REE abundances in sulfides from the Huize Zn-Pb ore field were determined with the ICPMS after preconcentration. The REE abundances in 26 sulfide samples （including pyrite, galena and sphalerite） are very low, with ...REE abundances in sulfides from the Huize Zn-Pb ore field were determined with the ICPMS after preconcentration. The REE abundances in 26 sulfide samples （including pyrite, galena and sphalerite） are very low, with the ~REE ranging from 1.6×10^-9 to 166.8×10^-9. Their LREE/HREE ratios range from 7.6 to 98, showing LREE enrichment relatively. The JEu values are below 1, indicating that they were deposited from an Eu-depleted and reducing fluid-system. Similar to the ore-hosting carbonate strata, calcite separates from carbonate veinlets filling in the fractures or faults crosscutting the carbonate strata also show clear Eu-depletion. This indicates that the carbonate veinlets and their parent fluid was possibly sourced from the strata and inherited the REE geochemical features of the strata. Therefore, REE-geochemical characteristics of both the sulfides and calcites, which were deposited from an ore-forming hydrothermal system, are similar to those of carbonate strata, and strongly suggest that the ore metals were mainly sourced from carbonate strata.展开更多
1 Introduction The Tudimiaogou-Yindongshan lead-zinc polymetallic orefield is located in the Tudimiaogou-Weimoshi lead and zinc silver polymetallic metallogenic belt.The belt is an important part of southwestern Henan...1 Introduction The Tudimiaogou-Yindongshan lead-zinc polymetallic orefield is located in the Tudimiaogou-Weimoshi lead and zinc silver polymetallic metallogenic belt.The belt is an important part of southwestern Henan lead and zinc展开更多
The compositions of REE in quartz and pyrite from the main stage of the Laowan gold deposit in Henan Province and that in quartz from Laowan granite were determined by inductively coupled plasma-mass-spectrometry （IC...The compositions of REE in quartz and pyrite from the main stage of the Laowan gold deposit in Henan Province and that in quartz from Laowan granite were determined by inductively coupled plasma-mass-spectrometry （ICP-MS） to trace the source of ore-forming materials. Meanwhile, the REE compositions of the deposit ore, granite and metamorphic wall rock were also considered for comparative studies in detail. The range of ∑REE of quartz and pyrite from the deposit ores is 4.18 × 10^-6- 30.91 × 10^-6, the average of ∑REE is 13.39 × 10^-6, and the average of ∑REE of quartz in the Laowan granite is 6.68 × 10^-6. There is no distinct difference of REE parameters between the deposit ore quartz and granite quartz. The quartz in gold deposit has the same REE particular parameters as quartzes from Laowan granite, such as δEu, δCe, （La/Yb）N and （La/Sm）N, partition degree of LREE to HREE, especially, the chondrite-normalized REE patterns, but no similarity to those from metamorphic wall rock, which shows that ore-forming hydrothermal fluid is mainly the fluid coming from the Laowan granite magma, rather than metamorphic fluid. Meanwhile, comparison studies on REE features between minerals from the deposit ores and related geological bodies in the deposit show that REE characteristics of minerals can serve as an indicator of ore-forming fluid properties and sources, while the REE characteristics of the bulk samples （such as deposit ores, granites and wall rocks） can not trace the source of the ore-forming materials exactly.展开更多
The Xiajinbao gold deposit is located in Yong’an-Xiayingfang-Maojiagou polymetallic metallogenic belt,which is animportant metallogenic belt in North China block.In this paper,we present a detailed study on fluid inc...The Xiajinbao gold deposit is located in Yong’an-Xiayingfang-Maojiagou polymetallic metallogenic belt,which is animportant metallogenic belt in North China block.In this paper,we present a detailed study on fluid inclusions and stable isotopes ofthe Xiajinbao gold deposit,Hebei Province,China,aiming at discussing the ore source,evolution of ore-forming fluid andore-forming mechanism of the deposit.The macroscopic geological characteristics,S and Pb isotopic analysis results show that thesource of ore-forming materials is mainly from granitic magma,and subordinately from country rocks.H and O isotopic compositionfeatures indicate that the ore-forming fluid is mainly derived from magmatic water.Fluid inclusion characteristics show that theore-forming fluid experienced boiling during the early mineralization stage,which led to the precipitation of gold.Fluid mixingdominated the precipitation of the ore-forming materials during the middle and late stages.The gold precipitation was caused bywater/rock reaction throughout the whole ore-forming process.展开更多
