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Tuning the solubility of polysulfides for constructing practical lithium-sulfur battery
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作者 Jiapeng Li Jianlong Cong +3 位作者 Haijin Ji Ting Shi Lixia Yuan Yunhui Huang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期611-617,I0013,共8页
Li-S batteries are regarded as one of the most promising candidates for next-generation battery systems with high energy density and low cost.However,the dissolution-precipitation reaction mechanism of the sulfur(S)ca... Li-S batteries are regarded as one of the most promising candidates for next-generation battery systems with high energy density and low cost.However,the dissolution-precipitation reaction mechanism of the sulfur(S)cathode enhances the kinetics of the redox processes of the insulating sulfu r,which also arouses the notorious shuttle effect,leading to serious loss of S species and corrosion of Li anode.To get a balance between the shuttle restraining and the kinetic property,a combined strategy of electrolyte regulation and cathode modification is proposed via introducing 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoroprpyl ether(HFE)instead of 1,2-dimethoxyethane(DME),and SeS_(7)instead of S_8.The introduction of HFE tunes the solvation structure of the LiTFSI and the dissolution of intermediate polysulfides with Se doping(LiPSSes),and optimize the interface stability of the Li anode simultaneously.The minor Se substitution compensates the decrease in kinetic due to the decreased solubility of LiPSs.In this way,the Li-SeS_(7)batteries deliver a reversible capacity of 1062 and 1037 mAh g^(-1)with 2.0 and 5.5 mg SeS_(7)cm^(-2)loading condition,respectively.Besides,an electrolyte-electrode loading model is established to explain the relationship between the optimal electrolyte and cathode loading.It makes more sense to guide the electrolyte design for practical Li-S batteries. 展开更多
关键词 Li-S batteries Lithium polysulfides solubility Shuttle effect Interface Se doping
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Solubility determination and comparison ofβ-HMX and RDX in two binary mixed solvents(acetonitrile+water,nitric acid+water)
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作者 Yuehua Yao Fan Wang +3 位作者 Yinguang Xu Zishuai Xu Lizhen Chen Jianlong Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期238-249,共12页
In order to remove hexahydro-1,3,5-trinitro-1,3,5-triazine(RDX),the main impurity,in process of polymorphic transformation of octrahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine(HMX),the solubility ofβ-HMX and RDX in a... In order to remove hexahydro-1,3,5-trinitro-1,3,5-triazine(RDX),the main impurity,in process of polymorphic transformation of octrahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine(HMX),the solubility ofβ-HMX and RDX in acetonitrile(ACN)+water in the temperature range of 288.15-333.15 K and in nitric acid(HNO_(3))+water in the temperature range of 298.15-333.15 K were measured by laser dynamic method.The results showed that the solubility of bothβ-HMX and RDX in binary mixed solvents increased monotonously as the temperature increase at a given solvent composition or with increasing of mole fraction of solvent(ACN and nitric acid).Solubility data were well correlated by the modified Apelblat equation,Jouyban-Acree model,Yaws equation and van't Hoff equation,and the Yaws equation achieved the best fitting results according to the relative error and the mean square error root.Furthermore,the solubility ofβ-HMX and RDX in binary mixed solvent was compared,based on the solubility difference and the solvent's own properties,the best separation degree ofβ-HMX and RDX was found when the mole fraction of nitric acid was 0.22 at room temperature,which provided data support for HMX crystallization in mixed solvent.The solubility differences between RDX andβ-HMX in mixed solvents were explained from the formation of intermolecular and intramolecular hydrogen bonds. 展开更多
关键词 solubility Octrahydro-1 3 5 7-tetranitro-1 3 5 7-tetrazocine Hexahydro-1 3 5-trinitro-1 3 5-triazine Separation Model Hydrogen bond
