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Overview of the Synthesis, Characterization, and Application of Tannin-Glyoxal Adhesive for Wood-Based Composites
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作者 Awanda Wira Anggini Rita Kartika Sari +3 位作者 Efri Mardawati Tati Karliati Apri Heri Iswanto Muhammad Adly Rahandi Lubis 《Journal of Renewable Materials》 EI CAS 2024年第7期1165-1186,共22页
More than a century after its initial synthesis,urea-formaldehyde(UF)resins still have dominant applications as adhesives,paints,and coatings.However,formaldehyde in this industry produces formaldehyde emissions that ... More than a century after its initial synthesis,urea-formaldehyde(UF)resins still have dominant applications as adhesives,paints,and coatings.However,formaldehyde in this industry produces formaldehyde emissions that are dangerous to health.Scientists have spent the last decade replacing formaldehyde and phenol with environmentally friendly substances such as glyoxal and tannin to create bio-based adhesives.This review covers recent advances in synthesizing glyoxal tannin-based resins,especially those made from sustainable raw material substitutes and changes made to synthetic processes to improve mechanical properties.The efficacy of using tannin-glyoxal adhesives in producing wood-based composites has been proven.The glyoxylate reaction forms cross-linked bridges between the aromatic sites of the tannin and glyoxal molecular structures.Glyoxal tannin adhesive with a greater percentage of glyoxal than tannin will produce an adhesive with better characteristics.The gel time reduces as the hardener concentration rises from 7.5%to 15%when glyoxal is used in adhesives.However,excessive amounts of glyoxal will result in a decrease in viscosity values.Glyoxal exhibits faster delivery degradation when it reaches a maximum temperature of approximately 130°C,although it initiates the curing process slightly slower at 110°C.Adding glyoxal to tannin-based adhesives can improve the mechanical properties of composite boards.The wet shear strength of the resulting plywood is increased by 105.4%with the addition of 5-weight percent tannin-based resin with glyoxal as a cross-linker in Soy Protein Adhesive.With glyoxal as a hardener,the panels produced showed good internal bond strengths(>0.35 MPa)and met the international standard specifications for interior-grade panels. 展开更多
关键词 Bio-based adhesives GLYOXAL TANNIN wood adhesives wood-based composites
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Adhesion of Technical Lignin-Based Non-Isocyanate Polyurethane Adhesives for Wood Bonding
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作者 Jaewook Lee Byung-Dae Park Qinglin Wu 《Journal of Renewable Materials》 EI CAS 2024年第7期1187-1205,共19页
Lignin is the most abundant aromatic natural polymer,and receiving great attention in replacing various petro-leum-based polymers.The aim of this study is to investigate the feasibility of technical lignin as a polyol... Lignin is the most abundant aromatic natural polymer,and receiving great attention in replacing various petro-leum-based polymers.The aim of this study is to investigate the feasibility of technical lignin as a polyol for the synthesis of non-isocyanate polyurethane(NIPU)adhesives to substitute current polyurethane(PU)adhesives that have been synthesized with toxic isocyanate and polyols.Crude hardwood kraft lignin(C-HKL)was extracted from black liquor from a pulp mill followed by acetone fractionation to obtain acetone soluble-HKL(AS-HKL).Then,C-HKL,AS-HKL,and softwood sodium lignosulfonate(LS)were used for the synthesis of technical lignin-based NIPU adhesives through carbonation and polyamination and silane as a cross-linker.Their adhesion per-formance was determined for plywood.FTIR spectra showed the formation of urethane bonds and the reaction between lignin and silane.The NIPU adhesives prepared with C-HKL showed the highest adhesion strength among the three lignin-based NIPU adhesives.As the silane addition level increased,the adhesion strength of NIPU adhesives increased whereas formaldehyde emission decreased for all NIPU adhesives prepared.These results indicate that NIPU adhesives based on technical kraft lignin have a great potential as polyol for the synth-esis of bio-based NIPU adhesives for wood bonding. 展开更多
关键词 Technical lignin non-isocyanate polyurethane wood adhesives adhesion strength formaldehyde emission
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Theoretical optimization of micropillar arrays for structurally stable bioinspired dry adhesives
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作者 Ke Ni Zhengzhi Wang 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2024年第2期124-129,共6页