The compositions of REE in quartz and pyrite from main mineralized stage of the Laowan gold deposit in Henan province and that of quartz from Laowan granite were determined by Inductively Coupled Plasma-Mass-Spectrome...The compositions of REE in quartz and pyrite from main mineralized stage of the Laowan gold deposit in Henan province and that of quartz from Laowan granite were determined by Inductively Coupled Plasma-Mass-Spectrometry （ICP-MS）. The REE of deposit ore of the Laowan gold deposit, wall-rock and Laowan granite also were studied to trace the source of metallogenic materials in Laowan gold deposit in detail. The range of ∑ REE in quartz and pyrite from gold deposit is 4.18 × 10^-6 - 30.91 × 10^-6, average of 13.39 × 10^-6, 6.68 × 10^-6 of the Laowan granite quartz, obviously lower to REE concentration of deposit, granite and wall-rock. The value of （La/ Yb）N and （La/Sm）N of ore minerals from the gold deposit is 13.23 and 4.17 respectively. The differences in REE parameters, such as δEu, δCe and diffusion degree in REE from light to heavy, among deposit ore minerals and granite mineral are weak. Especially, there are no differences between the chondrite-normalised REE curves of minerals from gold deposit and those of quartzs in Laowan granite, no similarity to wall-rock＇, which shows that ore-forming hydrothermal fluid mainly came from magma fluid resulting from the Laowan granite magma, metamorphic fluid in few. The results also show that REE characteristics of ore minerals in deposit are effective for disclosing oreforming fluid quality comparing with deposit ore＇REE compositions.展开更多
Southwestern Guizhou province is one of China’s most important distribution areas of Carlin-type gold deposits. The Nibao deposit is a typical gold deposit in southwestern Guizhou. To elucidate the genesis of the Nib...Southwestern Guizhou province is one of China’s most important distribution areas of Carlin-type gold deposits. The Nibao deposit is a typical gold deposit in southwestern Guizhou. To elucidate the genesis of the Nibao gold deposit, establish a metallogenic model, and guide prospecting prediction, we systematically collected previously reported geological, geochemical, and dating data and discussed the genesis of the Nibao gold deposit,based on which we proposed the metallogenic model.Earlier works show that the Nibao anticline, F1 fault, and its hanging wall dragged anticline(Erlongqiangbao anticline) were formed before or simultaneously with gold mineralization, while F2, F3, and F4 faults postdate gold mineralization. Regional geophysical data showed extensive low resistivity anomaly areas near the SBT(the product of tectonic slippage and hydrothermal alteration)between the P2/P3 and the strata of the Longtan Formation in the SSE direction of Nibao anticline in the lower plate of F1 and hanging wall dragged anticline(Erlongqiangbao anticline), and the anomaly areas are distributed within the influence range of anticlines. Simultaneously, soil and structural geochemistry show that F1, Nibao anticline,Erlongqiangbao anticline, and their transition areas all show good metallogenic elements(Au, As, and S) assemblage anomalies, with good metallogenic space and prospecting possibilities. There are five main hypotheses about the source of ore-forming fluids and Au in the Nibao gold deposit:(1) related to the Emeishan mantle plume activity;(2) source from the Emeishan basalt;(3) metamorphic fluid mineralization;(4) basin fluid mineralization;(5) related to deep concealed magmatic rocks;of these, the mainstream understanding is the fifth speculation. It is acknowledged that the ore-forming fluids are hydrothermal fluids with medium–low temperature, high pressure, medium–low salinity, low density, low oxygen fugacity, weak acidity, weak reduction, and rich in CO_(2)and CH_(4). The fluid pressure is 2–96.54 MPa, corresponding to depths of 0.23–3.64 km. The dating results show that the metallogenic age is ~141 Ma, the extensional tectonic environment related to the westward subduction of the Pacific Plate. Based on the above explanation, the genetic model related to deep concealed magmatic rocks of the Nibao gold deposit is established, and favorable prospecting areas are outlined;this is of great significance for regional mineral exploration and studying the genesis of gold deposits.展开更多
