This study was conducted in Xinkou Experimental Forestry Farm of Fujian Agricultural and Forestry University, Sanming, Fujian Province in January 1999. Taking pure stand of Chinese fir as control, the authors measured...This study was conducted in Xinkou Experimental Forestry Farm of Fujian Agricultural and Forestry University, Sanming, Fujian Province in January 1999. Taking pure stand of Chinese fir as control, the authors measured and studied the content of organic carbon, content of humic acid (HA), ratio of HA to fulvic acid (FA), and the characteristics of infrared light spectrum and visible light spectrum of soil humus in the mixed forest of Chinese fir and Tsoong?tree. Compared to humus composition in the pure stand of Chinese fir, the content of soil organic C, HA content, and the E4 value of HA for different layers of soil, except for the ratio of HA to FA, showed a significant increase in the mixed forest, while the ratios of E4 to E6 had a little decrease. The infrared light spectrum of humic acid had an absorptive peak at 1650 cm-1. It is concluded that the levels of humification and aromaticity of soil humus are higher in the mixed forest, which is favorable for the improvement of soil structure and nutrient supply, thus improving the soil fertility to a certain degree.展开更多
This paper deals with the development of a sequential extraction method to separate the Ca-bound and Fe-and Al-bound humus from soils.First,comparative analyses were carried out on dissolution of synthetic organo-mine...This paper deals with the development of a sequential extraction method to separate the Ca-bound and Fe-and Al-bound humus from soils.First,comparative analyses were carried out on dissolution of synthetic organo-mineral complexes by different extractants,i.e.0.1M Na4P2O7,0.1M NaOH+0.1M Na4P2O7 mixture,0.1M NaOH,0.5M (NaPO3)6 and 0.5M neutral Na2SO4.Among the five extractants,0.1M NaOH+0.1M Na4P2O7 mixture was the most efficient in extracting humus from various complexes.0.5M Na2SO4 had a better specificity to Ca than 0.5M (NaPO3)6,by only extracting Ca-bound humus without destorying Fe-and Al-bound organo-mineral complexes.Then sequential extractions first with 0.5M Na2SO4 and then with 0.1M NaOH+0.1M Na4P2O7 mixture were applied to a series of soil samples with different degrees of base saturation.The cations were dominated by Ca in the 0.5M Na2SO4 extract and by Al in the 0.1M NaOH+0.1M Na4P2O7 mixture.The sequential extraction method can efficiently separate or isolate Ca-bound and Fe-and Al-bound humus from each other.展开更多
The sorption-desorption behavior of dicyandiamide (DCD) is an importantchemical process that affects DCD fate and mobility in soils. Therefore, this study quantified DCDsorption-desorption on a phaeozem (Mollisol), a ...The sorption-desorption behavior of dicyandiamide (DCD) is an importantchemical process that affects DCD fate and mobility in soils. Therefore, this study quantified DCDsorption-desorption on a phaeozem (Mollisol), a burozem (Alfisol), a soil with organicmatter-removed and peat humus using the batch-equilibration procedure, and identified soilproperties that influenced DCD sorption. The sorption on peat humus was higher than that on thephaeozem and the burozem, with much lower sorption observed on the soil with organic matter-removed,indicating that soil organic matter was the main carrier of DCD sorption. Due to its amphipathicproperty the DCD molecule sorption on the phaeozem and the burozem decreased as pH increased fromabout 2 to 5, but a further increase in pH led to a rise in DCD sorption. The DCD desorptionhysteretic effect for peat humus was greater than that for the phaeozem and the burozem using 0.01mol L^(-1) CaCl_2 as the background electrolyte, suggesting that the hydrophobic domains of organicmatter may play an important role in DCD sorption.展开更多
The organic carbon and humus content in oil polluted brown and grey-brown soils in Mangyshlak,Pre-Caspian Sea Region,was analyzed from 2000 to 2008.The results indicated that bitumen substances from crude oil pollutio...The organic carbon and humus content in oil polluted brown and grey-brown soils in Mangyshlak,Pre-Caspian Sea Region,was analyzed from 2000 to 2008.The results indicated that bitumen substances from crude oil pollution deteriorated the soil property,however,the organic carbon content increased significantly.The products of oil pollution changed the composition of car-bonaceous substances which formed soil humus,and changed the ratios of the humus components.Residual insoluble carbon increased with the rise of oil organic carbon.The mobility of humus components was significantly increased because of the high oxidation-reduction process in the topsoil,and the humus content and microorganism activity increased.The organic carbon content increased significantly,while it decreased with the distance away from the oil well.The rearrangement of physical,physical-chemical and chemical properties of the polluted soils was significant.展开更多