Inspired by the excellent adhesion performances of setae structure from organisms,micro/nano-pillar array has become one of the paradigms for adhesive surfaces.The micropillar arrays are composed of the resin pillars ... Inspired by the excellent adhesion performances of setae structure from organisms,micro/nano-pillar array has become one of the paradigms for adhesive surfaces.The micropillar arrays are composed of the resin pillars for adhesion and the substrate with different elastic modulus for supporting.The stress singularity at the bi-material corner between the pillars and the substrate can induce the failure of the micropillar-substrate corner and further hinder the fabrication and application of micropillar arrays,yet the design for the stability of the micropillar array lacks systematical and quantitative guides.In this work,we develop a semi-analytical method to provide the full expressions for the stress distribution within the bi-material corner combining analytical derivations and numerical calculations.The predictions for the stress within the singularity field can be obtained based on the full expressions of the stress.The good agreement between the predictions and the FEM results demonstrates the high reliability of our method.By adopting the strain energy density factor approach,the stability of the pillar-substrate corner is assessed by predicting the failure at the corner.For the elastic mismatch between the pillar and substrate given in this paper,the stability can be improved by increasing the ratio of the shear modulus of the substrate to that of the micropillar.Our study provides accurate predictions for the stress distribution at the bi-material corner and can guide the optimization of material combinations of the pillars and the substrate for more stable bioinspired dry adhesives. 展开更多
关键词 Micropillar array Stability Bi-material corner Dry adhesive
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Universal Encapsulation Adhesive for Lead Sedimentation and Attachable Perovskite Solar Cells with Enhanced Performance
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作者 Xuehao Zhu Haoyu Cai +7 位作者 Cong Bai Zhengzhe Wu Wenjian Shen Yiming Xiong Juan Zhao Fuzhi Huang Yibing Cheng Jie Zhong 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期303-310,共8页
In this work,a modified polyurethane adhesive(PUA)was prepared to realize a convenient encapsulation strategy for lead sedimentation and attachable perovskite solar cells(A-PSCs).The modified PUA can completely self-h... In this work,a modified polyurethane adhesive(PUA)was prepared to realize a convenient encapsulation strategy for lead sedimentation and attachable perovskite solar cells(A-PSCs).The modified PUA can completely self-heal within 45 min at room temperature with an efficient lead ion-blocking rate of 99.3%.The PUA film can be coated on a metal electrode with slight efficiency improvement from 23.96%to 24.15%.The thermal stability at 65℃and the humidity stability at 55%relative humidity(RH)are superior to the devices encapsulated with polyisobutylene.The PUA film has strong adhesion to the flexible substrate and the initial efficiency of the flexible perovskite module(17.2%)encapsulated by PUA remains 92.6%within 1825 h.These results suggest that PUA encapsulation is universal for rigid and flexible PSCs with enhanced stability and low lead hazards.Moreover,it was found that flexible PSCs can be well attached to various substrates with PUA,providing a facile route for the A-PSCs in various scenarios without additional encapsulation and installation. 展开更多
关键词 adhesive attachable device flexible module lead leakage POLYURETHANE
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Mussel-inspired Methacrylic Gelatin-dopamine/Ag Nanoparticles/Graphene Oxide Hydrogels with Improved Adhesive and Antibacterial Properties for Applications as Wound Dressings
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作者 宿正楠 HU Yanru +5 位作者 MENG Lihui OUYANG Zhiyuan LI Wenchao ZHU Fang XIE Bin 吴庆知 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期512-521,共10页
A novel strategy was developed to prepare the methacrylic gelatin-dopamine(GelMA-DA)/Ag nanoparticles(NPs)/graphene oxide(GO) composite hydrogels with good biocompatibility,mechanical properties,and antibacterial acti... A novel strategy was developed to prepare the methacrylic gelatin-dopamine(GelMA-DA)/Ag nanoparticles(NPs)/graphene oxide(GO) composite hydrogels with good biocompatibility,mechanical properties,and antibacterial activity.Mussel-inspired DA was utilized to modify the GelMA molecules,which imparts good adhesive performance to the hydrogels.GO,interfacial enhancer,not only improves mechanical properties of the hydrogels,but also provides anchor sites for loading Ag NPs through numerous oxygencontaining functional groups on the surface.The experimental results show that the GelMA/Ag NPs/GO hydrogels have good biocompatibility,and exhibit a swelling rate of 202±16%,the lap shear strength of 147±17 kPa,and compressive modulus of 136±53 kPa,in the case of the Ag NPs/GO content of 2 mg/mL.Antibacterial activity of the hydrogels against both gram-negative and gram-positive bacteria is dependent on the Ag NPs/GO content derived from the release of Ag^(+).Furthermore,the GelMA/Ag NPs/GO hydrogels possess good adhesive ability,which is resistant to highly twisted state when stuck on the surface of pigskin.These results demonstrate promising potential of the GelMA-DA/Ag NPs/GO hydrogels as wound dressings for biomedical applications in clinical and emergent treatment. 展开更多
关键词 GelMA dopamine graphene oxide adhesion antibacterial ability
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Effect of Adhesive Type on the Quality of Coconut Shell Charcoal Briquettes Prepared by the Screw Extruder Machine
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作者 Samsudin Anis Deni Fajar Fitriyana +7 位作者 Aldias Bahatmaka Muhammad Choirul Anwar Arsyad Zanadin Ramadhan Fajar Chairul Anam Raffanel Adi Permana Ahmad Jazilussurur Hakim Natalino Fonseca Da Silva Guterres Mateus De Sousa Da Silva 《Journal of Renewable Materials》 EI CAS 2024年第2期381-396,共16页
