-like slabs. Its optical energy gap is determined to be 2.17 eV, which is also verified by the electronic band structure calculation.
基金supported by the National Natural Science Foundation of China(Grant No.11375112)
文摘The electronic structures of cubic structure of ABX3(A=CH3NH3, Cs; B=Sn, Pb; X=Cl, Br, I) are analyzed by den- sity functional theory using the Perdew-Burke-Ernzerhof exchange-correlation functional and using the Heyd-Scuseria- Ernzerhof hybrid functional. The valence band maximum (VBM) is found to be made up by an antibonding hybridization of B s and X p states, whereas bands made up by the π antibonding of B p and X p states dominates the conduction band minimum (CBM). The changes of VBM, CBM, and band gap with ion B and X are then systematically summarized. The natural band offsets of ABX3 are partly given. We also found for all the ABX3 perovskite materials in this study, the bandgap increases with an increasing lattice parameter. This phenomenon has good consistency with the experimental results.
基金supported by the NNSFC (20521101)NSF for Distinguished Young Scientist of China (20425104)+1 种基金NSF of Fujian Province (2007J0173)the Fund of Fujian Key Laboratory of Nanomaterials (2006L2005)
文摘Two new quaternary sulfides, KSmSiS4 (1) and KYbSiS4 (2), have been synthesized by high-temperature solid-state reaction. Single,crystal X-ray diffraction analyses indicate that both compounds crystallize in the space group P21/m, and the crystal data are as follows: a = 6.426(11), b = 6.582(11), c = 8.602(15)A, β= 107.90(13)°, Z = 2, V= 346.2(10) A^3, Dc = 3.317 g/cm^3, F(000) = 318,μ(MoKα) = 10.334 mm^-1, the final R = 0.0559 and wR = 0.1370 for 1; and α= 6.3244(10), b = 6.5552(10), c = 8.5701(15)A, β= 108.001(13)°, Z = 2, V = 337.91(9) A^3, De= 3.621 g/cm^3, F(000) = 334, μ(MoKα) = 15.737 mm^-1, the final R = 0.0422 and wR = 0.0960 for 2. The KLnSiS4 (Ln = Sm, Yb) structure consists of corrugated ∞^2 [LnSiS4]^- layers which are formed by edge-sharing LnS8 bicapped trigonal prisms and SiS4 tetrahedra. The K^+ cations are located in the cavities defined by S2 anions between the ∞^2[LnSiS4]^- layers. Band-gap analyses show that compounds 1 and 2 are semiconductors with optical band-gaps of 2.40 and 2.34 eV, respectively.
基金Project supported by the National Basic Research Program of China(Grant No.2011CB211708)the National Natural Science Foundation of China(Grant Nos.51272097,61265004,and 61307111)the Natural Science Foundation of Yunnan Province,China(Grant No.2012FD009)
文摘A complete solid solutions with monophasic zircon-type structure of vanadates of formula GdxBio.95-xVO4:0.05Eu3+ (x = 04).95) are synthesized by combined method of co-precipitation and hydrothermal synthesis. Their microstructures and morphologies are characterized by X-ray powder diffraction and transmission electronic microscope, and the results show that each of all the samples has a monophasic zircon-type structure. The absorption spectrum of the prepared phosphor shows a blue-shift of the fundamental absorption band edge with increasing the gadolinium content. Under UV-light and visible-light excitation, all the prepared phosphors show the typical luminescence properties of Eu3+ in the zircon-type structure. The emission intensity of GdxBi0.95-xVO4:0.05Eu3+ (x = 0.55) is strongest in all samples under UV-light and visible-light excitations. Finally, the mechanisms of luminescence of Eu3+ in the GdxBi0.95-xVO4:0.05Eu3+ (x = 0-0.95) solid solutions are analyzed and discussed.
文摘Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. The P-type semiconductor of copper oxide is an important functional material used for photovoltaic cells. Cu O is attractive as a selective solar absorber since it has high solar absorbance and a low thermal emittance. The present work describes the synthesis and characterization of semiconducting Cu O nanoparticles via one-step, solid-state reaction in the presence of Polyethylene glycol400 as size controlling agent for the preparation of Cu O nanoparticles at different temperatures. Solid-state mechanochemical processing, which is not only a physical size reduction process in conventional milling but also a chemical reaction, is mechanically activated at the nanoscale during grinding. The present method is a simple and efficient method of preparing nanoparticles with high yield at low cost. The structural and chemical composition of the nanoparticles were analyzed by X-ray diffraction, field emission scanning electron microscopy and energy-dispersive spectrometer, respectively. Optical properties and band gap of Cu O nanoparticles were studied by UV-Vis spectroscopy. These results showed that the band gap energy decreased with increase of annealing temperature, which can be attributed to the improvement in grain size of the samples.
文摘Electrophysical properties of multicomponent system Zn2TiO4–Zn2ZrO4–ZnFe2O4 were investigated. The electrical conductivity, band gap, dielectric permittivity, and molar polarizability of formed solid solutions –Zn2-x(TiaZrb)1-xFe2xO4 (x = 0 - 1.0 are defined;Δх = 0.05;a + b = 1;a:b = 1:5;1:4;1:3;1:2;1:1;2:1;3:1;4:1) were defined. Electrophysical properties of samples are in linear dependence on their composition. All the synthesized samples are semiconductors with high electrical resistivity. Was confirmed the formation of two phases of variable composition with a wide homogeneity range.
基金supported by the NNSFC (20801026)the NSF of Jiangxi Province (2008GQC0036)Foundation of State Key Laboratory of Structural Chemistry (20100015)
文摘A mercury pnictide halide semiconductor Hg19As10Br18(1) has been prepared by the solid-state reaction and structurally characterized by single-crystal X-ray diffraction analysis.Compound 1 crystallizes in triclinic,space group P with a = 11.262(4),b = 11.352(4),c = 12.309(5) ,α = 105.724(2),β = 105.788(4),γ = 109.0780(10)° and V = 1314.3(8) 3.The structure of 1 is composed of parallel perovskite-like layers bridged by the linearly coordinated Br atoms to form a three-dimensional framework.The optical properties were investigated in terms of the diffuse reflectance spectrum.The electronic band structure along with density of states(DOS) calculated by DFT method indicates that compound 1 is a semiconductor with an indirect band gap,and that the optical absorption is mainly originated from the charge transitions from Br-4p and As-4p to the Hg-6s states.