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Study of the Relationship Between New Ionic Interaction Parameters and Salt Solubility in Electrolyte Solutions Based on Molecular Dynamics Simulation
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作者 SUN Wenting HU Yangdong +5 位作者 ZHENG Jiahuan SUN Qichao Chen Xia DING Jiakun ZHANG Weitao WU Lianying 《Journal of Ocean University of China》 CAS CSCD 2024年第2期467-476,共10页
Studying the relationship between ionic interactions and salt solubility in seawater has implications for seawater desalination and mineral extraction.In this paper,a new method of expressing ion-to-ion interaction is... Studying the relationship between ionic interactions and salt solubility in seawater has implications for seawater desalination and mineral extraction.In this paper,a new method of expressing ion-to-ion interaction is proposed by using molecular dynamics simulation,and the relationship between ion-to-ion interaction and salt solubility in a simulated seawater water-salt system is investigated.By analyzing the variation of distance and contact time between ions in an electrolyte solution,from both spatial and temporal perspectives,new parameters were proposed to describe the interaction between ions:interaction distance(ID),and interaction time ratio(ITR).The best correlation between characteristic time ratio and solubility was found for a molar ratio of salt-to-water of 10:100 with a correlation coefficient of 0.96.For the same salt,a positive correlation was found between CTR and the molar ratio of salt and water.For type 1-1,type 2-1,type 1-2,and type 2-2 salts,the correlation coefficients between CTR and solubility were 0.93,0.96,0.92,and 0.98 for a salt-to-water molar ratio of 10:100,respectively.The solubility of multiple salts was predicted by simulations and compared with experimental values,yielding an average relative deviation of 12.4%.The new ion-interaction parameters offer significant advantages in describing strongly correlated and strongly hydrated electrolyte solutions. 展开更多
关键词 molecular dynamics simulation interaction distance interaction time rate electrolyte aqueous solutions solubility
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Theoretical analysis of hydrogen solubility in direct coal liquefaction solvents
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作者 Xiaobin Zhang Aoqi Wang +1 位作者 Xingbao Wang Wenying Li 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第2期187-197,共11页
The cyclic hydrogenation technology in a direct coal liquefaction process relies on the dissolved hydrogen of the solvent or oil participating in the hydrogenation reaction.Thus,a theoretical basis for process optimiz... The cyclic hydrogenation technology in a direct coal liquefaction process relies on the dissolved hydrogen of the solvent or oil participating in the hydrogenation reaction.Thus,a theoretical basis for process optimization and reactor design can be established by analyzing the solubility of hydrogen in liquefaction solvents.Experimental studies of hydrogen solubility in liquefaction solvents are challenging due to harsh reaction conditions and complex solvent compositions.In this study,the composition and content of liquefied solvents were analyzed.As model compounds,hexadecane,toluene,naphthalene,tetrahydronaphthalene,and phenanthrene were chosen to represent the liquefied solvents in chain alkanes and monocyclic,bicyclic,and tricyclic aromatic hydrocarbons.The solubility of hydrogen X(mol/mol)in pure solvent components and mixed solvents(alkanes and aromatics mixed in proportion to the chain alkanes+bicyclic aromatic hydrocarbons,bicyclic saturated aromatic hydrocarbons+bicyclic aromatic hydrocarbons,and bicyclic aromatic hydrocarbons+compounds containing het-eroatoms composed of mixed components)are determined using Aspen simulation at temperature and pressure conditions of 373–523 K and 2–10 MPa.The results demonstrated that at high temperatures and pressures,the solubility of hydrogen in the solvent increases with the increase in temperature and pressure,with the pressure having a greater impact.Further-more,the results revealed that hydrogen is more soluble in straight-chain alkanes than in other solvents,and the solubility of eicosanoids reaches a maximum of 0.296.The hydrogen solubility in aromatic ring compounds decreased gradually with an increase in the aromatic ring number.The influence of chain alkanes on the solubility of hydrogen predominates in a mixture of solvents with different mixing ratios of chain alkanes and aromatic hydrocarbons.The solubility of hydrogen in mixed aromatic solvents is less than that in the corresponding single solvents.Hydrogen is less soluble in solvent compounds containing heteroatoms than in compounds without heteroatoms. 展开更多
