Fundamental influence of irreversible stress-strain properties in solids on the validity of the ramp loading method

The widely used quasi-isentropic ramp loading technique relies heavily on back-calculation methods that convert the measured free-surface velocity profiles to the stress-density states inside the compressed sample.Existing back-calculation methods are based on one-dimensional isentropic hydrodynamic equations,which assume a well-defined functional relationship P(p)between the longitudinal stress and density throughout the entire flow field.However,this kind of idealized stress-density relation does not hold in general,because of the complexities introduced by structural phase transitions and/or elastic-plastic response.How and to what extent these standard back-calculation methods may be affected by such inherent complexities is still an unsettled question.Here,we present a close examination using large-scale molecular dynamics(MD)simulations that include the detailed physics of the irreversibly compressed solid samples.We back-calculate the stress-density relation from the MD-simulated rear surface velocity profiles and compare it directly against the stress-density trajectories measured from the MD simulation itself.Deviations exist in the cases studied here,and these turn out to be related to the irreversibility between compression and release.Rarefaction and compression waves are observed to propagate with different sound velocities in some parts of the flow field,violating the basic assumption of isentropic hydrodynamic models and thus leading to systematic back-calculation errors.In particular,the step-like feature of the P(p)curve corresponding to phase transition may be completely missed owing to these errors.This kind of mismatch between inherent properties of matter and the basic assumptions of isentropic hydrodynamics has a fundamental influence on how the ramp loading method can be applied.

Quantifying Uncertainty in Dielectric Solids’ Mechanical Properties Using Isogeometric Analysis and Conditional Generative Adversarial Networks

Accurate quantification of the uncertainty in the mechanical characteristics of dielectric solids is crucial for advancing their application in high-precision technological domains,necessitating the development of robust com-putational methods.This paper introduces a Conditional Generation Adversarial Network Isogeometric Analysis(CGAN-IGA)to assess the uncertainty of dielectric solids’mechanical characteristics.IGA is utilized for the precise computation of electric potentials in dielectric,piezoelectric,and flexoelectric materials,leveraging its advantage of integrating seamlessly with Computer-Aided Design(CAD)models to maintain exact geometrical fidelity.The CGAN method is highly efficient in generating models for piezoelectric and flexoelectric materials,specifically adapting to targeted design requirements and constraints.Then,the CGAN-IGA is adopted to calculate the electric potential of optimum models with different parameters to accelerate uncertainty quantification processes.The accuracy and feasibility of this method are verified through numerical experiments presented herein.

Impacts of Climate Change on Seawater Temperature and Total Dissolved Solids: Challenges and Sustainable Solutions for Reverse Osmosis Desalination in the Arabian Gulf Region

This article examines the influence of seawater temperature and total dissolved solids (TDS) on reverse osmosis (RO) desalination in the Arabian Gulf region, with a focus on the impact of climate change. The study highlights the changes in seawater temperature and TDS levels over the years and discusses their effects on the efficiency and productivity of RO desalination plants. It emphasizes the importance of monitoring TDS levels and controlling seawater temperature to optimize water production. The article also suggests various solutions, including intensive pre-treatment, development of high-performance membranes, exploration of alternative water sources, and regulation of discharges into the Gulf, to ensure sustainable water supply in the face of rising TDS levels and seawater temperature. Further research and comprehensive monitoring are recommended to understand the implications of these findings and develop effective strategies for the management of marine resources in the Arabian Gulf.

Study of Total Dissolved Solids (TDS) Concentrations Factor of SWCC Al-Khobar Plant Seawater Intakes

This study presents a significant contribution to the field of water quality assessment and sustainable water management practices. By evaluating the levels of total dissolved solids (TDS) in seawater intakes within Al-Khobar desalination production system, the study addresses a crucial aspect of water treatment and environmental impact assessment. The findings provide valuable insights into the variations and trends of TDS levels across different phases of the system, highlighting the importance of monitoring and management strategies. The study provided both gravimetric total dissolved solids (TDS) and electrical conductivity (EC) measurements to analyze TDS calculation factor and evaluate measurement accuracy. Results revealed significant variations in TDS levels across the sampling locations, with phase-2 exhibiting higher levels and greater fluctuations. Phase-3 displayed similar trends but with lower TDS levels, while phase-4 showed slightly different behavior with higher average TDS levels. EC measurements demonstrated a strong correlation with TDS, providing a reliable estimation. However, additional methods such as gravimetric analysis should be employed to confirm TDS measurements. The findings contribute to understanding water quality in the Al-Khobar desalination system, aiding in monitoring, management, and decision-making processes for water treatment and environmental impact assessment. The study enhances the credibility of water quality assessments and supports sustainable water management practices.

