For the test of rotation speed of high spinning projectile, the general formula of the motional electromotive force (MEMF) of planar magnetic induction coil (PMIC) is derived in case of 3D rotation in a stable mag...For the test of rotation speed of high spinning projectile, the general formula of the motional electromotive force (MEMF) of planar magnetic induction coil (PMIC) is derived in case of 3D rotation in a stable magnetic field. Under a reasona-ble assumption, the MEMF of PMIC is simplified after the aforementioned general formula is used to calculate high spinning PMIC in the geomagnetic field environment. The determination approach of half-cycle is discussed and the method of rotation speed test is studied, and a test is conducted in the paper. The rotation speed curve obtained by the approach in this paper is consistent with the curve by telemetry.展开更多
Ball spinning is applied to manufacturing thin-walled tube with high precision and high mechanical properties. On the basis of plastic mechanics, by simplifying ball spinning of thin-walled tube as plane strain proble...Ball spinning is applied to manufacturing thin-walled tube with high precision and high mechanical properties. On the basis of plastic mechanics, by simplifying ball spinning of thin-walled tube as plane strain problem, slab method is used for the purpose of calculating the contact deformation pressure. The spinning force components, the torsional moment, the deformation power and the deformation work are calculated further as well. The influence of the two important process parameters such as the feed ratio and the ball diameter on the spinning force components is analyzed in order to further control the spinning force components by regulating the two process variables during the ball spinning process. The stress and strain state in deformable zone as well as mechanics boundary conditions in ball spinning are obtained. The effect of the three spinning force components on the formability of the spun part is analyzed and validated through the ball spinning experiments. The theoretical and experimental results show that the radial spinning component plays a significant role in ball spinning of thin-walled tube, and the mechanics situation in backward ball spinning contributes to enhancing the plasticity of the metal material, but that in forward ball spinning contributes to advancing the axial flow of the metal material.展开更多
Hot spinning process has attracted significant attention because it can be used to manufacture complex parts, extend the forming limit of materials, decrease forming forces and reduce process chains. In this paper, we...Hot spinning process has attracted significant attention because it can be used to manufacture complex parts, extend the forming limit of materials, decrease forming forces and reduce process chains. In this paper, we review researches on lightweight metals spun at elevated temperatures since they are difficult to deform at room temperature. These metals include light alloys, such as titanium, magnesium and aluminum alloys, and metal composites. Then, the heating methods used in the hot spinning process and the treatment methods employed for the temperature boundary condition in finite element analyses for the process were discussed. Finally, the future development directions for the hot spinning process of lightweight but difficult-to-deform alloys were highlighted.展开更多
As a new attempt,ball spinning was used to manufacture the nickel-titanium shape memory alloy(NiTi SMA) tube at elevated temperature.The NiTi bar with a nominal composition of Ni50.9Ti49.1(mole fraction,%) was sol...As a new attempt,ball spinning was used to manufacture the nickel-titanium shape memory alloy(NiTi SMA) tube at elevated temperature.The NiTi bar with a nominal composition of Ni50.9Ti49.1(mole fraction,%) was solution treated and was used as the original tube blank for ball spinning.Based on the variable temperature field and the constitutive equation,rigid-viscoplastic finite element method(FEM) was applied in order to simulate the ball spinning of NiTi SMA tube.The temperature field,the stress field,the strain field and the load prediction were obtained by means of FEM.FEM results reveal that there is a temperature increase of about 160 ℃ in the principal deformation zone of the spun part.It can be found from the stress fields and the strain fields that the outer wall of NiTi SMA tube is easier to meet the plastic yield criterion than the inner wall,and the plastic deformation zone is caused to be in a three-dimensional compressive stress state.The radial strain and the tangential strain are characterized by the compressive strain,while the axial strain belongs to the tensile strain.The variation of spinning loads with the progression of the ball is of great importance in predicting the stable flow of the spun part.展开更多
Material properties of blank have a great effect on power spinning process of aluminum alloy parts with transverse inner rib.By using finite element(FE) and Taguchi method,the effects and significance of five key mate...Material properties of blank have a great effect on power spinning process of aluminum alloy parts with transverse inner rib.By using finite element(FE) and Taguchi method,the effects and significance of five key material parameters,namely,anisotropic index in thickness direction,yield strength,hardening exponent,strengthening factor and elastic modulus on the formability of inner rib,tendency of wall fracture and degree of inhomogeneous deformation of finished spun parts were obtained.The achievements provide an important guide for selecting reasonable spinning material,and are very significant for the optimum design and precision control of power spinning process of parts with transverse inner rib.展开更多