关键词 Direct coal liquefaction Liquefaction solvents Process simulation Hydrogen solubility
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Solubility of iron(Ⅲ) and nickel(Ⅱ) acetylacetonates in supercritical carbon dioxide
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作者 Haixin Sun Jianlei Qi +4 位作者 Jianfei Sun Lin Li Kunpeng Yu Jintao Wu Jianzhong Yin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期29-34,共6页
As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates hav... As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates have shown great potential for the preparation of single-atom catalytic materials.In this study,the solubilities of iron(Ⅲ)acetylacetonate(Fe(acac)3)and nickel(Ⅱ)acetylacetonate(Ni(acac)2)were measured at the temperature from 313.15 to 333.15 K and in the pressure range of 9.5–25.2 MPa to accumulate new solubility data.Solubility was measured using a static weight loss method.The semi-empirical models proposed by Chrastil and Sung et al.were used to correlate the solubility data of Fe(acac)3 and Ni(acac)2.The equations obtained can be used to predict the solubility of the same system in the experimental range. 展开更多
关键词 Iron(III)acetylacetonate Nickel(II)acetylacetonate Supercritical carbon dioxide solubility measurement Correlation model Phase equilibrium
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RETRACTED: Determination of the Mesalazine Solubility at Biorelevant Temperature
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作者 Ekin Güler Kader Poturcu +1 位作者 Elaheh Rahimpour Abolghasem Jouyban 《International Journal of Analytical Mass Spectrometry and Chromatography》 2024年第1期1-12,共14页
Short Retraction NoticeThis article has been retracted to straighten the academic record. In making this decision the Editorial Board follows COPE's Retraction Guidelines. The aim is to promote the circulation of ... Short Retraction NoticeThis article has been retracted to straighten the academic record. In making this decision the Editorial Board follows COPE's Retraction Guidelines. The aim is to promote the circulation of scientific research by offering an ideal research publication platform with due consideration of internationally accepted standards on publication ethics. The Editorial Board would like to extend its sincere apologies for any inconvenience this retraction may have caused. The full retraction notice in PDF is preceding the original paper, which is marked "RETRACTED". 展开更多
关键词 MESALAZINE solubility Shake-Flask Method Biorelevant Temperature XRD
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Preparation, characterization and evaluation of kaempferol phospholipid complex: Improvement of its solubility and biological effect
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作者 Dezhi Gao Honghui Zhao +4 位作者 Fengmao Zou Ming Yang Jing Wang Lina Fang Xu Zhao 《Journal of Polyphenols》 2024年第2期56-64,共9页
Kaempferol(KA),as one of the flavonoids,has extensive pharmacological properties.However,the poor solubility of KA severely limits its clinical application.In our study,the kaempferol phospholipid complex(KA-PC)has be... Kaempferol(KA),as one of the flavonoids,has extensive pharmacological properties.However,the poor solubility of KA severely limits its clinical application.In our study,the kaempferol phospholipid complex(KA-PC)has been prepared by solvent evaporation for the enhancement of the bioavailability of KA.KA-PC was verified by scanning electron microscope characterization methods.Drug loading,solubility and long-term stability were measured.The characterization results showed that KA-PC was formed through the intermolecular interaction between KA and phospholipids.The solubility of KA-PC in water was 189 times higher than that of KA,and the solubility in n-octanol was also significantly improved.Besides,pharmacodynamic studies showed that KA-PC can significantly reduce the level of serum uric acid in mice without causing renal injury.This study expanded the clinical application of KA by preparing KA-PC. 展开更多
