Electrochemical technologies for the on-site treatment of spent acid etchant have received great attention due their ease of operation and economic benefits. On the other hand, a large amount of Cl2 is generated durin...Electrochemical technologies for the on-site treatment of spent acid etchant have received great attention due their ease of operation and economic benefits. On the other hand, a large amount of Cl2 is generated during the electrolysis process, which leads to potential environmental risks. In the present work, a novel threecompartment ceramic membrane flow reactor, including a cathode chamber, an anode chamber, and a gas absorption chamber was developed. The three chambers were divided by an Al2O3 ceramic membrane and a breathable hydrophobic anode diffusion electrode(ADE). The Cl2 evolution onset potential of the ADE was increased to 1.19 V from 1.05 V of the graphite felt, effectively inhibiting the chlorine evolution reaction(CER).The anode-generated Cl2 diffused into the gas absorption chamber through the ADE and was eventually consumed by the H2O2 adsorbent. Cu could be recovered without emitting chlorine due to the special structure of reactor. The current efficiency of copper precipitation and cathode reduction from Cu2+to Cu+reached 97.7%at a working current of 150 m A. These results indicated that the novel membrane reactor had high potential for application in the copper recovery industry.展开更多
Considering the characteristics of carbonate reservoirs in the Middle East,a low-viscosity microemulsion acid that can be prepared on site and has an appropriate retardation ability was developed.It was compared with ...Considering the characteristics of carbonate reservoirs in the Middle East,a low-viscosity microemulsion acid that can be prepared on site and has an appropriate retardation ability was developed.It was compared with four conventional acid systems(hydrochloric acid,gelled acid,emulsified acid and surfactant acid)through experiments of rotating disk,multistage acid fracturing and core flooding with CT scanning.The micro-etching characteristics and conductivity of fracture surfaces were clarified,and the variation of saturation field during water invasion and flowback of spent acid and the recovery of oil phase relative permeability were quantitatively evaluated.The study shows that the addition of negatively charged agent to the oil core of microemulsion acid can enhance its adsorption capacity on the limestone surface and significantly reduce the H+mass transfer rate.Moreover,the negatively charged oil core is immiscible with the Ca^(2+)salt,so that the microemulsion acid can keep an overall structure not be damaged by Ca^(2+)salt generated during reaction,with adjustable adsorption capacity and stable microemulsion structure.With high vertical permeability along the fracture walls,the microemulsion acid can penetrate into deep fracture wall to form network etching,which helps greatly improve the permeability of reservoirs around the fractures and keep a high conductivity under a high closure pressure.The spent microemulsion acid is miscible with crude oil to form microemulsion.The microemulsion,oil and water are in a nearly miscible state,with basically no water block and low flowback resistance,the flowback of spent acid and the relative permeability of oil are recovered to a high degree.展开更多
Sulfuric acid leaching process was applied to extract nickel from roasting-dissolving residue of a spent catalyst, the effect of different parameters on nickel extraction was investigated by leaching experiments, and ...Sulfuric acid leaching process was applied to extract nickel from roasting-dissolving residue of a spent catalyst, the effect of different parameters on nickel extraction was investigated by leaching experiments, and the leaching kinetics of nickel was analyzed. The experimental results indicate that the effects of particle size and sulfuric acid concentration on the nickel extraction are remarkable; the effect of reaction temperature is mild; while the effect of stirring speed in the range of 400-1 200 r/min is negligible. Decreasing particle size or increasing sulfuric acid concentration and reaction temperature, the nickel extraction efficiency is improved. 93.5% of nickel in residue is extracted under suitable leaching conditions, including particle size (0.074-0.100) mm, sulfuric acid concentration 30% (mass fraction), temperature 80 ℃, reaction time 180 min, mass ratio of liquid to solid 10 and stirring speed 800 r/min. The leaching kinetics analyses shows that the reaction rate of leaching process is controlled by diffusion through the product layer, and the calculated activation energy of 15.8 kJ/mol is characteristic for a diffusion controlled process.展开更多
Auto-catalysts were the largest consumers of platinum group metals and the most important secondary resources, recovery of PGMs from spent auto-catalysts by leaching with various acidities were investigated. The leach...Auto-catalysts were the largest consumers of platinum group metals and the most important secondary resources, recovery of PGMs from spent auto-catalysts by leaching with various acidities were investigated. The leaching thermodynamics of PGMs at 363 K was first discussed. At 363 K the higher the acidities of HCl, the higher the leaching recoveries of PGMs, and the sequence of leaching recovery was Pd>Pt>Rh. When H2SO4 used alone, the leaching recoveries of PGMs was low, when the acidity of H2SO4 increasing, the leaching recovery of Rh kept stable.展开更多
基金Supported by the National Natural Science Foundation of China(21838005,21676139)the Higher Education Natural Science Foundation of Jiangsu Province(15KJA530001)+1 种基金the Key Scientific Research and Development Projects of Jiangsu Province(BE201800901)Research Fund of State Key Laboratory of MaterialsOriented Chemical Engineering(ZK201604).