The macroscopic and microscopic studies (in mineral inclusions, stable isotopes, traceelements, etc.) on the Donchuan-Yimen type copper deposits show that the ore material deriv-ed from host rocks and their underlying...The macroscopic and microscopic studies (in mineral inclusions, stable isotopes, traceelements, etc.) on the Donchuan-Yimen type copper deposits show that the ore material deriv-ed from host rocks and their underlying beds, and Bi, Pb, Zn probably did from deep frac-tures. The ore-forming fluid is hot brine in nature, and the water in it is probably stratumwater in origin. The sulphur derived from bacteria reducing of sulphate in sea water. Thecarbon derived from marine carbonate. The organic carbon plays an important role in themetallogenesis. In the Kangdian Axis, two deep fractures controlled the sedimentation of thecupriferous algal reef carbonate formation. They were ore-, heat-, brine-conducting tectonicsand led to the formation and transformation of many copper ore beds.展开更多
The source and evolution of ore-forming fluids is important to understand the genesis of Carlin-type gold deposit.Constraints on the source and evolution of ore fluid components by the con-ventional geochemical method...The source and evolution of ore-forming fluids is important to understand the genesis of Carlin-type gold deposit.Constraints on the source and evolution of ore fluid components by the con-ventional geochemical methods have long been a challenge due to the very fine-grained nature and complex textures of hydrothermal minerals in these deposits.In this study,we present the crush-leach analyzed solute data of fluid inclusion extracts within quartz,calcite,realgar,and fluorite from the Shuiyindong,Nibao,and Yata gold deposits in the Youjiang Basin,providing new insights into the source and evolution of ore-forming fluids.The results show that the high molar Cl/Br ratios up to 2508 in fluid inclusion extracts are indicative of a contribution of magmatic hydrothermal fluids.Flu-ids mixing between basinal and magmatic-hydrothermal fluids are evident on the plots of Cl/Br versus Na/K ratios,showing that ore-stage milky quartz near the magmatic-hydrothermal fluids reflects magma origin of the ore-forming fluids,whereas late ore-stage drusy quartz and realgar near the de-fined basinal fluids suggest the later input of basinal fluids in late-ore stage.Although the predominate-ly host rocks in Shuiyindong,Nibao and Yata gold deposit are bioclastic limestone,sedimentary tuff,and calcareous siltstone,respectively,the solute data of fluid inclusion extracts records they underwent the similar fluid-rocks reactions between the Na-rich magmatic hydrothermal fluids and the Ca-and Mg-rich host rocks.This study highlights the solute data of fluid inclusion extracts obtained by crush-leach analyses have the potential to fingerprint the source and evolution of ore-forming fluids of the Carlin-type gold deposit.展开更多
基金This Project is supported by the National Natural Science Foundation （No. 40502011, 40372048 and 40425006）.
文摘REE abundances in sulfides from the Huize Zn-Pb ore field were determined with the ICPMS after preconcentration. The REE abundances in 26 sulfide samples （including pyrite, galena and sphalerite） are very low, with the ~REE ranging from 1.6×10^-9 to 166.8×10^-9. Their LREE/HREE ratios range from 7.6 to 98, showing LREE enrichment relatively. The JEu values are below 1, indicating that they were deposited from an Eu-depleted and reducing fluid-system. Similar to the ore-hosting carbonate strata, calcite separates from carbonate veinlets filling in the fractures or faults crosscutting the carbonate strata also show clear Eu-depletion. This indicates that the carbonate veinlets and their parent fluid was possibly sourced from the strata and inherited the REE geochemical features of the strata. Therefore, REE-geochemical characteristics of both the sulfides and calcites, which were deposited from an ore-forming hydrothermal system, are similar to those of carbonate strata, and strongly suggest that the ore metals were mainly sourced from carbonate strata.
