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Balmer H_α,H_β and H_γ Spectral Lines Intensities in High-Power RF Hydrogen Plasmas 被引量:1
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作者 王松柏 雷光玖 +1 位作者 刘东平 杨思泽 《Plasma Science and Technology》 SCIE EI CAS CSCD 2014年第3期219-222,共4页
Hα(Balmer-alpha), Hβ (Balmer-beta) and Hγ (Balmer-gamma) spectral line inten- sities in atomic hydrogen plasma are investigated by using a high-power RF source. The intensities of the Hα, Hβ and Hγ spectra... Hα(Balmer-alpha), Hβ (Balmer-beta) and Hγ (Balmer-gamma) spectral line inten- sities in atomic hydrogen plasma are investigated by using a high-power RF source. The intensities of the Hα, Hβ and Hγ spectral lines are detected by increasing the input power (0-6 kW) of ICPs (inductively coupled plasmas). With the increase of net input power, the intensity of Hα im- proves rapidly (0-2 kW), and then reaches its dynamic equilibrium; the intensities of Hβ can be divided into three processes: obvious increase (0-2 kW), rapid increase (2-4 kW), almost constant (4-6 kW); while the intensities of Hγ increase very slowly. The energy levels of the excited hydro- gen atoms and the splitting energy levels produced by an obvious Stark effect play an important role in the results. 展开更多
关键词 Keywords: high-power RF (radio frequency) source ICPs (inductively coupled plasmas) and spectral lines intensity Boltzmann distribution law Stark effect transitionprobability
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Extreme ultraviolet and soft x-ray spectral lines in Rb ⅩⅩⅨ
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作者 Indu Khatri Arun Goyal +2 位作者 Sunny Aggarwal A K Singh Man Mohan 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第3期134-144,共11页
An extensive theoretical set of atomic data for Rb XXIX in a wide range with L-shell electron excitations to the M-shell has been reported. We have computed energy levels for the lowest 113 fine structure levels of Rb... An extensive theoretical set of atomic data for Rb XXIX in a wide range with L-shell electron excitations to the M-shell has been reported. We have computed energy levels for the lowest 113 fine structure levels of Rb XXIX. The fully relativistic multiconfigurational Dirac-Fock method (MCDF) within the framework of Dirac-Coulomb Hamiltonian taking quantum electrodynamics (QED) and Breit corrections into account has been adopted for calculations. Radiative data are reported for electric dipole (El), magnetic dipole (MI), electric quadrupole (E2), and magnetic quadrupole (M2) transitions from the ground level, although calculations have been performed for a much larger number of levels. To assess the accuracy of results, we performed analogous calculations using flexible atomic code (FAC). Comparisons are made with existing available results and a good agreement has been achieved. Most of the wavelengths calculated lie in the soft x-ray (SXR) region. Lifetimes for all 113 levels have also been provided for the first time. Additionally, we have provided the spectra for allowed transitions from n = 2 to n = 3 within the x-ray region and also compared our SXR photon wavelengths with experimentally recognized wavelengths. We hope that our results will be beneficial in fusion plasma research and astrophysical applications. 展开更多
关键词 energy levels WAVELENGTHS radiative rates spectral lines
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Stark-Broadened Profiles of the Spectral Line P_α in He Ⅱ Ions
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作者 段斌 Muhammad Abbas Bari +2 位作者 吴泽清 颜君 王建国 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第3期24-27,共4页
We report a systematic method to perform calculations of spectral line broadening parameters in plasmas. This method is applied to calculate Stark-broadening line profiles of Pα(n = 4 → n = 3) transitions under ce... We report a systematic method to perform calculations of spectral line broadening parameters in plasmas. This method is applied to calculate Stark-broadening line profiles of Pα(n = 4 → n = 3) transitions under certain specific plasma conditions, by treating this case as an example. In the framework of the fully relativistic Dirac R- matrix theory, we calculate the electron-impact broadening operators, which are assumed to be diagonal matrix to simplify the situation. The electric microfield distribution function is calculated by retaining Hooper's formalism. The dipole matrix elements and atomic structure parameters used in these calculations have been obtained from atomic structure GRASP code. Based on this required data, we calculate the Stark-broadened line profiles of the Paschen spectral lines in He Ⅱ ions in a systematic manner. Overall, there is a very good agreement between our calculated Stark-broadened line profiles and other line Our reported spectral line-broadening data have real also play a fundamental role in plasma modeling. broadening numerical simulation codes (Sire U and MELS). applications in plasma spectroscopy, plasma diagnosis and 展开更多