关键词 KAEMPFEROL phospholipid complex solubility uric acid-lowering effect
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Solubility measurement,correlation and thermodynamic properties of 2,3,4-trichloro-1,5-dinitrobenzene in fifteen mono-solvents at temperatures from 278.15 to 323.15 K 被引量:1
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作者 Yun-Zhang Liu Lu-Yao Zhang +3 位作者 Dan He Li-Zhen Chen Zi-Shuai Xu Jian-Long Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第6期224-233,共10页
The solubility of 2,3,4-trichloro-1,5-dinitrobenzene(TCDNB) was measured by a laser dynamic method over the temperature range from 278.15 K to 323.15 K under 0.1 MPa in fifteen mono-solvents(methanol,ethanol,isopropan... The solubility of 2,3,4-trichloro-1,5-dinitrobenzene(TCDNB) was measured by a laser dynamic method over the temperature range from 278.15 K to 323.15 K under 0.1 MPa in fifteen mono-solvents(methanol,ethanol,isopropanol,n-butanol,toluene,dichloromethane,chloroform,tetrachloromethane,1,2-dichloroethane,acetone,ethyl acetate,acetonitrile,N-methylpyrrolidone(NMP),N,Ndimethylformamide dimethyl sulfoxide(DMF),dimethyl sulfoxide(DMSO).The solubility of TCDNB could be increased with increasing temperature in fifteen mono-solvents.TCDNB solubility is in the following order at 298.15 K:NMP>DMF>DMSO>toluene>acetone>ethyl acetate>dichloromethane>1,2-dich loroethane>chloroform>acetonitrile>tetrachloromethane>methanol>ethanol>n-butanol>isopropanol.The KAT-LSER model was used to investigate the solvent effect,which revealed that the hydrogen bond acidity of solvents has a greater effect on TCDNB solubility.The van't Hoff model,the modified Apelblat model,theλh model,and the non-random two liquid(NRTL)model were used to correlate the solubility of TCDNB.The calculated solubility data agreed well with the experimental data,and the modified Apelblat model fit best.Furthermore,the van't Hoff and Gibbs equations were also used to calculate the dissolution thermodynamic properties of TCDNB in various solvents.TCDNB dissolution could be an enthalpy-driven,non-spontaneous,and endothermic process in fifteen mono-solvents.The determination and fitting solubility of TCDNB,as well as the calculation of its thermodynamic properties,would be critical in the purification and crystallization of its preparation process research. 展开更多
关键词 2 3 4-Trichloro-1 5-dinitrobenzene(TCDNB) Solid-liquid equilibrium Laser dynamic method solubility model Thermodynamics properties
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Solubility study and selective purification of HMX explosive in organic electrolyte solution of zinc acetate/diethylene glycol
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作者 Javad Ghorbani Sajjad Damiri Hamid Reza Pouretedal 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第11期15-23,共9页
In this study, an organic electrolyte solution based on zinc acetate/diethylene glycol(ZA/DEG) is introduced for the selective purification of cyclotetramethylene tetranitramine(HMX) high explosive from its identical ... In this study, an organic electrolyte solution based on zinc acetate/diethylene glycol(ZA/DEG) is introduced for the selective purification of cyclotetramethylene tetranitramine(HMX) high explosive from its identical homologue cyclotrimethylene trinitramine(RDX). The dielectric constant of various organic solutions were investigated through Electrochemical Impedance Spectroscopy(EIS) in the range of 1.0 Hz—30 MHz. and some quantum-chemical descriptors of RDX and HMX dissolutions in the ZA cosolvent were analyzed using Density Functional Theory(DFT). The results show dielectric constant and solubility of RDX is higher than that of HMX, and by increasing of ZA concentration in DEG