In order to obtain a high output energy from a xenon lamp-pumped solid-state dye laser, homogeneities of laser mediums and flatnesses of medium faces with different processing treatments are discussed in the paper. Th...In order to obtain a high output energy from a xenon lamp-pumped solid-state dye laser, homogeneities of laser mediums and flatnesses of medium faces with different processing treatments are discussed in the paper. The mediums without aging treatment, which are prepared by using a prepolymer process and have diamond-machined end faces to produce the required optical finish, give a highest laser output of 281.9 mJ with 0.215% slope efficiency at 2.0x 10^-4 mol/L. The best medium lifetime is 21 shots to 50% of original output equating 74.6 k J/liter.展开更多
Laser action in methyl methacrylate (MMA) co-doped with sulforhodamine B and crystal violet dyes was investi- gated. The dye mixture was incorporated into a solid polymeric matrix and was pumped by a 532-nm Nd:YAG ...Laser action in methyl methacrylate (MMA) co-doped with sulforhodamine B and crystal violet dyes was investi- gated. The dye mixture was incorporated into a solid polymeric matrix and was pumped by a 532-nm Nd:YAG laser. Distributed feedback dye laser (DFDL) action was induced in the dye mixture using a prism arrangement both in the donor and acceptor regions by an energy transfer mechanism. Theoretically, the characteristics of acceptor and donor DFDLs, and the dependence of their pulse widths and output powers on acceptor-donor concentrations and pump power, were studied. Experimentally, the output energy of DFDL was measured at the emission peaks of donor and acceptor dyes for different pump powers and different acceptor-donor concentrations. Tuning of the output wavelength was achieved by varying the period of the gain modulation of the laser medium. The laser wavelength showed continuous tunability from 563 nm to 648 nm.展开更多
The intrinsic features involving a circularly symmetric beam profile with low divergence, planar geometry as well as the increasingly enhanced power of vertical-cavity surface-emitting lasers (VCSELs) have made the ...The intrinsic features involving a circularly symmetric beam profile with low divergence, planar geometry as well as the increasingly enhanced power of vertical-cavity surface-emitting lasers (VCSELs) have made the VCSEL a promising pump source in direct end bonding to a solid-state laser medium to form the minimized, on-wafer integrated laser system. This scheme will generate a surface contact pump configuration and thus additional end thermal coupling to the laser medium through the joint interface of both materials, apart from pump beam heating. This paper analytically models temperature distributions in both VCSEL and the laser medium from the end thermal coupling regarding surface contact pump configuration using a top-emitting VCSEL as the pump source for the first time. The analytical solutions are derived by introducing relative temperature and mean temperature expressions. The results show that the end contact heating by the VCSEL could lead to considerable temperature variations associated with thermal phase shift and thermal lensing in the laser medium. However, if the central temperature of the interface is increased by less than 20 K, the end contact heating does not have a significant thermal influence on the laser medium. In this case, the thermal effect should be dominated by pump beam heating. This work provides useful analytical results for further analysis of hybrid thermal effects on those lasers pumped by a direct VCSEL bond.展开更多
A high-power cw all-solid-state Nd:GdVO4 laser operating at 88Onto is reported. The laser consists of a low doped level Nd:GdV04 crystal dual-end-pumped by two high-power diode lasers and a compact negative confocM ...A high-power cw all-solid-state Nd:GdVO4 laser operating at 88Onto is reported. The laser consists of a low doped level Nd:GdV04 crystal dual-end-pumped by two high-power diode lasers and a compact negative confocM unstable-stable hybrid resonator. At an incident pump power of 820 W, a maximum cw output of 240 W at 1064nm is obtained. The optical-to-optical efficiency and Mope efficiency are 40.7% and 53.2%, respectively. The M2 factors in the unstable direction and in the stable direction are 4.38 and 5.44, respectively.展开更多
A new organic dye, trans-4-[p-(N-hydroxyethyl-N-ethylamino)styryl]-N-methyl- pyridinium p-toluene sulfonate (HEASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser pulse...A new organic dye, trans-4-[p-(N-hydroxyethyl-N-ethylamino)styryl]-N-methyl- pyridinium p-toluene sulfonate (HEASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser pulses, 0.05 mol/L HEASPS/DMF solution showed the two-photon pumped (TPP) output/input efficiency of 9.1% which is higher than that of known TPP laser dyes trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium iodide (ASPI) and trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium p-toluene sulfonate (HMASPS) at the same experimental conditions.展开更多