关键词 Stark-Broadened Profiles of the spectral line P line on is II in He IONS of
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Saturated absorption spectrum of cesium micrometric-thin cell with suppressed crossover spectral lines
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作者 韩俊龙 王博闻 +5 位作者 郑俊鹤 陈书源 肖伟 吴腾 郭弘 彭翔 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第7期353-360,共8页
Micrometric-thin cells(MCs)with alkali vapor atoms have been valuable for research and applications of hyperfine Zeeman splitting and atomic magnetometers under strong magnetic fields.We theoretically and experimental... Micrometric-thin cells(MCs)with alkali vapor atoms have been valuable for research and applications of hyperfine Zeeman splitting and atomic magnetometers under strong magnetic fields.We theoretically and experimentally study the saturated absorption spectra using a 100-μm cesium MC,where the pump and probe beams are linearly polarized with mutually perpendicular polarizations,and the magnetic field is along the pump beam.Because of the distinctive thin chamber of the MC,crossover spectral lines in saturated absorption spectra are largely suppressed leading to clear splittings of hyperfine Zeeman transitions in experiments,and the effect of spatial magnetic field gradient is expected to be reduced.A calculation method is proposed to achieve good agreements between theoretical calculations and experimental results.This method successfully explains the suppression of crossover lines in MCs,as well as the effects of magnetic field direction,propagation and polarization directions of the pump/probe beam on saturated absorption spectrum.The saturated absorption spectrum with suppressed crossover lines is used for laser frequency stabilization,which may provide the potential value of MCs for high spatial resolution strong-field magnetometry with high sensitivity. 展开更多
关键词 micrometric-thin cells saturated absorption spectrum hyperfine Zeeman splitting crossover spectral lines laser frequency stabilization
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Effect of Characteristic Spectral Lines on Rock Identification of LIBS
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作者 Ke ZhiQuan Wang YangEn +2 位作者 Xu Yi Dong XiPu Zhou MaoHui 《Journal of Physical Science and Application》 2015年第4期296-308,共13页
The LIBS (Laser induced-breakdown spectroscopy) combined with BPNN (Back propagation neural network) was applied in rock sorting and distinguishing for 26 rock samples of 6 types. According to contents of major el... The LIBS (Laser induced-breakdown spectroscopy) combined with BPNN (Back propagation neural network) was applied in rock sorting and distinguishing for 26 rock samples of 6 types. According to contents of major elements in samples, we selected lines of Si, Al, Fe, K, Ca, Mg, Na, Ti and Mn. These lines of 9 elements composed three characteristic spectral models which were the WSLM (Wide spectral line model), the PM (Peak model) and the PRM (Peak ratio model). The first and the second characteristic spectral model were divided into 9 kinds, as follows: the characteristic spectrum with 1 element, the characteristic spectrum with 2 elements, we can deduce the rest from this and the last one has 9 elements. The third model was divided into 8 kinds which were using AI as reference element. We analysed spectrums of the three models by BPNN. Experimental results shown that whether sorting or distinguishing these samples, identification accuracies of the PM were more than that of the PRM overall, the same as the WSLM did to the PM. While the selected number of elements was 5, 6 or 7, the identification accuracy of the WSLM could reach more than 90%. Continuing to add the number of elements to improve identification accuracy was not very obvious. 展开更多
关键词 LIBS (Laser induced-breakdown spectroscopy) BPNN (Back propagation neural network) characteristic spectral model WSLM (Wide spectral line model).