In this paper,a robust adaptive controller is designed for a guided spinning rocket,whose dynamics presents the characteristics of pitch-yaw cross coupling,fast time-varying aerodynamics parameters and wide flight env...In this paper,a robust adaptive controller is designed for a guided spinning rocket,whose dynamics presents the characteristics of pitch-yaw cross coupling,fast time-varying aerodynamics parameters and wide flight envelop.First,a coupled nonlinear six-degree-of-freedom equation of motion for a guided spinning rocket is developed,and the lateral acceleration motion is modeled as a control plant with time-varying matched uncertainties and unmodeled dynamics.Then,a robust adaptive control method is proposed by combining Bregman divergence and variational method to achieve fast adaption and maintain bounded tracking.The stability of the resulting closed-loop system is proved,and the ultimate bound and convergence rate are also analyzed.Finally,numerical simulations are performed for a single operating point and the whole flight trajectory to show the robustness and adaptability of the proposed method with respect to timevarying uncertainties and unmodeled dynamics.展开更多
The numerical simulation model of single roller melt spinning for rapid quenching process of NdFeB alloy was built,and the vacuum chamber,cooling roller and sample were taken into account as a system.The existing matu...The numerical simulation model of single roller melt spinning for rapid quenching process of NdFeB alloy was built,and the vacuum chamber,cooling roller and sample were taken into account as a system.The existing mature technology was in order to verify the correctness of simulation.The rapid quenching ribbons with different roll speeds were used as the simulation objects.The results of the numerical simulation and experiments show that the validity of the model has been testified and the reasons of the formation of complete quenching ribbons and by-product have been explained.The experimental thickness of the ribbons is proportional to the theoretical thickness.In the same spray condition,with the roll speed increasing,the thickness decreases linearly.At the speed range of25-30 m·s^(-1),the simulated calculation date is close to the experimental date,which can be considered as an ideal technological parameter.展开更多
Nacre is a lightweight, strong, stiff, and tough material, which makes it a mimicking object for material design. Many attempts to mimic nacre by various methods resulted in the synthesis of artificial nacre with exce...Nacre is a lightweight, strong, stiff, and tough material, which makes it a mimicking object for material design. Many attempts to mimic nacre by various methods resulted in the synthesis of artificial nacre with excellent properties. However, the fabrication procedure was very laborious and time-consuming due to the sequential steps, and only limited-sized materials could be obtained. Hence, a novel design enabling scalable production of high-performance artificial nacre with uniform layered structures is urgently needed. We developed a novel wet-spinning assembly technique to rapidly manufacture continuous nacre- mimic graphene oxide (GO, brick)-sodium alginate (SA, mortar) films and fibers with excellent mechanical properties. At high concentrations, the GO-SA mixtures spontaneously produced liquid crystals (LCs) due to the template effect of GO, and continuous, 6 m long nacre-like GO-SA films were wet-spun from the obtained GO-SA liquid crystalline (LC) dope with a speed of up to 1.5 m/min. The assembled macroscopic GO-SA composites inherited the alignment of the GO sheets from the LC phase, and their mechanical properties were investigated by a joint experimental-computational study. The tensile tests revealed that the maximum strength (0) and Young's modulus (E) of the obtained films reached 239.6 MPa and 22.4 GPa, while the maximum values of o and E for the fibers were 784.9 MPa and 58 GPa, respectively. The described wet-spinning assembly method is applicable for a large-scale and fast production of high-performance continuous artificial nacre.展开更多
Finite element method is used to simulate the high-speed melt spinning process, based on the equation system proposed by Doufas et al. Calculation predicts a neck-like deformation, as well as the related profiles of v...Finite element method is used to simulate the high-speed melt spinning process, based on the equation system proposed by Doufas et al. Calculation predicts a neck-like deformation, as well as the related profiles of velocity, diameter, temperature, chain orientation, and crystallinity in the fiber spinning process. Considering combined effects on the process such as flow-induced crystallization, viscoelasticity, filament cooling, air drag, inertia, surface tension and gravity, the simulated material flow behaviors are consistent with those observed for semi-crystalline polymers under various spinning conditions, The structure change of polymer coils in the necking region described by the evolution of conformation tensor is also investigated. Based on the relaxation mechanism of macromolecules in flow field different types of morphology change of polymer chains before and in the neck are proposed, giving a complete prospect of structure evolution and crystallization of semi-crystalline polymer in the high speed fiber spinning process.展开更多