Indonesia is one of the largest coconut-producing countries in the world.The utilization of coconut shell waste into briquettes will increase the selling value and become a great export opportunity.However,the effect ... Indonesia is one of the largest coconut-producing countries in the world.The utilization of coconut shell waste into briquettes will increase the selling value and become a great export opportunity.However,the effect of adhesives on the quality of coconut shell charcoal briquettes made using screw extruder machine has not been widely studied.This study aims to determine the effect of adhesive type on the quality of coconut shell charcoal briquettes.The process of fabricating briquettes in this study included crushing,mixing,blending,pressing,and drying.In the mixing process,3 types of adhesives were used,namely tapioca flour(Briquette_1),cassava flour(Briquette_2),and modified cassava flour(Briquette_3)with a concentration of 5%of the weight of coconut shell charcoal powders.The quality of the resulting briquettes and commercial briquettes will be evaluated by moisture content,ash content,volatile matter,fixed carbon,calorific value,density,compressive,and drop test testing.The results of this research showed that the type of adhesive had a significant effect on the quality of the briquettes produced.Specimen Briquette_1 had better quality than commercial briquettes(Briquette_4)and other briquette specimens.The test results showed that Briquette_1 produced briquettes with better compressive strength and friability than the other specimens,at 6.95 N/mm^(2) and 4.44%,respectively.The moisture content,ash content,fixed carbon,and calorific value of Briquette_1 have met the requirements set by the Indonesian National Standard(SNI)number 01-6235-2000.Meanwhile,the volatile matter content and density of Briquette_1 are by the standards of Japan and the United States America(USA). 展开更多
关键词 COCONUT charcoal BRIQUETTES adhesive MIXING BLENDING PRESSING
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Semi-liquid metal-based highly permeable and adhesive electronic skin inspired by spider web
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作者 Rui Guo Xiaoqing Li +6 位作者 Yingtong Zhou Yuqi Zhang Chengjie Jiang Yang Yu Qingting Tan Wenbo Ding Hongzhang Wang 《Science Bulletin》 SCIE EI CAS CSCD 2024年第17期2723-2734,共12页
Soft and stretchable electronics have garnered significant attention in various fields, such as wearable electronics, electronic skins, and soft robotics. However, current wearable electronics made from materials like... Soft and stretchable electronics have garnered significant attention in various fields, such as wearable electronics, electronic skins, and soft robotics. However, current wearable electronics made from materials like conductive elastomers, hydrogels, and liquid metals face limitations, including low permeability, poor adhesion, inadequate conductivity, and limited stretchability. These issues hinder their effectiveness in long-term healthcare monitoring and exercise monitoring. To address these challenges,we introduce a novel design of web-droplet-like electronics featuring a semi-liquid metal coating for wearable applications. This innovative design offers high permeability, excellent stretchability, strong adhesion, and good conductivity for the electronic skin. The unique structure, inspired by the architecture of a spider web, significantly enhances air permeability compared to commercial breathable patches.Furthermore, the distribution of polyborosiloxane mimics the adhesive properties of spider web mucus,while the use of semi-liquid metals in this design results in remarkable conductivity(9 × 10^(6)S/m) and tensile performance(up to 850% strain). This advanced electronic skin technology enables long-term monitoring of various physiological parameters and supports machine learning recognition functions with unparalleled advantages. This web-droplet structure design strategy holds great promise for commercial applications in medical health monitoring and disease diagnosis. 展开更多
关键词 Wearable electronics Web-droplet structure Semi-liquid metal High permeability Strong adhesion Long-term monitoring
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Preparation of Environmentally Friendly Urea-Hexanediamine-Glyoxal(HUG)Resin Wood Adhesive
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作者 Qianyu Zhang Shi Chen +4 位作者 Long Cao Hong Lei Antonio Pizzi Xuedong Xi Guanben Du 《Journal of Renewable Materials》 EI CAS 2024年第2期235-244,共10页