Advancements and Challenges in Organic–Inorganic Composite Solid Electrolytes for All‑Solid‑State Lithium Batteries

To address the limitations of contemporary lithium-ion batteries,particularly their low energy density and safety concerns,all-solid-state lithium batteries equipped with solid-state electrolytes have been identified as an up-and-coming alternative.Among the various SEs,organic–inorganic composite solid electrolytes(OICSEs)that combine the advantages of both polymer and inorganic materials demonstrate promising potential for large-scale applications.However,OICSEs still face many challenges in practical applications,such as low ionic conductivity and poor interfacial stability,which severely limit their applications.This review provides a comprehensive overview of recent research advancements in OICSEs.Specifically,the influence of inorganic fillers on the main functional parameters of OICSEs,including ionic conductivity,Li+transfer number,mechanical strength,electrochemical stability,electronic conductivity,and thermal stability are systematically discussed.The lithium-ion conduction mechanism of OICSE is thoroughly analyzed and concluded from the microscopic perspective.Besides,the classic inorganic filler types,including both inert and active fillers,are categorized with special emphasis on the relationship between inorganic filler structure design and the electrochemical performance of OICSEs.Finally,the advanced characterization techniques relevant to OICSEs are summarized,and the challenges and perspectives on the future development of OICSEs are also highlighted for constructing superior ASSLBs.

Aligned Ion Conduction Pathway of Polyrotaxane‑Based Electrolyte with Dispersed Hydrophobic Chains for Solid‑State Lithium–Oxygen Batteries

A critical challenge hindering the practical application of lithium–oxygen batteries(LOBs)is the inevitable problems associated with liquid electrolytes,such as evaporation and safety problems.Our study addresses these problems by proposing a modified polyrotaxane(mPR)-based solid polymer electrolyte(SPE)design that simultaneously mitigates solvent-related problems and improves conductivity.mPR-SPE exhibits high ion conductivity(2.8×10^(−3)S cm^(−1)at 25℃)through aligned ion conduction pathways and provides electrode protection ability through hydrophobic chain dispersion.Integrating this mPR-SPE into solid-state LOBs resulted in stable potentials over 300 cycles.In situ Raman spectroscopy reveals the presence of an LiO_(2)intermediate alongside Li_(2)O_(2)during oxygen reactions.Ex situ X-ray diffraction confirm the ability of the SPE to hinder the permeation of oxygen and moisture,as demonstrated by the air permeability tests.The present study suggests that maintaining a low residual solvent while achieving high ionic conductivity is crucial for restricting the sub-reactions of solid-state LOBs.

Industrial solid wastes to environmental protection materials for removal of gaseous pollutants:A review

The application of industrial solid wastes as environmentally functional materials for air pollutants control has gained much attention in recent years due to its potential to reduce air pollution in a cost-effective manner.In this review,we investigate the development of industrialwaste-based functional materials for various gas pollutant removal and consider the relevant reaction mechanism according to different types of industrial solid waste.We see a recent effort towards achieving high-performance environmental functional materials via chemical or physical modification,in which the active components,pore size,and phase structure can be altered.The review will discuss the potential of using industrial solid wastes,these modified materials,or synthesized materials from raw waste precursors for the removal of air pollutants,including SO_(2),NO_(x),Hg^(0),H_(2)S,VOCs,and CO_(2).The challenges still need to be addressed to realize this potential and the prospects for future research fully.The suggestions for future directions include determining the optimal composition of these materials,calculating the real reaction rate and turnover frequency,developing effective treatment methods,and establishing chemical component databases of raw industrial solid waste for catalysts/adsorbent preparation.

Boosting high-performance in Zr-rich side protonic solid oxide electrolysis cells by optimizing functional interlayer

Protonic solid oxide electrolysis cells(P-SOECs)are a promising technology for water electrolysis to produce green hydrogen.However,there are still challenges related key materials and anode/electrolyte interface.P-SOECs with Zr-rich electrolyte,called Zr-rich side P-SOECs,possess high thermodynamically stability under high steam concentrations but the large reaction resistances and the current leakage,thus the inferior performances.In this study,an efficient functional interlayer Ba_(0.95)La_(0.05)Fe_(0.8)Zn_(0.2)O_(3-δ)(BLFZ)in-between the anode and the electrolyte is developed.The electrochemical performances of P-SOECs are greatly enhanced because the BLFZ can greatly increase the interface contact,boost anode reaction kinetics,and increase proton injection into electrolyte.As a result,the P-SOEC yields high current density of 0.83 A cm^(-2) at 600℃ in 1.3 Vamong all the reported Zr-rich side cells.This work not only offers an efficient functional interlayer for P-SOECs but also holds the potential to achieve P-SOECs with high performances and long-term stability.

