Analytical investigations of in situ stress inversion from borehole breakout geometries

This study aims to investigate the feasibility of deriving in situ horizontal stresses from the breakout width and depth using the analytical method.Twenty-three breakout data with different borehole sizes were collected and three failure criteria were studied.Based on the Kirsch equations,relatively accurate major horizontal stress(sH)estimations from known minor horizontal stress(sh)were achieved with percentage errors ranging from 0.33%to 44.08%using the breakout width.The Mogi-Coulomb failure criterion(average error:13.1%)outperformed modified Wiebols-Cook(average error:19.09%)and modified Lade(average error:18.09%)failure criteria.However,none of the tested constitutive models could yield reasonable sh predictions from known sH using the same approach due to the analytical expression of the redistributed stress and the nature of the constitutive models.In consideration of this issue,the horizontal stress ratio(sH/sh)is suggested as an alternative input,which could estimate both sH and sh with the same level of accuracy.Moreover,the estimation accuracies for both large-scale and laboratory-scale breakouts are comparable,suggesting the applicability of this approach across different breakout sizes.For breakout depth,conformal mapping and complex variable method were used to calculate the stress concentration around the breakout tip,allowing the expression of redistributed stresses using binomials composed of sH and sh.Nevertheless,analysis of the breakout depth stabilisation mechanism indicates that additional parameters are required to utilise normalised breakout depth for stress estimation compared to breakout width.These parameters are challenging to obtain,especially under field conditions,meaning utilising normalised breakout depth analytically in practical applications faces significant challenges and remains infeasible at this stage.Nonetheless,the normalised breakout depth should still be considered a critical input for any empirical and statistical stress estimation method given its significant correlation with horizontal stresses.The outcome of this paper is expected to contribute valuable insights into the breakout stabilisation mechanisms and estimation of in situ stress magnitudes based on borehole breakout geometries.

High-density lipoproteins:an emerging target in the prevention of cardiovascular disease

High-density lipoproteins （HDLs） have been well established to protect against the development of atherosclerotic cardiovascular disease. It has become apparent that in addition to the promotion of reverse cholesterol transport, HDLs possess a number of additional functional properties that may contribute to their beneficial influence on the arterial wall. A number of exciting therapeutic strategies have been developed that target HDL and its ability to protect against the development of atherosclerotic plaque. This paper will review how the promotion of the functional properties of HDL inhibits the formation of atherosclerotic plaque and stabilises lesions in patients with established disease.

Emerging trends in expansive soil stabilisation: A review

Expansive soils are problematic due to the performances of their clay mineral constituent, which makes them exhibit the shrink-swell characteristics. The shrink-swell behaviours make expansive soils inappropriate for direct engineering application in their natural form. In an attempt to make them more feasible for construction purposes, numerous materials and techniques have been used to stabilise the soil. In this study, the additives and techniques applied for stabilising expansive soils will be focused on,with respect to their efficiency in improving the engineering properties of the soils. Then we discussed the microstructural interaction, chemical process, economic implication, nanotechnology application, as well as waste reuse and sustainability. Some issues regarding the effective application of the emerging trends in expansive soil stabilisation were presented with three categories, namely geoenvironmental,standardisation and optimisation issues. Techniques like predictive modelling and exploring methods such as reliability-based design optimisation, response surface methodology, dimensional analysis, and artificial intelligence technology were also proposed in order to ensure that expansive soil stabilisation is efficient.

Sternoclavicular joint dislocation and its management: A review of the literature

Dislocations of the sternoclavicular joint(SCJ) occur with relative infrequency and can be classified into anterior and posterior dislocation, with the former being more common. The SCJ is inherently unstable due to its lack of articular contact and therefore relies on stability from surrounding ligamentous structures, such as the costoclavicular, interclavicular and capsular ligaments. The posterior capsule has been shown in several studies to be the most important structure in determining stability irrespective of the direction of injury. Posterior dislocation of the SCJ can be associated with life threatening complications such as neurovascular, tracheal and oesophageal injuries. Due to the high mortality associated with such complications, these injuries need to be recognised acutely and managed promptly. Investigations such as x-ray imaging are poor at delineating anatomy at the level of the mediastinum and therefore CT imaging has become the investigation of choice. Due to its rarity, the current guidance on how to manage acute and chronic dislocations is debatable. This analysis of historical and recent literature aims to determine guidance on current thinking regarding SCJ instability, including the use of the Stanmore triangle. The described methods of reduction for both anterior and posterior dislocations and the various surgical reconstructive techniques are also discussed.

