A Novel Technology for Synthesizing Pentasil Zeolites Based on Solid-Solid Mass Transformation Mechanism

A novel technology of preparing zeolites based on solid-solid mass transformation mechanism is developed for the first time. By employing this technology, three different types of highly crystallized pentasil zeolites, ZSM-35 (FER-type), Silicalite-1(MFI-type) and Mordenite(MOR-type), are successfully synthesized in the solid system. In terms of commercial production, the technology-could simplify synthesis procedure and make the continuous production of zeolites possible, so as to improve the productivity. Additionally, it is environmentally friendly because the crystallization occurs in solid phase where there exists no pollution caused by waste liquid. Therefore, this technique provides us with a new industrial process for the clean and continuous production of zeolites. The characteristics in synthesis chemistry and the crystallization mechanism involved in the technology are also discussed.

Transformation of microstructure and phase of disodium guanosine 5′-monophosphate: Thermodynamic perspectives

Microstructure and phase transformation of disodium guanosine 5′-monophosphate(5′-GMPNa_2) are extremely important for controlling the process and understanding the mechanism of crystallization. In this work, the thermodynamic properties of polymorphous 5′-GMPNa_2 especially the solubility were studied, the solubility results show that 5′-GMPNa_2 is more soluble in ethanol–water(E–W) than in isopropanol–water(I–W). The amorphous form of 5′-GMPNa_2 is more soluble than the crystalline form at the same mole fraction and temperature. Meanwhile, the crystalline forms and morphologies of the residual solids were characterized by PXRD and SEM. The results indicate that solid forms of 5′-GMPNa_2 transformed spontaneously from amorphous to crystalline when the ethanol proportion is ≥20%. In addition, increasing the pH facilitates the dissolution of 5′-GMPNa_2 and helps to maintain the crystalline form. The associated Gibbs free energy values were calculated to verify the trend of transformation from amorphous to crystalline 5′-GMPNa_2. These results should help to guide the industrial crystallization process and to obtain the crystalline form of 5′-GMPNa_2.

Development of a Medium Voltage, High Power, High Frequency Four-Port Solid State Transformer

The power and voltage levels of renewable energy resources is growing with the evolution of the power electronics and switching module technologies.For that,the need for the development of a compact and highly efficient solid-state transformer is becoming a critical task in-order to integrate the current AC grid with the new renewable energy systems.The objective of this paper is to present the design,implementation,and testing of a compact multi-port solid-state transformer for microgrid integration applications.The proposed system has a four-port transformer and four converters connected to the ports.The transformer has four windings integrated on a single common core.Thus,it can integrate different renewable energy resources and energy storage systems.Each port has a rated power of 25 kW,and the switching frequency is pushed to 50 k Hz.The ports are chosen to represent a realistic industrial microgrid model consisting of grid,energy storage system,photovoltaic system,and load.The grid port is designed to operate at 4.16 k VAC corresponding to 7.2 kV DC bus voltage,while the other three ports operate at 500 VDC.Moreover,the grid,energy storage and photovoltaic ports are active ports with dual active bridge topologies,while the load port is a passive port with full bridge rectifier one.The proposed design is first validated with simulation results,and then the proposed transformer is implemented and tested.Experimental results show that the designed system is suitable for 4.16 k VAC medium voltage grid integration.

Modeling and Control of the Modular Multilevel Converter (MMC) based Solid State Transformer (SST) with Magnetic Integration

Solid state transformer(SST)can provide more advanced functionalities compared with conventional transformer,and has great potential in smart grid application.Recently,the SST with medium frequency(MF)isolation link and magnetic integration feature has been proposed,which can reduce the system volume and thus increase the power density.However,the magnetic integration also introduces strong coupling between the line frequency(LF)and MF variables,which poses a great challenge on modeling and control issues.This paper proposes a modeling and control method for an SST with magnetic integration and mixed-frequency modulation.A mathematical model based on dual d-q references is deduced,and then a cascaded control system is designed according to the model.Parameters of the controller for the variables at one frequency are properly designed to avoid disturbance from the variables at the other frequency.The simulation and experimental results show good decoupling effect and satisfactory dynamics performance of the proposed control system.

Sliding mode control of solid state transformer using a three-level hysteresis function

The solid state transformer(SST) can be viewed as an energy router in energy internet. This work presents sliding mode control(SMC) to improve dynamic state and steady state performance of a three-stage(rectifier stage, isolated stage and inverter stage) SST for energy internet. SMC with three-level hysteresis sliding functions is presented to control the input current of rectifier stage and output voltage of inverter stage to improve the robustness under external disturbance and parametric uncertainties and reduce the switching frequency. A modified feedback linearization technique using isolated stage simplified model is presented to achieve satisfactory regulation of output voltage of the isolated stage. The system is tested for steady state operation, reactive power control, dynamic load change and voltage sag simulations, respectively. The switching model of SST is implemented in Matlab/ Simulink to verify the SST control algorithms.

Smart Transformer-based Medium Voltage Grid Support by Means of Active Power Control

In the last decades the voltage regulation has been challenged by the increase of power variability in the electric grid,due to the spread of non-dispatchable generation sources.This paper introduces a Smart Transformer(ST)-based Medium Voltage(MV)grid support by means of active power control in the ST-fed Low Voltage(LV)grid.The aim of the proposed strategy is to improve the voltage profile in MV grids before the operation of On-Load Tap Changer in the primary substation transformer,which needs tens of seconds.This is realized through reactive power injection by the AC/DC MV converter and simultaneous decrease of the active power consumption of voltage-dependent loads in ST-fed LV grid,controlling the ST output voltage.The last feature has two main effects:the first is to reduce the active power withdrawn from MV grid,and consequently the MV voltage drop caused by the active current component.At the same time,higher reactive power injection capability in the MV converter is unlocked,due to the lower active power demand.As result,the ST increases the voltage support in MV grid.The analysis and simulation results carried out in this paper show improvements compared to similar solutions,i.e.the only reactive power compensation.The impact of the proposed solution has been finally evaluated under different voltage-dependence of the loads in the LV grid.

