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Recent progresses in the development of tubular segmented-in-series solid oxide fuel cells:Experimental and numerical study 被引量:2
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作者 Shuo Han Tao Wei +6 位作者 Sijia Wang Yanlong Zhu Xingtong Guo Liang He Xiongzhuang Li Qing Huang Daifen Chen 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期427-442,共16页
Solid oxide fuel cells(SOFCs)have attracted a great deal of interest because they have the highest efficiency without using any noble metal as catalysts among all the fuel cell technologies.However,traditional SOFCs s... Solid oxide fuel cells(SOFCs)have attracted a great deal of interest because they have the highest efficiency without using any noble metal as catalysts among all the fuel cell technologies.However,traditional SOFCs suffer from having a higher volume,current leakage,complex connections,and difficulty in gas sealing.To solve these problems,Rolls-Royce has fabricated a simple design by stacking cells in series on an insulating porous support,resulting in the tubular segmented-in-series solid oxide fuel cells(SIS-SOFCs),which achieved higher output voltage.This work systematically reviews recent advances in the structures,preparation methods,perform-ances,and stability of tubular SIS-SOFCs in experimental and numerical studies.Finally,the challenges and future development of tubular SIS-SOFCs are also discussed.The findings of this work can help guide the direction and inspire innovation of future development in this field. 展开更多
关键词 solid oxide fuel cell SEGMENTED-IN-SERIES TUBULAR experimental study numerical study
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Boosting oxygen reduction activity and CO_(2) resistance on bismuth ferrite-based perovskite cathode for low-temperature solid oxide fuel cells below 600℃ 被引量:1
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作者 Juntao Gao Zhiyun Wei +5 位作者 Mengke Yuan Zhe Wang Zhe Lü Qiang Li Lingling Xu Bo Wei 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期600-609,I0013,共11页
Developing efficient and stable cathodes for low-temperature solid oxide fuel cells(LT-SOFCs) is of great importance for the practical commercialization.Herein,we propose a series of Sm-modified Bi_(0.7-x)Sm_xSr_(0.3)... Developing efficient and stable cathodes for low-temperature solid oxide fuel cells(LT-SOFCs) is of great importance for the practical commercialization.Herein,we propose a series of Sm-modified Bi_(0.7-x)Sm_xSr_(0.3)FeO_(3-δ) perovskites as highly-active catalysts for LT-SOFCs.Sm doping can significantly enhance the electrocata lytic activity and chemical stability of cathode.At 600℃,Bi_(0.675)Sm_(0.025)Sr_(0.3)FeO_(3-δ)(BSSF25) cathode has been found to be the optimum composition with a polarization resistance of 0.098 Ω cm^2,which is only around 22.8% of Bi_(0.7)Sr_(0.3)FeO_(3-δ)(BSF).A full cell utilizing BSSF25 displays an exceptional output density of 790 mW cm^(-2),which can operate continuously over100 h without obvious degradation.The remarkable electrochemical performance observed can be attributed to the improved O_(2) transport kinetics,superior surface oxygen adsorption capacity,as well as O_(2)p band centers in close proximity to the Fermi level.Moreover,larger average bonding energy(ABE) and the presence of highly acidic Bi,Sm,and Fe ions restrict the adsorption of CO_(2) on the cathode surface,resulting in excellent CO_(2) resistivity.This work provides valuable guidance for systematic design of efficient and durable catalysts for LT-SOFCs. 展开更多
关键词 Low-temperature solid oxide fuel cell Perovskite cathode DFT calculations CO_(2) tolerance
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Investigation and optimization of high-valent Ta-doped SrFeO_(3-δ)as air electrode for intermediate-temperature solid oxide fuel cells
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作者 Shanshan Jiang Hao Qiu +7 位作者 Shaohua Xu Xiaomin Xu Jingjing Jiang Beibei Xiao Paulo Sérgio Barros Juliao) Chao Su Daifen Chen Wei Zhou 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第9期2102-2109,共8页