14C-tracer technique and closed incubation method were used to study straw 14C decomposition and distribution in different fractions of newly formed humus under different moisture regimes. Decomposition of straw 14C w...14C-tracer technique and closed incubation method were used to study straw 14C decomposition and distribution in different fractions of newly formed humus under different moisture regimes. Decomposition of straw 14C was faster during the initial days, and slower thereafter. Decay rate constants of straw 14C varied from 3.29x10-3 d-1 to 7.06x10-3 d-1. After 112 d incubation, the amount of straw 14C mineralized was 1.17~1.46 times greater in submerged soils than in upland soils. of the soil residual 14C, 9.08%~15.73%was present in humic acid (HA) and 31.01%~37.62% in fulvic acid (FA). Submerged condition favored the formation of HA, and HA/FA ratio of newly formed humus (labelled) was greater in submerged soils than in upland soils. Clay minerals affected the distribution of straw 14C in different humus fractions. Proportion of 14C present in HA to 14C remaining in soil was greater in Vertisol than in Ultisol.展开更多
Effects of humus fractions (fulvic acid, brown humic acid and grey humic acid) on the leachability and transferring activity of five types of mineral-bound Hg were investigated. Under the acid leaching condition: fulv...Effects of humus fractions (fulvic acid, brown humic acid and grey humic acid) on the leachability and transferring activity of five types of mineral-bound Hg were investigated. Under the acid leaching condition: fulvic acid could promote leachability and vertical transference of all the mineral-bound Hg. Brown humic acid could retard the leaching and transferring processes of CaCO3-Hg, Fe2O3-Hg, MnO2-Hg and kaolinite Hg but not bentonite-Hg. Grey humic acid could greatly enhance residing ability of the mineral-bound Hg in the soil column and restrain them from vertical transferring. The effect of humus on leachability and transferring activity on the mineral-bound Hg was closely related to its ability to convert the mineral-bound Hg into organic-bound form and the transferability of the latter in the soil column. The characteristics of the mineral-bound Hg in speciation were the internal factors that determined the extent and rate of the influence of the humus.展开更多
In this paper, author will report on the process of rice cultivation in paddy fields using treated water which treated domestic sewage wastewater. Odor problems from sewage treatment plants have been solved by confine...In this paper, author will report on the process of rice cultivation in paddy fields using treated water which treated domestic sewage wastewater. Odor problems from sewage treatment plants have been solved by confinement and ventilation, but reducing the color and odor of treated water is economically difficult and is a subject of recycling of discharged water. Humus pellet bioreactors can be attached to existing sewage treatment plants to suppress the odor of the sewage treatment plants as a whole and to prevent sludge from deteriorating and to improve the quality of treated water. The odor and color of the treated water discharged from the sewage treatment plant was reduced. In addition, we were able to obtain performance of treated water with nitrogen 3 mg/L, phosphorus 1 mg/L or less throughout the year. On the other hand, there are many cases of results that cannot be used for paddy rice cultivation and vegetable production etc. by ignoring plant growth and physiology (fertilizer). For that reason, laws and guidance such as having to dilute more than 50 times in order to use processed water for agriculture are being conducted without learning. It is a case of using humus pellets in sewage treatment system and using deodorized wastewater of sewage by adjusting fertilizer when used in paddy field rice production.展开更多