Microstructure evolution and phase transitions in metals simulated by the multiphase-field method

The phase-field method has emerged as the method of choice for the description of microstructure evolution and phase transitions in metallic materials.Following general thermodynamic laws a set of evolution equations for the structural variables of the system,the so called phase-fields,are derived.The paper reviews shortly the theoretical background of the multi-phase-field.Different examples demonstrating the applicability of the method to technical steels will be presented ranging from deformation of the dendritic strand shell during peritectic transformation,grain growth in Austenite to stress driven growth of Pearlite.

Assessment of malathion and its effects on leukocytes in human blood samples

In the present paper,we report a reproducible,cost effective,fast response method for detection of malathion and its effects on leukocytes in different human blood groups.Spectroscopic methods（UV-Vis spectrometry）and Fourier transform infrared coupled with solid phase extraction were applied for analyzing malathion content in human blood plasma.The spiking levels of malathion in the range of 0.1-1.7μg/mL were extracted from blood plasma samples using SPE.The present active functional groups（C=0;P-O-C;-OH;P=S）were also characterized.The recovery rate of malathion was 80%±4.5%.The calculated correlation coefficient was 0.9799,indicating the linearity of the results.The limit of detection（LOD）and limit of quantification（LOQ）were（0.1-1.7）μg/mL and（0.3-1.5）μg/mL,respectively.Malathion〈1.0μg/mL showed no significant change while higher levels of malathion exposure（1.5μg/mL and 3.0｜ig/mL）reduced the number of white blood cells.In conclusion,the spectroscopic results may be useful to understand the mechanism of other pesticides such as methyl parathion and parathion.

Microstructural development of vanadium-nickel crystalline alloy membranes

V85Ni15(at%)alloy was proposed as a promising candidate for hydrogen separation membranes.To date,investigations of V85Ni15 alloy have concentrated on hydrogen permeation characteristics,and little work has been done on the microstructural development.In the present study,various fabrication and heat-treatment techniques were used to develop different microstructures which would then be tailored to achieve a desired candidate for acceptable mechanical stability while maintaining high hydrogen permeability.The arc-melted(AM)V85Ni15 alloy are supersaturated solid solution with dendritic segregation of Ni-solute atoms.Cold rolling(CR)followed by annealing at 1050℃and 850℃can produce a two-phase(V+σ)microstructure and a three-phase(V+σ+NiV3)microstructure,respectively.Very fine two-phase microstructure obtained at 1050℃involves a simultaneous reaction of second-phase precipitation and V-matrix recrystallization.Sigma phase is formed via primary precipitation,while NiV3 phase is formed by peritectoidal reaction.When AMCR samples were homogenized at1250℃for 2 h and sequential heat-treated at 850℃or900℃for 2 h,precipitation-strengthening microstructure is obtained:large grain structure of V-matrix with uniform distribution of second-phase particles produced by recrystallization and grain growth followed by precipitation process.

Microstructure and mechanical properties of hybrid fabricated 1Cr12Ni2WMoVNb steel by laser melting deposition

Laser melting deposition was carried out to deposit a 1Cr12Ni2WMoVNb steel bar on a wrought bar of same material. Room-temperature tensile properties of the hybrid fabricated 1Cr12Ni2WMoVNb steel sample were evaluated, and microstructure, fracture surface morphology, and hardness profile were analyzed by an optical microscope （OM）, a scanning electron microscope （SEM）, and a hardness tester. Results show that the hybrid fabricated 1Cr12Ni2WMoVNb steel sample consists of laser deposited zone, wrought substrate zone, and heat affected zone （HAZ） of the wrought substrate. The laser deposited zone has coarse columnar prior austenite grains and fine well-aligned dendritic structure, while the HAZ of the wrought substrate has equiaxed prior austenite grains which are notably finer than those in the wrought substrate zone. Besides, austenitic transformation mechanism of the HAZ of the wrought substrate is different from that of the laser deposited zone during the reheating period of the laser deposition, which determines the different prior austenite grain morphologies of the two zones. Microhardness values of both the laser deposited zone and the HAZ of the wrought substrate are higher than that of the wrought substrate zone. Tensile properties of the hybrid fabricated 1Cr12Ni2WMoVNb steel sample are comparable to those of the wrought bar, and fracture occurs in the wrought substrate zone during the tensile test.

Preparation,characterization and combustion properties of Zr/ZrH_2 particles coated with α-FeOOH crystal grains

Zr/ZrH2 particles with irregular morphologies and broad size distribution were uniformly coated with acicular α-FeOOH crystal grains via a facile route without using polymers or surfactants. The as-synthesized material was characterized by X-ray diffraction （XRD）, scanning electron microscopy （SEM）, energy dispersive X-ray （EDX）, UV-vis diffusion reflection （UV-vis） and Raman spectrometry. Based on these characterizations, the synthesis mechanism was explained in terms of combined heterogeneous nucleation and solid state transformation reaction. The presence of α-FeOOH coating greatly changed the combustion behavior of Zr/ZrH2 particles： the combustion lasting time decreased from 32 s for un-coated Zr/ZrH2 particles to 0.2 s for coated particles while the maximum temperature in the combustion process increased from 1510 ℃ to 2036℃.