Solid Waste Management:A MADM Approach Using Fuzzy Parameterized Possibility Single-Valued Neutrosophic Hypersoft Expert Settings

The dramatic rise in the number of people living in cities has made many environmental and social problems worse.The search for a productive method for disposing of solid waste is the most notable of these problems.Many scholars have referred to it as a fuzzy multi-attribute or multi-criteria decision-making problem using various fuzzy set-like approaches because of the inclusion of criteria and anticipated ambiguity.The goal of the current study is to use an innovative methodology to address the expected uncertainties in the problem of solid waste site selection.The characteristics(or sub-attributes)that decision-makers select and the degree of approximation they accept for various options can both be indicators of these uncertainties.To tackle these problems,a novel mathematical structure known as the fuzzy parameterized possibility single valued neutrosophic hypersoft expert set(ρˆ-set),which is initially described,is integrated with a modified version of Sanchez’s method.Following this,an intelligent algorithm is suggested.The steps of the suggested algorithm are explained with an example that explains itself.The compatibility of solid waste management sites and systems is discussed,and rankings are established along with detailed justifications for their viability.This study’s strengths lie in its application of fuzzy parameterization and possibility grading to effectively handle the uncertainties embodied in the parameters’nature and alternative approximations,respectively.It uses specific mathematical formulations to compute the fuzzy parameterized degrees and possibility grades that are missing from the prior literature.It is simpler for the decisionmakers to look at each option separately because the decision is uncertain.Comparing the computed results,it is discovered that they are consistent and dependable because of their preferred properties.

Sc-doped strontium iron molybdenum cathode for high-efficiency CO_(2)electrolysis in solid oxide electrolysis cell

Solid oxide electrolysis cells(SOECs)can effectively convert CO_(2)into high value-added CO fuel.In this paper,Sc-doped Sr_(2)Fe_(1.5)Mo_(0.3)Sc_(0.2)O_(6−δ)(SFMSc)perovskite oxide material is synthesized via solid-phase method as the cathode for CO_(2)electrolysis by SOECs.XRD confirms that SFMSc exhibits a stable cubic phase crystal structure.The experimental results of TPD,TG,EPR,CO_(2)-TPD further demonstrate that Sc-doping increases the concentration of oxygen vacancy in the material and the chemical adsorption capacity of CO_(2)molecules.Electrochemical tests reveal that SFMSc single cell achieves a current density of 2.26 A/cm^(2) and a lower polarization impedance of 0.32Ω·cm^(2) at 800°C under the applied voltage of 1.8 V.And no significant performance attenuation or carbon deposition is observed after 80 h continuous long-term stability test.This study provides a favorable support for the development of SOEC cathode materials with good electro-catalytic performance and stability.

Advancements in chromium-tolerant air electrode for solid oxide cells:A mini-review

Solid oxide cells(SOCs)are emerging devices for efficient energy storage and conversion.However,during SOC operation,gaseous chromium(Cr)species released from Fe-Cr alloy interconnect can lead to Cr deposition and poisoning of air electrodes,causing substantial degradation in electrochemical performance and compromising the longterm stability of SOCs.This mini-review examines the mechanism of Cr deposition and poisoning in air electrodes under both fuel-cell and electrolysis modes.Furthermore,emphasis is placed on the recent advancements in strategies to mitigate Cr poisoning,offering insights into the rational design and development of active and Cr-tolerant air electrodes for SOCs.

A high entropy stabilized perovskite oxide La_(0.2)Pr_(0.2)Sm_(0.2)Gd_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_(3−δ)as a promising air electrode for reversible solid oxide cells

Reversible solid oxide cell(RSOC)is a new energy conversion device with significant applications,especially for power grid peaking shaving.However,the reversible conversion process of power generation/energy storage poses challenges for the performance and stability of air electrodes.In this work,a novel high-entropy perovskite oxide La_(0.2)Pr_(0.2)Gd_(0.2)Sm_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_(3−δ)(HE-LSCF)is proposed and investigated as an air electrode in RSOC.The electrochemical behavior of HE-LSCF was studied as an air electrode in both fuel cell and electrolysis modes.The polarization impedance(Rp)of the HE-LSCF electrode is only 0.25Ω·cm^(2) at 800℃ in an air atmosphere.Notably,at an electrolytic voltage of 2 V and a temperature of 800℃,the current density reaches up to 1.68 A/cm^(2).The HE-LSCF air electrode exhibited excellent reversibility and stability,and its electrochemical performance remains stable after 100 h of reversible operation.With these advantages,HE-LSCF is shown to be an excellent air electrode for RSOC.

