A micro-modeling method (MM) for the quantitative prediction of the shrinkage cavity formation in SGiron castings is proposed. The mathematical models describing the volume changes during the solidification ofspheroid...A micro-modeling method (MM) for the quantitative prediction of the shrinkage cavity formation in SGiron castings is proposed. The mathematical models describing the volume changes during the solidification ofspheroidal graphite cast iron are established based on the models of solidification kinetics. The shrinkage cavityformation of T-shaped SG iron castings is calculated with MM method. The calculated results are compared with theexperimental results. It is shown that the predicted size, shape and distribution of shrinkage cavity by MM methodare in good agreement with the measured results.展开更多
The shrinkage and chilling tendency of spheroidal graphite (abbreviated SG) cast iron is much greater than that of the flake graphite cast iron in spite of its higher amount of C and Si contents. Why? The main reason ...The shrinkage and chilling tendency of spheroidal graphite (abbreviated SG) cast iron is much greater than that of the flake graphite cast iron in spite of its higher amount of C and Si contents. Why? The main reason should be the difference in their graphitization during the eutectic solidification. In this paper, we discuss the difference in the solidification mechanism of both cast irons for solving these problems using unidirectional solidification and the cooling curves of the spheroidal graphite cast iron. The eutectic solidification rate of the SG cast iron is controlled by the diffusion of carbon through the austenite shell, and the final thickness is 1.4 times the radius of the SG, therefore, the reduction of the SG size, namely, the increase in the number, is the main solution of these problems.展开更多
This paper reviews the original work of the authors published recently,describing the influence of B on the matrix of the Cuadded spheroidal graphite cast iron.The effect of Cu has been corrected as a ferrite formatio...This paper reviews the original work of the authors published recently,describing the influence of B on the matrix of the Cuadded spheroidal graphite cast iron.The effect of Cu has been corrected as a ferrite formation promoter in the matrix of the grey cast iron by the usage of high-purity material.Also,this paper focuses on the ferrite formation and the observation of the Cu distribution in the B-added and B-free Cu-containing spheroidal graphite cast iron.The Cu film on the spheroidal graphite can be successfully observed in the B-free sample using a special etching method.However,in the B-added sample,no Cu film could be found,while the secondary graphite was formed on the surface of the spheroidal graphite.The interaction between B and Cu is stressed as a peculiar phenomenon by the employment of a contrast experiment of B and Mn.The heat treatment could make Cu precipitate more significantly in the eutectic cells and in the matrix in the form of large Cu particles because of the limited solubility of Cu.展开更多
The effects of metallurgical and processing parameters on the formation of shrinkage cavities and porosities in spheroidal graphite cast iron have been studied, considering the parameters of carbon equivalent, inocula...The effects of metallurgical and processing parameters on the formation of shrinkage cavities and porosities in spheroidal graphite cast iron have been studied, considering the parameters of carbon equivalent, inoculation, casting modulus, mold type (green or dry) and pouring temperature within specific ranges of these variables. Based on the orthogonal experiments, the metallurgical and processing parameters of the minimum casting shrinkage and the maximum casting shrinkage were obtained, and the effects of metallurgical and processing parameters on the formation of shrinkage cavities and porosities in spheroids graphite cast iron castings were discussed. Finally, two regression equations relating these variables to the formation of shrinkage porosity were derived based upon the orthogonal experiments conducted.展开更多
A multiphase cellular automaton model was developed to simulate microstructure evolution of near eutectic spheroidal graphite cast iron(SGI) during its solidification process, and both dendritic austenite and spheroid...A multiphase cellular automaton model was developed to simulate microstructure evolution of near eutectic spheroidal graphite cast iron(SGI) during its solidification process, and both dendritic austenite and spheroidal graphite growth models were adopted. To deduce the mesh anisotropy of cellular automaton method, the composition averaging and geometrical parameter were introduced to simulate the spheroidal graphite growth. Solute balance method and decentered square algorithms were employed to simulate austenite dendrites growth with different crystallographic orientations. The simulated results indicate that the graphite nodule grows in a spherical morphology when the surrounding environment of a single graphite nodule is same. However, for two adjacent graphite nodules, the environment is different. The higher the carbon concentration, the faster the growth of graphite. By comparison with experimental results, it is found that the microstructure evolution of near eutectic spheroidal graphite cast iron during solidification process can be reproduced quantitatively by numerical simulation with this model.展开更多
Wear behavior and mechanism of spheroidal graphite cast iron were studied on a pin on-disk elevated tem- perature wear tester. The phase and morphology of worn surfaces were examined by X ray diffraction and scanning ...Wear behavior and mechanism of spheroidal graphite cast iron were studied on a pin on-disk elevated tem- perature wear tester. The phase and morphology of worn surfaces were examined by X ray diffraction and scanning electron microscopy. Results show that with an increase of load, wear rate of spheroidal graphite cast iron gradually increases under low loads, rapidly increases or potentially increases under high loads; wear rate increases with in- creasing ambient temperature. At 25 200 ℃, adhesive wear prevails; oxidative wear and adhesive wear coexist at 400 ℃. As load surpasses 150 N at 400 ℃, extrusive wear appears. The elevated-temperature wear of spheroidal graphite cast iron is a physical and chemical process including the following reactions: xFe+y/2O2-FexOy , 2C+ O2- 2CO and Fex Oy +yCO-xFe+yCO2. Hence, at 400 ℃, the amount of graphite and tribo oxides are substan- tially reduced because of reductive function of graphite. It can be suggested that wear reduced effect of graphite and tribo-oxides is impaired.展开更多
文摘A micro-modeling method (MM) for the quantitative prediction of the shrinkage cavity formation in SGiron castings is proposed. The mathematical models describing the volume changes during the solidification ofspheroidal graphite cast iron are established based on the models of solidification kinetics. The shrinkage cavityformation of T-shaped SG iron castings is calculated with MM method. The calculated results are compared with theexperimental results. It is shown that the predicted size, shape and distribution of shrinkage cavity by MM methodare in good agreement with the measured results.