Diagnosing syndesmotic instability in ankle fractures

The precise diagnosis of distal tibiofibular syndesmotic ligament injury is challenging and a distinction should be made between syndesmotic ligament disruption and real syndesmotic instability.This article summarizes the available evidence in the light of the author’s opinion.Pre-operative radiographic assessment,standard radiographs,computed tomography scanning and magnetic resonance imaging are of limited value in detecting syndesmotic instability in acute ankle fractures but can be helpful in planning.Intra-operative stress testing,in the sagittal,coronal or exorotation direction,is more reliable in the diagnosis of syndesmotic instability of rotational ankle fractures.The Hook or Cotton test is more reliable than the exorotation stress test.The lateral view is more reliable than the AP mortise view because of the larger displacement in this direction.When the Hook test is used the force should be applied in the sagittal direction.A force of 100 N applied to the fibula seems to be appropriate.In the case of an unstable joint requiring syndesmotic stabilisation,the tibiofibular clear space would exceed 5 mm on the lateral stress test.When the surgeon is able to perform an ankle arthroscopy this technique is useful to detect syndesmotic injury and can guide anatomic reduction of the syndesmosis.Many guidelines formulated in this article are based on biomechanical and cadaveric studies and clinical correlation has to be established.

In-situ stabilisation followed by ex-situ composting for treatment and disposal of heavy metals polluted sediments

An innovative in-situ stabilisation treatment followed by ex-situ sediment composting was tested for its ability to treat and dispose of heavy-metal-polluted sediments in a river near the Chinese Pearl Delta. First, polluted sediments were treated in-situ to stabilise the heavy metals. Then the treated sediments were dredged, dewatered and sent for high temperature aerobic composting （HTAC） treatment. Finally, the compost products were used as a fertiliser for fiver bank plants. The stabilisation efficiency of heavy metals during the process was investigated and the results are as follows： （1） using in-situ stabilisation, the extraction concentrations of Cu, Zn and Pb were reduced by 65.0%, 82.2% and 90.0%, respectively, which are much lower than the national standard given in the Identification Standard for Hazardous Waste （GB5085.3-1996）; （2） chemical fraction analysis showed that heavy metals were further stabilized during the HTAC treatment; （3） the concentrations of Cu, Zn and Pb in rainwater leachate through the river bank met the level of class V in the Environmental Quality Standards for Surface Water in China （GB3838-2002）. Therefore, using this new process, the toxicities of heavy metals in sediments were reduced markedly.

Incorporation of a nanotechnology-based additive in cementitious products for clay stabilisation

The mechanical performances and water retention characteristics of clays,stabilised by partial substitution of cement with by-products and inclusion of a nanotechnology-based additive called RoadCem(RC),are studied in this research.The unconfined compression tests and one-dimensional oedometer swelling were performed after 7 d of curing to understand the influence of addition of 1%of RC material in the stabilised soils with the cement partially replaced by 49%,59%and 69%of ground granulated blast furnace slag(GBBS)or pulverised fuel ash(PFA).The moisture retention capacity of the stabilised clays was also explored using the soil-water retention curve(SWRC)from the measured suctions.Results confirmed an obvious effect of the use of RC with the obtained strength and swell properties of the stabilised clays suitable for road application at 50%replacement of cement.This outcome is associated with the in-depth and penetrating hydration of the cementitious materials by the RC and water which results in the production of needle-like matrix with interlocking filaments e a phenomenon referred to as the‘wrapping’effect.On the other hand,the SWRC used to describe the water holding capacity and corresponding swell mechanism of clays stabilised by a proportion of RC showed a satisfactory response.The moisture retention of the RC-modified clays was initially higher but reduced subsequently as the saturation level increased with decreasing suction.This phenomenon confirmed that clays stabilised by including the RC are water-proof in nature,thus ensuring reduced porosity and suction even at reduced water content.Overall,the stabilised clays with the combination of cement,GGBS and RC showed a better performance compared to those with the PFA included.