To explore highly active and thermomechanical stable air electrodes for intermediate-temperature solid oxide fuel cells(ITSOFCs),10mol%Ta5+doped in the B site of strontium ferrite perovskite oxide(SrTa_(0.1)Fe_(0.9)O_... To explore highly active and thermomechanical stable air electrodes for intermediate-temperature solid oxide fuel cells(ITSOFCs),10mol%Ta5+doped in the B site of strontium ferrite perovskite oxide(SrTa_(0.1)Fe_(0.9)O_(3-δ),STF)is investigated and optimized.The effects of Ta^(5+)doping on structure,transition metal reduction,oxygen nonstoichiometry,thermal expansion,and electrical performance are evaluated systematically.Via 10mol%Ta^(5+)doping,the thermal expansion coefficient(TEC)decreased from 34.1×10^(-6)(SrFeO_(3-δ))to 14.6×10^(-6) K^(-1)(STF),which is near the TEC of electrolyte(13.3×10^(-6) K^(-1) for Sm_(0.2)Ce_(0.8)O_(1.9),SDC),indicates excellent thermomechanical compatibility.At 550-750℃,STF shows superior oxygen vacancy concentrations(0.262 to 0.331),which is critical in the oxygen-reduction reaction(ORR).Oxygen temperature-programmed desorption(O_(2)-TPD)indicated the thermal reduction onset temperature of iron ion is around 420℃,which matched well with the inflection points on the thermos-gravimetric analysis and electrical conductivity curves.At 600℃,the STF electrode shows area-specific resistance(ASR)of 0.152Ω·cm^(2) and peak power density(PPD)of 749 mW·cm^(-2).ORR activity of STF was further improved by introducing 30wt%Sm_(0.2)Ce_(0.8)O_(1.9)(SDC)powder,STF+SDC composite cathode achieving outstanding ASR value of 0.115Ω·cm2 at 600℃,even comparable with benchmark cobalt-containing cathode,Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3-δ)(BSCF).Distribution of relaxation time(DRT)analysis revealed that the oxygen surface exchange and bulk diffusion were improved by forming a composite cathode.At 650℃,STF+SDC composite cathode achieving an outstanding PPD of 1117 mW·cm^(-2).The excellent results suggest that STF and STF+SDC are promising air electrodes for IT-SOFCs. 展开更多
关键词 strontium ferrite-based perovskite Ta doping composite cathode intermediate-temperature solid oxide fuel cells
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Lattice Boltzmann simulation study of anode degradation in solid oxide fuel cells during the initial aging process
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作者 Shixue Liu Zhijing Liu +1 位作者 Shuxing Zhang Hao Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第2期405-411,共7页
For present solid oxide fuel cells(SOFCs),rapid performance degradation is observed in the initial aging process,and the dis-cussion of the degradation mechanism necessitates quantitative analysis.Herein,focused ion b... For present solid oxide fuel cells(SOFCs),rapid performance degradation is observed in the initial aging process,and the dis-cussion of the degradation mechanism necessitates quantitative analysis.Herein,focused ion beam-scanning electron microscopy was em-ployed to characterize and reconstruct the ceramic microstructures of SOFC anodes.The lattice Boltzmann method(LBM)simulation of multiphysical and electrochemical processes in the reconstructed models was performed.Two samples collected from industrial-size cells were characterized,including a reduced reference cell and a cell with an initial aging process.Statistical parameters of the reconstructed microstructures revealed a significant decrease in the active triple-phase boundary and Ni connectivity in the aged cell compared with the reference cell.The LBM simulation revealed that activity degradation is dominant compared with microstructural degradation during the initial aging process,and the electrochemical reactions spread to the support layer in the aged cell.The microstructural and activity de-gradations are attributed to Ni migration and coarsening. 展开更多
关键词 solid oxide fuel cell anode degradation focused ion beam-scanning electron microscopy lattice Boltzmann method
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From concept to commercialization:A review of tubular solid oxide fuel cell technology 被引量:1
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作者 Ruyan Chen Yuan Gao +4 位作者 Jiutao Gao Huiyu Zhang Martin Motola Muhammad Bilal Hanif Cheng-Xin Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期79-109,I0003,共32页
The reduced sealing difficulty of tubular solid oxide fuel cells(SOFCs)makes the stacking of tubular cell groups relatively easy,and the thermal stress constraints during stack operation are smaller,which helps the st... The reduced sealing difficulty of tubular solid oxide fuel cells(SOFCs)makes the stacking of tubular cell groups relatively easy,and the thermal stress constraints during stack operation are smaller,which helps the stack to operate stably for a long time.The special design of tubular SOFC structures can completely solve the problem of high-temperature sealing,especially in the design of multiple single-cell series integrated into one tube,where each cell tube is equivalent