The microstructure and electrochemical characteristics of Ml(NiCoMnAl) 5 alloys prepared by both the melt spinning method and the conventional induction melting were investigated and compared. SEM and XRD studies sh...The microstructure and electrochemical characteristics of Ml(NiCoMnAl) 5 alloys prepared by both the melt spinning method and the conventional induction melting were investigated and compared. SEM and XRD studies show that the microstructure of melt spinning alloys is columnar structure. With increasing melt spinning rate, the crystal grains become finer and preferentially grow along (111)[111] direction. The melt spinning and cast alloys belong to CaCu 5 type hexagonal crystal structure. The electrochemical measurements show that the initial capacities of melt spinning alloy electrodes are all above 210 mAh·g -1 with good activation behavior, reaching their maximum capacities after two charge discharge cycles. The maximum capacity (294 mAh·g -1 ) of melt spinning (10 m·s -1 ) alloy electrodes is as the same as that of as cast alloy electrode, and stability of charge discharge cycles of all melt spinning alloy electrodes is better than that of the as cast alloy electrodes. When charged at 600 mA·g -1 , the capacity of melt spinning (10 m·s -1 ) alloy electrode could reach 65% of its maximum capacity about 45 min with high rate discharge capability; but with the cycle number increasing, the stability of its capacity is less than that electrodes of melt spinning rate.展开更多
When programming the daily generation strategies, power plants consider not only the competitive bids in spot market and the original purchase contracts with distribution companies or users, but also the spinning rese...When programming the daily generation strategies, power plants consider not only the competitive bids in spot market and the original purchase contracts with distribution companies or users, but also the spinning reserve. Aiming at this goal, the paper puts forward a daily generating model, which is a nonlinear programming model containing integral and continous variables, to coordinate the power volumes of competitive bids, contract and the spinning reserve of power plants and thus to maximize their profits. Then, the model is simplified to ease its solving process, and solved by priority ranking method based on efficiency and quadratic programming. The simulation result of a case study shows that the proposed scheme is reasonable and practicable.展开更多
The aim of this study is to investigate the surface quality of the melt spinning wheel, which was changed from smooth type to textured structure, to atomize liquid metal to form powders. The effects of melt spinning p...The aim of this study is to investigate the surface quality of the melt spinning wheel, which was changed from smooth type to textured structure, to atomize liquid metal to form powders. The effects of melt spinning process parameters like wheel speed, gas ejection pressure, molten metal temperature, nozzle–wheel gap and wheel surface quality on the morphological and microstructural features of 6060 aluminum alloy powders and ribbons were investigated. It was observed that ribbon type material was obtained with the smooth wheel and the powder was produced with textured type. The sizes of produced ribbons with smooth surface wheel varied in the range of 30-170 μm in thickness, 4-8 mm in width, and 0.5-1 m in length. The average powder size of the powders manufactured using the textured wheel was in the range of 161-274 μm, depending on the process parameters.Increasing the wheel speed, melt temperature and decreasing gas ejection pressure, nozzle-wheel gap resulted in the decrease of both ribbon thickness and powder size. The microstructures of the powders and ribbons were the equiaxed cellular type, and the average grain sizes diminished with decreasing the ribbon thickness and powder size. The maximum cooling rates were 2.00×10^5 and 1.26×10^4 K/s for the ribbon with thickness of 30 μm and for the powder with size of 87 μm, respectively.展开更多
In this paper, dynamic economic dispatch model is proposed for power systems with bulk wind power integration. The wind turbine generators are assumed to partially undertake the spinning reserve for the thermal genera...In this paper, dynamic economic dispatch model is proposed for power systems with bulk wind power integration. The wind turbine generators are assumed to partially undertake the spinning reserve for the thermal generator. A double-layer optimization model is proposed. The outer layer use the differential evolution to search for the power output of thermal generators, and the inner layer use the primal-dual interior point method to solve the OPF of the established output state. Finally, the impact of spinning reserve with wind power on power system operating is validated.展开更多