solvent, the values of dielectric constants were enhanced. Furthermore, the presence of ZA cosolvent on the solubility of two explosives was statistically investigated by Central Composite Design(CCD) of experiment, and some solubility parameters including activity coefficient, dissolving enthalpy, and mixing enthalpies were determined. The experimental results indicate that the weight ratio of RDX to HMX solubility in the proposed organic electrolyte changes up to 30 times, which provides a selective and sequential separation method to separate two materials with similar chemical properties with a separation efficiency>98% and HMX purity> 99.8%. The X-Ray Diffraction(XRD) analysis, High-Performance Liquid Chromatography(HPLC), Laser-Induced Breakdown Spectroscopy(LIBS), and Fourier Transform Infrared Spectroscopy(FT-IR) approves the acceptable quality of the separated materials. The proposed method makes the efficient and safe purification of high-quality HMX for application in oil and gas well perforating gun charges, using a nonvolatile and inflammable organic electrolyte. 展开更多
关键词 Organic electrolyte PURIFICATION solubility HMX RDX Diethylene glycol
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Measurement and model of density,viscosity,and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid
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作者 Zhonghao Li Yuanyuan Yang +7 位作者 Huanong Cheng Yun Teng Chao Li Kangkang Li Zhou Feng Hongwei Jin Xinshun Tan Shiqing Zheng 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第7期210-221,共12页
The density and viscosity of ferric chloride/trioctylmethylammonium chloride ionic liquid(rFeCl_(3)/[A336]Cl)with different molar ratios(r=0.1-0.8)of FeCl_(3) to[A336]Cl were measured at temperatures from 313.15 to 35... The density and viscosity of ferric chloride/trioctylmethylammonium chloride ionic liquid(rFeCl_(3)/[A336]Cl)with different molar ratios(r=0.1-0.8)of FeCl_(3) to[A336]Cl were measured at temperatures from 313.15 to 358.15 K and atmospheric pressure.The density and viscosity data were fitted by the relevant temperature variation equations,respectively.The variation of density and viscosity with temperature and r was obtained.The solubility of rFeCl_(3)/[A336]Cl to H_2S was measured at temperatures from 318.15 to 348.15 K and pressures from 0 to 150 kPa.The effects of temperature,pressure,and r on the solubility of H_(2)S were discussed.The reaction equilibrium thermodynamic model(RETM)was used to fit the H_(2)S solubility data,and the average relative error was less than 1.3%,indicating that the model can relate the solubility data well.And Henry's constant and chemical reaction equilibrium constant were obtained by the RETM fitting.The relationships of Henry's constant and chemical reaction equilibrium constant with temperature and r were analyzed. 展开更多
关键词 Ionic liquids Hydrogen sulfide solubility Henry's constant Chemical reaction equilibrium constant Model
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Solubility study of hydrogen in direct coal liquefaction solvent based on quantitative structure–property relationships model
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作者 Xiao-Bin Zhang A.Rajendran +1 位作者 Xing-Bao Wang Wen-Ying Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第12期250-258,共9页
Direct coal liquefaction(DCL)is an important and effective method of converting coal into high-valueadded chemicals and fuel oil.In DCL,heating the direct coal liquefaction solvent(DCLS)from low to high temperature an... Direct coal liquefaction(DCL)is an important and effective method of converting coal into high-valueadded chemicals and fuel oil.In DCL,heating the direct coal liquefaction solvent(DCLS)from low to high temperature and pre-hydrogenation of the DCLS are critical steps.Therefore,studying the dissolution of hydrogen in DCLS under liquefaction conditions gains importance.However,it is difficult to precisely determine hydrogen solubility only by experiments,especially under the actual DCL conditions.To address this issue,we developed a prediction model of hydrogen solubility in a single solvent based on the machine-learning quantitative