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Atomic epn(ep) Spin Models and Spectral Lines
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作者 Daekyoum Kim Baik-Hyon Ha 《American Journal of Analytical Chemistry》 2015年第13期1030-1037,共8页
We confirmed that how many kinds of epn spins the atoms have by calculating heat capacity of metals according to energy levels in the previous reference. To know more the spin models of epn of hydrogen and helium are ... We confirmed that how many kinds of epn spins the atoms have by calculating heat capacity of metals according to energy levels in the previous reference. To know more the spin models of epn of hydrogen and helium are imagined and their line spectra are counted. And the explanation of interference is discussed. Gas atoms make line spectra by optical interference. Solid atoms make them by exciting the lowest epns of their cluster first. They all make s, p energy orbit. One axis is composed of two epns. 1s or 2s of atoms except for lithium generally makes the symmetric axis. When each energy level is filled up by epns, these are symmetrically paired first. The atoms which fit the number of line spectra correctly by optical interference are hydrogen and helium. By counting the number of alignments of epns spins within the cluster, the atoms which fit the number of line spectra correctly are lithium, beryllium and phosphorus. The number of line spectra of the rest atoms which we have counted approaches the experimented numbers approximately, not correctly. 展开更多
关键词 ATOMIC Model ATOMIC CLUSTER spectral lineS RESONANCE
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Degenerate cascade fluorescence: Optical spectral-line narrowing via a single microwave cavity
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作者 Liang Hu Xiang-Ming Hu Qing-Ping Hu 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第6期346-358,共13页
For a three-level atom, two nondegenerate(even microwave and optical) electric dipole transitions are usually allowed;for either of these, the fluorescence spectra are well-described in terms of spontaneous transition... For a three-level atom, two nondegenerate(even microwave and optical) electric dipole transitions are usually allowed;for either of these, the fluorescence spectra are well-described in terms of spontaneous transitions from a triplet of dressed sublevels to an adjacent lower-lying triplet. When the three dressed sublevels are equally spaced from each other, a remarkable feature known as degenerate cascade fluorescence takes place, which displays a five-peaked structure. We show that a single cavity can make all the spectral lines extremely narrow, whether they arise from cavity-coupled or cavity-free transitions. This effect is based on intrinsic cascade lasing feedback and makes it possible to use a single microwave cavity(even a bad cavity) to narrow the spectral lines in the optical frequency regime. 展开更多
关键词 resonance fluorescence narrow spectral lines microwave cavity
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A METHOD DESCRIBING PROFILE ASYMMETRY OF SPECTRAL LINES
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作者 顾啸马 李秋莎 《Chinese Science Bulletin》 SCIE EI CAS 1991年第19期1618-1621,共4页
One of the common spectral features is asymmetry of spectral line profile for the solar activity phenomena, such as flare, erupted prominence and loop prominence system. The asymmetry is a spectral reflection of the c... One of the common spectral features is asymmetry of spectral line profile for the solar activity phenomena, such as flare, erupted prominence and loop prominence system. The asymmetry is a spectral reflection of the complex active phenomena. In general, a radial motion of matter and some special physical conditions are responsible for the asymmetry of a spectral line profile. So, it is an important aspect in researching the activity phenomena of the Sun to observe and study the asymmetry of the profile. Ye Shi-hui et al. studied the ef- 展开更多
关键词 the SUN spectral line PROFILE asymmetry.
