Study on the Treatment of Acid Mine Drainage Containing Fe^(2+) and Mn^(2+) Using Modified Spontaneous Combustion Gangue

The high concentrations of Fe^(2+) and Mn^(2+) in acid mine drainage make it difficult and expensive to treat.It is urgent that we find a cheap and efficient adsorption material to treat Fe^(2+) and Mn^(2+).As a solid waste in mining areas,coal gangue occupies a large area and pollutes the surrounding environment during the stacking process.Developing a method of resource utilization is thus a research hotspot.In this study,we modified spontaneous combustion gangue using NaOH,NaCl,and HCl by chemically modifying the minerals.We determined the optimal conditions for treating Fe^(2+) and Mn^(2+) in acid mine drainage with spontaneous combustion gangue and modified coal gangue using the single factor test method.Based on results of the static test,two dynamic test columns,column No.1(spontaneous combustion gangue)and column No.2(NaOH modified spontaneous combustion gangue),were constructed,and the repair effects of acid mine drainage were compared and analyzed using dynamic experiments.The results show that overall,NaOH modified spontaneous combustion gangue is the most efficient at removing the Fe^(2+) and Mn^(2+) in acid mine drainage.The optimal conditions for NaOH modification are an NaOH concentration of 3 mol/L,a liquid to solid ratio of 2 L/kg,and a modification time of 8 h.The overall efficiency of column No.2 at removing Fe^(2+) and Mn^(2+) from acid mine drainage is better than that of column No.1.Among them,the average removal efficiency of Fe^(2+)and Mn^(2+) from acid mine drainage in column No.2 were 97.73%and 44.82%,respectively.The above results show that NaOH modified spontaneous combustion gangue is a good adsorbent,which has application potential in wastewater remediation,as it can achieve the purpose of“treating dust with waste”.

Experimental study on explosive mechanism of spontaneous combustion gangue dump

In order to explore the reason for the frequency explosion of spontaneous combustion coal gangue dump and get to know their explosion mechanism, established the experiment platform about spontaneous combustion coal gangue dump interoperable water. The gangue dump was heated using the external heat source, and rainy weather through water mist was simulated. Simulated experiment about explosion of spontaneous combustion coal gangue dump was carried out on the different conditions of the rainfall or not. The unusual gases produced in the course of gangue combustion and the changes in temperature were observed, and their impacts on the explosion of gangue dump were analyzed. The experimental results show that overall warming phenomenon of the gangue dump after watering occurred, the amount of H2 is three times than that before watering, and the amount of CO is far greater than that on the conditions of no-watering, at the same time combining with local observation and tests. It is found that the content of the oxygen reduce with the temperature increasing; however, gangue dump internal hydrogen content increase unusually on the rainfall conditions at 90 ℃, but the local measuring points reach the explosion limit. The existence of the CO and H2 is the main reason for inducing the explosion of spontaneous combustion coal gangue dump.