to a small electric stack,with unique characteristics of high voltage and low current output,which can significantly reduce the ohmic polarization loss of tubular cells.This paper provides an overview of typical tubular SOFC structural designs both domestically and internationally.Based on the geometric structure of tubular SOFCs,they can be divided into bamboo tubes,bamboo flat tubes,single-section tubes,and single-section flat tube structures.Meanwhile,this article provides an overview of commonly used materials and preparation methods for tubular SOFCs,including commonly used materials and preparation methods for support and functional layers,as well as a comparison of commonly used preparation methods for microtubule SOFCs,It introduced the three most important parts of building a fuel cell stack:manifold,current collector,and ceramic adhesive,and also provided a detailed introduction to the power generation systems of different tubular SOFCs,Finally,the development prospects of tubular SOFCs were discussed. 展开更多
关键词 Tubular solid oxide fuel cell Support material Geometric structure Preparation methods STACK
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Effects of operating conditions on the performance degradation and anode microstructure evolution of anode-supported solid oxide fuel cells 被引量:4
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作者 Xin Yang Zhihong Du +5 位作者 Qian Zhang Zewei Lyu Shixue Liu Zhijing Liu Minfang Han Hailei Zhao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第6期1181-1189,共9页
Performance degradation shortens the life of solid oxide fuel cells in practical applications.Revealing the degradation mechanism is crucial for the continuous improvement of cell durability.In this work,the effects o... Performance degradation shortens the life of solid oxide fuel cells in practical applications.Revealing the degradation mechanism is crucial for the continuous improvement of cell durability.In this work,the effects of cell operating conditions on the terminal voltage and anode microstructure of a Ni-yttria-stabilized zirconia anode-supported single cell were investigated.The microstructure of the anode active area near the electrolyte was characterized by laser optical microscopy and focused ion beam-scanning electron microscopy.Ni depletion at the anode/electrolyte interface region was observed after 100 h discharge tests.In addition,the long-term stability of the single cell was evaluated at 700℃for 3000 h.After an initial decline,the anode-supported single cell exhibits good durability with a voltage decay rate of 0.72%/kh and an electrode polarization resistance decay rate of 0.17%/kh.The main performance loss of the cell originates from the initial degradation. 展开更多
关键词 solid oxide fuel cell Ni-YSZ anode focused ion beam Ni migration electrochemical performance
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Recent advances and influencing parameters in developing electrode materials for symmetrical solid oxide fuel cells 被引量:2
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作者 Wan Nor Anasuhah Wan Yusoff Nurul Akidah Baharuddin +3 位作者 Mahendra Rao Somalu Andanastuti Muchtar Nigel P.Brandon Huiqing Fan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第10期1933-1956,共24页
This article delivers a robust overview of potential electrode materials for use in symmetrical solid oxide fuel cells(S-SOFCs),a relatively new SOFC technology.To this end,this article provides a comprehensive review... This article delivers a robust overview of potential electrode materials for use in symmetrical solid oxide fuel cells(S-SOFCs),a relatively new SOFC technology.To this end,this article provides a comprehensive review of recent advances and progress in electrode materials for S-SOFC,discussing both the selection of materials and the challenges that come with making that choice.This article discussed the relevant factors involved in developing electrodes with nano/microstructure.Nanocomposites,e.g.,non-cobalt and lithiated materials,are only a few of the electrode types now being researched.Furthermore,the phase structure and microstructure of the produced materials are heavily influenced by the synthesis procedure.Insights into the possibilities and difficulties of the material are discussed.To achieve the desired microstructural features,this article focuses on a synthesis technique that is either the most recent or a better iteration of an existing process.The portion of this analysis that addresses the risks associated with manufacturing and the challenges posed by materials when fabricating S-SOFCs is the most critical.This article also provides important and useful recommendations for the strategic design of electrode materials researchers. 展开更多