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Gridless Variational Bayesian Inference of Line Spectral from Quantized Samples
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作者 Jiang Zhu Qi Zhang Xiangming Meng 《China Communications》 SCIE CSCD 2021年第10期77-95,共19页
Efficient estimation of line spectral from quantized samples is of significant importance in information theory and signal processing,e.g.,channel estimation in energy efficient massive MIMO systems and direction of a... Efficient estimation of line spectral from quantized samples is of significant importance in information theory and signal processing,e.g.,channel estimation in energy efficient massive MIMO systems and direction of arrival estimation.The goal of this paper is to recover the line spectral as well as its corresponding parameters including the model order,frequencies and amplitudes from heavily quantized samples.To this end,we propose an efficient gridless Bayesian algorithm named VALSE-EP,which is a combination of the high resolution and low complexity gridless variational line spectral estimation(VALSE)and expectation propagation(EP).The basic idea of VALSE-EP is to iteratively approximate the challenging quantized model of line spectral estimation as a sequence of simple pseudo unquantized models,where VALSE is applied.Moreover,to obtain a benchmark of the performance of the proposed algorithm,the Cram′er Rao bound(CRB)is derived.Finally,numerical experiments on both synthetic and real data are performed,demonstrating the near CRB performance of the proposed VALSE-EP for line spectral estimation from quantized samples. 展开更多
关键词 variational Bayesian inference expectation propagation QUANTIZATION line spectral estimation MMSE gridless
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Legendre Rational Spectral Method for Nonlinear Klein-Gordon Equation 被引量:3
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作者 Zhongqing Wang Benyu Guo 《Numerical Mathematics A Journal of Chinese Universities(English Series)》 SCIE 2006年第2期143-149,共7页
A Legendre rational spectral method is proposed for the nonlinear Klein-Gordon equation on the whole line. Its stability and convergence are proved. Numerical results coincides well with the theoretical analysis and d... A Legendre rational spectral method is proposed for the nonlinear Klein-Gordon equation on the whole line. Its stability and convergence are proved. Numerical results coincides well with the theoretical analysis and demonstrate the e?ciency of this approach. 展开更多
关键词 勒让德有理数光谱方法 非线性方程 克莱因-戈登方程 收敛 稳定性
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Iterative Reweighted <i>l</i><sub>1</sub>Penalty Regression Approach for Line Spectral Estimation
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作者 Fei Ye Xian Luo Wanzhou Ye 《Advances in Pure Mathematics》 2018年第2期155-167,共13页
In this paper, we proposed an iterative reweighted l1?penalty regression approach to solve the line spectral estimation problem. In each iteration process, we first use the ideal of Bayesian lasso to update the sparse... In this paper, we proposed an iterative reweighted l1?penalty regression approach to solve the line spectral estimation problem. In each iteration process, we first use the ideal of Bayesian lasso to update the sparse vectors;the derivative of the penalty function forms the regularization parameter. We choose the anti-trigonometric function as a penalty function to approximate the?l0? norm. Then we use the gradient descent method to update the dictionary parameters. The theoretical analysis and simulation results demonstrate the effectiveness of the method and show that the proposed algorithm outperforms other state-of-the-art methods for many practical cases. 展开更多