Polymers are a kind of attractive hosts for laser dyes due to their high transparency in both pumping and lasing ranges and superior optical homogeneity. In this paper solid dye samples based on polymethyl methacryla...Polymers are a kind of attractive hosts for laser dyes due to their high transparency in both pumping and lasing ranges and superior optical homogeneity. In this paper solid dye samples based on polymethyl methacrylate (PMMA) doped with different concentrations of 1, 3, 5, 7, 8 -pentamethyl-2, 6-diethylpyrromethene-BF2 (PM567) are prepared. The absorption, fluorescence and lasing spectra of the samples are obtained. Wide absorption and fluorescence bands are obtained and a red shift of the maxima of the lasing emission spectra is observed. With the second-harmonic generation of Q-switched Nd:YAC laser (532 nm, -20 ns) pumping the samples longitudinally, the slope efficiencies of the samples are obtained. There is an optimal dye concentration for the highest slope efficiency when the pumping energy is lower than some typical value (-250 mJ), and the highest slope efficiency 35.6% is obtained in the sample with a dye concentration of 2 × 10^-4 mol/L. Pumping the samples at a rate of 10Hz with a pulse energy as high as 200 mJ (the fluence is 0.2 J/cm^2), the output energy drops to one-half of its initial value after approximate 15500 pulses and the normalized photostability is 5.17CJ/mol. A kind of solid dye laser which could have some applications is built.展开更多
The solid-state medium containing pyrromethene 567 (PM567) in a polymethylmethacrylate polymer host is shown to lase under the flash lamp excitation. The experimental setup is an ordinary industrial product without ...The solid-state medium containing pyrromethene 567 (PM567) in a polymethylmethacrylate polymer host is shown to lase under the flash lamp excitation. The experimental setup is an ordinary industrial product without special design. The bulk transmission losses, the output energy, and the other lasing properties are compared. The medium with the lowest transmission loss, measured to be 0.392 %/cm at 633 nm, gives a laser output of 130 mJ with a slope efficiency of 0.082%.展开更多
Solid-state tunable dye laser materials developed by incorporation of stable laser dye molecules into solid host matrices like polymers, organically modified silicates (ORMOSILS) and porous sol-gel glasses. These mate...Solid-state tunable dye laser materials developed by incorporation of stable laser dye molecules into solid host matrices like polymers, organically modified silicates (ORMOSILS) and porous sol-gel glasses. These materials have technical advantages such as compactness, better manageability and suitability for field measurement. The recent research work with highly porous sol-gel glasses having good transparency in UV-Near UV region used as solid host for solid-state dye laser materials has attracted a great deal of attention because of its high potential utility than polymers. Two different procedure’s are used for incorpoerating the Stilbine-3 (STB-3) laser dyes into porous sol-gel matrices such as dope or dip methods. In dope method dye is mixed at the sol state and drying is carried out afterward;while in dip method matrix is first prepared and the matrix is dipped in desired dye solution. After preparation of these dye embedded sol-gel glasses we studied their spectroscopic properties of using absorption and fluorescence spectroscopy. Along with spectroscopy properties, the studies for longevity or the shelf life and lasing action of these materials were carried out. Laser dye STB-3 incorporated in sol-gel glass samples shows the same result as in methanolic solution.展开更多
A non-polar organic dye, E, E-1, 4-bis[4'-(N,N-dibutylamino)styryl]-2,5-dimethoxybenzene (DBASDMB), has been synthesized and characterized, and its structure has been determined. Pumped with a 200fs pulse this dy...A non-polar organic dye, E, E-1, 4-bis[4'-(N,N-dibutylamino)styryl]-2,5-dimethoxybenzene (DBASDMB), has been synthesized and characterized, and its structure has been determined. Pumped with a 200fs pulse this dye showed the up-conversion laser properties. The influences of various organic solvents and different pumping wavelength on the laser properties have been demonstrated.展开更多
A new organic dye, trans-4-[4'-(N-hydroxyethyl-N-methylamino)styryl]-N-methylpyridinium p-toluene sulfonate (HMASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser p...A new organic dye, trans-4-[4'-(N-hydroxyethyl-N-methylamino)styryl]-N-methylpyridinium p-toluene sulfonate (HMASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser pulses, 0.05 mol/L HMASPS/DMF solution showed the two-photon pumped (TPP) output/input efficiency of 8.4% which is higher than that of trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium iodide (ASPI)(1) at the same pump level.展开更多