关键词 nano composites ELECTRODE microstructure tailoring OXIDATION symmetrical solid oxide fuel cell
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Fabrication of Gd_(2)O_(3)-doped CeO_(2)thin films through DC reactive sputtering and their application in solid oxide fuel cells 被引量:3
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作者 Fuyuan Liang Jiaran Yang +1 位作者 Haiqing Wang Junwei Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第6期1190-1197,共8页
Physical vapor deposition(PVD)can be used to produce high-quality Gd_(2)O_(3)-doped CeO2(GDC)films.Among various PVD methods,reactive sputtering provides unique benefits,such as high deposition rates and easy upscalin... Physical vapor deposition(PVD)can be used to produce high-quality Gd_(2)O_(3)-doped CeO2(GDC)films.Among various PVD methods,reactive sputtering provides unique benefits,such as high deposition rates and easy upscaling for industrial applications.GDC thin films were successfully fabricated through reactive sputtering using a Gd_(0.2)Ce_(0.8)(at%)metallic target,and their application in solid oxide fuel cells,such as buffer layers between yttria-stabilized zirconia(YSZ)/La0.6Sr0.4Co0.2Fe0.8O_(3−δ)and as sublayers in the steel/coating system,was evaluated.First,the direct current(DC)reactive-sputtering behavior of the GdCe metallic target was determined.Then,the GDC films were deposited on NiO-YSZ/YSZ half-cells to investigate the influence of oxygen flow rate on the quality of annealed GDC films.The results demonstrated that reactive sputtering can be used to prepare thin and dense GDC buffer layers without high-temperature sintering.Furthermore,the cells with a sputtered GDC buffer layer showed better electrochemical performance than those with a screen-printed GDC buffer layer.In addition,the insertion of a GDC sublayer between the SUS441 interconnects and the Mn-Co spinel coatings contributed to the reduction of the oxidation rate for SUS441 at operating temperatures,according to the area-specific resistance tests. 展开更多
关键词 solid oxide fuel cell physical vapor deposition Gd2O3-doped CeO_(2) metallic interconnects electrical conductivity
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Low molecular weight alkane-fed solid oxide fuel cells for power and chemicals cogeneration
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作者 Ermete Antolini 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第5期711-735,I0015,共26页
This paper presents a review of low molecular weight alkane-fed solid oxide fuel cells(SOFCs),which,unlikely the conventional use of SOFCs for only power production,are utilized to cogenerate produce useful chemicals ... This paper presents a review of low molecular weight alkane-fed solid oxide fuel cells(SOFCs),which,unlikely the conventional use of SOFCs for only power production,are utilized to cogenerate produce useful chemicals at the same time.The cogeneration processes in SOFC have been classified according to the different types of fuel.C_(2)and C_(3)alkenes and synthesis gas are the main cogenerated chemicals together with electricity.The chemicals and energy cogeneration in a fuel cell reactor seems to be an effective alternative to conventional reactors for only chemicals production and conventional fuel cells for only power production.Although,the use of SOFCs for chemicals and energy cogeneration has proved successful in the industrial setting,the development of new catalysts aimed at obtaining the desired chemicals together with the production of a high amount of energy,and optimizing SOFC operation conditions is still a challenge to enhance system performance and make commercial applications workable. 展开更多
关键词 solid oxide fuel cells ALKANE ALKENE SYNGAS COGENERATION
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Interface engineering of an electrospun nanofiber-based composite cathode for intermediate-temperature solid oxide fuel cells
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作者 Seo Ju Kim Deokyoon Woo +3 位作者 Donguk Kim Tae Kyeong Lee Jaeyeob Lee Wonyoung Lee 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2023年第1期345-353,共9页