Laboratory-scale model of carbon dioxide deposition for soilstabilisation

Olivine sand is a natural mineral,which,when added to soil,can improve the soil’s mechanical properties while also sequester carbon dioxide(CO2)from the surrounding environment.The originality of this paper stems from the novel two-stage approach.In the first stage,natural carbonation of olivine and carbonation of olivine treated soil under different CO2pressures and times were investigated.In this stage,the unconfined compression test was used as a tool to evaluate the strength performance.In the second stage,details of the installation and performance of carbonated olivine columns using a laboratory-scale model were investigated.In this respect,olivine was mixed with the natural soil using the auger and the columns were then carbonated with gaseous CO2.The unconfined compressive strengths of soil in the first stage increased by up to 120% compared to those of the natural untreated soil.The strength development was found to be proportional to the CO2pressure and carbonation period.Microstructural analyses indicated the presence of magnesite on the surface of carbonated olivinetreated soil,demonstrating that modified physical properties provided a stronger and stiffer matrix.The performance of the carbonated olivine-soil columns,in terms of ultimate bearing capacity,showed that the carbonation procedure occurred rapidly and yielded a bearing capacity value of 120 k Pa.Results of this study are of significance to the construction industry as the feasibility of carbonated olivine for strengthening and stabilizing soil is validated.Its applicability lies in a range of different geotechnical applications whilst also mitigates the global warming through the sequestration of CO2.

Bronchodilatory and mast cell stabilising activity of Cressa cretica L.:Evaluation through in vivo and in vitro experimental models

Objective:To evaluate the effect of ethylacetate fraction(Fr-Et) and methanolic fraction(FrMe) obtained from Cressa cretica L.(C.crelica) L on experimental models for bronchodilatory activity and mast cell stabilising activity.Methods:The effect of Fr-Et and Fr-Me were studied on acetylcholine and histamine aerosol-induced broncospasm using guinea pigs as experimental animals.Also,the effects of these fractions were evaluated on the isolated guinea pig tracheal preparations.Besides this mast cell degranulation effect was assessed using egg albumin and compound 48/80 on rat peritoneal mast cells.Results:Significant increase in nreconvulsion time was observed due to pretrealment with the fractions when guinea pigs were exposed to histamine and acetylcholine aerosol.Fr-Et and Fr-Me significantly increased the preconvulsion in a dose depended manner that suggestive of bronchodilating activity.Fr-Et and Fr-Me exhibited a significant concentration dependant relaxant effect on guinea pig trachea pre-contracted with CCh,K^+ and histamine.The results revealed that Fr-Et to be more potent than Fr-Me in relaxing histamine and K^+ and calcium induced contraction than CCh induced conlractions.Studies on the fractions in protecting mast cell degranulation,which were elicited by the egg albumin as well as synthetic compound 48/80 revealed both the fractions significantly protect the mast cell degranulation,which release mediators such as histamine and proinflammatory cytokines through various stimuli in a dose depended manner.Conclusions:Thus our study established the bronchodilator activity,and mast cell stabilizing activity which are important mediators that provoke or sustain in asthma.