Quenching the fluorescence of the dyes 3-(4’-dimethylaminophenyl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one (DMAPrP), 3- (4’-dimethylaminophenyl)-1-(2-furanyl)prop-2-en-1-one (DMAFP) and 3-(4’-dimethylaminophenyl)-1-(2-thi...Quenching the fluorescence of the dyes 3-(4’-dimethylaminophenyl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one (DMAPrP), 3- (4’-dimethylaminophenyl)-1-(2-furanyl)prop-2-en-1-one (DMAFP) and 3-(4’-dimethylaminophenyl)-1-(2-thienyl)prop- 2-en-1-one (DMATP) has been investigated in the presence of silver cation and silver nanoparticles in different media. The results of the quenching experiments were analyzed using Stern-Volmer equation. Quenching the fluorescence of the dyes decreased with increasing medium viscosity. The Stern-Volmer constant (KSV) values in the absence and presence of ethylene glycol show that the quenching efficiencies decrease as the medium viscosity increases indicating that the quenching process is a diffusion-controlled process, and this is consistent with a dynamic-type quenching.展开更多
The purpose of the study is to evatuate the feasibility of pulsed dye laser(PDL)throm bolysis In vitro and the effect of PDL on vascular function and structure invivo.In vitro,fifty hum an throm biwere divided into la...The purpose of the study is to evatuate the feasibility of pulsed dye laser(PDL)throm bolysis In vitro and the effect of PDL on vascular function and structure invivo.In vitro,fifty hum an throm biwere divided into laser treated group(n=35),irritation group(n=11),and controgroup(n=4).In the laser treated group thethrom biwere irradiated by PDL with 300 pulses at 100m J/pulse.No irradiation wasgiven to the throm bi in the irritation group,while the catheter was put to and frointo the throm bi for there times,Neither irradintion nor irritation was given to thethrom bi in the controlgroup.Sixteen healthy dogs were studied in vivo.Under theguidance of the guide-w ire PDL catheter was put into the left coronary arteries(n=16)from which PDL was em itted for 1380±60 pulses at 100m J/pulse,whereasthe rightcoronary srteries(n=16)which did not receieve PDL em ission were servedas irritation group.Then the PDL were irradiated directly to the right coronaryarterial wall in the irritation group without the guidance of the guide-wire.AfterPDL irradiation.the weight of the throm bi was reduced from 1.79±0.23g to0.61±0.12g while in the irritation group theweight of the throm biwas only reducedfrom 1.65±0.19 to 1.42±0.15g.In these two aroups the reduction of throm biweightwere 68%±6% and 15%±7% resoectively(P【0.001).No self-dissolution of thethrom bi occurred in the control group.The finding under the contrast phasem icroscope indicated 91% of the debris size were smaller than the size of redcells.In vivo study,coronary angiography showed that no changes in luminalduam eter of both groups.Nomechanicalor thermal in jury to the coronary arterieswas found excepta light irregularity of the intima.PDL Throm bolysis was effectivein vitro.There was no mechanicaldam age or therm al in jury to the vessels during theprocedure of intracoronary PDL irradiation in vivo.展开更多
Cutaneous infections with the human papilloma virus, despite being almost always asymptomatic, can induce slow-growing lesions knowed as warts that can remain subclinical for long periods of time. There are several th...Cutaneous infections with the human papilloma virus, despite being almost always asymptomatic, can induce slow-growing lesions knowed as warts that can remain subclinical for long periods of time. There are several therapeutical options namely keratolytics, retinoids, imiquimod, cryotherapy, electrosurgery, lasers and classic surgery, but none has antiviral effects. We describe the case of a patient with large warts located on the dorsal surface of the right hand, treated with cryotherapy, CO2 laser and topical imiquimod having either no clinical response or quick relapse. Treatment with PDL was started and after 13 sessions, the patient was without lesions, with a good cosmetic result and so far without relapse. This case report is relevant to us and deserves to be published because of the size of the lesions and the great response to PDL despite all the failures with the other treatments.展开更多