文摘1 Introduction The Tudimiaogou-Yindongshan lead-zinc polymetallic orefield is located in the Tudimiaogou-Weimoshi lead and zinc silver polymetallic metallogenic belt.The belt is an important part of southwestern Henan lead and zinc
文摘The compositions of REE in quartz and pyrite from the main stage of the Laowan gold deposit in Henan Province and that in quartz from Laowan granite were determined by inductively coupled plasma-mass-spectrometry （ICP-MS） to trace the source of ore-forming materials. Meanwhile, the REE compositions of the deposit ore, granite and metamorphic wall rock were also considered for comparative studies in detail. The range of ∑REE of quartz and pyrite from the deposit ores is 4.18 × 10^-6- 30.91 × 10^-6, the average of ∑REE is 13.39 × 10^-6, and the average of ∑REE of quartz in the Laowan granite is 6.68 × 10^-6. There is no distinct difference of REE parameters between the deposit ore quartz and granite quartz. The quartz in gold deposit has the same REE particular parameters as quartzes from Laowan granite, such as δEu, δCe, （La/Yb）N and （La/Sm）N, partition degree of LREE to HREE, especially, the chondrite-normalized REE patterns, but no similarity to those from metamorphic wall rock, which shows that ore-forming hydrothermal fluid is mainly the fluid coming from the Laowan granite magma, rather than metamorphic fluid. Meanwhile, comparison studies on REE features between minerals from the deposit ores and related geological bodies in the deposit show that REE characteristics of minerals can serve as an indicator of ore-forming fluid properties and sources, while the REE characteristics of the bulk samples （such as deposit ores, granites and wall rocks） can not trace the source of the ore-forming materials exactly.
基金Project(2015CX008) supported by the Innovation Driven Plan of Central South University,China
文摘The Xiajinbao gold deposit is located in Yong’an-Xiayingfang-Maojiagou polymetallic metallogenic belt,which is animportant metallogenic belt in North China block.In this paper,we present a detailed study on fluid inclusions and stable isotopes ofthe Xiajinbao gold deposit,Hebei Province,China,aiming at discussing the ore source,evolution of ore-forming fluid andore-forming mechanism of the deposit.The macroscopic geological characteristics,S and Pb isotopic analysis results show that thesource of ore-forming materials is mainly from granitic magma,and subordinately from country rocks.H and O isotopic compositionfeatures indicate that the ore-forming fluid is mainly derived from magmatic water.Fluid inclusion characteristics show that theore-forming fluid experienced boiling during the early mineralization stage,which led to the precipitation of gold.Fluid mixingdominated the precipitation of the ore-forming materials during the middle and late stages.The gold precipitation was caused bywater/rock reaction throughout the whole ore-forming process.
文摘The compositions of REE in quartz and pyrite from main mineralized stage of the Laowan gold deposit in Henan province and that of quartz from Laowan granite were determined by Inductively Coupled Plasma-Mass-Spectrometry （ICP-MS）. The REE of deposit ore of the Laowan gold deposit, wall-rock and Laowan granite also were studied to trace the source of metallogenic materials in Laowan gold deposit in detail. The range of ∑ REE in quartz and pyrite from gold deposit is 4.18 × 10^-6 - 30.91 × 10^-6, average of 13.39 × 10^-6, 6.68 × 10^-6 of the Laowan granite quartz, obviously lower to REE concentration of deposit, granite and wall-rock. The value of （La/ Yb）N and （La/Sm）N of ore minerals from the gold deposit is 13.23 and 4.17 respectively. The differences in REE parameters, such as δEu, δCe and diffusion degree in REE from light to heavy, among deposit ore minerals and granite mineral are weak. Especially, there are no differences between the chondrite-normalised REE curves of minerals from gold deposit and those of quartzs in Laowan granite, no similarity to wall-rock＇, which shows that ore-forming hydrothermal fluid mainly came from magma fluid resulting from the Laowan granite magma, metamorphic fluid in few. The results also show that REE characteristics of ore minerals in deposit are effective for disclosing oreforming fluid quality comparing with deposit ore＇REE compositions.