Sluggish oxygen reduction reaction(ORR)kinetics are a major obstacle to developing intermediate-temperature solid-oxide fuel cells(IT-SOFCs).In particular,engineering the anion defect concentration at an interface bet... Sluggish oxygen reduction reaction(ORR)kinetics are a major obstacle to developing intermediate-temperature solid-oxide fuel cells(IT-SOFCs).In particular,engineering the anion defect concentration at an interface between the cathode and electrolyte is important for facilitating ORR kinetics and hence improving the electrochemical performance.We developed the yttria-stabilized zirconia(YSZ)nanofiber(NF)-based composite cathode,where the oxygen vacancy concentration is controlled by varying the dopant cation(Y2O3)ratio in the YSZ NFs.The composite cathode with the optimized oxygen vacancy concentration exhibits maximum power densities of 2.66 and 1.51 W cm^(−2)at 700 and 600℃,respectively,with excellent thermal stability at 700℃ over 500 h under 1.0 A cm^(−2).Electrochemical impedance spectroscopy and distribution of relaxation time analysis revealed that the high oxygen vacancy concentration in the NF-based scaffold facilitates the charge transfer and incorporation reaction occurred at the interfaces between the cathode and electrolyte.Our results demonstrate the high feasibility and potential of interface engineering for achieving IT-SOFCs with higher performance and stability. 展开更多
关键词 solid oxide fuel cells NANOFIBER INFILTRATION oxygen reduction reactions oxygen vacancy
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Plasma-Sprayed Coating of an Apatite-Type Lanthanum Silicate Electrolyte for Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFCs)
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作者 陈军 黄建军 +4 位作者 李信军 刘英 齐冰 江石寿 王喜省 《Plasma Science and Technology》 SCIE EI CAS CSCD 2013年第7期673-676,共4页
Apatite-type lanthanum silicate was successfully synthesized via a solid state re- action protocol at 1400~C in a vacuum for 4 hours. The powder was synthesized faster and at a lower reaction temperature than by conve... Apatite-type lanthanum silicate was successfully synthesized via a solid state re- action protocol at 1400~C in a vacuum for 4 hours. The powder was synthesized faster and at a lower reaction temperature than by conventional solid state reaction methods. The resulting powder was used in the fabrication of a coating deposited by atmospheric plasma spray (APS) technology. The microstructure of the coating was analyzed by X-ray diffraction and scanning electron microscopy. Heat treatment was found to fully crystallize the coating, increasing its den-sity. The ionic conductivity of the apatite coating was 0.39 (0.054) mS/cm at 850 (700) ℃, and its activation energy was 0.67 eV. 展开更多
关键词 lanthanum silicate solid oxide fuel cell atmospheric plasma spraying IONICCONDUCTIVITY activation energy
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Temperature Gradient Analyses of a Tubular Solid Oxide Fuel Cell Fueled by Methanol
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作者 Qidong Xu Meiting Guo +5 位作者 Lingchao Xia Zheng Li Qijiao He Dongqi Zhao Keqing Zheng Meng Ni 《Transactions of Tianjin University》 EI CAS 2023年第1期14-30,共17页
Thermal management in solid oxide fuel cells(SOFC)is a critical issue due to non-uniform electrochemical reactions and convective fl ows within the cells.Therefore,a 2D mathematical model is established herein to inve... Thermal management in solid oxide fuel cells(SOFC)is a critical issue due to non-uniform electrochemical reactions and convective fl ows within the cells.Therefore,a 2D mathematical model is established herein to investigate the thermal responses of a tubular methanol-fueled SOFC.Results show that unlike the low-temperature condition of 873 K,where the peak temperature gradient occurs at the cell center,it appears near the fuel inlet at 1073 K because of the rapid temperature rise induced by the elevated current density.Despite the large heat convection capacity,excessive air could not eff ectively eliminate the harmful temperature gradient caused by the large current density.Thus,optimal control of the current density by properly selecting the operating potential could generate a local thermal neutral state.Interestingly,the maximum axial temperature gradient could be reduced by about 18%at 973 K and 20%at 1073 K when the air with a 5 K higher temperature is supplied.Additionally,despite the higher electrochemical performance observed,the cell with a counter-fl ow arrange-ment featured by a larger hot area and higher maximum temperature gradients is not preferable for a ceramic SOFC system considering thermal durability.Overall,this study could provide insightful thermal information for the operating condition selection,structure design,and stability assessment of realistic SOFCs combined with their internal reforming process. 展开更多