Performance Evaluation of Waste Stabilisation Ponds

Waste stabilisation pond system has been used more especially in developing countries for sewage treatment. The objective of this study was to investigate the hydraulic and performance efficiency of Palapye waste stabilisation ponds. The hydraulic efficiency was evaluated through drogue, pond geometry and sludge accumulation assessment. The performance efficiency was evaluated through periodic sampling and analysis of physiochemical and bacteriological parameters of individual units and of the system as a whole. Except for the maturation ponds, the depth of the anaerobic pond had reduced from 4 m to 0.45 m, for facultative ponds from 2.0 m to a range of 0.52 m - 0.91 m. The design hydraulic retention time of the system had reduced from 20 days to 7.1 days. The concentration of some physiochemical parameters in the effluent was 305 mg·L-1, 277 Nephelometric Turbidity Units (NTU), 204 mg·L-1, 156 mg·L-1, 110 mg·L-1, and 15 mg·L-1 being total suspended solids, turbidity, nitrates, chemical oxygen demand, biochemical oxygen demand and phosphate respectively. These values were more than the standard limits of the country. Effluent total coliforms concentration was 3.6 log units and within the threshold of 4.3 log units, faecal coliforms concentration was 3.5 log units, slightly higher than the threshold of 3 log units. Though Escherichia coli have no limits for discharge into other environments, the concentration in the effluent was reasonable at 2.5 log units and also within irrigation limit of 3 log counts. Palapye wastewater treatment system hydraulic efficiency is lower than the design criterion. The system was overall poor in physiochemical parameters removal but better in bacteriological removal.

U-model Enhanced Dynamic Control of a Heavy Oil Pyrolysis/Cracking Furnace

This paper proposes a case study in the control of a heavy oil pyrolysis/cracking furnace with a newly extended U-model based pole placement controller(U-PPC). The major work of the paper includes: 1) establishing a control oriented nonlinear dynamic model with Naphtha cracking and thermal dynamics; 2) analysing a U-model(i.e., control oriented prototype) representation of various popular process model sets; 3)designing the new U-PPC to enhance the control performance in pole placement and stabilisation; 4) taking computational bench tests to demonstrate the control system design and performance with a user-friendly step by step procedure.

Stabilisation of Pb in Pb Smelting Slag-Contaminated Soil by Compost-Modified Biochars and Their Effects on Maize Plant Growth

Compost has been used to stabilise lead (Pb) in soil. However, compost contains a high level of dissolved organic matter (DOM) which may make Pb bioavailable in plant and thereby limiting its effectiveness and application. Addition of biochar to compost can reduce this effect. Rice husk (RH) and Cashew nut shell (CNS) biochars and compost-modified biochars were used in comparison to compost for stabilizing Pb in lead smelting slag (LSS)-contaminated soil (Pb = 18,300 mg/kg) in Nigeria. Efficiency of Pb stabilisation in control and amended soils was assessed using CaCl2 batch leaching experiment and plant performance. In pot experiments, maize plant was grown on the contaminated soil and on soil treated with minimum and optimum doses of the amendments singly and in combination for 6 weeks. Agronomical and chemical parameters of the plants were measured. CaCl2-extractable Pb in the untreated soil was reduced from 60 mg/kg to 0.55 mg/kg in RHB amended soils and non-detectable in other amended soils. RH-biochar/compost increased plant height, number of leaf and leaf area more than the others. Similarly, at minimum rate, it reduced root and shoot Pb by 91% and 86.0% respectively. Compost-modified rice husk biocharstabilised Pb in lead smelting slag contaminated soil reduced Pb plant uptake and improved plant growth. Lead stabilisation through the use of rice husk biochar with compost may be a green method for remediation of lead smelting slag-contaminated soil.

Effect of Gum Arabic as Partial Replacement of Cement on the Durability Properties of Compressed Laterite Blocks

Compressed stabilized earth blocks are the innovation of building materials replacing the earth blocks commonly called adobe. Common stabilizers (cement and lime) have been found to be expensive and harmful to the environment. Finding a natural, available, environmentally friendly stabilizer is vital. The objective of this study was therefore to assess the effects of gum Arabic (GA) as binder on the durability properties of laterite blocks. Compressed laterite blocks were stabilized with 2% and 6% respectively as total percentage of binders in the blocks (cement and/or GA). The results showed that GA improved the abrasion and drop resistances of compressed blocks. It has been found that the abrasion resistance of compressed blocks increased with the increase of GA content and the decrease of cement content. For instance, the mass abraded away of blocks stabilized with cement only was reduced up to 95.18% when GA was used to partially replace cement. As for drop test, the higher the content of GA the higher the resistance of blocks to drop.