structure–property relationship(ML-QSPR)methods.The results showed that the squared correlation coefficient R^(2)=0.92 and root mean square error RMSE=0.095,indicating the model’s good statistical performance.The external validation of the model also reveals excellent accuracy and predictive ability.Molecular polarization(a)is the main factor affecting the dissolution of hydrogen in DCLS.The hydrogen solubility in acyclic alkanes increases with increasing carbon number.Whereas in polycyclic aromatics,it decreases with increasing ring number,and in hydrogenated aromatics,it increases with hydrogenation degree.This work provides a new reference for the selection and proportioning of DCLS,i.e.,a solvent with higher hydrogen solubility can be added to provide active hydrogen for the reaction and thus reduce the hydrogen pressure.Besides,it brings important insight into the theoretical significance and practical value of the DCL. 展开更多
关键词 Hydrogen solubility Liquefied solvents Predictive model Density generalized function theory Quantitative structure-property RELATIONSHIP
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Enhancing effect of choline chloride-based deep eutectic solvents with polyols on the aqueous solubility of curcumin–insight from experiment and theoretical calculation
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作者 Wen Yu Yiyang Bo +3 位作者 Yiling Luo Xiyan Huang Rixiang Zhang Jiaheng Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第7期160-168,共9页
The development of green solvents for enhancing aqueous solubility of drug curcumin remains a challenge. This study explores the enhancing effect of deep eutectic solvents(DESs) on the aqueous solubility of curcumin(C... The development of green solvents for enhancing aqueous solubility of drug curcumin remains a challenge. This study explores the enhancing effect of deep eutectic solvents(DESs) on the aqueous solubility of curcumin(CUR) via experiment and theoretical calculation. Choline chloride-based DESs with polyols 1,2-propanediol(1,2-PDO), 1,3-propanediol, ethylene glycol, and glycerol as hydrogen bond donors were prepared and used as co-solvents. The CUR aqueous solubility increased with increasing the DESs content at temperature of 303.15-318.15 K, especially in aqueous ChCl/1,2-PDO(mole ratio 1:4) solutions. The positive apparent molar volume values and reduced density gradient analysis confirmed the existence of strong interactions between CUR and solvent. The van der Waals interactions and hydrogen bonding coexisted in DESs monomer retained the stability of DESs structure after introducing CUR. Moreover,the lower interaction energy of DESs…CUR system than that of the counterpart DESs further proved the strong interaction between CUR and DESs. The lowest interaction energy of ChCl/1,2-PDO…CUR system indicated that this system was the most stable and ChCl/1,2-PDO was promising for CUR dissolution.This work provides efficient solvents for utilizing curcumin, contributing to a deep insight into the interactions between DES and CUR at the molecular level, and the role of DESs on enhancing drugs solubility. 展开更多
关键词 Choline chloride-polyol Deep eutectic solvents CURCUMIN Aqueous solubility Theoretical calculation
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Measurement and correlation of solubility of 9-fluorenone in 11 pure organic solvents from T = 283.15 to 323.15 K
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作者 Huiqi Wang Jianpo Ren +5 位作者 Shihao Zhang Jiayu Dai Yue Niu Ketao Shi Qiuxiang Yin Ling Zhou 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第8期235-241,共7页