In CZTSSe solar cells,a simple sodium-incorporation post-treatment method toward solution-processed Cu2Zn Sn S4precursor films is presented in this work.An ultrathin NaCl film is deposited on Cu2Zn Sn S4precursor film...In CZTSSe solar cells,a simple sodium-incorporation post-treatment method toward solution-processed Cu2Zn Sn S4precursor films is presented in this work.An ultrathin NaCl film is deposited on Cu2Zn Sn S4precursor films by spin-coating NaCl solution.In subsequent selenization process,the introduction of Na Cl is found to be benefacial for the formation of Cu2-xSe,which can further facilitate the element transportation,leading to dense and smooth CZTSSe films with large grains and less impurity Cu2Sn(S,Se)3phase.SIMS depth profiles confirm the gradient distribution of the sodium element in Na-doped absorbers.Photoluminescence spectra show that the introduction of appropriate sodium into the absorber can inhibit the band tail states.As high as 11.18% of power conversion efficiency(PCE)is achieved for the device treated with 5 mg mL^-1 NaCl solution,and an average efficiency of Na-doped devices is 10.71%,13%higher than that of the control groups(9.45%).Besides,the depletion width and the charge recombination lifetime can also have regular variation with sodium treatment.This work offers an easy modification method for high-quality Na-doped CZTSSe films and high-performance devices,in the meantime,it can also help to further understand the effects of sodium in CZTSSe solar cells.展开更多
A new hybrid organic-inorganic structure of FTO/TiO2/Se/HTL/Au based selenium solar cell has been fabricated through a low-cost spin-coating process in air. In this process, selenium is completely dissolved in hydrazi...A new hybrid organic-inorganic structure of FTO/TiO2/Se/HTL/Au based selenium solar cell has been fabricated through a low-cost spin-coating process in air. In this process, selenium is completely dissolved in hydrazine, to fk)rm a homogeneous precursor solution. After spin-coating the precursor solution on the TiO2 substrates, following by sintering at 200 ℃ for 5rain, a uniform selenium film with crystalline grains is formed. The selenium based solar cell exhibits an efficiency of 1.23% under AM1.5 illumination (100 mW.cm-2), short-circuit current density of 8 mA.cm 2, open-circuit voltage of 0.55 V, and fill factor of 0.37. Moreover, the device shows a stable ability with almost the same performance alter 60 days.展开更多
This paper introduces a new method for a formula for electron spin relaxation time of a system of electrons interacting with phonons through phonon-modulated spin-orbit coupling using the projection-reduction method. ...This paper introduces a new method for a formula for electron spin relaxation time of a system of electrons interacting with phonons through phonon-modulated spin-orbit coupling using the projection-reduction method. The phonon absorption and emission processes as well as the photon absorption and emission processes in all electron transition processes can be explained in an organized manner, and the result can be represented in a diagram that can provide intuition for the quantum dynamics of electrons in a solid. The temperature (T) dependence of electron spin relaxation times (T1) in silicon is T1 ∝ T-1.07 at low temperatures and T1 ∝ T-3.3 at high temperatures for acoustic deformation constant Pad = 1.4 × 10^7 eV and optical deformation constant Pod = 4.0 × 10^17 eV/m. This means that electrons are scattered by the acoustic deformation phonons at low temperatures and optical deformation phonons at high temperatures, respectively. The magnetic field (B) dependence of the relaxation times is T1 ∝ B-2.7 at 100 K and T1 ∝ B-2.3 at 150 K, which nearly agree with the result of Yafet, T1 ∝ B-3.0- B -2.5.展开更多
Approximate analytical bound-state solutions of the Dirac particle in the fields of attractive and repulsive Rosen–Morse (RM) potentials including the Coulomb-like tensor (CLT) potential are obtained for arbitrar...Approximate analytical bound-state solutions of the Dirac particle in the fields of attractive and repulsive Rosen–Morse (RM) potentials including the Coulomb-like tensor (CLT) potential are obtained for arbitrary spin–orbit quantum number κ. The Pekeris approximation is used to deal with the spin–orbit coupling terms κ(κ ± 1)r 2 . In the presence of exact spin and pseudospin (p-spin) symmetries, the energy eigenvalues and the corresponding normalized two-component wave functions are found by using the parametric generalization of the Nikiforov–Uvarov (NU) method. The numerical results show that the CLT interaction removes degeneracies between the spin and p-spin state doublets.展开更多
Whether the proposed mechanical model fits in the nature of technology is the key to solving the problems during three dimensional simulation of power spinning. The study of mechanical model includes: the definition o...Whether the proposed mechanical model fits in the nature of technology is the key to solving the problems during three dimensional simulation of power spinning. The study of mechanical model includes: the definition of the contour of contact zone and processing the velocity and frictional force boundary conditions on contact zone. The movement locus of roller surface is a spiral cone and contact zone between roller and workpiece is a part of cone surface of roller. So the contour of the contact zone is intersected by roller cone surface, spiral cone surface and cylindrical surfaces. In this paper, a solution to defining the contour and applying space restriction of the contact zone was proposed. Considering the sudden change in the direction of foctional force on the contact zone during power spinning, an inverse tangential frictional model was adopted to solve the problem. So a new mechanical model comes into being and the 3 - D FEM simulation results prove it to be right.展开更多