关键词 line spectral Estimation PENALTY Regression Bayesian Lasso ITERATIVE Reweighted APPROACH
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Humidity-Induced Spectral Shift in a Cross-DispersionEchelle Spectrometer and Its Theoretical Investigation 被引量:1
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作者 LIU Ke-ling HUANG Mao Hieftje Gary M 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2010年第9期2555-2559,共5页
The relationship between ambient relative humidity H and the position shift of a spectral line was investigated both experimentally and theoretically.An echelle-based ICP emission spectrometer equipped with a CID dete... The relationship between ambient relative humidity H and the position shift of a spectral line was investigated both experimentally and theoretically.An echelle-based ICP emission spectrometer equipped with a CID detector was used for experimental verification of the derived model.The shift of a spectral line is quantitatively described by two defined spectral shift functions: Δλx(x,λ,H)(in the x direction of the CID detector) and Δλy(y,λ,H)(in the y direction of the CID detector).Experimental results indicate that Δλx(x,λ,H) does not change with a variation in ambient relative humidity, but Δλy(y,λ,H) does.A spectral shift equation,i.e.an empirical second-order polynomial equation,can be used to describe the relationship between Δλy(y,λ,H) and H.Based on the classical dipole model,classical mechanics and electrodynamics the empirical spectral-shift equation involving Δλy(y,λ,H) and H was theoretically deduced.The theoretical result is in good agreement with the experimental findings.The theoretical results indicate that the coefficients of the empirical spectral-shift equation are related to the basic physical parameters of materials and the geometric configuration of the echelle CID ICP-AES,and also provide physical meaning to the coefficients of the empirical shift equation obtained experimentally. 展开更多
关键词 Emission spectrometry Position shift of a spectral line spectral-shift equation
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Absorption linewidth inversion with wavelength modulation spectroscopy 被引量:3
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作者 颜悦 杜振辉 +1 位作者 李金义 王瑞雪 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第2期368-373,共6页
For absorption linewidth inversion with wavelength modulation spectroscopy(WMS), an optimized WMS spectral line fitting method was demonstrated to infer absorption linewidth effectively, and the analytical expressio... For absorption linewidth inversion with wavelength modulation spectroscopy(WMS), an optimized WMS spectral line fitting method was demonstrated to infer absorption linewidth effectively, and the analytical expressions for relationships between Lorentzian linewidth and the separations of first harmonic peak-to-valley and second harmonic zero-crossing were deduced. The transition of CO_2 centered at 4991.25 cm^(-1) was used to verify the optimized spectral fitting method and the analytical expressions. Results showed that the optimized spectra fitting method was able to infer absorption accurately and compute more than 10 times faster than the commonly used numerical fitting procedure. The second harmonic zero-crossing separation method calculated an even 6 orders faster than the spectra fitting without losing any accuracy for Lorentzian dominated cases. Additionally, linewidth calculated through second harmonic zero-crossing was preferred for much smaller error than the first harmonic peak-to-valley separation method. The presented analytical expressions can also be used in on-line optical sensing applications, electron paramagnetic resonance, and further theoretical characterization of absorption lineshape. 展开更多