In this work, the solubility data of 9-fluorenone in 11 pure solvents(methanol, ethanol, n-propanol, isopropanol, n-butanol, iso-butanol, acetonitrile, ethyl formate, ethyl acetate, dimethyl sulfoxide, n-hexane)were m... In this work, the solubility data of 9-fluorenone in 11 pure solvents(methanol, ethanol, n-propanol, isopropanol, n-butanol, iso-butanol, acetonitrile, ethyl formate, ethyl acetate, dimethyl sulfoxide, n-hexane)were measured by the gravimetric method from 278.15 K to 318.15 K under atmospheric pressure. The results showed that the solubility of 9-fluorenone in all tested solvents increased with the raised temperature. The solubility data were correlated by the modified Apelblat equation, λh model and NRTL(nonradom two fluid) model. The average relative deviation(ARD) correlated by three thermodynamic models in different solvents was all below 5%, which indicated that the three thermodynamic models fit the solubility data well. Furthermore, the mixing thermodynamic properties of 9-fluorenone in pure solvent systems were calculated via NRTL model. The results indicated the dissolution process of 9-fluorenone is spontaneous and entropically favorable. The solubility and the mixing thermodynamic properties provided in this paper would play an important role in industrial manufacture and follow-up operation of 9-fluorenone. 展开更多
关键词 9-Fluorenone solubility Correlation model Thermodynamic properties
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Experimental verification of nanonization enhanced solubility for poorly soluble optoelectronic molecules
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作者 Jingzhou Guo Yuanzuo Zou +4 位作者 Bo Shi Yuan Pu Jiexin Wang Dan Wang Jianfeng Chen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第8期8-15,共8页
Solubility enhancement has been a priority to overcome poor solubility with optoelectronic molecules for solution-processable devices. This study aims to obtain experimental data on the effect of particle sizes on the... Solubility enhancement has been a priority to overcome poor solubility with optoelectronic molecules for solution-processable devices. This study aims to obtain experimental data on the effect of particle sizes on the solubility properties of several typical optoelectronic molecules in organic solvents, including the solubility results of 1,3-bis(9-carbazolyl)benzene(m CP), 1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)ben zene(TPBi) and 2-(4-tert-butylphenyl)-5-(4-biphenyl)-1,3,4-oxadiazole(PBD) in ethanol and acetonitrile,respectively. Nanoparticles of m CP, TPBi and PBD with sizes from dozens to several hundred nanometers were prepared by solvent antisolvent precipitation method and their solubility were determined by using isothermal saturation method. The saturation solubility of nanoparticles of three kinds of optoelectronic molecules exhibited increase of 12.9%-25.7% in comparison to the same raw materials in the form of microparticles. The experimental evidence indicates that nanonization technology is a feasible way to make optoelectronic molecules dissolve in liquids with enhanced solubility. 展开更多
关键词 Nanonization solubility enhancement Optoelectronic molecules Solution processing
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Solubility of water in bridgmanite
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作者 Wenhua Lu Yuan Li 《Acta Geochimica》 EI CAS CSCD 2023年第6期998-1006,共9页
Water in Earth's mantle plays a critical role in both geodynamic and surficial habitability.Water in the upper mantle and transition zone is widely discussed,but less is known about the water in the lower mantle d... Water in Earth's mantle plays a critical role in both geodynamic and surficial habitability.Water in the upper mantle and transition zone is widely discussed,but less is known about the water in the lower mantle despite it constituting over half of Earth's mass.Understanding the water storage in Earth's lower mantle relies on comprehending the water solubility of bridgmanite,which is the most abundant mineral both in the lower mantle and throughout Earth.Nevertheless,due to limited access to the lower mantle,our understanding of water in bridgmanite mainly comes from laboratory experiments and theoretical calculations,and a huge controversy still exists.In this paper,we provide a review of the commonly employed research methods and current findings concerning the solubility of water in bridgmanite.Potential factors,such as pressure,temperature,compositions,etc.,that influence the water solubility of bridgmanite will be discussed,along with insights into future research directions. 展开更多
关键词 Water solubility Bridgmanite Lower mantle HABITABILITY
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大麻二酚递送体系的研究进展 被引量:1
