Iron is an impurity widely occurred in sphalerite,and its effect on sphalerite flotation is complex.In this work,the effects of iron content and spin state on electronic properties and floatability of iron-bearing sph...Iron is an impurity widely occurred in sphalerite,and its effect on sphalerite flotation is complex.In this work,the effects of iron content and spin state on electronic properties and floatability of iron-bearing sphalerite are comprehensively studied using density functional theory Hubbard U(DFT+U)calculations combined with coordination chemistry flotation.The band gap of ideal sphalerite is 3.723 eV,and thus electron transition is difficult to occur,resulting in poor floatability.The results suggest the band gap of sphalerite decreases with increasing iron content.For low iron content,the decreased band gap facilitates electron transition;at this case,Fe^(2+)in a high-spin state possesses oneπelectron pair,which can form a weakπ-backbonding with xanthate,causing increasing floatability.However,for medium and high iron-bearing sphalerite,with the further decrease of band gap,Fe^(2+)is oxidized to Fe^(3+)due to electrochemical interaction,and henceπ-backbonding is eliminated,leading to lower floatability of iron-bearing sphalerite,which is consistent with the flotation experimental results.This work could give a deeper understanding of how sphalerite flotation behaviors are affected by iron content.展开更多
The Dulong deposit,located in the Laojunshan area of southeastern Yunnan,China,is an important polymetallic deposit due to its high reserves of tin,zinc,and indium.The occurrence state of indium is critical for unders...The Dulong deposit,located in the Laojunshan area of southeastern Yunnan,China,is an important polymetallic deposit due to its high reserves of tin,zinc,and indium.The occurrence state of indium is critical for understanding its supernormal enrichment mechanism.Previous studies investigated the occurrence state of indium(including the valence state)based on the indium content in sphalerite and the correlation between metal concentrations.However,more evidence is needed to better constrain indium occurrence at the micro-,nano-,or even atomic scale.In this study,EPMA-FIB-SEM-TEM and XPS techniques were employed to investigate the indium distribution characteristics and occurrence state in sphalerite from the Dulong Sn–Zn–In polymetallic deposit.The maximum concentration of indium in the indium-rich sphalerite samples is 0.37%,and the results of the EPMA analysis showed a relatively homogeneous distribution of indium in sphalerite.The FIB-SEM-TEM results demonstrated that the lattice stripes of sphalerite were periodically and continuously distributed at the nanoscale,confirming that sphalerite in the deposit was an excellent single crystal structure,and the peak heights of the various characteristic peaks of indium in the EDX spectra were relatively close to each other,with no distinct peaks of high indium content.In addition,the XPS results indicate that the element valence state of indium in sphalerite is In^(3+),and it combines with S^(2-)to form a bond.These results indicate that indium in sphalerite of the Dulong deposit is uniformly distributed at both the micro-and nanoscale,and there is no indium-independent mineral.In^(3+)enters the crystal lattice of sphalerite by replacing Zn2+in the form of isomorphic substitution.展开更多
The western Hunan-eastern Guizhou Zn-Pb metallogenic belt is one of the important Zn-Pb mineralization regions in China.The Dadongla deposit,located in the northeast of Guizhou Province,is one of the typical Zn-Pb dep...The western Hunan-eastern Guizhou Zn-Pb metallogenic belt is one of the important Zn-Pb mineralization regions in China.The Dadongla deposit,located in the northeast of Guizhou Province,is one of the typical Zn-Pb deposits in the region and has estimated resources more than 12 million metric tons(Mt)with an average grade of 4.11 wt%Zn+Pb.Its orebodies are hosted in the lower Cambrian Aoxi Formation dolomite,occurring as bedded,para-bedded in shape,and in conformity with the wall rock.The ore mineral assemblage is simple,dominated by sphalerite with minor pyrite and galena,and the gangue minerals are composed of dolomite,calcite with minor bitumen and barite.In view of the lack of geological and geochemical researches,the genesis of Zn-Pb ore is still unclear.Laser ablation-inductively coupled plasma mass spectrometry(LA-ICPMS)spot and mapping analyses were used to obtain sphalerite trace element chemistry in the Dadongla Zn-Pb deposit in Guizhou,China,aiming to constrain its ore genesis.The results show that sphalerite is characterized by the enrichment of Cd,Fe,Ge and Hg,corresponding with that of typical MVT deposits.Four zones were identified in the sphalerite crystal from Dadongla from the center to margin according to the color bands.in which the zone in the center,representing the early ore-stage sphalerite,is characterized by enrichment of Cd relatively,while the zone forming at late ore-stage is enriched in Ge and Hg relatively.The finding was controlled by differential leached metals content in ore-forming fluid from its source rock.Notably,critical element Ge trends to be enriched at the late ore-stage and follows a substitution of 2 Zn^2+(?)Ge^4++□(vacancy).Moreover,the calculated ore-forming temperature ranges from 79.9℃to 177.6℃by the empirical formula,which is similar to that of typical Mississippi Valley-type(MVT)deposits.Compared with the features of trace elements in sphalerite from different types of deposits,together with the geology,the Dadongla deposit belongs to an MVT Zn-Pb deposit.展开更多