关键词 absorption linewidth wavelength modulation spectroscopy absorption spectroscopy spectral line fitting separation of harmonics
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Intensities and shifts of Lyman and Balmer lines of hydrogen-like ions in high density plasmas 被引量:1
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作者 G.P.Zhao L.Liu +2 位作者 J.G.Wang R.K.Janev J.Yan 《Matter and Radiation at Extremes》 SCIE EI CAS 2018年第6期300-311,共12页
The spectral line intensities and line shifts of Lyman and Balmer series for transitions up to n=5 of hydrogen-like ion are studied in plasmas with densities and temperatures in the ranges n_(c)~10^(18)-10^(21)cm^(-3)... The spectral line intensities and line shifts of Lyman and Balmer series for transitions up to n=5 of hydrogen-like ion are studied in plasmas with densities and temperatures in the ranges n_(c)~10^(18)-10^(21)cm^(-3),T_(e)=0.3e1.2 eV respectively.The screened potential used to describe the interaction between charged particles includes the electron exchange-correlation and finite-temperature gradient effects and is valid for both weakly and strongly coupled plasmas.The dependencies of alpha,beta and gamma line shifts of Lyman and Balmer series on plasma density(for fixed temperature)and temperature(for fixed density)are investigated.The results for the H_(a)line shifts are compared with the available high-density experimental data. 展开更多
关键词 Screened coulomb interaction Hydrogen-like ion spectral lines High density plasmas
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FFT Nuttall 窗四谱线插值修正谐波检测算法
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作者 邓慧慧 杨松霖 +2 位作者 杨学良 洪应平 徐贺杨 《测试技术学报》 2025年第1期96-103,共8页
利用传统傅里叶变换进行谐波信号分析时,由于很难严格做到同步采样,整周期截断,从而不可避免地产生频谱泄露与栏栅效应,降低了检测结果的精确性。为了提高检测结果精确度,在FFT(Fast Fourier Transformation)的基础上,对Hann窗、Blackma... 利用传统傅里叶变换进行谐波信号分析时,由于很难严格做到同步采样,整周期截断,从而不可避免地产生频谱泄露与栏栅效应,降低了检测结果的精确性。为了提高检测结果精确度,在FFT(Fast Fourier Transformation)的基础上,对Hann窗、Blackman窗、Blackmanharris窗、Nuttall窗的四谱线插值算法进行了研究,通过多项式拟合推导出不同余旋窗四线插值对应的幅值、频率、相位的修正公式。并在Matlab上对不同余旋窗四线插值算法进行仿真实验,与对应余旋窗的三谱线插值算法进行对比分析,结果表明四项三阶Nuttall窗的四谱线插值算法幅值精确度可达到10^(-5)~10^(-9)数量级,频率精确度可达到10^(-8)~10^(-9)数量级,相位精确度可达到10^(-3)~10^(-7)数量级,与其它算法相比精确度更高,旁瓣性能更好,能更好地抑制频谱泄露与栏栅效应。 展开更多
关键词 频谱泄露 栏栅效应 窗函数 三线谱插值 四线谱插值
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Balmer-alpha and Balmer-beta Stark line intensity profiles for high-power hydrogen inductively coupled plasmas
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作者 王松柏 雷光玖 +1 位作者 刘东平 杨思泽 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第7期499-504,共6页
We compare Balmer-alpha (Ha) and Balmer-beta (Hβ) emissions from high-power (1.0-6.0 kW) hydrogen inductively coupled plasmas (ICPs), and propose region Ⅰ (0.0-2.0 kW), region Ⅱ (2.0-5.0 kW), and region... We compare Balmer-alpha (Ha) and Balmer-beta (Hβ) emissions from high-power (1.0-6.0 kW) hydrogen inductively coupled plasmas (ICPs), and propose region Ⅰ (0.0-2.0 kW), region Ⅱ (2.0-5.0 kW), and region Ⅲ (5.0-6.0 kW). In region Ⅰ, both Ha emission intensity (la) and Hβ emission intensity (1β) increase with radio frequency (RF) power, which is explained by the corona model and Boltzmann's law, etc. However, in region II, la almost remains constant while 1β rapidly achieves its maximum value. In region Ⅲ, 1α slightly increases with RF power, while 1β decreases with RF power, which deviates significantly from the theoretical explanation for the Ha and Hβ emissions in region I. It is suggested that two strong electric fields are generated in high-power (2.0-6.0 kW) hydrogen ICPs: one is due to the external electric field of high-power RF discharge, and the other one is due to the micro electric field of the ions and electrons around the exited state hydrogen atoms in ICPs. Therefore, the strong Stark effect can play an important role in explaining the experimental results. 展开更多