This work is devoted to building-up of ultrahigh resolution cw-dye laser spectrometer system. This system used self-frequency-stabilized and temperature-compensated plano-confocal reference cavity. The one-way propaga...This work is devoted to building-up of ultrahigh resolution cw-dye laser spectrometer system. This system used self-frequency-stabilized and temperature-compensated plano-confocal reference cavity. The one-way propagation is achieved using new construction of optical diode. The laser frequency selection and tuning is accomplished using Mach-Zehnder interferometer of free spectral range 42.5 GHz. In combination with computerized tunable radio frequency technique, this system is capable of a resolution of about ±1 KHz. Applications for measuring high lying, weakly occupied metastable states of free atoms (line 548.792 nm of V-51) are investigated to a high degree of accuracy. The results of the constants A and B of the hfs as measured by fluorescence spectroscopy show that A = 160.762 and B = -17.918, while the obtained results for the hfs constants A and B as measured by laser-RF double resonance technique give A = 160.9950 and B = -17.3358.展开更多
Infantile hemangiomas, occurring at birth or during the first weeks of life, are benign vascular tumors with an initial proliferative phase and a later involutional phase. The massive proliferation on the key regions ...Infantile hemangiomas, occurring at birth or during the first weeks of life, are benign vascular tumors with an initial proliferative phase and a later involutional phase. The massive proliferation on the key regions and unpredicted regression may threaten?life. Thus, early management of infantile hemangiomas is necessary for affected infancies. Recent studies showed that propranolol for infantile hemangiomas had high efficacy for disappearance or reduction of infantile hemangiomas. However, a most recent study demonstrated existence of propranolol-resistant infantile hemangiomas. Therefore, we retrospectively evaluated efficacy of established early pulsed dye laser treatment for infantile hemangiomas in the 50 Japanese infancies which were applied in the period from 2000 to 2005, because our series included from the plaque subtype to the more proliferative tumor subtype. High efficacy in both subtypes suggests that early pulsed dye laser treatment can still be included as the first option for the mixed type of infantile hemangiomas and that pulsed dye laser treatment may be useful as the second line for the propranolol-resistant mixed type of infantile hemangiomas.展开更多
To assess the effectiveness of the flashlamp- pumped pulsed dye laser (Photogeneca V, Synosure Corp, Boston, United States) in the treatment of port- wine stains. Methods. One hundred and ninety- four consecutive pati...To assess the effectiveness of the flashlamp- pumped pulsed dye laser (Photogeneca V, Synosure Corp, Boston, United States) in the treatment of port- wine stains. Methods. One hundred and ninety- four consecutive patients with port- wine stains were treated with a flashlamp- pumped pulsed dye laser in Peking Union Medical College Hospital from January 1998 to August 1999. Results. Of 194 patients who completed treatment, 56.2% had more than 60% fading of the lesion and only 6.7% had less than 20% fading. An average of 3.6 treatments were needed to achieve more than 60% fading. The response was better in children than in adults, although the difference was not significant. Pigmentary change (usually transient) occurred in 3.1% of patients. Conclusions. This study confirms the efficacy of the flashlamp- pumped pulsed dye laser in the treatment of port- wine stains in children and adults.展开更多
In 1967 the first work in solid state dye laser was performed by doping rhodamine dyes in Polymethylmethacrylate (PMMA) materials. Since then </span><span style="white-space:normal;"><spa...In 1967 the first work in solid state dye laser was performed by doping rhodamine dyes in Polymethylmethacrylate (PMMA) materials. Since then </span><span style="white-space:normal;"><span style="font-family:"">some</span></span><span style="white-space:normal;"><span style="font-family:""> materials like various types of polymers, co-polymers, poly</span></span><span style="white-space:normal;"><span style="font-family:""> </span></span><span style="white-space:normal;"><span style="font-family:"">composite glasses have been used as host matrices for doping different laser dyes. Polymers suffer from limited mechanical and thermal stability. Hence glasses can be the alternative hosts. However, because of high processing temperature leading to permanent destruction of dye molecules, </span></span><span style="white-space:normal;"><span style="font-family:"">the </span></span><span style="white-space:normal;"><span style="font-family:"">conventional glass preparation technique is not suitable for the introduction of organic laser dyes. This difficulty can be overcome by introducing the laser dye molecules in sol-gel glass which is prepared at low temperature. Recent work with sol-gel glasses shows that these glasses may prove to be better materials compared to polymeric materials because glasses being hard, best optically transparency in Near UV-UV and Visible region and show better photostability. In this research work we reported, comparative study of the photophysical properties of Coumarin-120 (C-120) belonging to 7-aminocoumarin family having two hydrogen atoms attached to the N atom at the 7-position, with Stilbene-3 (STB-3) in three types of HCl catalyzed SiO<sub>2</sub> sol-gel matrices prepared by Method I, Method II and Method III respectively.展开更多