In this paper the formulation of finite element analysis for frame casing problems of theharmonic type is described. Attention is paid to the OE spinning rotor bearing assembly (RBA)’ sdynamic model, whose harmonic p...In this paper the formulation of finite element analysis for frame casing problems of theharmonic type is described. Attention is paid to the OE spinning rotor bearing assembly (RBA)’ sdynamic model, whose harmonic parameters, such as natural frequencies and modal shapes, aresolved by means of structural analysis program using personal computer, i.e. SAP84 software. Ac-cording to orthogonal factorial design table (OFDT), the predominant sensitive influential factors(PSIF) of RBA are determined.展开更多
Based on the coupled harmonic oscillator model, which is born of Heisenberg ferromagnetic spin chain with nearest-neighbor interactions, we adopt the invariant eigen-operator method to derive its energy level, which p...Based on the coupled harmonic oscillator model, which is born of Heisenberg ferromagnetic spin chain with nearest-neighbor interactions, we adopt the invariant eigen-operator method to derive its energy level, which provides an alternate approach to dealing with the dynamics of spin chain.展开更多
基金National Key Lab for Electronic Measurement and Technology,North University of China(No.9140C120401080C12)
文摘For the test of rotation speed of high spinning projectile, the general formula of the motional electromotive force (MEMF) of planar magnetic induction coil (PMIC) is derived in case of 3D rotation in a stable magnetic field. Under a reasona-ble assumption, the MEMF of PMIC is simplified after the aforementioned general formula is used to calculate high spinning PMIC in the geomagnetic field environment. The determination approach of half-cycle is discussed and the method of rotation speed test is studied, and a test is conducted in the paper. The rotation speed curve obtained by the approach in this paper is consistent with the curve by telemetry.
基金supported by Overseas Returnee Foundation of Heilongjiang Province, China (lc01c13).
文摘Ball spinning is applied to manufacturing thin-walled tube with high precision and high mechanical properties. On the basis of plastic mechanics, by simplifying ball spinning of thin-walled tube as plane strain problem, slab method is used for the purpose of calculating the contact deformation pressure. The spinning force components, the torsional moment, the deformation power and the deformation work are calculated further as well. The influence of the two important process parameters such as the feed ratio and the ball diameter on the spinning force components is analyzed in order to further control the spinning force components by regulating the two process variables during the ball spinning process. The stress and strain state in deformable zone as well as mechanics boundary conditions in ball spinning are obtained. The effect of the three spinning force components on the formability of the spun part is analyzed and validated through the ball spinning experiments. The theoretical and experimental results show that the radial spinning component plays a significant role in ball spinning of thin-walled tube, and the mechanics situation in backward ball spinning contributes to enhancing the plasticity of the metal material, but that in forward ball spinning contributes to advancing the axial flow of the metal material.
基金Project(51222509) supported by the National Science Fund for Excellent Young Scholars of ChinaProject(51175429) supported by the National Natural Science Foundation of ChinaProjects(97-QZ-2014,90-QP-2013) supported by the Research Fund of the State Key Laboratory of Solidification Processing(NWPU) of China
文摘Hot spinning process has attracted significant attention because it can be used to manufacture complex parts, extend the forming limit of materials, decrease forming forces and reduce process chains. In this paper, we review researches on lightweight metals spun at elevated temperatures since they are difficult to deform at room temperature. These metals include light alloys, such as titanium, magnesium and aluminum alloys, and metal composites. Then, the heating methods used in the hot spinning process and the treatment methods employed for the temperature boundary condition in finite element analyses for the process were discussed. Finally, the future development directions for the hot spinning process of lightweight but difficult-to-deform alloys were highlighted.
基金Project(51071056) supported by the National Natural Science Foundation of ChinaProject(HEUCF121712) supported by the Fundamental Research Funds for the Central Universities of China
文摘As a new attempt,ball spinning was used to manufacture the nickel-titanium shape memory alloy(NiTi SMA) tube at elevated temperature.The NiTi bar with a nominal composition of Ni50.9Ti49.1(mole fraction,%) was solution treated and was used as the original tube blank for ball spinning.Based on the variable temperature field and the constitutive equation,rigid-viscoplastic finite element method(FEM) was applied in order to simulate the ball spinning of NiTi SMA tube.The temperature field,the stress field,the strain field and the load prediction were obtained by means of FEM.FEM results reveal that there is a temperature increase of about 160 ℃ in the principal deformation zone of the spun part.It can be found from the stress fields and the strain fields that the outer wall of NiTi SMA tube is easier to meet the plastic yield criterion than the inner wall,and the plastic deformation zone is caused to be in a three-dimensional compressive stress state.The radial strain and the tangential strain are characterized by the compressive strain,while the axial strain belongs to the tensile strain.The variation of spinning loads with the progression of the ball is of great importance in predicting the stable flow of the spun part.