Using non-toxic,low-volatile glyoxal to completely replace formaldehyde for preparing urea-glyoxal(UG)resin adhesive is a hot research topic that could be of great interest for the wood industry.However,urea-glyoxal(U... Using non-toxic,low-volatile glyoxal to completely replace formaldehyde for preparing urea-glyoxal(UG)resin adhesive is a hot research topic that could be of great interest for the wood industry.However,urea-glyoxal(UG)resins prepared by just using glyoxal instead of formaldehyde usually yields a lower degree of polymerization.This results in a poorer bonding performance and water resistance of UG resins.A good solution is to pre-react urea to preform polyurea molecules presenting already a certain degree of polymerization,and then to condense these with glyoxal to obtain a novel UG resin.Therefore,in this present work,the urea was reacted with hexamethylene diamine to form a polyurea named HU,and then this was used to react it with different amounts of glyoxal to synthesize hexamethylenediamine-urea-glyoxal(HUG)polycondensation resins,and to use this for bonding plywood.The results show that the glyoxal can well react with HU polyuria via addition and schiff base reaction,and also the HUG resin exhibits excellent bonding strength and water resistance.The shear strength of the plywood bonded with this HUG at 160°C hot press temperature as high as 1.93 MPa,2.16 MPa and 1.61 MPa,respectively,which meets the requirement of the China national standard GB/T 9846-2015(≥0.7 MPa),and can be a good choice as a wood adhesive for industrial application. 展开更多
关键词 Urea-glyoxal resin hexamethylene diamine wood adhesives water resistance
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Efficacy of Cyanoacrylate Tissue Adhesive Application in the Management of Corneal Perforations at Preah Ang Duong Hospital in Cambodia
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作者 Guechlaing Chea Amarin Mar +3 位作者 Saly Saint Remy Tor Ponndara Ith Piseth Kong 《Open Journal of Ophthalmology》 2024年第1期44-54,共11页
Purpose: The study was to evaluate the efficacy of cyanoacrylate tissue adhesive (CTA) application in corneal perforations. Method: This was a prospective study on 20 patients of corneal perforations who received cyan... Purpose: The study was to evaluate the efficacy of cyanoacrylate tissue adhesive (CTA) application in corneal perforations. Method: This was a prospective study on 20 patients of corneal perforations who received cyanoacrylate tissue adhesive application as treatment between March 2021 and March 2022 at Preah Ang Duong Hospital. The primary outcome measure was success rate of CTA application, while the secondary outcome was to measure postoperative best-corrected visual acuity (BCVA) and ocular complications. Results: The mean age of patients was 44.15 ± 16.05 years old and 7 (35%) were female. Causes of perforation were microbial infection in 12 patients (60%), trauma in 5 patients (25%), and sterile melting in 3 patients (15%). The perforation of size smaller than 1.5 mm was in 8 patients (40%) while 12 patients (60%) had perforated size between 1.5 mm to 3 mm. The perforation was 60% (12 patients) central, 25% (5 patients) paracentral, and 15% (3 patients) peripherally. Out of 20 patients, 5 patients (25%) received CTA application more than 1 time. The mean glue retention was 57.60 ± 31.84 days. Success rate of glue application (defined as intact globe without surgical intervention regardless of number of CTA applications) was 85%. At the last visit, 7 patients (35%) had BCVA of 6/120 or better. Common complications were uveitis (45%), ocular hypertension (30%), cataract (25%) and neovascularization (20%). No serious complications were found. Conclusion: Cyanoacrylate tissue adhesive is an effective treatment option in sealing corneal perforations with no serious complications. . 展开更多
关键词 Cyanoacrylate Tissue adhesive Corneal Perforation Microbial Infection Sterile Melting
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Properties of Bark Particleboard Bonded with Demethylated Lignin Adhesives Derived from Leucaena leucocephala Bark
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作者 Rafidah Md Salim Jahimin Asik Mohd Sani Sarjadi 《Journal of Renewable Materials》 EI CAS 2024年第4期737-769,共33页
Lignin extraction from bark can maximize the utilization of biomass waste,offer cost-effectiveness,and promote environmental friendliness when employed as an adhesive material in bark particleboard production.Particle... Lignin extraction from bark can maximize the utilization of biomass waste,offer cost-effectiveness,and promote environmental friendliness when employed as an adhesive material in bark particleboard production.Particles of fine(0.2 to 1.0 mm),medium(1.0 to 2.5 mm),and coarse(2.5 to 12.0 mm)sizes,derived from the bark of Leucaena leucocephala,were hot-pressed using a heating plate at 175℃for 7 min to create single-layer particleboards measuring 320 mm×320 mm×10 mm,targeting a density of 700 kg/m^(3).Subsequently,the samples were trimmed and conditioned at 20℃and 65%relative humidity.In this study,we compared bark particleboard bonded with urea formaldehyde(UF)adhesive to fine-sized particleboard bonded with demethylated lignin adhesive.The results indicated that bark particleboards utilizing demethylated lignin and UF adhesives exhibited similar qualities.Coarse particleboard showed differences in modulus of elasticity(MOE)and modulus of rupture(MOR),while medium-sized particles exhibited significant variations in moisture content(MC)and water absorption(WA).Furthermore,the thickness swelling of coarse and medium-sized particles under wet and oven-dried conditions exhibited notable distinctions.Overall,the demethylated lignin adhesive extracted from L.leucocephala bark demonstrated similar quality to UF adhesive,with particle size correlating inversely to the strength of the bark particleboard. 展开更多
关键词 Bark particleboard properties demethylated lignin lignin adhesives Leucaena leucocephala bark particles
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Endoscopic band ligation or endoscopic tissue adhesive injection in the treatment of gastric varices:Which is better?