关键词 solid oxide fuel cell MODELING Methanol fuel Temperature gradient Internal reforming
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Ni doped La_(0.6)Sr_(0.4)FeO_(3-δ) symmetrical electrode for solid oxide fuel cells 被引量:1
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作者 马朝晖 孙春文 +3 位作者 马超 吴昊 占忠亮 陈立泉 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2016年第8期1347-1353,共7页
The conventional Ni cermet anode suffers from severe carbon deposition and sulfur poisoning when fossil fuels are used. Alternative anode materials are desired for high performance hydrocarbon fuel solid oxide fuel ce... The conventional Ni cermet anode suffers from severe carbon deposition and sulfur poisoning when fossil fuels are used. Alternative anode materials are desired for high performance hydrocarbon fuel solid oxide fuel cells (SOFCs). We report the rational design of a very active Ni doped La0.6Sr0.4FeO3‐δ(LSFN) electrode for hydrocarbon fuel SOFCs. Homogeneously dispersed Ni‐Fe alloy nanoparticles were in situ extruded onto the surface of the LSFN particles during the operation of the cell. Sym‐metric SOFC single cells were prepared by impregnating a LSFN precursor solution onto a YSZ (yt‐tria stabilized zirconia) monolithic cell with a subsequent heat treatment. The open circuit voltage of the LSFN symmetric cell reached 1.18 and 1.0 V in humidified C3H8 and CH4 at 750??, respective‐ly. The peak power densities of the cells were 400 and 230 mW/cm2 in humidified C3H8 and CH4, respectively. The electrode showed good stability in long term testing, which revealed LSFN has good catalytic activity for hydrocarbon fuel oxidation. 展开更多
关键词 solid oxide fuel cells Ni dopedLa0.6Sr0.4FeO3-δ Symmetrical electrode Hydrocarbon fuels
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Samaria-doped Ceria Modified Ni/YSZ Anode for Direct Methane Fuel in Tubular Solid Oxide Fuel Cells by Impregnation Method 被引量:1
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作者 张龙山 高建峰 +1 位作者 田瑞芬 夏长荣 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2009年第4期429-434,448,共7页
A porous NiO/yttria-stabilized zirconia was prepared by gel casting technique. anode substrate for tubular solid oxide fuel cells Nano-scale samaria-doped ceria (SDC) particles were formed onto the anode substrate t... A porous NiO/yttria-stabilized zirconia was prepared by gel casting technique. anode substrate for tubular solid oxide fuel cells Nano-scale samaria-doped ceria (SDC) particles were formed onto the anode substrate to modify the anode microstructure by the impregnation of solution of Sm(NO3)3 and Ce(NO3)3. Electrochemical impedance spectroscopy, current-voltage and current-powder curves of the cells were measured using an electrochemical workstation. Scanning electron microcopy was used to observe the microstructure. The results indicate that the stability of the performance of the cell operated on humidified methane can be significantly improved by incorporating the nano-structured SDC particles, compared with the unmodified cell. This verifies that the coated SDC electrodes are very effective in suppressing catalytic carbon formation by blocking methane from approaching the Ni, which is catalytically active towards methane pyrolysis. In addition, it was found that a small amount of deposited carbon is beneficial to the performance of the anode. The cell showed a peak power density of 225 mW/cm^2 when it was fed with H2 fuel at 700 ℃, but the power density increased to 400 mW/cm^2 when the fuel was switched from hydrogen to methane at the same flow rate. Methane conversion achieved about 90%, measured by gas chromatogram with a 10.0 mL/min flow rate of fuel at 700 ℃. Although the carbon deposition was not suppressed absolutely, some deposited carbon was beneficial for performance improvement. 展开更多
关键词 Tubular solid oxide fuel cell Gel casting IMPREGNATION METHANE
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Progress and challenges of carbon-fueled solid oxide fuel cells anode 被引量:9
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作者 Minjian Ma Xiaoxia Yang +3 位作者 Jinshuo Qiao Wang Sun Zhenhua Wang Kening Sun 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第5期209-222,共14页