Models to predict sunlight-induced photodegradation rates of contaminants in wastewater stabilisation ponds and clarifiers

Two kinetic models were established for conservative estimates of photodegradation rates of contaminants under sunlight irradiation,in particular for wastewater stabilisation ponds and clarifiers in conventional wastewater treatment plants.These two models were designated for(1)contaminants with high photolytic rates or high photolytic quantum yields,whose photodegradation is unlikely to be enhanced by aquatic photosensitisers;and(2)contaminants withstanding direct photolysis in sunlit waters but subjected to indirect photolysis.The effortlessly intelligible prediction procedure involves sampling and analysis of real water samples,simulated solar experiments in the laboratory,and transfer of the laboratory results to realise water treatment using the prediction models.Although similar models have been widely used for laboratory studies,this paper provides a preliminary example of translating laboratory results to the photochemical fate of contaminants in real waters.

Influence of Impurities of Zircon Sand on the Microstructure of Fused Zirconia Grains for Continuous Casting of Steel Refractories

Certain impurities of zircon sands, especially alumina, titania, calcia and yttria cannot be completely re- moved in the production of fused zirconia and may have an influence on the corrosion resistance and other product properties of refractories for continuous casting of steel. In this paper, we present our findings on how impurities in raw materials end up in different stabilised zirconia refractory grains, in particular calcia-, magnesia- and yttria-stabilised zirconia. The microstructure （and phase composition） is affected by both the raw materials and the fusion conditions （furnace type and cooling technology）.

One and Two Photon Excitation of Radiofrequency Trapped Ca

Radiofrequency （rf） trapped ions are versatile candidates for a large panel of applications ranging from quantum information to the creation of cold molecules. Sample size can range from a single to 10^6 ions, and the internal and external energy states of the atoms can be controlled with high precision. In the experiment, we focus on different protocols related to frequency metrology using rf trapped Ca.

Effects of Lateral Variation in Vegetation and Basin ‘Dome' Shape on Tropical Lowland Peat Stabilisation in the Kota Samarahan-Asajaya Area, West Sarawak, Malaysia

Field surveys indicate lateral variation in peat humification levels （von Post） in dominantly occurring fibric,fibric to hemic,sapric and hemie to sapric peats across a gradient from the margin towards the centre of tropical lowland peat domes.Cement-peat stabilisation can be enhanced by adding mineral soil fillers （silt,clays and fine sands） obtained from Quaternary floodplain deposits and residual soil （weathered schist）.The unconfined compressive strength （UCS） of the stabilised cement-mineral soil fifler-peat mix increases with the increased addition of selected mineral soil filler.Lateral variation in the stabilised peat strength （UCS） in the top 0 to 0.5 m layer was found from the margin towards the centre of the tropical lowland peat dome.The variations in the UCS of stabilised tropical lowland peats along a gradient from the periphery towards the centre of the peat dome are most likely caused by a combination of factors due to variations in the mineral soil or ash content of the peat and horizontal zonation or lateral variation in the dominant species of the plant assemblages （due to successive vegetation zonation of the peat swamp forest from the periphery towards the centre of the tropical lowland peat dome）.

SPH Particle Collisions for the Reduction of Particle Clustering, Interface Stabilisation and Wall Modelling

The pair-wise forces in the SPH momentum equation guarantee the conservation of momentum, but they cannot prevent particle clustering and wall penetration. Particle clustering may occur for several reasons. A fundamental issue is the tensile instability, which is caused by negative numerical pressures. Clustering may also occur due to certain properties of the kernel gradient. Discontinuities in the pressure and its gradient, due to surface tension and gravity, may cause particle instabilities near the interface between two fluids. Wall penetration is also a form of particle clustering. In this paper the particle collision concept is introduced to suppress particle clustering. Here, the use of kinematic conditions (motion) rather than dynamic conditions (forces) is explored. These kinematic conditions are obtained from kinetic collision theory. Conservation of momentum is maintained, and under elastic conditions conservation of energy as well. The particle collision model only becomes active when needed. It may be seen as a particle shifting method, in the sense that the velocities are changed, and as a consequence of that the particle positions change. It is demonstrated in several case studies that the particle collision model allows for realistic (low) viscosities. It was also found to stabilise the interface between two fluids up to high, realistic density ratios (1000:1) in typical liquid-gas applications. As such it can be used as a multi-fluid model. The concept allows for real wave speed ratios (and far beyond), which, as well as real viscosities, are essential in the modelling of heat transfer applications. The collisions with walls allow for no-slip conditions at real viscosities while wall penetration is suppressed. In summary, the particle collision model makes SPH more robust for engineering.