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作者 Li-Zhi Yi Sheng-Bing Zhao 《World Journal of Gastroenterology》 SCIE CAS 2024年第21期2827-2828,共2页
The combination of endoscopic ultrasound with endoscopic treatment of type 1 gastric variceal hemorrhage may improve the robustness and generalizability of the findings in future studies.Moreover,the esophageal varice... The combination of endoscopic ultrasound with endoscopic treatment of type 1 gastric variceal hemorrhage may improve the robustness and generalizability of the findings in future studies.Moreover,the esophageal varices should also be included in the evaluation of treatment efficacy in subsequent studies to reach a more convincing conclusion. 展开更多
关键词 Gastric varices Esophageal varices Endoscopic band ligation Endoscopic tissue adhesive injection Endoscopic ultrasound
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Ginger oil-loaded transdermal adhesive patch treats post-traumatic stress disorder
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作者 Xingshuang Song Yizhi Zhang +7 位作者 Ziyan Tang Jing Dai Yanping Wu Guiyu Huang Hong Niu Yaxin Wang Xu Jin Lina Du 《Journal of Traditional Chinese Medical Sciences》 CAS 2024年第3期316-329,共14页
Objective To find a viable alternative to reduce the number of doses required for the patients with post-traumatic stress disorder(PTSD),and to improve efficacy and patient compliance.Methods In this study,we used gin... Objective To find a viable alternative to reduce the number of doses required for the patients with post-traumatic stress disorder(PTSD),and to improve efficacy and patient compliance.Methods In this study,we used ginger oil,a phytochemical with potential therapeutic properties,to prepare ginger oil patches.High-performance liquid chromatography(HPLC)was used to quantify the main active component of ginger oil,6-gingerol.Transdermal absorption experiments were conducted to optimize the various pressure-sensitive adhesives and permeation enhancers,including their type and concentration.Subsequently,the ginger oil patches were optimized and subjected to content determination and property evaluations.A PTSD mouse model was established using the foot-shock method.The therapeutic effect of ginger oil patches on PTSD was assessed through pathological sections,behavioral tests,and the evaluation of biomarkers such as tumor necrosis factor-α(TNF-α),interleukin-6(IL-6),brain-derived neurotrophic factor(BDNF),and melatonin(MT).Results The results demonstrated that ginger oil patches exerted therapeutic effects against PTSD by inhibiting inflammatory responses and modulating MT and BDNF levels.Pharmacokinetic experiments revealed that ginger oil patches maintained a stable blood drug concentration for at least one day,addressing the rapid metabolism drawback of 6-gingerol and enhancing its therapeutic efficacy.Conclusions Ginger oil can be prepared as a transdermal drug patch that meets these requirements,and the bioavailability of the prepared patch is better than that of oral administration.It can improve PTSD with good patient compliance and ease of administration.Therefore,it is a promising therapeutic formulation for the treatment of PTSD. 展开更多
关键词 Post-traumatic stress disorder 6-GINGEROL Pressure sensitive adhesive patch Transdermal delivery
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Polyurethane Hybrid-Based Wood Adhesive: Review
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作者 Rahul Khandagale Sainath Gadhave Ravindra V. Gadhave 《Open Journal of Polymer Chemistry》 2024年第1期41-62,共22页
Based on commercially available polyvinyl alcohol (PVA) stabilised polyvinyl acetate (PVAc), emulsion adhesives are neither heat nor moisture-resistant and show weak strength at high relative humidity and high tempera... Based on commercially available polyvinyl alcohol (PVA) stabilised polyvinyl acetate (PVAc), emulsion adhesives are neither heat nor moisture-resistant and show weak strength at high relative humidity and high temperatures. Pre- or post-crosslinking is another method used to manufacture a conventional vinyl-based homopolymers or copolymers system with improved water resistance. Vinyl neodecanoate (VeoVa), N-methylolacrylamide (NMA), Methacrylamide, methacrylic acid (MAA), and other self-crosslinking comonomers are typically inserted to produce highly water-resistant vinyl based homopolymers or copolymers. Additionally, organic crosslinkers like glyoxal, glutaraldehyde, citric acid, tartaric acid, and the like, as well as inorganic crosslinkers like acidic metal salts like aluminium chloride, aluminium nitrate, boric acid, and the like, can be used to prepare the highly water-resistant vinyl based homopolymers or copolymers. It is also possible to combine the self-crosslinking comonomers with the organic crosslinkers. Recently, a different hybrid chemistry has been developed that improves lap shear strength, has outstanding water resistance, good durability, and doesn’t require any additional crosslinker agents. Two distinct polymers were combined to develop hybrid polymers. They usually involve mixing an organic polymer with a polymer. There are many capping agents that are used for polyurethanes to produce acrylics that are capped with polyurethane and used as an oligomer in PVAc wood glue. Here, in this paper, we reviewed the different hybrid chemistry based on polyurethane chemistry for wood bonding applications. 展开更多