基金Projects(50405039,50575186) supported by the National Natural Science Foundation of ChinaProject(50225518) supported by the National Natural Science Foundation of China for Distinguished Young ScholarsProject(2008AA04Z122) supported by the National High-tech Research and Development Program of China
文摘Material properties of blank have a great effect on power spinning process of aluminum alloy parts with transverse inner rib.By using finite element(FE) and Taguchi method,the effects and significance of five key material parameters,namely,anisotropic index in thickness direction,yield strength,hardening exponent,strengthening factor and elastic modulus on the formability of inner rib,tendency of wall fracture and degree of inhomogeneous deformation of finished spun parts were obtained.The achievements provide an important guide for selecting reasonable spinning material,and are very significant for the optimum design and precision control of power spinning process of parts with transverse inner rib.
基金supported by the National Natural Science Foundation of China (No. 11532002)。
文摘In this paper,a robust adaptive controller is designed for a guided spinning rocket,whose dynamics presents the characteristics of pitch-yaw cross coupling,fast time-varying aerodynamics parameters and wide flight envelop.First,a coupled nonlinear six-degree-of-freedom equation of motion for a guided spinning rocket is developed,and the lateral acceleration motion is modeled as a control plant with time-varying matched uncertainties and unmodeled dynamics.Then,a robust adaptive control method is proposed by combining Bregman divergence and variational method to achieve fast adaption and maintain bounded tracking.The stability of the resulting closed-loop system is proved,and the ultimate bound and convergence rate are also analyzed.Finally,numerical simulations are performed for a single operating point and the whole flight trajectory to show the robustness and adaptability of the proposed method with respect to timevarying uncertainties and unmodeled dynamics.
基金financially supported by the National Natural Science Foundation of China(No.51571064)the National Basic Research Program of China(No.2014CB643701)。
文摘The numerical simulation model of single roller melt spinning for rapid quenching process of NdFeB alloy was built,and the vacuum chamber,cooling roller and sample were taken into account as a system.The existing mature technology was in order to verify the correctness of simulation.The rapid quenching ribbons with different roll speeds were used as the simulation objects.The results of the numerical simulation and experiments show that the validity of the model has been testified and the reasons of the formation of complete quenching ribbons and by-product have been explained.The experimental thickness of the ribbons is proportional to the theoretical thickness.In the same spray condition,with the roll speed increasing,the thickness decreases linearly.At the speed range of25-30 m·s^(-1),the simulated calculation date is close to the experimental date,which can be considered as an ideal technological parameter.
基金This research was financially supported by The National Natural Science Foundation of China (Nos. 21325417, 51173162 and 51533008) and State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University (No. LK1403).
文摘Nacre is a lightweight, strong, stiff, and tough material, which makes it a mimicking object for material design. Many attempts to mimic nacre by various methods resulted in the synthesis of artificial nacre with excellent properties. However, the fabrication procedure was very laborious and time-consuming due to the sequential steps, and only limited-sized materials could be obtained. Hence, a novel design enabling scalable production of high-performance artificial nacre with uniform layered structures is urgently needed. We developed a novel wet-spinning assembly technique to rapidly manufacture continuous nacre- mimic graphene oxide (GO, brick)-sodium alginate (SA, mortar) films and fibers with excellent mechanical properties. At high concentrations, the GO-SA mixtures spontaneously produced liquid crystals (LCs) due to the template effect of GO, and continuous, 6 m long nacre-like GO-SA films were wet-spun from the obtained GO-SA liquid crystalline (LC) dope with a speed of up to 1.5 m/min. The assembled macroscopic GO-SA composites inherited the alignment of the GO sheets from the LC phase, and their mechanical properties were investigated by a joint experimental-computational study. The tensile tests revealed that the maximum strength (0) and Young's modulus (E) of the obtained films reached 239.6 MPa and 22.4 GPa, while the maximum values of o and E for the fibers were 784.9 MPa and 58 GPa, respectively. The described wet-spinning assembly method is applicable for a large-scale and fast production of high-performance continuous artificial nacre.
基金This work was financially supported by the National Natural Science Foundation of China(Nos.20204007,50390090,20490220,10590355)the Doctoral Foundation of National Education Committee of China(No.20030248008)the 863 Project of China(No.2002AA336120).
文摘Finite element method is used to simulate the high-speed melt spinning process, based on the equation system proposed by Doufas et al. Calculation predicts a neck-like deformation, as well as the related profiles of velocity, diameter, temperature, chain orientation, and crystallinity in the fiber spinning process. Considering combined effects on the process such as flow-induced crystallization, viscoelasticity, filament cooling, air drag, inertia, surface tension and gravity, the simulated material flow behaviors are consistent with those observed for semi-crystalline polymers under various spinning conditions, The structure change of polymer coils in the necking region described by the evolution of conformation tensor is also investigated. Based on the relaxation mechanism of macromolecules in flow field different types of morphology change of polymer chains before and in the neck are proposed, giving a complete prospect of structure evolution and crystallization of semi-crystalline polymer in the high speed fiber spinning process.