The kinetics of ferric chloride leaching of sphalerite in the microwave field has being studied in this paper.According to the experimental data,the rate of dissolution of sphalerite microwave irradiation heating is f...The kinetics of ferric chloride leaching of sphalerite in the microwave field has being studied in this paper.According to the experimental data,the rate of dissolution of sphalerite microwave irradiation heating is faster than that with conventional heating.The dissolution of sphalerite in the microwave field was investigated in different condition of temperature,concentration of FeCl,and particle size and a nonisothermal kinetic equation has being obtained.展开更多
The Hongdonggou Pb-Zn polymetallic ore deposit,located in the southwestern part of the Luanchuan Mo-W-Pb-Zn-Ag polymetallic ore mineralization in Henan Province,China,is an important part of the East Qinling metalloge...The Hongdonggou Pb-Zn polymetallic ore deposit,located in the southwestern part of the Luanchuan Mo-W-Pb-Zn-Ag polymetallic ore mineralization in Henan Province,China,is an important part of the East Qinling metallogenic belt.The orebodies in the deposit,which are vein,bedded and lenticular,are mainly hosted in the syenite porphyry,and formed within the carbonate and clastic rocks of the Yuku and Qiumugou formations partially.The genesis of the deposit has previously been argued to be of hydrothermal-vein type or of skarn-hydrothermal type.In this study,we report the results of Rb-Sr isotopic dating based on sphalerites from the main orebody of the Hongdonggou Pb-Zn polymetallic ore deposit,which yield an isochron age of 135.7 ± 3.2 Ma,constraining the timing of mineralization as early Cretaceous.The age is close to those reported for the Pb-Zn deposits in the Luanchuan ore belt.The(^(87)Sr/^(86)Sr),values of the sphalerites(0.71127 + 0.00010) are lower than that of terrigenous silicates(0.720) and higher than the mantle(0.707),suggesting that the metallogenic components were mainly derived through crust-mantle mixing.Combining the results from this study with those from previous work,we propose that the Hongdonggou Pb-Zn polymetallic ore deposit is a hydrothermal-vein deposit associated with the early Cretaceous tectonothermal event,and the mineralization is controlled by NWand near EW-trending faults in the Luanchuan Mo-W-Pb-Zn-Ag polymetallic ore concentration belt.展开更多
The potential autoclave was used to study the catalytic mechanism of Cu^2+during the oxygen pressure leaching process of artificial sphalerite.By studying the potential change of the system at different temperatures a...The potential autoclave was used to study the catalytic mechanism of Cu^2+during the oxygen pressure leaching process of artificial sphalerite.By studying the potential change of the system at different temperatures and the SEM–EDS difference of the leaching residues,it was found that in the temperature range of 363–423 K,the internal Cu^2+formed a Cu S deposit on the surface of sphalerite,which hindered the leaching reaction,resulting in a zinc leaching rate of only 51.04%.When the temperature exceeds 463 K,the system potential increases steadily.The increase in temperature leads to the dissolution of the CuS,which is beneficial to the circulation catalysis of Cu^2+.At this time,the leaching rate of Zn exceeds 95%.In addition,the leaching kinetics equations at 363–423 and 423–483 K were established.The activation energy of zinc leaching at 363–423 and 423–483 K is 38.66 and 36.25 kJ/mol,respectively,and the leaching process is controlled by surface chemical reactions.展开更多
The collectorless flotation behaviors of sphalerite in the presence of Cu 2+ ions have been established. The effects of pH, potential and Cu 2+ concentration on the flotation have been studied using a micro flotation ...The collectorless flotation behaviors of sphalerite in the presence of Cu 2+ ions have been established. The effects of pH, potential and Cu 2+ concentration on the flotation have been studied using a micro flotation cell specially designed, where the potential can be controlled by a potentiostat. The flotation results have shown that the Cu activated sphalerite displays a good collectorless floatability in a pH range of 0~13. The higher potentials can improve the flotation recovery. The surface species formed during the Cu ion activation have been examined using a special electrochemical technique—a composite sphalerite electrode. Zinc deficient sulfide (Zn 1- x Cu x S) and Cu poly sulfide (Cu y+z S y ) species have been determined. They are responsible for the collectorless flotation of sphalerite. In additional, they can improve the conductivity of the sphalerite surface.展开更多