关键词 Vinyl Acetate HYBRID POLYURETHANE WOOD adhesive
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Reinforcing Effect of Graphene in Epoxy Adhesives: Review
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作者 Fatehbahadur Purushottam Lodh Ravindra Vilas Indubai Gadhave 《Open Journal of Composite Materials》 2024年第1期60-70,共11页
Due to its great strength, hardness, and chemical resistance, epoxy adhesives are becoming more and more used. They continue to have drawbacks, nevertheless, such as poor thermal stability, and poor electrical conduct... Due to its great strength, hardness, and chemical resistance, epoxy adhesives are becoming more and more used. They continue to have drawbacks, nevertheless, such as poor thermal stability, and poor electrical conductivity. Two-dimensional graphene is a wonderful substance with exceptional qualities including high strength, high electrical conductivity, and large surface area. Because of these characteristics, graphene has been thoroughly researched for its prospective uses in a variety of industries, including electronics, energy storage, and biomedical engineering. The use of graphene as an additive in epoxy adhesives to enhance the characteristics of such materials is one of its promising uses. This paper reviewed the latest findings about graphene’s effects on epoxy adhesives. The various methods to produce graphene-epoxy composites and their improvements are discussed. This research additionally discusses the challenges associated with the production and processing of graphene-epoxy composites, as well as the mechanisms behind the improvements in mechanical, electrical, and thermal characteristics. The final section of this review discusses the challenges and prospective uses of graphene in epoxy adhesives in the future. 展开更多
关键词 GRAPHENE EPOXY adhesives COMPOSITE Mechanical Properties
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Polyvinyl Acetate and Vinyl Acetate-Ethylene Hybrid Adhesive: Synthesis, Characterization, and Properties
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作者 Ravindra V. Gadhave 《Open Journal of Polymer Chemistry》 2024年第1期1-18,共18页
The goal is to develop a hybrid IPN network of polyvinyl acetate (PVAc) and ethylene-vinyl acetate (VAE). In this research work, the vinyl acetate (VAc)/ VAE hybrid emulsion and polyvinyl acetate emulsion (PVAc) were ... The goal is to develop a hybrid IPN network of polyvinyl acetate (PVAc) and ethylene-vinyl acetate (VAE). In this research work, the vinyl acetate (VAc)/ VAE hybrid emulsion and polyvinyl acetate emulsion (PVAc) were effectively synthesized. Emulsions with various characteristics have been developed by adjusting the weight ratios between the vinyl acetate monomer and the VAE component. The impacts on the mechanical, thermal, and physical properties of the films were investigated using tests for pencil hardness, tensile shear strength, pH, contact angle measurement, differential scanning calorimetry (DSC), and viscosity. When 5.0 weight percent VAE was added, the tensile shear strength in dry conditions decreased by 18.75% after a 24-hour bonding period, the heat resistance decreased by 26.29% (as per WATT 91) and the tensile shear strength decreased by approximately 36.52% in wet conditions (per EN 204). The pristine sample’s results were also confirmed by the contact angle test. The interpenetrating network (IPN) formation in hybrid PVAc emulsion as primary bonds does not directly attach to PVAc and VAE chains. The addition of VAE reduced the mechanical properties (at dry conditions) and heat resistance as per WATT 91. Contact angle analysis demonstrated that PVAc adhesives containing VAE had increased water resistance when compared to conventional PVA stabilised PVAc homopolymer-based adhesives. When compared to virgin PVAc Homo, the water resistance of the PVAc emulsion polymerization was enhanced by the addition of VAE. 展开更多
关键词 Ethylene-Vinyl Acetate Dispersion Polyvinyl Acetate HYBRID WOOD adhesive
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Adhesive hydrogels in osteoarthritis:from design to application 被引量:2
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作者 Wang-Lin Duan Li-Ning Zhang +6 位作者 Raghvendra Bohara Sergio Martin-Saldana Fei Yang Yi-Yang Zhao Yong Xie Ya-Zhong Bu Abhay Pandit 《Military Medical Research》 SCIE CAS CSCD 2023年第5期652-679,共28页