Precision oncology: The role of minimally-invasive ablation therapy in the management of solid organ tumors

Solid organ tumors present a significant healthcare challenge,both economically and logistically,due to their high incidence and treatment complexity.In 2023,out of the 1.9 million new cancer cases in the United States,over 73%were solid organ tumors.Ablative therapies offer minimally invasive solutions for malignant tissue destruction in situ,often with reduced cost and morbidity compared to surgical resection.This review examines the current Food and Drug Administration-approved locoregional ablative therapies(radiofrequency,microwave,cryogenic,high-intensity focused ultrasound,histotripsy)and their evolving role in cancer care.Data were collected through a comprehensive survey of the PubMed-inde-xed literature on tumor ablation techniques,their clinical indications,and outco-mes.Over time,emerging clinical data will help establish these therapies as the standard of care in solid organ tumor treatment,supported by improved long-term outcomes and progression-free survival.

Heavy-metal contents in suspended solids of Meiliang Bay,Taihu Lake and its environmental significances

Surface water was taken from river mouth to the central area of Meiliang Bay, Taihu Lake, a large shallow eutrophic lake in China. Suspended solids were condensed by centrifugation 25 L surface water samples from each selected site. Suspended solids and surface sediments were further freeze-dried and microwave digested before determining the metals by ICP-AES. Among the metals analyzed in suspended solids and sediments, contents of Cr, Cu, Mn, Ni, and Zn in suspended solids were significantly higher than those in sediments while contents of Al, Ba, Be, Ca, Co, Fe, K, Mg, Pb, and V in suspended solids were 10%—30% higher than those in sediments. Sr and Ti contents in suspended solids and sediments were very similar. Na content in suspended solids was lower than that in sediments. Heavy metals were significantly accumulated in suspended solids. From the river mouth to the center of Meiliang Bay, contents of Cr, Cu, Pb, and Zn in suspended solids showed a gradual decreasing trend indicating the river(Zhihugang River) still discharged large quantity of heavy metals to Meiliang Bay. The study suggests that the geochemical behaviors and ecological effects of heavy metals in suspended solids may serve as a good indicator for the pollution of lake.

Prediction of the amount of urban waste solids by applying a gray theoretical model

Urban waste solids are now becoming one of the most crucial environmental problems. There are several different kinds of technologies normally used for waste solids disposal, among which landfill is more favorable in China than others, especially for urban waste solids. Most of the design works up to now are based on a roughly estimation of the amount of urban waste solids without any theoretical support, which lead to a series problems. To meet the basic information requirements for the design work, the amount of the urban waste solids was predicted in this research by applying the gray theoretical model GM (1,1) through non linear differential equation simulation. The model parameters were estimated with the least square method (LSM) by running a certain MATALAB program, and the hypothesis test results show that the residual between the prediction value and the actual value approximately comply with the normal distribution N (0,0 21 2), and the probability of the residual within the range (-0 17, 0 19) is more than 95%, which indicate obviously that the model can be well used for the prediction of the amount of waste solids and those had been already testified by the latest two years data about the urban waste solids from Loudi City of China. With this model, the predicted amount of the waste solids produced in Loudi City in the next 30 years is 8049000 ton in total.

The migration of total dissolved solids during natural freezing process in Ulansuhai Lake

High total dissolved solids （TDS） content is one of the most important pollution contributors in lakes in arid and semiarid areas. Ulansuhai Lake, located in Urad Qianqi, Inner Mongolia, China, was selected as the object of study. Temperatures and TDS contents of both ice and under-ice water were collected together with corresponding ice thickness. TDS profiles were drawn to show the distribution of TDS and to describe TDS migration. The results showed that about 80% （that is 3.602x108 kg） of TDS migrated from ice to water during the whole growth period of ice. Within ice layer, TDS migration only occurred during initial ice-on period, and then perished. The TDS in ice decreased with increasing ice thickness, following a negative exponential-like trend. Within un- der-ice water, the TDS migrated from ice-water interface to the entire water column under the effect of concentra- tion gradient until the water TDS content was uniform. In winter, 6.044x 107 kg （16.78% of total TDS） TDS migrated from water to sedirnent, which indicated that winter is the best time for dredging sediment. The migration effect gives rise to TDS concentration in under-ice water and sediment that is likely to affect ecosystem and water quality of the Yellow River. The trend of transfer flux of ice-water and water-sediment interfaces is similar to that of ice growth rate, which reveals that ice growth rate is one of the determinants of TDS migration. The process and mechanism of TDS migration can be referenced by research on other lakes with similar TDS content in cold and arid areas.