Carbon-fueled solid oxide fuel cells(CF-SOFCs)can electrochemically convert the chemical energy in carbon into electricity,which demonstrate both superior electrical efficiency and fuel utilisation compared to all oth... Carbon-fueled solid oxide fuel cells(CF-SOFCs)can electrochemically convert the chemical energy in carbon into electricity,which demonstrate both superior electrical efficiency and fuel utilisation compared to all other types of fuel cells.However,using solid carbon as the fuel of SOFCs also faces some challenges,the fluid mobility and reactive activity of carbon-based fuels are much lower than those of gaseous fuels.Therefore,the anode reaction kinetics plays a crucial role in determining the electrochemical performance of CF-SOFCs.Herein,the progress of various anodes in CF-SOFCs is reviewed from the perspective of material compositions,electrochemical performance and microstructures.Challenges faced in developing high performance anodes for CF-SOFCs are also discussed. 展开更多
关键词 CARBON Anodes solid oxide fuel cells Energy conversion Reaction processes
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The Effect of Fabrication Conditions for GDC Buffer Layer on Electrochemical Performance of Solid Oxide Fuel Cells 被引量:2
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作者 Jung-Hoon Song Myung Geun Jung +1 位作者 Hye Won Park Hyung-Tae Lim 《Nano-Micro Letters》 SCIE EI CAS 2013年第3期151-158,共8页
A Gd-doped ceria(GDC) buffer layer is required between a conventional yttria-stabilized zirconia(YSZ) electrolyte and a La-Sr-Co-Fe-O3(LSCF) cathode to prevent their chemical reaction. In this study,the effect o... A Gd-doped ceria(GDC) buffer layer is required between a conventional yttria-stabilized zirconia(YSZ) electrolyte and a La-Sr-Co-Fe-O3(LSCF) cathode to prevent their chemical reaction. In this study,the effect of varying the conditions for fabricating the GDC buffer layer, such as sintering temperature and amount of sintering aid, on the solid oxide fuel cell(SOFC) performance was investigated. A finer GDC powder(i.e., ultra-high surface area), a higher sintering temperature(1290℃), and a larger amount of sintering aid(12%) resulted in improved densification of the buffer layer; however, the electrochemical performance of an anode-supported cell containing this GDC buffer layer was poor. These conflicting results are attributed to the formation of(Zr, Ce)O2 and/or excess cobalt grain boundaries(GBs) at higher sintering temperatures with a large amount of sintering aid(i.e., cobalt oxide). A cell comprising of a cobalt-free GDC buffer layer, which was fabricated using a low-temperature process, had lower cell resistance and higher stability. The results indicate that electrochemical performance and stability of SOFCs strongly depend on fabrication conditions for the GDC buffer layer. 展开更多
关键词 solid oxide fuel cell(sofc) Gd-doped ceria Sintering aid Sol-gel spin coating
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Solid oxide fuel cells in combination with biomass gasification for electric power generation 被引量:6
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作者 Huangang Shi Qianjun Li +2 位作者 Wenyi Tan Hao Qiu Chao Su 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2020年第4期1156-1161,共6页
Biomass,a source of renewable energy,represents an effective substitute to fossil fuels.Gasification is a process that organics are thermochemically converted into valuable gaseous products(e.g.biogas).In this work,th... Biomass,a source of renewable energy,represents an effective substitute to fossil fuels.Gasification is a process that organics are thermochemically converted into valuable gaseous products(e.g.biogas).In this work,the catalytic test demonstrated that the biogas produced from biomass gasification mainly consists of H2,CH4,CO,and CO2,which were then be used as the fuel for solid oxide fuel cell(SOFC).Planar SOFCs were fabricated and adopted.The steam reforming of biogas was carried out at the anode of a SOFC to obtain a hydrogen-rich fuel.The performance of the SOFCs operating on generated biogas was investigated by I-V polarization and electrochemical impedance spectra characterizations.An excellent cell performance was obtained,for example,the peak power density of the SOFC reached 1391 mW·cm-2 at 750℃when the generated biogas was used as the fuel.Furthermore,the SOFC fuelled by simulated biogas delivered a very stable operation. 展开更多
关键词 Biomass gasification BIOGAS solid oxide fuel cell Steam reforming
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Sealing Glass of Barium-Calcium-Aluminosilicate System for Solid Oxide Fuel Cells 被引量:2
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作者 朴金花 孙克宁 +2 位作者 张乃庆 陈新冰 周德瑞 《Journal of Rare Earths》 SCIE EI CAS CSCD 2007年第4期434-438,共5页