Osteoarthritis(OA)is the most common type of degenerative joint disease which affects 7%of the global population and more than 500 million people worldwide.One research frontier is the development of hydrogels for OA ... Osteoarthritis(OA)is the most common type of degenerative joint disease which affects 7%of the global population and more than 500 million people worldwide.One research frontier is the development of hydrogels for OA treatment,which operate either as functional scaffolds of tissue engineering or as delivery vehicles of functional additives.Both approaches address the big challenge:establishing stable integration of such delivery systems or implants.Adhesive hydrogels provide possible solutions to this challenge.However,few studies have described the current advances in using adhesive hydrogel for OA treatment.This review summarizes the commonly used hydrogels with their adhesion mechanisms and components.Additionally,recognizing that OA is a complex disease involving different biological mechanisms,the bioactive therapeutic strategies are also presented.By presenting the adhesive hydrogels in an interdisciplinary way,including both the fields of chemistry and biology,this review will attempt to provide a comprehensive insight for designing novel bioadhesive systems for OA therapy. 展开更多
关键词 adhesive hydrogel OSTEOARTHRITIS Functional additives Cartilage regeneration Interdisciplinary therapy
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MALDI ToF Investigation of the Reaction of Soy Protein Isolate with Glutaraldehyde for Wood Adhesives 被引量:1
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作者 Qianyu Zhang Antonio Pizzi +3 位作者 Hong Lei Xuedong Xi Ming Cao Long Cao 《Journal of Renewable Materials》 SCIE EI 2023年第3期1439-1450,共12页
Soy protein adhesives are currently a hot research topic in the wood panels industry for the abundant raw material reserves,reasonable price and outstanding environmental features.But their poor water resistance,low b... Soy protein adhesives are currently a hot research topic in the wood panels industry for the abundant raw material reserves,reasonable price and outstanding environmental features.But their poor water resistance,low bonding strength and intolerance to mold are major drawbacks,so that proper modification before use is essential.Glutaraldehyde is one of the more apt cross-linking agents for soybean protein adhesives,which can effectively improve the bonding strength and water resistance of the adhesive.Equally,glutaraldehyde is also an efficient and broad-spectrum fungicide that can significantly improve the anti-fungal properties of a soy protein adhesive.In the work presented here,matrix assisted laser desorption ionization(MALDI-ToF)mass spectrometry and Fourier transform infrared spectroscopy techniques were used to analyze the reaction mechanism of glutaraldehyde cross-linking soybean protein.The results confirmed the reaction of the aldehyde group with amino groups of the side chains and the amide groups of the peptide linkages constituting the skeletal chain of the protein.The laboratory plywood and particleboard bonded with glutaraldehyde-soy bean protein adhesives were prepared to determine the adhesive bonding properties,the dry strength,24 h cold water soaking wet strength and 3 h hot water(63°C)wet strength of plywood were 2.03,1.13 and 0.75 MPa,respectively,which satisfied the requirements of industrial production. 展开更多
关键词 Bio-based adhesives soy bean protein MALDI-TOF PARTICLEBOARD PLYWOOD
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Little Secrets for the Successful Industrial Use of Tannin Adhesives:A Review 被引量:1
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作者 Antonio Pizzi 《Journal of Renewable Materials》 EI 2023年第9期3403-3415,共13页
This brief article reviews a very particular and quite narrowfield,namely what has been done and what is needed to know for tannin adhesives for wood panels to succeed industrially.The present fashionable focus on bio... This brief article reviews a very particular and quite narrowfield,namely what has been done and what is needed to know for tannin adhesives for wood panels to succeed industrially.The present fashionable focus on bioadhe-sives has led to producing chemical adhesive formulations and approaches for tannin adhesives as a subject of academic publications.These,as good and original they might be,are and will still remain a rather empty aca-demic exercise if not put to the test of real industrial trials and industrial use.They will remain so without the“little”secrets and techniques outlined here that show that there is a great gap between developing an adhesive formulation in the laboratory and the hard reality to make it work where it does really count,in its industrial application.It outlines the fact that even more modern and excellent,newly developed bioadhesive formulations might well miserably fail once tried in the industry if the problems that always arise in their upgrading are not identified and solved,and solved well.It also outlines the fact that not only must costs always be taken into account and that a practical and possibly easy-to-handle approach must always be used,but too expensive or complex and unyielding adhesive systems are also often shown to be unusable or unsuitable in industry. 展开更多