基金supported by the National Natural Science Fund of China (41962008)the Talent Team Program of Guizhou Science and Technology Fund (Qianke Pingtairen Caixintang[2021]007)+3 种基金the Geological Exploration Fund Project of Guizhou Province (520000214TLCOG7DGTDRG)the National Natural Science Foundation of China (U1812402)Scientific Research Project of Hubei Geological Bureau (KJ2022-21)the Graduate Research Fund of Guizhou Province (YJSCXJH [2020] 095)。
文摘Southwestern Guizhou province is one of China’s most important distribution areas of Carlin-type gold deposits. The Nibao deposit is a typical gold deposit in southwestern Guizhou. To elucidate the genesis of the Nibao gold deposit, establish a metallogenic model, and guide prospecting prediction, we systematically collected previously reported geological, geochemical, and dating data and discussed the genesis of the Nibao gold deposit,based on which we proposed the metallogenic model.Earlier works show that the Nibao anticline, F1 fault, and its hanging wall dragged anticline(Erlongqiangbao anticline) were formed before or simultaneously with gold mineralization, while F2, F3, and F4 faults postdate gold mineralization. Regional geophysical data showed extensive low resistivity anomaly areas near the SBT(the product of tectonic slippage and hydrothermal alteration)between the P2/P3 and the strata of the Longtan Formation in the SSE direction of Nibao anticline in the lower plate of F1 and hanging wall dragged anticline(Erlongqiangbao anticline), and the anomaly areas are distributed within the influence range of anticlines. Simultaneously, soil and structural geochemistry show that F1, Nibao anticline,Erlongqiangbao anticline, and their transition areas all show good metallogenic elements(Au, As, and S) assemblage anomalies, with good metallogenic space and prospecting possibilities. There are five main hypotheses about the source of ore-forming fluids and Au in the Nibao gold deposit:(1) related to the Emeishan mantle plume activity;(2) source from the Emeishan basalt;(3) metamorphic fluid mineralization;(4) basin fluid mineralization;(5) related to deep concealed magmatic rocks;of these, the mainstream understanding is the fifth speculation. It is acknowledged that the ore-forming fluids are hydrothermal fluids with medium–low temperature, high pressure, medium–low salinity, low density, low oxygen fugacity, weak acidity, weak reduction, and rich in CO_(2)and CH_(4). The fluid pressure is 2–96.54 MPa, corresponding to depths of 0.23–3.64 km. The dating results show that the metallogenic age is ~141 Ma, the extensional tectonic environment related to the westward subduction of the Pacific Plate. Based on the above explanation, the genetic model related to deep concealed magmatic rocks of the Nibao gold deposit is established, and favorable prospecting areas are outlined;this is of great significance for regional mineral exploration and studying the genesis of gold deposits.
基金the National Natural Science Foundation of China.
文摘The macroscopic and microscopic studies (in mineral inclusions, stable isotopes, traceelements, etc.) on the Donchuan-Yimen type copper deposits show that the ore material deriv-ed from host rocks and their underlying beds, and Bi, Pb, Zn probably did from deep frac-tures. The ore-forming fluid is hot brine in nature, and the water in it is probably stratumwater in origin. The sulphur derived from bacteria reducing of sulphate in sea water. Thecarbon derived from marine carbonate. The organic carbon plays an important role in themetallogenesis. In the Kangdian Axis, two deep fractures controlled the sedimentation of thecupriferous algal reef carbonate formation. They were ore-, heat-, brine-conducting tectonicsand led to the formation and transformation of many copper ore beds.
基金This study is supported by the Natural Science Foundation of China(Nos.41802094,U1812402)the National Basic Research Program(No.2014CB440906).
文摘The source and evolution of ore-forming fluids is important to understand the genesis of Carlin-type gold deposit.Constraints on the source and evolution of ore fluid components by the con-ventional geochemical methods have long been a challenge due to the very fine-grained nature and complex textures of hydrothermal minerals in these deposits.In this study,we present the crush-leach analyzed solute data of fluid inclusion extracts within quartz,calcite,realgar,and fluorite from the Shuiyindong,Nibao,and Yata gold deposits in the Youjiang Basin,providing new insights into the source and evolution of ore-forming fluids.The results show that the high molar Cl/Br ratios up to 2508 in fluid inclusion extracts are indicative of a contribution of magmatic hydrothermal fluids.Flu-ids mixing between basinal and magmatic-hydrothermal fluids are evident on the plots of Cl/Br versus Na/K ratios,showing that ore-stage milky quartz near the magmatic-hydrothermal fluids reflects magma origin of the ore-forming fluids,whereas late ore-stage drusy quartz and realgar near the de-fined basinal fluids suggest the later input of basinal fluids in late-ore stage.Although the predominate-ly host rocks in Shuiyindong,Nibao and Yata gold deposit are bioclastic limestone,sedimentary tuff,and calcareous siltstone,respectively,the solute data of fluid inclusion extracts records they underwent the similar fluid-rocks reactions between the Na-rich magmatic hydrothermal fluids and the Ca-and Mg-rich host rocks.This study highlights the solute data of fluid inclusion extracts obtained by crush-leach analyses have the potential to fingerprint the source and evolution of ore-forming fluids of the Carlin-type gold deposit.