The electronic properties of sphalerite(110)surface bearing Fe,Mn and Cd impurities were calculated using density-functional theory,and the effects of impurities on the copper activation of sphalerite were investigate...The electronic properties of sphalerite(110)surface bearing Fe,Mn and Cd impurities were calculated using density-functional theory,and the effects of impurities on the copper activation of sphalerite were investigated.Calculated results indicate that both Fe and Mn impurities narrow the band gap of sphalerite surface and lead to the Fermi level shifting to conduction band.Impurity levels composed of Fe 3d and Mn 3d orbital appearing in band gap are beneficial to electrons transfer from the valence band to the conduction band and promote the surface conductivity and the electrochemical activity.The results show that Fe and Mn impurities cannot be replaced by Cu atom,which reduces the exchange sites(Zn)for Cu atom,hence Fe-and Mn-bearing sphalerites are hard to be activated by copper.Cd impurity has little effect on electronic structure of sphalerite surface;however,Cd atom is easily replaced by Cu atom,and this is the reason why the Cd-bearing sphalerite can be easily floated.展开更多
Sphalerite in the Niujiaotang Cd rich zinc deposit, Duyun, Guizhou is characteristically light yellow in color with significant enrichment of cadmium which ranges from 0.83% to 1.97% (averaging 1.38%) in concentration...Sphalerite in the Niujiaotang Cd rich zinc deposit, Duyun, Guizhou is characteristically light yellow in color with significant enrichment of cadmium which ranges from 0.83% to 1.97% (averaging 1.38%) in concentration in the mineral, corresponding to an enrichment coefficient as high as 30.47 to 72.96. In comparison with other major Pb Zn deposits in the world (the Mississippi Valley deposits, and the Fankou and Jinding deposits in China) the Niujiaotang deposit is n-n×10 times richer in cadmium. Sphalerite in the deposit is also rich in Ga and Ge, but poor in In, Mn and Fe, suggesting some special mechanisms that govern the geochemical behavior of these trace elements. Except for a minor amount of independent minerals like greenockite, cadmium occurs mainly as isomorphous impurity in the crystal lattice of sphalerite. During weathering and leaching under supergene condition, cadmium was separated from Zn, resulting in some secondary minerals of Cd, including oxides and otavite.展开更多
The electronic properties of sphalerite(110) surface with Zn-vacancy and S-vacancy were calculated by using density-functional theory,and the effects of vacancy defect on the copper activation of sphalerite were inves...The electronic properties of sphalerite(110) surface with Zn-vacancy and S-vacancy were calculated by using density-functional theory,and the effects of vacancy defect on the copper activation of sphalerite were investigated.The calculated results indicate that surface state occurs in the band gap of Zn-vacancy sphalerite,which is from the contribution of S 3p orbital at the first layer of the surface.The presence of S-vacancy results in surface state appearing near the Fermi level and the bottom of conductor band,which are composed of S 3p and Zn 4s orbital,respectively.The surface structure of Zn-vacancy sphalerite is more stable than S-vacancy surface due to the occupation of Zn-vacancy by Cu atoms;hence,the substitution reaction of Cu for Zn vacancy is easier than the substitution of Cu for Zn atoms with S-vacancy surface.展开更多
Elective culture of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans in 9K medium modified with pyrrhotite was studied.Bioleaching of flotation concentrate of sphalerite by the selected bacteria was ca...Elective culture of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans in 9K medium modified with pyrrhotite was studied.Bioleaching of flotation concentrate of sphalerite by the selected bacteria was carried out.The results show that the microorganisms cultured by pyrrhotite are a mixture of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans,of which the capability to oxidize ferrous to ferric irons is enhanced by the high mass ratio of Fe to S in pyrrhotite.Three pyrrhotite samples were separated into various parts with corresponding S/Fe ratios by magnetic separation and were used to culture the elective bacteria as the substrate.The association of the cultures could provide a more rapid and complete oxidation of sphalerite than that of bacteria cultivated by conventional methods.展开更多
基金This work was supported by the National Natural Science Foundation of People’s Republic of China(No.NSFC52174246)the Interdisciplinary Scientific Research Foundation of Guangxi University(No.2022JCC016).