关键词 Tannin adhesive industrial techniques industrial formulations industrial hardeners wood panels wood composites fast press times
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Adhesive cryogel particles for bridging confined and irregular tissue defects
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作者 Yao-Ting Xue Ming-Yu Chen +14 位作者 Jia-Sheng Cao Lei Wang Jia-Hao Hu Si-Yang Li Ji-Liang Shen Xin-Ge Li Kai-Hang Zhang Shu-Qiang Hao Sarun Juengpanich Si-Bo Cheng Tuck-Whye Wong Xu-Xu Yang Tie-Feng Li Xiu-Jun Cai Wei Yang 《Military Medical Research》 SCIE CAS CSCD 2023年第6期763-777,共15页
Background Reconstruction of damaged tissues requires both surface hemostasis and tissue bridging.Tissues with damage resulting from physical trauma or surgical treatments may have arbitrary surface topographies,makin... Background Reconstruction of damaged tissues requires both surface hemostasis and tissue bridging.Tissues with damage resulting from physical trauma or surgical treatments may have arbitrary surface topographies,making tissue bridging challenging.Methods This study proposes a tissue adhesive in the form of adhesive cryogel particles(ACPs) made from chitosan,acrylic acid,1-ethyl-3-(3-dimethylaminopropyl) carbodiimide(EDC) and N-hydroxysuccinimide(NHS).The adhesion performance was examined by the 180-degree peel test to a collection of tissues including porcine heart,intestine,liver,muscle,and stomach.Cytotoxicity of ACPs was evaluated by cell proliferation of human normal liver cells(LO2)and human intestinal epithelial cells(Caco-2).The degree of inflammation and biodegradability were examined in dorsal subcutaneous rat models.The ability of ACPs to bridge irregular tissue defects was assessed using porcine heart,liver,and kidney as the ex vivo models.Furthermore,a model of repairing liver rupture in rats and an intestinal anastomosis in rabbits were established to verify the effectiveness,biocompatibility,and applicability in clinical surgery.Results ACPs are applicable to confined and irregular tissue defects,such as deep herringbone grooves in the parenchyma organs and annular sections in the cavernous organs.ACPs formed tough adhesion between tissues[(670.9±50.1) J/m^(2) for the heart,(607.6±30.0) J/m^(2) for the intestine,(473.7±37.0) J/m^(2) for the liver,(186.1±13.3) J/m^(2) for the muscle,and(579.3±32.3) J/m^(2) for the stomach].ACPs showed considerable cytocompatibility in vitro study,with a high level of cell viability for 3 d[(98.8±1.2)%for LO2 and(98.3±1.6)%for Caco-2].It has comparable inflammation repair in a ruptured rat liver(P=0.58 compared with suture closure),the same with intestinal anastomosis in rabbits(P=0.40 compared with suture anastomosis).Additionally,ACP-based intestinal anastomosis(less than 30 s) was remarkably faster than the conventional suturing process(more than 10 min).When ACPs degrade after surgery,the tissues heal across the adhesion interface.Conclusions ACPs are promising as the adhesive for clinical operations and battlefield rescue,with the capability to bridge irregular tissue defects rapidly. 展开更多
关键词 Tissue reconstruction Wet adhesion adhesive hydrogel BIOadhesive
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Xanthan Gum—Bio-Based Raw Material for Wood Adhesive
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作者 Ravindra V. Gadhave 《Green and Sustainable Chemistry》 CAS 2023年第2期153-161,共9页
Due to their lower environmental impact, ease of accessibility, low cost, and biodegradability, bio-renewable sources have been used extensively in the last several decades to synthesize adhesives, substituting petroc... Due to their lower environmental impact, ease of accessibility, low cost, and biodegradability, bio-renewable sources have been used extensively in the last several decades to synthesize adhesives, substituting petrochemical-based adhesive. Vegetable oils (including palm, castor, jatropha, and soybean oils), lactic acid, potato starch, and other bio-renewable sources are all excellent sources for the synthesis of adhesives that are being taken into consideration for the synthesis of “eco-friendly” adhesives. Due to their widespread use, accessibility, affordability, and biodegradability, biobased raw materials like carbohydrates used to synthesize wood and wood composite adhesive have gradually replaced petrochemical-based adhesive. Recently, xanthan gum, a naturally occurring polymer, has drawn the interest of scientists as a potentially petroleum source replacement. It possesses specific rheological characteristics, excellent water solubility, and stability to heat, and can be used as a binder, thickener, suspending agent, and stabilizer. Xanthan gum increases the adhesive strength in addition to increasing the viscosity of water-soluble adhesives. This article discusses xanthan gum as a potential substitute for traditional raw materials derived from petroleum that is used as a raw material for adhesives. 展开更多
关键词 Xanthan Gum Bio-Polymer adhesive WOOD Carbohydrates
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