为了推进工业固废资源化,同时有效提高工程弃土的利用率。选用高炉矿渣、钢渣、磷石膏3种常见的工业固废协同水泥,复配聚羧酸减水剂,对工程弃土进行固化处理。通过D-最优混料试验,确定固化剂的最优配合比为高炉矿渣:钢渣∶磷石膏∶水泥...为了推进工业固废资源化,同时有效提高工程弃土的利用率。选用高炉矿渣、钢渣、磷石膏3种常见的工业固废协同水泥,复配聚羧酸减水剂,对工程弃土进行固化处理。通过D-最优混料试验,确定固化剂的最优配合比为高炉矿渣:钢渣∶磷石膏∶水泥∶聚羧酸=59.9∶5∶20∶15∶0.1,在该配方下固化土的7 d无侧限抗压强度达到了5583 kPa。利用X射线衍射(diffraction of X-rays,XRD)试验和扫描电镜(scanning electron microscope,SEM)试验对新型固化剂固化土的微观结构进行分析,结果发现固化土中生成大量的丝状物、针状物和絮状物,使孔隙减小,土体结构更加紧密。该研究成果不仅可为工业固废和工程弃土资源化处理提供参考,同时也为工程弃土二次利用提供一定的理论指导,具有较好的工程适用性。展开更多
Aging of a solid composite propellant containing HTPB/AP/AL was performed in order to validate the conformance of the accelerated aging data to the Arrhenius law. The main objective of the work was to examine the infl...Aging of a solid composite propellant containing HTPB/AP/AL was performed in order to validate the conformance of the accelerated aging data to the Arrhenius law. The main objective of the work was to examine the influence of the aziridine bonding agents family on the propellant aging. Aging of the prepared propellant samples was conducted as follows: 1. Four samples, one free of bonding agents, and three containing aziridine based bonding agents MAPO,HX-752, MAT4 were aged at 65°C. 2. Another four samples based on HX-752, MAT4 with different curing agents were aged at 65°C. The measured mechanical properties of the free bonding agent propellant samples were very far from the specifications and this illustrates the importance of the bonding agents in both the preparation and the aging phases.The prepared bonding agent 'MAT4' gave remarkable improvements of the mechanical properties comparing with HX-752 and MAPO. The aziridine bonding agents family inhibited the rate of decomposition of the propellant during the aging periods and supported the propellant matrix against decomposition at the elevate temperatures. Using of HMDI as curing agent gave slight better mechanical properties to the IPDI.展开更多
文摘为了推进工业固废资源化,同时有效提高工程弃土的利用率。选用高炉矿渣、钢渣、磷石膏3种常见的工业固废协同水泥,复配聚羧酸减水剂,对工程弃土进行固化处理。通过D-最优混料试验,确定固化剂的最优配合比为高炉矿渣:钢渣∶磷石膏∶水泥∶聚羧酸=59.9∶5∶20∶15∶0.1,在该配方下固化土的7 d无侧限抗压强度达到了5583 kPa。利用X射线衍射(diffraction of X-rays,XRD)试验和扫描电镜(scanning electron microscope,SEM)试验对新型固化剂固化土的微观结构进行分析,结果发现固化土中生成大量的丝状物、针状物和絮状物,使孔隙减小,土体结构更加紧密。该研究成果不仅可为工业固废和工程弃土资源化处理提供参考,同时也为工程弃土二次利用提供一定的理论指导,具有较好的工程适用性。
文摘Aging of a solid composite propellant containing HTPB/AP/AL was performed in order to validate the conformance of the accelerated aging data to the Arrhenius law. The main objective of the work was to examine the influence of the aziridine bonding agents family on the propellant aging. Aging of the prepared propellant samples was conducted as follows: 1. Four samples, one free of bonding agents, and three containing aziridine based bonding agents MAPO,HX-752, MAT4 were aged at 65°C. 2. Another four samples based on HX-752, MAT4 with different curing agents were aged at 65°C. The measured mechanical properties of the free bonding agent propellant samples were very far from the specifications and this illustrates the importance of the bonding agents in both the preparation and the aging phases.The prepared bonding agent 'MAT4' gave remarkable improvements of the mechanical properties comparing with HX-752 and MAPO. The aziridine bonding agents family inhibited the rate of decomposition of the propellant during the aging periods and supported the propellant matrix against decomposition at the elevate temperatures. Using of HMDI as curing agent gave slight better mechanical properties to the IPDI.