A direct Kerr-lens mode-locked Tm:LuYO_(3)ceramic laser without the aid of any mode-locked starting element is reported for the first time. A pulse duration as short as 259 fs and a maximum average output power of 326...A direct Kerr-lens mode-locked Tm:LuYO_(3)ceramic laser without the aid of any mode-locked starting element is reported for the first time. A pulse duration as short as 259 fs and a maximum average output power of 326 m W are obtained at a repetition rate of 97.1 MHz. The corresponding optical spectrum centered at 2053 nm exhibits a bandwidth of 19.8 nm,which indicates the presence of nearly Fourier transform-limited pulses. Such a Kerr-lens mode-locked Tm:LuYO_(3)ceramic laser is a promising ultrashort pulse source, with both the excellent laser characteristics of Tm:LuYO3and the high-power 790 nm laser diode pumping scheme.展开更多
文摘In order to obtain a high output energy from a xenon lamp-pumped solid-state dye laser, homogeneities of laser mediums and flatnesses of medium faces with different processing treatments are discussed in the paper. The mediums without aging treatment, which are prepared by using a prepolymer process and have diamond-machined end faces to produce the required optical finish, give a highest laser output of 281.9 mJ with 0.215% slope efficiency at 2.0x 10^-4 mol/L. The best medium lifetime is 21 shots to 50% of original output equating 74.6 k J/liter.
文摘Laser action in methyl methacrylate (MMA) co-doped with sulforhodamine B and crystal violet dyes was investi- gated. The dye mixture was incorporated into a solid polymeric matrix and was pumped by a 532-nm Nd:YAG laser. Distributed feedback dye laser (DFDL) action was induced in the dye mixture using a prism arrangement both in the donor and acceptor regions by an energy transfer mechanism. Theoretically, the characteristics of acceptor and donor DFDLs, and the dependence of their pulse widths and output powers on acceptor-donor concentrations and pump power, were studied. Experimentally, the output energy of DFDL was measured at the emission peaks of donor and acceptor dyes for different pump powers and different acceptor-donor concentrations. Tuning of the output wavelength was achieved by varying the period of the gain modulation of the laser medium. The laser wavelength showed continuous tunability from 563 nm to 648 nm.
文摘The intrinsic features involving a circularly symmetric beam profile with low divergence, planar geometry as well as the increasingly enhanced power of vertical-cavity surface-emitting lasers (VCSELs) have made the VCSEL a promising pump source in direct end bonding to a solid-state laser medium to form the minimized, on-wafer integrated laser system. This scheme will generate a surface contact pump configuration and thus additional end thermal coupling to the laser medium through the joint interface of both materials, apart from pump beam heating. This paper analytically models temperature distributions in both VCSEL and the laser medium from the end thermal coupling regarding surface contact pump configuration using a top-emitting VCSEL as the pump source for the first time. The analytical solutions are derived by introducing relative temperature and mean temperature expressions. The results show that the end contact heating by the VCSEL could lead to considerable temperature variations associated with thermal phase shift and thermal lensing in the laser medium. However, if the central temperature of the interface is increased by less than 20 K, the end contact heating does not have a significant thermal influence on the laser medium. In this case, the thermal effect should be dominated by pump beam heating. This work provides useful analytical results for further analysis of hybrid thermal effects on those lasers pumped by a direct VCSEL bond.
文摘A high-power cw all-solid-state Nd:GdVO4 laser operating at 88Onto is reported. The laser consists of a low doped level Nd:GdV04 crystal dual-end-pumped by two high-power diode lasers and a compact negative confocM unstable-stable hybrid resonator. At an incident pump power of 820 W, a maximum cw output of 240 W at 1064nm is obtained. The optical-to-optical efficiency and Mope efficiency are 40.7% and 53.2%, respectively. The M2 factors in the unstable direction and in the stable direction are 4.38 and 5.44, respectively.