文摘The shrinkage and chilling tendency of spheroidal graphite (abbreviated SG) cast iron is much greater than that of the flake graphite cast iron in spite of its higher amount of C and Si contents. Why? The main reason should be the difference in their graphitization during the eutectic solidification. In this paper, we discuss the difference in the solidification mechanism of both cast irons for solving these problems using unidirectional solidification and the cooling curves of the spheroidal graphite cast iron. The eutectic solidification rate of the SG cast iron is controlled by the diffusion of carbon through the austenite shell, and the final thickness is 1.4 times the radius of the SG, therefore, the reduction of the SG size, namely, the increase in the number, is the main solution of these problems.
文摘This paper reviews the original work of the authors published recently,describing the influence of B on the matrix of the Cuadded spheroidal graphite cast iron.The effect of Cu has been corrected as a ferrite formation promoter in the matrix of the grey cast iron by the usage of high-purity material.Also,this paper focuses on the ferrite formation and the observation of the Cu distribution in the B-added and B-free Cu-containing spheroidal graphite cast iron.The Cu film on the spheroidal graphite can be successfully observed in the B-free sample using a special etching method.However,in the B-added sample,no Cu film could be found,while the secondary graphite was formed on the surface of the spheroidal graphite.The interaction between B and Cu is stressed as a peculiar phenomenon by the employment of a contrast experiment of B and Mn.The heat treatment could make Cu precipitate more significantly in the eutectic cells and in the matrix in the form of large Cu particles because of the limited solubility of Cu.
基金The paper was financially supported by the National Natural Science Foundation of China(Grant No.59235102).
文摘The effects of metallurgical and processing parameters on the formation of shrinkage cavities and porosities in spheroidal graphite cast iron have been studied, considering the parameters of carbon equivalent, inoculation, casting modulus, mold type (green or dry) and pouring temperature within specific ranges of these variables. Based on the orthogonal experiments, the metallurgical and processing parameters of the minimum casting shrinkage and the maximum casting shrinkage were obtained, and the effects of metallurgical and processing parameters on the formation of shrinkage cavities and porosities in spheroids graphite cast iron castings were discussed. Finally, two regression equations relating these variables to the formation of shrinkage porosity were derived based upon the orthogonal experiments conducted.
基金supported by the National Natural Science Foundation of China(51601107)
文摘A multiphase cellular automaton model was developed to simulate microstructure evolution of near eutectic spheroidal graphite cast iron(SGI) during its solidification process, and both dendritic austenite and spheroidal graphite growth models were adopted. To deduce the mesh anisotropy of cellular automaton method, the composition averaging and geometrical parameter were introduced to simulate the spheroidal graphite growth. Solute balance method and decentered square algorithms were employed to simulate austenite dendrites growth with different crystallographic orientations. The simulated results indicate that the graphite nodule grows in a spherical morphology when the surrounding environment of a single graphite nodule is same. However, for two adjacent graphite nodules, the environment is different. The higher the carbon concentration, the faster the growth of graphite. By comparison with experimental results, it is found that the microstructure evolution of near eutectic spheroidal graphite cast iron during solidification process can be reproduced quantitatively by numerical simulation with this model.
基金Item Sponsored by National Natural Science Foundation of China(51071078)Research Fund of Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province of China(AE201035)Natural Science Foundation of Jiangsu Province of China(BK2012250)
文摘Wear behavior and mechanism of spheroidal graphite cast iron were studied on a pin on-disk elevated tem- perature wear tester. The phase and morphology of worn surfaces were examined by X ray diffraction and scanning electron microscopy. Results show that with an increase of load, wear rate of spheroidal graphite cast iron gradually increases under low loads, rapidly increases or potentially increases under high loads; wear rate increases with in- creasing ambient temperature. At 25 200 ℃, adhesive wear prevails; oxidative wear and adhesive wear coexist at 400 ℃. As load surpasses 150 N at 400 ℃, extrusive wear appears. The elevated-temperature wear of spheroidal graphite cast iron is a physical and chemical process including the following reactions: xFe+y/2O2-FexOy , 2C+ O2- 2CO and Fex Oy +yCO-xFe+yCO2. Hence, at 400 ℃, the amount of graphite and tribo oxides are substan- tially reduced because of reductive function of graphite. It can be suggested that wear reduced effect of graphite and tribo-oxides is impaired.