Monitoring of Anthocyanins and Colour in Electrochemically Processed <i>Hibiscus sabdariffa</i>Juice

The vital role of anthocyanins in Hibiscus sabdariffa L. is now known to most consumers. The richness of anthocyanins in antioxidants, vitamin C, minerals, etc., provides Hibiscus juice with proven nutritional qualities. The health requirements of recent years have made food products with added preservatives or processed at high temperatures less popular, thus explaining the new orientations towards innovative and interdisciplinary technologies. Anthocyanins from Hibiscus sabdariffa L. are, however, sensitive to degradation factors such as temperature, light, enzymes and also oxygen. The instability of anthocyanins has long been a subject of research using classic techniques such as heat treatment, the results of which are often limited by the rapid degradation and above all the destruction of the nutritional and organoleptic qualities of the product. Oxygen dissolved in juices is so far treated by bubbling with an inert gas or by adding other molecules such as preservatives which can cause a lot of health damage. The electrochemical approach is a new stabilisation technique that reduces the dissolved oxygen in the juice, cold and without the addition of other molecules. The electrolysis of Hibiscus juice was carried out by noble electrodes (Platinum and Stainless Steel) with a well-characterised Time/Potential or Time/Intensity couple. The electroreduced samples and the control were then stored at 4°C, 25°C and 37°C for more than 6 months. Monitoring of anthocyanins in the first month, of the samples and the control, showed a significant difference of 10% between the electroreduced extract and the untreated control at 37°C, which had previously been problematic for the heat treatment and even for the other membrane techniques. Oxygen reduction on the platinum electrode/ECS allowed the retention of more than 10% of anthocyanins after 4 weeks of storage at 25°C and 37°C. At 4°C, a significant difference of 5% between the electro-reduced Hibiscus juice and the control was maintained until the fifth month of storage with the 1/5 ratio (calyx/water). Non-significant losses in anthocyanin (10 mg/l), for the juice with reduced dissolved oxygen, were noted for the 1/5 and 1/15 ratios during the first month of storage at 4°C against 24 mg/l of significant losses for the 1/20 ratio. However, the untreated control showed significant losses for the ratios 1/20, 1/15 and 1/5. Oxygen dissolved in the juice therefore considerably degrades the anthocyanins of Hibiscus sabdariffa L. from the first month of storage at 4°C.

Electrostatic Complexes of Nano-Montmorillonite/Ethyl Lauroyl Arginate Stabilized Sunflower Oil Pickering Emulsions

Compared with traditional surfactant-stabilised emulsions, Pickering emulsions, stabilised by clay nanoparticles, have the advantages of strong interface stability, strong versatility, and low toxicity. Moreover, they have excellent application potential in the fields of food and medicine. In this study, a food-grade Pickering emulsion stabiliser was prepared by physically adsorbing the cationic surfactant ethyl lauroyl arginate (LAE) on the surface of nano-montmorillonite (NMMT). Different LAE/NMMT combinations were assessed for their capacity to stabilise an oil-in-water emulsion at a low solid concentration (0.5%, w/v). The controllability of the droplet diameter and stability of the Pickering emulsions can be realised by changing the content of LAE. Scanning electron microscopy (SEM), and laser confocal microscopy (CLSM) confirmed the successful preparation of sunflower oil Pickering emulsion droplets stabilised by LAE/NMMT (0.0075%/1%). Additionally, the LAE/NMMT studied in this work could be used as a highly effective antibacterial surfactant with inorganic nanoparticles to efficiently stabilise Pickering emulsions, thus expanding the potential of preparing edible Pickering emulsion formulae.