文摘A new organic dye, trans-4-[p-(N-hydroxyethyl-N-ethylamino)styryl]-N-methyl- pyridinium p-toluene sulfonate (HEASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser pulses, 0.05 mol/L HEASPS/DMF solution showed the two-photon pumped (TPP) output/input efficiency of 9.1% which is higher than that of known TPP laser dyes trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium iodide (ASPI) and trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium p-toluene sulfonate (HMASPS) at the same experimental conditions.
文摘Polymers are a kind of attractive hosts for laser dyes due to their high transparency in both pumping and lasing ranges and superior optical homogeneity. In this paper solid dye samples based on polymethyl methacrylate (PMMA) doped with different concentrations of 1, 3, 5, 7, 8 -pentamethyl-2, 6-diethylpyrromethene-BF2 (PM567) are prepared. The absorption, fluorescence and lasing spectra of the samples are obtained. Wide absorption and fluorescence bands are obtained and a red shift of the maxima of the lasing emission spectra is observed. With the second-harmonic generation of Q-switched Nd:YAC laser (532 nm, -20 ns) pumping the samples longitudinally, the slope efficiencies of the samples are obtained. There is an optimal dye concentration for the highest slope efficiency when the pumping energy is lower than some typical value (-250 mJ), and the highest slope efficiency 35.6% is obtained in the sample with a dye concentration of 2 × 10^-4 mol/L. Pumping the samples at a rate of 10Hz with a pulse energy as high as 200 mJ (the fluence is 0.2 J/cm^2), the output energy drops to one-half of its initial value after approximate 15500 pulses and the normalized photostability is 5.17CJ/mol. A kind of solid dye laser which could have some applications is built.
文摘The solid-state medium containing pyrromethene 567 (PM567) in a polymethylmethacrylate polymer host is shown to lase under the flash lamp excitation. The experimental setup is an ordinary industrial product without special design. The bulk transmission losses, the output energy, and the other lasing properties are compared. The medium with the lowest transmission loss, measured to be 0.392 %/cm at 633 nm, gives a laser output of 130 mJ with a slope efficiency of 0.082%.
文摘Solid-state tunable dye laser materials developed by incorporation of stable laser dye molecules into solid host matrices like polymers, organically modified silicates (ORMOSILS) and porous sol-gel glasses. These materials have technical advantages such as compactness, better manageability and suitability for field measurement. The recent research work with highly porous sol-gel glasses having good transparency in UV-Near UV region used as solid host for solid-state dye laser materials has attracted a great deal of attention because of its high potential utility than polymers. Two different procedure’s are used for incorpoerating the Stilbine-3 (STB-3) laser dyes into porous sol-gel matrices such as dope or dip methods. In dope method dye is mixed at the sol state and drying is carried out afterward;while in dip method matrix is first prepared and the matrix is dipped in desired dye solution. After preparation of these dye embedded sol-gel glasses we studied their spectroscopic properties of using absorption and fluorescence spectroscopy. Along with spectroscopy properties, the studies for longevity or the shelf life and lasing action of these materials were carried out. Laser dye STB-3 incorporated in sol-gel glass samples shows the same result as in methanolic solution.
基金the State Key Program of China,the National Natural Science Foundation of China(50173015)NSFC/RGC(50218001)+1 种基金the Foundation for University Key Teacher by the Ministry of EducationChina Postdoctoral Foundation.
文摘A non-polar organic dye, E, E-1, 4-bis[4'-(N,N-dibutylamino)styryl]-2,5-dimethoxybenzene (DBASDMB), has been synthesized and characterized, and its structure has been determined. Pumped with a 200fs pulse this dye showed the up-conversion laser properties. The influences of various organic solvents and different pumping wavelength on the laser properties have been demonstrated.
基金This tvork was supported by the grant for state key program of China by the National NaturalScience Foundation of China, al
文摘A new organic dye, trans-4-[4'-(N-hydroxyethyl-N-methylamino)styryl]-N-methylpyridinium p-toluene sulfonate (HMASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser pulses, 0.05 mol/L HMASPS/DMF solution showed the two-photon pumped (TPP) output/input efficiency of 8.4% which is higher than that of trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium iodide (ASPI)(1) at the same pump level.