文摘Electrochemical technologies for the on-site treatment of spent acid etchant have received great attention due their ease of operation and economic benefits. On the other hand, a large amount of Cl2 is generated during the electrolysis process, which leads to potential environmental risks. In the present work, a novel threecompartment ceramic membrane flow reactor, including a cathode chamber, an anode chamber, and a gas absorption chamber was developed. The three chambers were divided by an Al2O3 ceramic membrane and a breathable hydrophobic anode diffusion electrode(ADE). The Cl2 evolution onset potential of the ADE was increased to 1.19 V from 1.05 V of the graphite felt, effectively inhibiting the chlorine evolution reaction(CER).The anode-generated Cl2 diffused into the gas absorption chamber through the ADE and was eventually consumed by the H2O2 adsorbent. Cu could be recovered without emitting chlorine due to the special structure of reactor. The current efficiency of copper precipitation and cathode reduction from Cu2+to Cu+reached 97.7%at a working current of 150 m A. These results indicated that the novel membrane reactor had high potential for application in the copper recovery industry.
基金Supported by the National Science and Technology Major Project(2017ZX05009-005-003)National Natural Science Foundation of China Funded General Project(52174045)+1 种基金Chinese Academy of Engineering Strategic Consulting Project(2018-XZ-09)China National Petroleum Corporation-China University of Petroleum(Beijing)Strategic Cooperation Science and Technology Project(ZLZX2020-01).
文摘Considering the characteristics of carbonate reservoirs in the Middle East,a low-viscosity microemulsion acid that can be prepared on site and has an appropriate retardation ability was developed.It was compared with four conventional acid systems(hydrochloric acid,gelled acid,emulsified acid and surfactant acid)through experiments of rotating disk,multistage acid fracturing and core flooding with CT scanning.The micro-etching characteristics and conductivity of fracture surfaces were clarified,and the variation of saturation field during water invasion and flowback of spent acid and the recovery of oil phase relative permeability were quantitatively evaluated.The study shows that the addition of negatively charged agent to the oil core of microemulsion acid can enhance its adsorption capacity on the limestone surface and significantly reduce the H+mass transfer rate.Moreover,the negatively charged oil core is immiscible with the Ca^(2+)salt,so that the microemulsion acid can keep an overall structure not be damaged by Ca^(2+)salt generated during reaction,with adjustable adsorption capacity and stable microemulsion structure.With high vertical permeability along the fracture walls,the microemulsion acid can penetrate into deep fracture wall to form network etching,which helps greatly improve the permeability of reservoirs around the fractures and keep a high conductivity under a high closure pressure.The spent microemulsion acid is miscible with crude oil to form microemulsion.The microemulsion,oil and water are in a nearly miscible state,with basically no water block and low flowback resistance,the flowback of spent acid and the relative permeability of oil are recovered to a high degree.
基金Project (50574101) supported by the National Natural Science Foundation of ChinaProject (2003UDBEA00C020) supported by the Collaborative Project of School and Province of Yunnan Province,China
文摘Sulfuric acid leaching process was applied to extract nickel from roasting-dissolving residue of a spent catalyst, the effect of different parameters on nickel extraction was investigated by leaching experiments, and the leaching kinetics of nickel was analyzed. The experimental results indicate that the effects of particle size and sulfuric acid concentration on the nickel extraction are remarkable; the effect of reaction temperature is mild; while the effect of stirring speed in the range of 400-1 200 r/min is negligible. Decreasing particle size or increasing sulfuric acid concentration and reaction temperature, the nickel extraction efficiency is improved. 93.5% of nickel in residue is extracted under suitable leaching conditions, including particle size (0.074-0.100) mm, sulfuric acid concentration 30% (mass fraction), temperature 80 ℃, reaction time 180 min, mass ratio of liquid to solid 10 and stirring speed 800 r/min. The leaching kinetics analyses shows that the reaction rate of leaching process is controlled by diffusion through the product layer, and the calculated activation energy of 15.8 kJ/mol is characteristic for a diffusion controlled process.
文摘Auto-catalysts were the largest consumers of platinum group metals and the most important secondary resources, recovery of PGMs from spent auto-catalysts by leaching with various acidities were investigated. The leaching thermodynamics of PGMs at 363 K was first discussed. At 363 K the higher the acidities of HCl, the higher the leaching recoveries of PGMs, and the sequence of leaching recovery was Pd>Pt>Rh. When H2SO4 used alone, the leaching recoveries of PGMs was low, when the acidity of H2SO4 increasing, the leaching recovery of Rh kept stable.
基金the financial support on this research from the Talent Training Program of Yunnan Province, China (No. 202005AC160041)the Major R&D Project of Yunnan Province of China (No. 202002AB0800020102)。
文摘采用湿法冶金从废旧LiFePO_(4)正极粉末中回收有价金属锂和铁,回收产物作为原料制备磷酸铁锂。通过优化浸出工艺参数,在丙酮酸浓度为3.0 mol/L、H_(2)O_(2)体积为2 m L、固液比为0.1 g/m L、反应温度为80℃以及反应时间为20min的条件下,Li的浸出效率达到96.56%。采用XRD、XPS、FE-SEM和EDS对浸出残渣进行表征。结果表明,浸出残渣为FePO_(4),Fe/P摩尔比为0.974。将浸出液的pH值调整到12.0,并在80℃搅拌2 h后,浸出液中的Li通过原位沉淀以Li_(3)PO_(4)形式回收,其纯度为96.5%(质量分数)。丙酮酸/H_(2)O_(2)溶液浸出Li的反应动力学数据符合Avrami模型(R^(2)>0.95)。Li浸出过程的活化能较低,表明扩散限制浸出过程中的反应速率。