文摘The microstructure and electrochemical characteristics of Ml(NiCoMnAl) 5 alloys prepared by both the melt spinning method and the conventional induction melting were investigated and compared. SEM and XRD studies show that the microstructure of melt spinning alloys is columnar structure. With increasing melt spinning rate, the crystal grains become finer and preferentially grow along (111)[111] direction. The melt spinning and cast alloys belong to CaCu 5 type hexagonal crystal structure. The electrochemical measurements show that the initial capacities of melt spinning alloy electrodes are all above 210 mAh·g -1 with good activation behavior, reaching their maximum capacities after two charge discharge cycles. The maximum capacity (294 mAh·g -1 ) of melt spinning (10 m·s -1 ) alloy electrodes is as the same as that of as cast alloy electrode, and stability of charge discharge cycles of all melt spinning alloy electrodes is better than that of the as cast alloy electrodes. When charged at 600 mA·g -1 , the capacity of melt spinning (10 m·s -1 ) alloy electrode could reach 65% of its maximum capacity about 45 min with high rate discharge capability; but with the cycle number increasing, the stability of its capacity is less than that electrodes of melt spinning rate.
文摘When programming the daily generation strategies, power plants consider not only the competitive bids in spot market and the original purchase contracts with distribution companies or users, but also the spinning reserve. Aiming at this goal, the paper puts forward a daily generating model, which is a nonlinear programming model containing integral and continous variables, to coordinate the power volumes of competitive bids, contract and the spinning reserve of power plants and thus to maximize their profits. Then, the model is simplified to ease its solving process, and solved by priority ranking method based on efficiency and quadratic programming. The simulation result of a case study shows that the proposed scheme is reasonable and practicable.
文摘The aim of this study is to investigate the surface quality of the melt spinning wheel, which was changed from smooth type to textured structure, to atomize liquid metal to form powders. The effects of melt spinning process parameters like wheel speed, gas ejection pressure, molten metal temperature, nozzle–wheel gap and wheel surface quality on the morphological and microstructural features of 6060 aluminum alloy powders and ribbons were investigated. It was observed that ribbon type material was obtained with the smooth wheel and the powder was produced with textured type. The sizes of produced ribbons with smooth surface wheel varied in the range of 30-170 μm in thickness, 4-8 mm in width, and 0.5-1 m in length. The average powder size of the powders manufactured using the textured wheel was in the range of 161-274 μm, depending on the process parameters.Increasing the wheel speed, melt temperature and decreasing gas ejection pressure, nozzle-wheel gap resulted in the decrease of both ribbon thickness and powder size. The microstructures of the powders and ribbons were the equiaxed cellular type, and the average grain sizes diminished with decreasing the ribbon thickness and powder size. The maximum cooling rates were 2.00×10^5 and 1.26×10^4 K/s for the ribbon with thickness of 30 μm and for the powder with size of 87 μm, respectively.
文摘In this paper, dynamic economic dispatch model is proposed for power systems with bulk wind power integration. The wind turbine generators are assumed to partially undertake the spinning reserve for the thermal generator. A double-layer optimization model is proposed. The outer layer use the differential evolution to search for the power output of thermal generators, and the inner layer use the primal-dual interior point method to solve the OPF of the established output state. Finally, the impact of spinning reserve with wind power on power system operating is validated.