文摘Iron is an impurity widely occurred in sphalerite,and its effect on sphalerite flotation is complex.In this work,the effects of iron content and spin state on electronic properties and floatability of iron-bearing sphalerite are comprehensively studied using density functional theory Hubbard U(DFT+U)calculations combined with coordination chemistry flotation.The band gap of ideal sphalerite is 3.723 eV,and thus electron transition is difficult to occur,resulting in poor floatability.The results suggest the band gap of sphalerite decreases with increasing iron content.For low iron content,the decreased band gap facilitates electron transition;at this case,Fe^(2+)in a high-spin state possesses oneπelectron pair,which can form a weakπ-backbonding with xanthate,causing increasing floatability.However,for medium and high iron-bearing sphalerite,with the further decrease of band gap,Fe^(2+)is oxidized to Fe^(3+)due to electrochemical interaction,and henceπ-backbonding is eliminated,leading to lower floatability of iron-bearing sphalerite,which is consistent with the flotation experimental results.This work could give a deeper understanding of how sphalerite flotation behaviors are affected by iron content.
基金financially supported by the National Nature Science Foundation of China(42072094,42162012)。
文摘The Dulong deposit,located in the Laojunshan area of southeastern Yunnan,China,is an important polymetallic deposit due to its high reserves of tin,zinc,and indium.The occurrence state of indium is critical for understanding its supernormal enrichment mechanism.Previous studies investigated the occurrence state of indium(including the valence state)based on the indium content in sphalerite and the correlation between metal concentrations.However,more evidence is needed to better constrain indium occurrence at the micro-,nano-,or even atomic scale.In this study,EPMA-FIB-SEM-TEM and XPS techniques were employed to investigate the indium distribution characteristics and occurrence state in sphalerite from the Dulong Sn–Zn–In polymetallic deposit.The maximum concentration of indium in the indium-rich sphalerite samples is 0.37%,and the results of the EPMA analysis showed a relatively homogeneous distribution of indium in sphalerite.The FIB-SEM-TEM results demonstrated that the lattice stripes of sphalerite were periodically and continuously distributed at the nanoscale,confirming that sphalerite in the deposit was an excellent single crystal structure,and the peak heights of the various characteristic peaks of indium in the EDX spectra were relatively close to each other,with no distinct peaks of high indium content.In addition,the XPS results indicate that the element valence state of indium in sphalerite is In^(3+),and it combines with S^(2-)to form a bond.These results indicate that indium in sphalerite of the Dulong deposit is uniformly distributed at both the micro-and nanoscale,and there is no indium-independent mineral.In^(3+)enters the crystal lattice of sphalerite by replacing Zn2+in the form of isomorphic substitution.
基金supported by the National Natural Science Foundation of China(41673056 and U1812402)the Key Program of Guizhou Natural Science Foundation(Qiankehejichu[2017]1421)+1 种基金the State Key Program of National Natural Science Foundation of China(41430315)National Key R&D Program of China(2017YFC0602500)。
文摘The western Hunan-eastern Guizhou Zn-Pb metallogenic belt is one of the important Zn-Pb mineralization regions in China.The Dadongla deposit,located in the northeast of Guizhou Province,is one of the typical Zn-Pb deposits in the region and has estimated resources more than 12 million metric tons(Mt)with an average grade of 4.11 wt%Zn+Pb.Its orebodies are hosted in the lower Cambrian Aoxi Formation dolomite,occurring as bedded,para-bedded in shape,and in conformity with the wall rock.The ore mineral assemblage is simple,dominated by sphalerite with minor pyrite and galena,and the gangue minerals are composed of dolomite,calcite with minor bitumen and barite.In view of the lack of geological and geochemical researches,the genesis of Zn-Pb ore is still unclear.Laser ablation-inductively coupled plasma mass spectrometry(LA-ICPMS)spot and mapping analyses were used to obtain sphalerite trace element chemistry in the Dadongla Zn-Pb deposit in Guizhou,China,aiming to constrain its ore genesis.The results show that sphalerite is characterized by the enrichment of Cd,Fe,Ge and Hg,corresponding with that of typical MVT deposits.Four zones were identified in the sphalerite crystal from Dadongla from the center to margin according to the color bands.in which the zone in the center,representing the early ore-stage sphalerite,is characterized by enrichment of Cd relatively,while the zone forming at late ore-stage is enriched in Ge and Hg relatively.The finding was controlled by differential leached metals content in ore-forming fluid from its source rock.Notably,critical element Ge trends to be enriched at the late ore-stage and follows a substitution of 2 Zn^2+(?)Ge^4++□(vacancy).Moreover,the calculated ore-forming temperature ranges from 79.9℃to 177.6℃by the empirical formula,which is similar to that of typical Mississippi Valley-type(MVT)deposits.Compared with the features of trace elements in sphalerite from different types of deposits,together with the geology,the Dadongla deposit belongs to an MVT Zn-Pb deposit.