关键词 high-power radio frequency plasma and spectral lines in hydrogen ICPs Stark effect
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A NEW ALGORITHM FOR ADAPTIVE LATTICE FILTERAND ITS APPLICATION IN THE SPEECH LINEARPREDICTIVE SYNTHESIS 被引量:1
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作者 Jiang Taihui (institute of Information Science, Wuji University Jiangmen, Guangdong 529020) 《Journal of Electronics(China)》 1996年第4期325-332,共8页
In this paper, an adaptive line spectral pair filter is derived from an adaptive lattice filter. A least-mean-square(LMS) type adaptive algorithm used to calculate directly the line spectral pair(LSP) coefficients on ... In this paper, an adaptive line spectral pair filter is derived from an adaptive lattice filter. A least-mean-square(LMS) type adaptive algorithm used to calculate directly the line spectral pair(LSP) coefficients on a stage-by-stage basis is presented. Experimental results show that the algorithm has higher convergence rate and lower misadjustment as compared with the other algorithms. The LSP coefficients calculated by the algorithm have been used to carry out speech linear predictive synthesis, resulting in better results than PARCOR coefficients. 展开更多
关键词 line spectral PAIR FILTER Adaptive LATTICE FILTER linear prediction LMS algorithm
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CHARACTERISTICS OF MICROSTRIP TRANSMISSION LINES
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作者 吴晓东 林为干 《Journal of Electronics(China)》 1990年第1期1-5,共5页
An efficient hybrid field solution to microstrip transmission lines is presented byusing SLE and SLM modes in spectral domain.It by-passes the lengthy process of formulatingthe determinant equation for the unknown pro... An efficient hybrid field solution to microstrip transmission lines is presented byusing SLE and SLM modes in spectral domain.It by-passes the lengthy process of formulatingthe determinant equation for the unknown propagation constant.Compared with spectral domainadmittance approach,this method is clear in both physical and mathematical senses and may beapplied to a variety of structures. 展开更多
关键词 MICROSTRIP lineS SLE/SLM MODES spectral DOMAIN approach
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改进的迈克尔逊干涉仪测量钠黄光双线波长差
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作者 陈海良 侯岩雪 +1 位作者 高静 张素红 《科学技术创新》 2024年第13期205-208,共4页
在迈克尔逊干涉仪实验教学及科学研究过程中发现齿轮经常脱扣的现象,这对测量结果产生了严重影响。本文中,我们将传统的齿轮咬合式迈克尔逊干涉仪改进为杠杆式迈克尔逊干涉仪,有助于避免齿轮咬合式迈克尔逊干涉仪中多个齿轮间容易脱扣... 在迈克尔逊干涉仪实验教学及科学研究过程中发现齿轮经常脱扣的现象,这对测量结果产生了严重影响。本文中,我们将传统的齿轮咬合式迈克尔逊干涉仪改进为杠杆式迈克尔逊干涉仪,有助于避免齿轮咬合式迈克尔逊干涉仪中多个齿轮间容易脱扣的现象。利用钠光灯照射杠杆式迈克尔逊干涉仪,观察到了明显的光拍干涉图样,测量了钠黄光双线波长差。钠黄光双线波长差的测量结果为0.5953±0.0054(nm)。本文的研究有助于提升迈克尔逊干涉仪装置的测量稳定性,实现在光谱定标、光学传感、生化检测等领域的长期稳定使用;有助于提升学生发现问题、解决问题的能力;以及有助于学生提升将不同科目知识相结合的能力。 展开更多
关键词 迈克尔逊干涉仪 钠黄光 光拍 波长差
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X荧光测定铌钽原矿中铌和钽及不确定度评定
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作者 童晓旻 董再蒸 高鹏 《江西化工》 CAS 2024年第4期6-10,共5页
本文建立了X射线荧光熔片法测定铌钽原矿中铌和钽的分析方法。采用低稀释比(Li2B4O7:LiNO3:样品=4:0.6:1)制备熔融玻璃片,以光谱纯SiO2、Al2O3和Fe2O3混合物为基体,添加Nb、Ta标准溶液及少量干扰元素Rb、Y、Mo、Zr、W、Ce制备校准曲线... 本文建立了X射线荧光熔片法测定铌钽原矿中铌和钽的分析方法。采用低稀释比(Li2B4O7:LiNO3:样品=4:0.6:1)制备熔融玻璃片,以光谱纯SiO2、Al2O3和Fe2O3混合物为基体,添加Nb、Ta标准溶液及少量干扰元素Rb、Y、Mo、Zr、W、Ce制备校准曲线所用标准样品。使用Rh靶compton散射线为内标线校正基体效应对Nb元素的影响;Ta元素则外加HfO2,并用Hf Lβ3为内标线。本文讨论了复杂铌钽原矿和本实验试剂中含有的Br、Rb、Y、Mo、Zr、Nb、W、Hf和Ta各元素之间的光谱干扰。对于Br、Rb、Y、Nb及Hf和Ta之间的谱线重叠干扰,采用干扰系数法逐级扣除;而Mo Kα和Zr Kα背景对Nb Kα的影响及W Lα背景对Ta Lα的影响,则分别通过选取40.000°和70.500°公共背景点来避免,最后得到分析元素Nb Kα和Ta Lα谱线净强度。本文选用钽矿石成分分析标准物质(GBW07155)作为方法验证样品,并对Nb、Ta测量结果不确定度进行评定。最终本方法报出结果:w(Nb_(2)O_(5))=(0.044±0.002)%(k=2);w(Ta2O5)=(0.069±0.002)%(k=2)。 展开更多
关键词 X射线荧光 谱线重叠校正 不确定度
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