文摘Quenching the fluorescence of the dyes 3-(4’-dimethylaminophenyl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one (DMAPrP), 3- (4’-dimethylaminophenyl)-1-(2-furanyl)prop-2-en-1-one (DMAFP) and 3-(4’-dimethylaminophenyl)-1-(2-thienyl)prop- 2-en-1-one (DMATP) has been investigated in the presence of silver cation and silver nanoparticles in different media. The results of the quenching experiments were analyzed using Stern-Volmer equation. Quenching the fluorescence of the dyes decreased with increasing medium viscosity. The Stern-Volmer constant (KSV) values in the absence and presence of ethylene glycol show that the quenching efficiencies decrease as the medium viscosity increases indicating that the quenching process is a diffusion-controlled process, and this is consistent with a dynamic-type quenching.
文摘The purpose of the study is to evatuate the feasibility of pulsed dye laser(PDL)throm bolysis In vitro and the effect of PDL on vascular function and structure invivo.In vitro,fifty hum an throm biwere divided into laser treated group(n=35),irritation group(n=11),and controgroup(n=4).In the laser treated group thethrom biwere irradiated by PDL with 300 pulses at 100m J/pulse.No irradiation wasgiven to the throm bi in the irritation group,while the catheter was put to and frointo the throm bi for there times,Neither irradintion nor irritation was given to thethrom bi in the controlgroup.Sixteen healthy dogs were studied in vivo.Under theguidance of the guide-w ire PDL catheter was put into the left coronary arteries(n=16)from which PDL was em itted for 1380±60 pulses at 100m J/pulse,whereasthe rightcoronary srteries(n=16)which did not receieve PDL em ission were servedas irritation group.Then the PDL were irradiated directly to the right coronaryarterial wall in the irritation group without the guidance of the guide-wire.AfterPDL irradiation.the weight of the throm bi was reduced from 1.79±0.23g to0.61±0.12g while in the irritation group theweight of the throm biwas only reducedfrom 1.65±0.19 to 1.42±0.15g.In these two aroups the reduction of throm biweightwere 68%±6% and 15%±7% resoectively(P【0.001).No self-dissolution of thethrom bi occurred in the control group.The finding under the contrast phasem icroscope indicated 91% of the debris size were smaller than the size of redcells.In vivo study,coronary angiography showed that no changes in luminalduam eter of both groups.Nomechanicalor thermal in jury to the coronary arterieswas found excepta light irregularity of the intima.PDL Throm bolysis was effectivein vitro.There was no mechanicaldam age or therm al in jury to the vessels during theprocedure of intracoronary PDL irradiation in vivo.
文摘Cutaneous infections with the human papilloma virus, despite being almost always asymptomatic, can induce slow-growing lesions knowed as warts that can remain subclinical for long periods of time. There are several therapeutical options namely keratolytics, retinoids, imiquimod, cryotherapy, electrosurgery, lasers and classic surgery, but none has antiviral effects. We describe the case of a patient with large warts located on the dorsal surface of the right hand, treated with cryotherapy, CO2 laser and topical imiquimod having either no clinical response or quick relapse. Treatment with PDL was started and after 13 sessions, the patient was without lesions, with a good cosmetic result and so far without relapse. This case report is relevant to us and deserves to be published because of the size of the lesions and the great response to PDL despite all the failures with the other treatments.
文摘This work is devoted to building-up of ultrahigh resolution cw-dye laser spectrometer system. This system used self-frequency-stabilized and temperature-compensated plano-confocal reference cavity. The one-way propagation is achieved using new construction of optical diode. The laser frequency selection and tuning is accomplished using Mach-Zehnder interferometer of free spectral range 42.5 GHz. In combination with computerized tunable radio frequency technique, this system is capable of a resolution of about ±1 KHz. Applications for measuring high lying, weakly occupied metastable states of free atoms (line 548.792 nm of V-51) are investigated to a high degree of accuracy. The results of the constants A and B of the hfs as measured by fluorescence spectroscopy show that A = 160.762 and B = -17.918, while the obtained results for the hfs constants A and B as measured by laser-RF double resonance technique give A = 160.9950 and B = -17.3358.