基金Supported by the National Science Foundation of China。
文摘The kinetics of ferric chloride leaching of sphalerite in the microwave field has being studied in this paper.According to the experimental data,the rate of dissolution of sphalerite microwave irradiation heating is faster than that with conventional heating.The dissolution of sphalerite in the microwave field was investigated in different condition of temperature,concentration of FeCl,and particle size and a nonisothermal kinetic equation has being obtained.
基金supported by the National Science and Technology Support Project of the 12th"Five-Year Plan"(Grant No.2011BAB04B06)the Fundamental Research Funds for the Central Universities of China University of Geosciences,Beijing(Grant No.2-9-2012-143)the National Natural Science Foundation of China(Grant No.41572318)
文摘The Hongdonggou Pb-Zn polymetallic ore deposit,located in the southwestern part of the Luanchuan Mo-W-Pb-Zn-Ag polymetallic ore mineralization in Henan Province,China,is an important part of the East Qinling metallogenic belt.The orebodies in the deposit,which are vein,bedded and lenticular,are mainly hosted in the syenite porphyry,and formed within the carbonate and clastic rocks of the Yuku and Qiumugou formations partially.The genesis of the deposit has previously been argued to be of hydrothermal-vein type or of skarn-hydrothermal type.In this study,we report the results of Rb-Sr isotopic dating based on sphalerites from the main orebody of the Hongdonggou Pb-Zn polymetallic ore deposit,which yield an isochron age of 135.7 ± 3.2 Ma,constraining the timing of mineralization as early Cretaceous.The age is close to those reported for the Pb-Zn deposits in the Luanchuan ore belt.The(^(87)Sr/^(86)Sr),values of the sphalerites(0.71127 + 0.00010) are lower than that of terrigenous silicates(0.720) and higher than the mantle(0.707),suggesting that the metallogenic components were mainly derived through crust-mantle mixing.Combining the results from this study with those from previous work,we propose that the Hongdonggou Pb-Zn polymetallic ore deposit is a hydrothermal-vein deposit associated with the early Cretaceous tectonothermal event,and the mineralization is controlled by NWand near EW-trending faults in the Luanchuan Mo-W-Pb-Zn-Ag polymetallic ore concentration belt.
基金financially supported by the Joint Funds of the National Natural Science Foundation of China(Nos.51804136,U1402271,51764016)Jiangxi Province Nature Science Foundation,China(No.20181BAB216017)+1 种基金Jiangxi Science and Technology Landing Project,China(No.KJLD13046)Research Fund Program of State Key Laboratory of Rare Metals Separaten and Comprehensive Utilization,Guangzhou,China(No.GK-201803)。
文摘The potential autoclave was used to study the catalytic mechanism of Cu^2+during the oxygen pressure leaching process of artificial sphalerite.By studying the potential change of the system at different temperatures and the SEM–EDS difference of the leaching residues,it was found that in the temperature range of 363–423 K,the internal Cu^2+formed a Cu S deposit on the surface of sphalerite,which hindered the leaching reaction,resulting in a zinc leaching rate of only 51.04%.When the temperature exceeds 463 K,the system potential increases steadily.The increase in temperature leads to the dissolution of the CuS,which is beneficial to the circulation catalysis of Cu^2+.At this time,the leaching rate of Zn exceeds 95%.In addition,the leaching kinetics equations at 363–423 and 423–483 K were established.The activation energy of zinc leaching at 363–423 and 423–483 K is 38.66 and 36.25 kJ/mol,respectively,and the leaching process is controlled by surface chemical reactions.
