Structural and Optical Properties of Cu2+ + Ce3+ Co-Doped ZnO by Solution Combustion Method

In this work, ZnO, Ce3+ doped ZnO (ZnO/Ce3+) and Cu2+ + Ce3+ co-doped ZnO (ZnO/Cu2+ + Ce3+ ) solid solutions powders were synthesized by a solution combustion method maintaining the Ce3+ ion concentration constant in 3%Wt while the Cu2+ ion concentration was varied in 1, 2, 3, 10 and 20%Wt. After its synthesis, all the samples were annealed at 900?C by 24 h. The ZnO, ZnO/Ce3+ and ZnO/Cu2+ + Ce3+ powders were structurally characterized using X-ray diffraction (XRD) technique, and the XRD patterns showed that for pure ZnO, Cu2+ undoped ZnO/Ce3+ and ZnO/Ce3+ doped with the Cu2+ ion, the three samples exhibited the hexagonal wurtzite ZnO crystalline structure. However, the morphology and particle size of both samples were observed by means of a scanning electron microscopy (SEM);from SEM image, it is observed that the crystallites of both samples are agglomerated forming bigger amorphous particles with an approximate average size of 1 μm. In addition, the photoluminescence of the ZnO, Ce3+ doped ZnO and Cu2+ + Ce3+ doped ZnO samples was measurement under an illumination of 209 nm wavelength (UV region): for the ZnO/Ce3+ sample, your emission spectrum is in the visible region from blue color until red color;the UV band of the ZnO is suppressed. The multicolor emission visible is attributed to the Ce3+ ion photoluminescence, while for the ZnO/Cu2+ + Ce3+, its emission PL spectrum is quenching by the Cu2+ ion, present in the ZnO crystalline.

A modified solution combustion method to superfine Gd_2O_3:Eu^(3+) phosphor:preparation,phase transformation and optical properties

Cubic and monoclinic Gd2O3:Eu3+ phosphors in the range of nano-scale and submicron-scale were prepared by a modified solution combustion method.Coexistence of cubic and monoclinic phases was found in the highest luminescent sample synthesized at 600 oC.In relation to commercial sample,the relative luminescence intensity was 49.8%.The shape of emission spectrum of the sample thus changed and the charge-transfer-state band of excitation spectrum slightly shift toward higher energies.With increasing the anneal...

Characterization and photoluminescence of Lu_2O_3-Eu^(3+) nano-phosphor prepared by modified solution combustion method

Nanoscale Lu2O3：Eu3＋ phosphor was prepared by a modified solution combustion method using urea and acrylamide monomer.The particle sizes and photoluminescent properties of nano-phosphor were closely related to the molar ratio of urea-to-RE nitrates and acrylamide monomer-to-RE nitrates.The as-prepared samples with the sizes of 9.6-11.6 nm were characterized by X-ray diffraction,scanning electron microscopy,transmission electron microscopy and energy dispersive spectrometer.Lu2O3：Eu3＋ nano-phosphor that depicted high photoluminescence in the size around 10 nm was reported.Compared with the sample prepared by solid state reaction,the photoluminescence of sample was increased sufficiently to be 45.1%.The emission spectra of the samples presented the typical emission from 5D0 level to 7FJ（J=0,1,2,3,4） level of the Eu3＋ ion.

Solution combustion synthesis and luminescence properties of (Y,Gd)Al_3(BO_3)_4:Eu^(3+) phosphors

Ultrafine Y0.95–xGdxEu0.05Al3(BO3)4 phosphors with different Gd3+ concentrations were prepared by a solution combustion method, and characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM). Results showed that the pure phase of YAl3(BO3)4 was obtained at 1000 oC and the prepared particle size varied with calcining temperatures. Photoluminescence spectra indicated that the dominant emission peak was observed at 612 nm due to the 5D0→7F2 transition of Eu3+. The luminescence intensity of ...