Application Fourier transform near infrared spectrometer in rapid estimation of soluble solids content of intact citrus fruits

Nondestructive method of measuring soluble solids content (SSC) of citrus fruits was developed using Fourier transform near infrared reflectance (FT-NIR) measurements collected through optics fiber. The models describing the relationship between SSC and the NIR spectra of citrus fruits were developed and evaluated. Different spectra correction algorithms (standard normal variate (SNV), multiplicative signal correction (MSC)) were used in this study. The relationship between laboratory SSC and FT-NIR spectra of citrus fruits was analyzed via principle component regression (PCR) and partial least squares (PLS) re- gression method. Models based on the different spectral ranges were compared in this research. The first derivative and second derivative were applied to all spectra to reduce the effects of sample size, light scattering, instrument noise, etc. Different baseline correction methods were applied to improve the spectral data quality. Among them the second derivative method after baseline correction produced best noise removing capability and yielded optimal calibration models. A total of 170 NIR spectra were acquired; 135 NIR spectra were used to develop the calibration model; the remaining spectra were used to validate the model. The developed PLS model describing the relationship between SSC and NIR reflectance spectra could predict SSC of 35 samples with correlation coefficient of 0.995 and RMSEP of 0.79 °Brix.

Three-dimensional Reconstruction of Geological Solids Based on Section Topology Reasoning

In order to solve the dynamic reconstruction and local updating problem of three-dimensional geological solids, topology reasoning is used for three-dimensional geological modeling. This can advance the level of the corresponding section automation in implementing the 3D geological solid dynamical reconstruction by the construction of and reasoning on topology on the 3D curved surface. This method has been successfully used in the Nanjing city geological modeling and the Zijin gold mine modeling. The results prove that this method adapts to coplanar section and noncoplanar section data, and improves the efficiency of 3D geological modeling.

Chemistry under extreme conditions: Pressure evolution of chemical bonding and structure in dense solids

Recent advances in high-pressure technologies and large-scale experimental and computational facilities have enabled scientists,at an unprecedented rate,to discover and predict novel states and materials under the extreme pressure-temperature conditions found in deep,giant-planet interiors.Based on a well-documented body of work in this field of high-pressure research,we elucidate the fundamental principles that govern the chemistry of dense solids under extreme conditions.These include:(i)the pressure-induced evolution of chemical bonding and structure of molecular solids to extended covalent solids,ionic solids and,ultimately,metallic solids,as pressure increases to the terapascal regime;(ii)novel properties and complex transition mechanisms,arising from the subtle balance between electron hybridization(bonding)and electrostatic interaction(packing)in densely packed solids;and(iii)new dense framework solids with high energy densities,and with tunable properties and stabilities under ambient conditions.Examples are taken primarily fromlow-Z molecular systems that have scientific implications for giant-planet models,condensed materials physics,and solid-state core-electron chemistry.

An Experimental Approach for Detection of the Acoustic Radiation Induced Static Component in Solids

We propose an experimental approach to directly detect the acoustic radiation induced static component(SC)of primary longitudinal(L)wave propagation in solids using an ultrasonic pitch-catch technique,where a lowfrequency ultrasonic transducer is used to detect the SC generated by the co-propagating primary L-wave tone burst that is excited by a high-frequency ultrasonic transducer.Essentially,the experimental approach proposed uses a dynamic method to detect the SC generated.The basic requirement is that the central frequency of the low-frequency ultrasonic transducer needs to be near the center of the main lobe frequency range of the time-domain envelope of the primary L-wave tone burst.Under this condition,the main lobe of the frequency spectrum of the SC pulse generated adequately overlaps with that of the low-frequency ultrasonic transducer.This will enable the generated SC pulse to be directly detected by the low-frequency ultrasonic transducer.The performed experimental examination validates the feasibility and effectiveness of the proposed approach for direct detection of the acoustic radiation induced SC generated by L-wave propagation in solids.