基金financially supported by the National Natural Science Foundation of China (Nos. 51421002, 51627803, 91733301, 51761145042, 21501183, 51402348, 53872321, and 11874402)the Knowledge Innovation Program and the Strategic Priority Research Program (Grant XDB 12010400) of the Chinese Academy of Sciences
文摘In CZTSSe solar cells,a simple sodium-incorporation post-treatment method toward solution-processed Cu2Zn Sn S4precursor films is presented in this work.An ultrathin NaCl film is deposited on Cu2Zn Sn S4precursor films by spin-coating NaCl solution.In subsequent selenization process,the introduction of Na Cl is found to be benefacial for the formation of Cu2-xSe,which can further facilitate the element transportation,leading to dense and smooth CZTSSe films with large grains and less impurity Cu2Sn(S,Se)3phase.SIMS depth profiles confirm the gradient distribution of the sodium element in Na-doped absorbers.Photoluminescence spectra show that the introduction of appropriate sodium into the absorber can inhibit the band tail states.As high as 11.18% of power conversion efficiency(PCE)is achieved for the device treated with 5 mg mL^-1 NaCl solution,and an average efficiency of Na-doped devices is 10.71%,13%higher than that of the control groups(9.45%).Besides,the depletion width and the charge recombination lifetime can also have regular variation with sodium treatment.This work offers an easy modification method for high-quality Na-doped CZTSSe films and high-performance devices,in the meantime,it can also help to further understand the effects of sodium in CZTSSe solar cells.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51579057,5177090655,and 51379052)the State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology,China(Grant No.2016DX07)
文摘A new hybrid organic-inorganic structure of FTO/TiO2/Se/HTL/Au based selenium solar cell has been fabricated through a low-cost spin-coating process in air. In this process, selenium is completely dissolved in hydrazine, to fk)rm a homogeneous precursor solution. After spin-coating the precursor solution on the TiO2 substrates, following by sintering at 200 ℃ for 5rain, a uniform selenium film with crystalline grains is formed. The selenium based solar cell exhibits an efficiency of 1.23% under AM1.5 illumination (100 mW.cm-2), short-circuit current density of 8 mA.cm 2, open-circuit voltage of 0.55 V, and fill factor of 0.37. Moreover, the device shows a stable ability with almost the same performance alter 60 days.
文摘This paper introduces a new method for a formula for electron spin relaxation time of a system of electrons interacting with phonons through phonon-modulated spin-orbit coupling using the projection-reduction method. The phonon absorption and emission processes as well as the photon absorption and emission processes in all electron transition processes can be explained in an organized manner, and the result can be represented in a diagram that can provide intuition for the quantum dynamics of electrons in a solid. The temperature (T) dependence of electron spin relaxation times (T1) in silicon is T1 ∝ T-1.07 at low temperatures and T1 ∝ T-3.3 at high temperatures for acoustic deformation constant Pad = 1.4 × 10^7 eV and optical deformation constant Pod = 4.0 × 10^17 eV/m. This means that electrons are scattered by the acoustic deformation phonons at low temperatures and optical deformation phonons at high temperatures, respectively. The magnetic field (B) dependence of the relaxation times is T1 ∝ B-2.7 at 100 K and T1 ∝ B-2.3 at 150 K, which nearly agree with the result of Yafet, T1 ∝ B-3.0- B -2.5.
基金Project partially supported by the Scientific and Technological Research Council of Turkey (Grant No. TBíTAK)
文摘Approximate analytical bound-state solutions of the Dirac particle in the fields of attractive and repulsive Rosen–Morse (RM) potentials including the Coulomb-like tensor (CLT) potential are obtained for arbitrary spin–orbit quantum number κ. The Pekeris approximation is used to deal with the spin–orbit coupling terms κ(κ ± 1)r 2 . In the presence of exact spin and pseudospin (p-spin) symmetries, the energy eigenvalues and the corresponding normalized two-component wave functions are found by using the parametric generalization of the Nikiforov–Uvarov (NU) method. The numerical results show that the CLT interaction removes degeneracies between the spin and p-spin state doublets.
文摘Whether the proposed mechanical model fits in the nature of technology is the key to solving the problems during three dimensional simulation of power spinning. The study of mechanical model includes: the definition of the contour of contact zone and processing the velocity and frictional force boundary conditions on contact zone. The movement locus of roller surface is a spiral cone and contact zone between roller and workpiece is a part of cone surface of roller. So the contour of the contact zone is intersected by roller cone surface, spiral cone surface and cylindrical surfaces. In this paper, a solution to defining the contour and applying space restriction of the contact zone was proposed. Considering the sudden change in the direction of foctional force on the contact zone during power spinning, an inverse tangential frictional model was adopted to solve the problem. So a new mechanical model comes into being and the 3 - D FEM simulation results prove it to be right.
文摘In this paper the formulation of finite element analysis for frame casing problems of theharmonic type is described. Attention is paid to the OE spinning rotor bearing assembly (RBA)’ sdynamic model, whose harmonic parameters, such as natural frequencies and modal shapes, aresolved by means of structural analysis program using personal computer, i.e. SAP84 software. Ac-cording to orthogonal factorial design table (OFDT), the predominant sensitive influential factors(PSIF) of RBA are determined.
基金The project supported by the President Foundation of the Chinese Academy of Sciences
文摘Based on the coupled harmonic oscillator model, which is born of Heisenberg ferromagnetic spin chain with nearest-neighbor interactions, we adopt the invariant eigen-operator method to derive its energy level, which provides an alternate approach to dealing with the dynamics of spin chain.