文摘Infantile hemangiomas, occurring at birth or during the first weeks of life, are benign vascular tumors with an initial proliferative phase and a later involutional phase. The massive proliferation on the key regions and unpredicted regression may threaten?life. Thus, early management of infantile hemangiomas is necessary for affected infancies. Recent studies showed that propranolol for infantile hemangiomas had high efficacy for disappearance or reduction of infantile hemangiomas. However, a most recent study demonstrated existence of propranolol-resistant infantile hemangiomas. Therefore, we retrospectively evaluated efficacy of established early pulsed dye laser treatment for infantile hemangiomas in the 50 Japanese infancies which were applied in the period from 2000 to 2005, because our series included from the plaque subtype to the more proliferative tumor subtype. High efficacy in both subtypes suggests that early pulsed dye laser treatment can still be included as the first option for the mixed type of infantile hemangiomas and that pulsed dye laser treatment may be useful as the second line for the propranolol-resistant mixed type of infantile hemangiomas.
文摘To assess the effectiveness of the flashlamp- pumped pulsed dye laser (Photogeneca V, Synosure Corp, Boston, United States) in the treatment of port- wine stains. Methods. One hundred and ninety- four consecutive patients with port- wine stains were treated with a flashlamp- pumped pulsed dye laser in Peking Union Medical College Hospital from January 1998 to August 1999. Results. Of 194 patients who completed treatment, 56.2% had more than 60% fading of the lesion and only 6.7% had less than 20% fading. An average of 3.6 treatments were needed to achieve more than 60% fading. The response was better in children than in adults, although the difference was not significant. Pigmentary change (usually transient) occurred in 3.1% of patients. Conclusions. This study confirms the efficacy of the flashlamp- pumped pulsed dye laser in the treatment of port- wine stains in children and adults.
文摘In 1967 the first work in solid state dye laser was performed by doping rhodamine dyes in Polymethylmethacrylate (PMMA) materials. Since then </span><span style="white-space:normal;"><span style="font-family:"">some</span></span><span style="white-space:normal;"><span style="font-family:""> materials like various types of polymers, co-polymers, poly</span></span><span style="white-space:normal;"><span style="font-family:""> </span></span><span style="white-space:normal;"><span style="font-family:"">composite glasses have been used as host matrices for doping different laser dyes. Polymers suffer from limited mechanical and thermal stability. Hence glasses can be the alternative hosts. However, because of high processing temperature leading to permanent destruction of dye molecules, </span></span><span style="white-space:normal;"><span style="font-family:"">the </span></span><span style="white-space:normal;"><span style="font-family:"">conventional glass preparation technique is not suitable for the introduction of organic laser dyes. This difficulty can be overcome by introducing the laser dye molecules in sol-gel glass which is prepared at low temperature. Recent work with sol-gel glasses shows that these glasses may prove to be better materials compared to polymeric materials because glasses being hard, best optically transparency in Near UV-UV and Visible region and show better photostability. In this research work we reported, comparative study of the photophysical properties of Coumarin-120 (C-120) belonging to 7-aminocoumarin family having two hydrogen atoms attached to the N atom at the 7-position, with Stilbene-3 (STB-3) in three types of HCl catalyzed SiO<sub>2</sub> sol-gel matrices prepared by Method I, Method II and Method III respectively.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 62165012 and 61665010)Key research and development projects in Gansu Province (Grant No. 21YFIGE300)+5 种基金Gansu Province College Industry Support Plan Project (Grant Nos. 2020C-23 and 2022CYZC-59)Department of Education of Gansu Province: The Education Project of Open Competition for the Best Candidates (Grant No. 2021jyjbgs-06)Gansu Provincial University Innovation Fund Project (Grant No. 2021B-190)Qinzhou District Science and Technology Plan Project (Grant No. 2021-SHFZG1442)Gansu Province College Young Doctor Support Project (Grant No. 2023QB-013)Gansu Province Excellent Graduate Innovation Star Project (Grant No. 2022CXZX796)。
文摘A direct Kerr-lens mode-locked Tm:LuYO_(3)ceramic laser without the aid of any mode-locked starting element is reported for the first time. A pulse duration as short as 259 fs and a maximum average output power of 326 m W are obtained at a repetition rate of 97.1 MHz. The corresponding optical spectrum centered at 2053 nm exhibits a bandwidth of 19.8 nm,which indicates the presence of nearly Fourier transform-limited pulses. Such a Kerr-lens mode-locked Tm:LuYO_(3)ceramic laser is a promising ultrashort pulse source, with both the excellent laser characteristics of Tm:LuYO3and the high-power 790 nm laser diode pumping scheme.