文摘The collectorless flotation behaviors of sphalerite in the presence of Cu 2+ ions have been established. The effects of pH, potential and Cu 2+ concentration on the flotation have been studied using a micro flotation cell specially designed, where the potential can be controlled by a potentiostat. The flotation results have shown that the Cu activated sphalerite displays a good collectorless floatability in a pH range of 0~13. The higher potentials can improve the flotation recovery. The surface species formed during the Cu ion activation have been examined using a special electrochemical technique—a composite sphalerite electrode. Zinc deficient sulfide (Zn 1- x Cu x S) and Cu poly sulfide (Cu y+z S y ) species have been determined. They are responsible for the collectorless flotation of sphalerite. In additional, they can improve the conductivity of the sphalerite surface.
基金Project(50864001) supported by the National Natural Science Foundation of China
文摘The electronic properties of sphalerite(110)surface bearing Fe,Mn and Cd impurities were calculated using density-functional theory,and the effects of impurities on the copper activation of sphalerite were investigated.Calculated results indicate that both Fe and Mn impurities narrow the band gap of sphalerite surface and lead to the Fermi level shifting to conduction band.Impurity levels composed of Fe 3d and Mn 3d orbital appearing in band gap are beneficial to electrons transfer from the valence band to the conduction band and promote the surface conductivity and the electrochemical activity.The results show that Fe and Mn impurities cannot be replaced by Cu atom,which reduces the exchange sites(Zn)for Cu atom,hence Fe-and Mn-bearing sphalerites are hard to be activated by copper.Cd impurity has little effect on electronic structure of sphalerite surface;however,Cd atom is easily replaced by Cu atom,and this is the reason why the Cd-bearing sphalerite can be easily floated.
文摘Sphalerite in the Niujiaotang Cd rich zinc deposit, Duyun, Guizhou is characteristically light yellow in color with significant enrichment of cadmium which ranges from 0.83% to 1.97% (averaging 1.38%) in concentration in the mineral, corresponding to an enrichment coefficient as high as 30.47 to 72.96. In comparison with other major Pb Zn deposits in the world (the Mississippi Valley deposits, and the Fankou and Jinding deposits in China) the Niujiaotang deposit is n-n×10 times richer in cadmium. Sphalerite in the deposit is also rich in Ga and Ge, but poor in In, Mn and Fe, suggesting some special mechanisms that govern the geochemical behavior of these trace elements. Except for a minor amount of independent minerals like greenockite, cadmium occurs mainly as isomorphous impurity in the crystal lattice of sphalerite. During weathering and leaching under supergene condition, cadmium was separated from Zn, resulting in some secondary minerals of Cd, including oxides and otavite.
基金supported by the National BasicResearch Program of China(Grant No.2009CB825007and 2006CB403508)National Natural Science Foundation of China(Grant No.40730314 and40821002)
基金Project(50864001) supported by the National Natural Science Foundation of China
文摘The electronic properties of sphalerite(110) surface with Zn-vacancy and S-vacancy were calculated by using density-functional theory,and the effects of vacancy defect on the copper activation of sphalerite were investigated.The calculated results indicate that surface state occurs in the band gap of Zn-vacancy sphalerite,which is from the contribution of S 3p orbital at the first layer of the surface.The presence of S-vacancy results in surface state appearing near the Fermi level and the bottom of conductor band,which are composed of S 3p and Zn 4s orbital,respectively.The surface structure of Zn-vacancy sphalerite is more stable than S-vacancy surface due to the occupation of Zn-vacancy by Cu atoms;hence,the substitution reaction of Cu for Zn vacancy is easier than the substitution of Cu for Zn atoms with S-vacancy surface.
基金Project(50621063)supported by the National Natural Science Foundation of ChinaProject(2004CD619205)supported by the Major StateBasic Research Development Program of China
文摘Elective culture of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans in 9K medium modified with pyrrhotite was studied.Bioleaching of flotation concentrate of sphalerite by the selected bacteria was carried out.The results show that the microorganisms cultured by pyrrhotite are a mixture of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans,of which the capability to oxidize ferrous to ferric irons is enhanced by the high mass ratio of Fe to S in pyrrhotite.Three pyrrhotite samples were separated into various parts with corresponding S/Fe ratios by magnetic separation and were used to culture the elective bacteria as the substrate.The association of the cultures could provide a more rapid and complete oxidation of sphalerite than that of bacteria cultivated by conventional methods.