Glass-ceramic materials were developed as a sealant in the solid oxide fuel cell (SOFC) in the temperature range of 800 -850 ℃. The glass materials were based on the glass and glass-ceramic in the BaO-CaO-Al2O3-SiO... Glass-ceramic materials were developed as a sealant in the solid oxide fuel cell (SOFC) in the temperature range of 800 -850 ℃. The glass materials were based on the glass and glass-ceramic in the BaO-CaO-Al2O3-SiO2-La2O3-B2O3 system. The thermal expansion coefficient (TEC) decreased with lower Ba^2+ content and higher Ca^2+ content, but the glass transition temperature and crystallization temperature increased greatly with an increase in Ca^2+ content and a decrease in Ba^2+ content, when the other components in the sealant were invariable. The TEC of the sealant with Ba^2+ content of 25.4% was 10.8 × 10^-6 K^- 1(temperature range from 25 to 850℃), and its softening temperature was 950 ℃. The TEC of the sealant accorded well with that of La0.9Sr0.1Ga0.5Mg0.2o3- 6(LSGM) with a mismatch of only 3%. The sealant had superior stability and compatibility with the LSGM electrolyte during the process of operation in SOFC. The weight loss of the sealant with Ba^2+ content of 25.4% was approfimately zero after heat-treated at 800℃ for 500 h in H2 and O2 atmosphere, respectively. 展开更多
关键词 solid oxide fuel cell GLASS-CERAMIC SEALANT compatibility rare earths
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Electrochemical performance and stability of Sr-doped LaMnO_(3)-infiltrated yttria stabilized zirconia oxygen electrode for reversible solid oxide fuel cells 被引量:2
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作者 Hui Fan Minfang Han 《International Journal of Coal Science & Technology》 EI CAS 2014年第1期56-61,共6页
Porous Sr-doped lanthanum manganite–yttria stabilized zirconia(LSM–YSZ)oxygen electrode is prepared by an infiltration process for a reversible solid oxide fuel cell(RSOFC).X-ray diffraction and SEM analysis display... Porous Sr-doped lanthanum manganite–yttria stabilized zirconia(LSM–YSZ)oxygen electrode is prepared by an infiltration process for a reversible solid oxide fuel cell(RSOFC).X-ray diffraction and SEM analysis display that perovskite phase LSM submicro particles are evenly distributed in the porous YSZ matrix.Polarization curves and electrochemical impedance spectra are conducted for the RSOFC at 800 and 850C under both SOFC and SOEC modes.At 850℃,the single cell has the maximum power density of~726 mW/cm^(2)under SOFC mode,and electrolysis voltage of 1.35 V at 1 A/cm^(2)under SOEC mode.Fuel cell/water electrolysis cycle shows the cell has good performance stability during 6 cycles,which exhibits the LSM–YSZ oxygen electrode has high electrochemical performance and good stability.The results suggest that netw ork-like LSM–YSZ electrode made by infiltration process could be a promising oxygen electrode for high temperature RSOFCs. 展开更多
关键词 Reversible solid oxide fuel cell solid oxide electrolysis cell INFILTRATION Strontium-doped lanthanum manganite
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Electromotive Force for Solid Oxide Fuel Cells Using Biomass Produced Gas as Fuel 被引量:2
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作者 Wei Zhu Yan-hong Yin +2 位作者 Cen Gao Chang-rong Xia Guang-yao Meng 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2006年第4期325-328,共4页
The electromotive force (e.m.f.) of solid oxide fuel cells using biomass produced gas (BPG) as the fuels is calculated at 700-1,200 K using an in-house computer program, based on thermodynamic equilibrium analysis... The electromotive force (e.m.f.) of solid oxide fuel cells using biomass produced gas (BPG) as the fuels is calculated at 700-1,200 K using an in-house computer program, based on thermodynamic equilibrium analysis. Tour program also predicts the concentration of oxygen in the fuel chamber as well as the concentration of equilibrium species such as H2, CO, CO2 and CH4. Compared with using hydrogen as a fuel, the e.m.f. for cells using BPG as the fuels is relative low and strongly influenced by carbon deposition. To remove carbon deposition, the optimum amount of H2O to add is determined at various operating temperatures. Further the e.m.f, for cells based on yttria stabilized zirconia and doped ceria as electrolytes are compared. The study reveals that when using BPG as fuel, the depression of e.m.f, for a SOFC using doped ceria as electrolyte is relatively small when compared with that using Yttria stabilized zirconia. 展开更多
关键词 Biomass produced gas Electromotive force solid oxide fuel cells Thermodynamic equilibrium
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