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作者 谢洋 隋新 李鹏 《黑龙江科学》 2024年第6期9-11,15,共4页
大麻二酚因其在治疗疼痛、焦虑、神经及运动障碍等方面的作用而备受关注。但大麻二酚存在水溶性低、首过代谢效应及全身生物利用度较低的缺点,极大限制了它的应用。构建递送体系可改善大麻二酚的药代动力学特征和生物利用度。综述了近... 大麻二酚因其在治疗疼痛、焦虑、神经及运动障碍等方面的作用而备受关注。但大麻二酚存在水溶性低、首过代谢效应及全身生物利用度较低的缺点,极大限制了它的应用。构建递送体系可改善大麻二酚的药代动力学特征和生物利用度。综述了近年来用于提高大麻二酚溶解性及生物利用度的递送体系,分析了聚合物颗粒、脂质体、醇质体及环糊精递送体系的优势与局限性,展望了大麻二酚递送载体的发展方向,为开发新的大麻二酚纳米制剂提供参考。 展开更多
关键词 大麻二酚 递送体系 水溶性 生物利用度
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大豆地方种质资源鲜籽粒可溶性糖含量的全基因组关联分析 被引量:1
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作者 张玉梅 丁文涛 +5 位作者 蓝新隆 李清华 胡润芳 郭娜 林国强 赵晋铭 《中国农业科学》 CAS CSCD 北大核心 2024年第11期2079-2091,I0001-I0004,共17页
【目的】可溶性糖含量是鲜食大豆重要的品质性状之一,研究大豆鲜籽粒可溶性糖含量的遗传变异,深入解析可溶性糖含量的遗传机制,为鲜食大豆种质创新及品质育种提供依据。【方法】利用来自东北大豆生态区、北方大豆生态区、黄淮海大豆生... 【目的】可溶性糖含量是鲜食大豆重要的品质性状之一,研究大豆鲜籽粒可溶性糖含量的遗传变异,深入解析可溶性糖含量的遗传机制,为鲜食大豆种质创新及品质育种提供依据。【方法】利用来自东北大豆生态区、北方大豆生态区、黄淮海大豆生态区和南方大豆生态区的133份大豆地方种质,在2021年连江春季、福清春季和秋季3个环境下对鲜籽粒可溶性糖含量进行表型测定,结合82187个高质量SNP标记,基于混合线性模型MLM(Q+K)对可溶性糖含量进行全基因组关联分析,挖掘可溶性糖含量显著相关的SNP位点,并以显著SNP位点为中心,两端各扩展119.07 kb连锁不平衡衰减距离为候选区间,根据候选区间内基因的注释和组织表达信息预测候选基因。【结果】3个环境下,鲜籽粒可溶性糖含量的变异范围为3.37—33.84 mg·g^(-1),遗传变异系数为24.59%—32.69%,可溶性糖含量遗传率为68.14%。通过全基因组关联分析,连江春季、福清春季和秋季3个环境下分别检测到与鲜籽粒可溶性糖含量显著关联的SNP有6、8和22个,表型变异解释率为12.43%—29.27%,以表型变异解释率较高的9个显著SNP位点所在的候选区间进行搜索,共获得86个基因,结合基因注释和组织表达信息,进一步筛选到9个候选基因,主要涉及转录因子、糖蛋白家族和糖类合成转运等生物学过程。其中,Glyma.01g016500、Glyma.13g042100、Glyma.16g131800和Glyma.16g155300在大豆种子及荚中表达水平较高,可作为大豆鲜籽粒可溶性糖的最具潜力候选基因。【结论】通过全基因组关联分析,检测到36个与鲜籽粒可溶性糖含量显著关联的SNP,进一步筛选出9个候选基因可能参与大豆鲜籽粒可溶性糖含量的调控,其中,Glyma.01g016500、Glyma.13g042100、Glyma.16g131800和Glyma.16g155300可作为调控大豆鲜籽粒可溶性糖含量的关键目标基因。 展开更多
关键词 大豆 鲜籽粒 可溶性糖含量 全基因组关联分析 候选基因
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紫果西番莲‘满天星’二倍体与三倍体生长生理指标的比较
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作者 罗茜 朱雅静 +6 位作者 贺斌 陈诗 杨振欣 王雪 许玉兰 蔡年辉 王德新 《西南林业大学学报(自然科学)》 CAS 北大核心 2024年第3期27-34,共8页
以紫果西番莲‘满天星’二倍体与三倍体无菌苗为研究材料,测定不同年度生长阶段的生长和生理指标,比较其差异性,并进行相关性分析。结果表明:2种‘满天星’苗木的苗高、地径持续增长,表现出三倍体‘满天星’苗高较小、地径较大的特点。... 以紫果西番莲‘满天星’二倍体与三倍体无菌苗为研究材料,测定不同年度生长阶段的生长和生理指标,比较其差异性,并进行相关性分析。结果表明:2种‘满天星’苗木的苗高、地径持续增长,表现出三倍体‘满天星’苗高较小、地径较大的特点。同一位置叶片的叶片长、叶片宽、叶柄长随时间变化呈先增大后减小的趋势。随时间的变化2种‘满天星’的茎节数量逐渐一致,三倍体‘满天星’苗木表现出短粗的特征。在测定期中三倍体‘满天星’可溶性蛋白和叶绿素含量大于二倍体,测量前期可溶性糖含量小于二倍体,后期大于二倍体。不同倍性的西番莲的叶绿素a、叶绿素b、类胡萝卜素与苗高、茎节、地径呈负相关,与叶长、叶柄长呈正相关;但可溶性糖、可溶性蛋白与生长指标相关性略有差异。综上所述,三倍体与二倍体的生长生理指标存在差异,且可溶性糖、可溶性蛋白与生长指标相关性存在差异。 展开更多
关键词 紫果西番莲 生长指标 可溶性糖 可溶性蛋白 叶绿素
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黄河兰州段一株优势藻的分离鉴定及光照、pH、温度对其生长的影响
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作者 葸玉琴 雷赟 +2 位作者 赖金霞 孔维宝 张爱梅 《西北师范大学学报(自然科学版)》 2024年第1期52-60,共9页
为探究黄河兰州段水域的优势绿藻,从金牛街码头和中山桥水域采集水样,分离得到4株微藻,初步鉴定为小球藻属(Chlorella)、链带藻属(Desmodesmus)、近头状尖胞藻属(Raphidocelis)和空星藻属(Coelastrum),依次命名为Chlorella sp.HH13,Desm... 为探究黄河兰州段水域的优势绿藻,从金牛街码头和中山桥水域采集水样,分离得到4株微藻,初步鉴定为小球藻属(Chlorella)、链带藻属(Desmodesmus)、近头状尖胞藻属(Raphidocelis)和空星藻属(Coelastrum),依次命名为Chlorella sp.HH13,Desmodesmus sp.HH2C,Raphidocelis sp.HHTXZ和Coelastrum sp.HH4.4株藻培养9 d后生物量水平表现为HH13>HH2C>HHTXZ>HH4,选取HH13作为目标藻种探究其在最佳光照、pH和温度条件下的生物量、光合色素、可溶性蛋白以及可溶性糖的积累.在BG11培养基中培养HH13,确定最佳光照强度为6000 Lux,类胡萝卜素和总叶绿素含量达到最大值,分别为2.029和6.929 mg·g^(-1),可溶性糖和可溶性蛋白的含量也最高,分别为0.285%和7.661 mg·g^(-1);最佳pH值为7,生物量最高可达0.297 g·L^(-1),类胡萝卜素和总叶绿素含量达到最大值,分别为2.753和9.711 mg·g^(-1),可溶性糖和可溶性蛋白含量也最高,分别为0.484%和5.674 mg·g^(-1);最佳温度为28℃,生物量最高为0.289 g·L^(-1),类胡萝卜素和总叶绿素含量分别为1.796和6.073 mg·g^(-1),可溶性糖含量为0.288%,可溶性蛋白的含量为5.898 mg·g^(-1).最终得到HH13生长的最佳光照强度为6000 Lux、pH值为7、温度为28℃. 展开更多
关键词 微藻 分离鉴定 生物量 光合色素 可溶性蛋白 可溶性糖
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酸溶开孔筛管支撑完井工艺研究及应用
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作者 柳志翔 李会会 +3 位作者 邹伟 万小勇 王冲 马丁 《石油机械》 北大核心 2024年第6期38-44,共7页
为应对顺北断控油气藏支撑完井管柱无法穿越破碎带难题,研发了以高抗扭油管、酸溶开孔筛管和高抗扭液压丢手为关键技术的“酸溶开孔筛管”支撑完井工艺。设计的高抗扭油管和丢手器,满足下入期间旋转、钻磨对管柱抗扭能力的要求;设计的... 为应对顺北断控油气藏支撑完井管柱无法穿越破碎带难题,研发了以高抗扭油管、酸溶开孔筛管和高抗扭液压丢手为关键技术的“酸溶开孔筛管”支撑完井工艺。设计的高抗扭油管和丢手器,满足下入期间旋转、钻磨对管柱抗扭能力的要求;设计的酸溶开孔筛管,初始状态管体完全密封,完井液可循环至底端钻头,满足钻磨时冲洗钻头的要求,而注酸溶解可溶塞后管体变成带孔的筛管,又可满足储层改造和生产时大排量通道要求。通过开展一系列承压、耐盐、耐碱和酸溶等试验验证了工艺的可靠性。现场应用表明,酸溶开孔筛管支撑完井工艺有效解决了破碎带难以穿越的问题,已在现场应用6井次,支撑管柱到位率100%。该工艺简单可靠、便于现场操作,且与传统工艺相比,单井提高时效53.6%,节约费用90.0%。该成果可为其他类似井选择完井工艺提供参考。 展开更多
关键词 破碎带 支撑完井 高抗扭 酸溶开孔筛管 可溶塞
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