Nanowire(NW) structures is an alternative candidate for constructing the next generation photoelectrochemical water splitting system, due to the outstanding optical and electrical properties. NW photoelectrodes compar...Nanowire(NW) structures is an alternative candidate for constructing the next generation photoelectrochemical water splitting system, due to the outstanding optical and electrical properties. NW photoelectrodes comparing to traditional semiconductor photoelectrodes shows the comparatively shorter transfer distance of photo-induced carriers and the increase amount of the surface reaction sites, which is beneficial for lowering the recombination probability of charge carriers and improving their photoelectrochemical(PEC) performances. Here, we demonstrate for the first time that super-long Cu_2O NWs, more than 4.5 μm,with highly efficient water splitting performance, were synthesized using a cost-effective anodic alumina oxide(AAO) template method. In comparison with the photocathode with planar Cu_2O films, the photocathode with Cu_2O NWs demonstrates a significant enhancement in photocurrent, from –1.00 to –2.75 mA/cm^2 at –0.8 V versus Ag/AgCl. After optimization of the photoelectrochemical electrode through depositing Pt NPs with atomic layer deposition(ALD) technology on the Cu_2O NWs, the plateau of photocurrent has been enlarged to –7 mA/cm^2 with the external quantum yield up to 34% at 410 nm. This study suggests that the photoelectrode based on Cu_2O NWs is a hopeful system for establishing high-efficiency water splitting system under visible light.展开更多
在非合作接收场景中,对于一些特殊信号,在输出目标数据时会产生脉冲分裂现象,使得无法及时掌握目标真实参数。这是由于脉冲内部的幅度存在起伏,当信号到达接收设备时,同一脉冲幅度高的位置超过了接收设备灵敏度,幅度低的位置未达到灵敏...在非合作接收场景中,对于一些特殊信号,在输出目标数据时会产生脉冲分裂现象,使得无法及时掌握目标真实参数。这是由于脉冲内部的幅度存在起伏,当信号到达接收设备时,同一脉冲幅度高的位置超过了接收设备灵敏度,幅度低的位置未达到灵敏度造成的。针对这一问题,本文以脉内线性调频的雷达信号为例,深入分析了雷达脉冲分裂信号的内在规律,并在此基础上提出了分选与参数估计方法。本方法首先基于脉冲流的到达时间差分(differenceoftimeofarrival,DTOA)、频率(radiofrequency,RF)和脉冲宽度(pulse width, PW),利用双向长短时记忆网络(bidirectional long short-term memory,BLSTM),学习信号复杂的内在规律,提取多个参数之间的耦合关系,进而将属于同一目标的分裂脉冲从脉冲流中分选出来;再结合波形设计原理,基于分选后脉冲流的到达时间(time of arrival, TOA)、RF和PW,通过聚类和类间估计结果共享,反演得到雷达信号真实参数。仿真结果表明,本文所提的分选方法对于脉内线性调频的雷达脉冲分裂信号,具有极佳的分选效果;本文的参数估计方法,基于分选后的脉冲流数据,对原始信号斜率、RF、PW和PRI都有理想的估计结果。展开更多
基金supported by European Research Council(HiNaPc:737616)European Research Council(ThreeDsurface:240144)+8 种基金BMBF(ZIK-3DNanoDevice:03Z1MN11)DFG(LE2249_4-1)BMBF(Meta-ZIK-BioLithoMorphie:03Z1M511)National Natural Science Foundation of China(Nos.21577086,51702130,21503209)Natural Science Foundation of Jiangsu Province(BK 20170550)Jiangsu Specially-Appointed Professor ProgramHundred-Talent Program(Chinese Academy of Sciences)Beijing Natural Science Foundation(No.2162042)Key Research Program of Frontier Science,CAS(No.QYZDBSSW-SLH006)
文摘Nanowire(NW) structures is an alternative candidate for constructing the next generation photoelectrochemical water splitting system, due to the outstanding optical and electrical properties. NW photoelectrodes comparing to traditional semiconductor photoelectrodes shows the comparatively shorter transfer distance of photo-induced carriers and the increase amount of the surface reaction sites, which is beneficial for lowering the recombination probability of charge carriers and improving their photoelectrochemical(PEC) performances. Here, we demonstrate for the first time that super-long Cu_2O NWs, more than 4.5 μm,with highly efficient water splitting performance, were synthesized using a cost-effective anodic alumina oxide(AAO) template method. In comparison with the photocathode with planar Cu_2O films, the photocathode with Cu_2O NWs demonstrates a significant enhancement in photocurrent, from –1.00 to –2.75 mA/cm^2 at –0.8 V versus Ag/AgCl. After optimization of the photoelectrochemical electrode through depositing Pt NPs with atomic layer deposition(ALD) technology on the Cu_2O NWs, the plateau of photocurrent has been enlarged to –7 mA/cm^2 with the external quantum yield up to 34% at 410 nm. This study suggests that the photoelectrode based on Cu_2O NWs is a hopeful system for establishing high-efficiency water splitting system under visible light.
文摘在非合作接收场景中,对于一些特殊信号,在输出目标数据时会产生脉冲分裂现象,使得无法及时掌握目标真实参数。这是由于脉冲内部的幅度存在起伏,当信号到达接收设备时,同一脉冲幅度高的位置超过了接收设备灵敏度,幅度低的位置未达到灵敏度造成的。针对这一问题,本文以脉内线性调频的雷达信号为例,深入分析了雷达脉冲分裂信号的内在规律,并在此基础上提出了分选与参数估计方法。本方法首先基于脉冲流的到达时间差分(differenceoftimeofarrival,DTOA)、频率(radiofrequency,RF)和脉冲宽度(pulse width, PW),利用双向长短时记忆网络(bidirectional long short-term memory,BLSTM),学习信号复杂的内在规律,提取多个参数之间的耦合关系,进而将属于同一目标的分裂脉冲从脉冲流中分选出来;再结合波形设计原理,基于分选后脉冲流的到达时间(time of arrival, TOA)、RF和PW,通过聚类和类间估计结果共享,反演得到雷达信号真实参数。仿真结果表明,本文所提的分选方法对于脉内线性调频的雷达脉冲分裂信号,具有极佳的分选效果;本文的参数估计方法,基于分选后的脉冲流数据,对原始信号斜率、RF、PW和PRI都有理想的估计结果。
