A phase and microstructure selection map used for peritectic alloy directionally solidified under convection condition was presented,which is based on the nucleation,constitutional undercooling criterion（NCU criterio...A phase and microstructure selection map used for peritectic alloy directionally solidified under convection condition was presented,which is based on the nucleation,constitutional undercooling criterion（NCU criterion）,and the highest interface temperature criterion.This selection map shows the relationships between the phase/microstructure,the G/V ratio（G is the temperature gradient,V is the growth velocity）,and the alloy composition under different convection intensities and nucleation undercoolings.Comparing with the results from directional solidification experiments of Sn–Cd peritectic alloys,this selection map was generally in agreement with the experimental results.展开更多
Compositional dependences on microstructures and martensitic transformation behaviors in（Cu_（0.5）Zr_（0.5））_（100-x）Zn_x（x=1.5,2.5,4.5,7.0,10.0,and 14.0at.%）alloys were investigated.It was found that CuZr mart...Compositional dependences on microstructures and martensitic transformation behaviors in（Cu_（0.5）Zr_（0.5））_（100-x）Zn_x（x=1.5,2.5,4.5,7.0,10.0,and 14.0at.%）alloys were investigated.It was found that CuZr martensites were present in the present alloys.With increasing Zn content,the volume fractions of CuZr martensitic crystals and B2 CuZr phase gradually decrease and increase,respectively.With the addition of high Zn contents（i.e.,7.0,10.0,and 14.0at.%）,the matrix proves to be eutectic.Thermal analysis results show that the initial martensitic transformation temperature（M_s）decreases from（412±5）K to（329±5）K as the Zn content increases from 1.5at.% to14.0at.%.The values of Msof Cu-Zr-Zn shape memory alloys are inversely proportional to the number and concentrations of valence electrons（i.e.,e_v/a and c_v）,respectively,implying that the martensitic transformation in CuZrZn alloys could be of electronic nature.展开更多
基金financially supported by the National Natural Science Foundation of China (No.50774061)the Research Fund of State Key Laboratory of Solidification Processing (NWPU) (No.28-TP-2009)
文摘A phase and microstructure selection map used for peritectic alloy directionally solidified under convection condition was presented,which is based on the nucleation,constitutional undercooling criterion（NCU criterion）,and the highest interface temperature criterion.This selection map shows the relationships between the phase/microstructure,the G/V ratio（G is the temperature gradient,V is the growth velocity）,and the alloy composition under different convection intensities and nucleation undercoolings.Comparing with the results from directional solidification experiments of Sn–Cd peritectic alloys,this selection map was generally in agreement with the experimental results.
基金Item Sponsored by National Natural Science Foundation of China(51501103)Fundamental Research Funds for the Central Universities on Northwestern Polytechnical University of China(GEKY1008)
文摘Compositional dependences on microstructures and martensitic transformation behaviors in（Cu_（0.5）Zr_（0.5））_（100-x）Zn_x（x=1.5,2.5,4.5,7.0,10.0,and 14.0at.%）alloys were investigated.It was found that CuZr martensites were present in the present alloys.With increasing Zn content,the volume fractions of CuZr martensitic crystals and B2 CuZr phase gradually decrease and increase,respectively.With the addition of high Zn contents（i.e.,7.0,10.0,and 14.0at.%）,the matrix proves to be eutectic.Thermal analysis results show that the initial martensitic transformation temperature（M_s）decreases from（412±5）K to（329±5）K as the Zn content increases from 1.5at.% to14.0at.%.The values of Msof Cu-Zr-Zn shape memory alloys are inversely proportional to the number and concentrations of valence electrons（i.e.,e_v/a and c_v）,respectively,implying that the martensitic transformation in CuZrZn alloys could be of electronic nature.