The radioactive isotope tracer and ion exchange balanced method was used to study the stability of 109Cd, 65 Zn complexes with humus acids. In the 109Cd and 65 Zn single existing system with humic acids, the stability...The radioactive isotope tracer and ion exchange balanced method was used to study the stability of 109Cd, 65 Zn complexes with humus acids. In the 109Cd and 65 Zn single existing system with humic acids, the stability constants of the humic-109Cd(65Zn) complex compound was higher than the fulvic-109 Cd(65Zn) complex compound. The stability constant of the humic (fulvic) -65Zn was higher than that of the humic (ful-vic)-109Cd. In the 109Cd and 65 Zn coexisting system, the stability constant and the co-ordination number of the humic (fulvic)-65Zn complex obviously increased, but the stability constant and the co-ordination number of the humic (fulvic)-109Cd complex obviously decreased as compared with its respectively single existing system . The result showed that the humus matter with higher molecular weight could more effectively reduce plant availability of heavy metals than that with lower molecular weight in polluted soil by heavy metals. The humus matter could more effectively reduce plant availability of Zn than that of Cd. Application of humus-acid increased the harm of Cd and decreased the harm of Zn to plants in Cd-Zn coexisting system.展开更多
A systematic study concerning the effects of a long-term stationary fertilization on content and property of soil humus in fluvo-aquic soil sampled from Malan Farm, Xinji City, Hebei, and arid red soil and paddy red s...A systematic study concerning the effects of a long-term stationary fertilization on content and property of soil humus in fluvo-aquic soil sampled from Malan Farm, Xinji City, Hebei, and arid red soil and paddy red soil sampled from the Institute of Red Soil, Jinxian County, Jiangxi was conducted. The results showed that long-term fertilization had effects not only on the content and composition of soil humus, but also on the physico-chemical property of humus. With applying organic manure or combined application of organic manure and chemical fertilizer, E4 and E6 values of humic acid decreased in fluvo-aquic soil and arid red soil, but increased in paddy red soil. In paddy red soil, E4 and E6 values of humic acid increased also with a single application of chemical fertilizer, but E4 and E6 values had less change of humic acid in fluvo-aquic soil and arid red soil. The effects on the visible spectroscopic property of f ulvic acid were different from that of humic acid. Long-term application of organic manure or combined application of organic manure and chemical fertilizer could increase E4 and E6 values of f ulvic acid in three types of soil. Single application of chemical fertilizer had less effect on the E4 and E6. Long-term fertilization could also influence the ultraviolet spectroscopic property of humus. With a single application of organic manure or combined application of organic manure and chemical fertilizer, the ultraviolet absorbance of humic acid and f ulvic acid increased in the three types of soil. But this effect was obvious only in short wave length, and the effect could decrease if the wave length increased. With a single application of chemical fertilizer the ultraviolet absorbance of fulvic acid could increase, but it of humic acid increased only in fluvo-aquic soil. Long-term application of organic manure or combined application of organic manure and chemical fertilizer could increase the content of total acidic groups, carboxy groups and phenolic hydroxy groups of humic acid and fuvic acid in the three types of soil. Single application of chemical fertilizer had less effect on the content of total acidic groups, carboxy groups and phenolic hydroxy groups of humic acid and fuvic acid in the three types of soil.展开更多
Calcium-bound and iron-and aluminium-bound humus extracted from different soils collected from north to south of China were characterized by chemical and spectroscopic methods. Meaningful differences in the compositio...Calcium-bound and iron-and aluminium-bound humus extracted from different soils collected from north to south of China were characterized by chemical and spectroscopic methods. Meaningful differences in the composition and structure between them were revealed by (13)C NMR, visible spectroscopy and elemental analysis. Results showed that the contents of carbon, hydrogen and nitrogen were higher in iron-and aluminium-bound humus than in calcium-bound humus while oxygen content in calcium-bound humus was shown to be higher. The calcium-bound humus had hasher C/N and O/C ratios than iron- and aluminumbound humus. The calcium-bound humic acid (HA1) showed higher E4/E6 ratios than iron- and aluminumbound humic acid (HA2) while iron- and aluminum-bound pulvic acid (FA2) showed higher E4/E6 ratios than calcium-bound fulvic acid (PA1). An inverse relationship between E4/E6 ratios and aromaticity as determined by (13)C NMR spectra was observed for HA and FA from black soil. The (13)C NMR spectroscopy revealed that HA2 was more aromatic than HA1. On the other hand, FA1 exhibited a higher aromaticitythan FA2.展开更多
Through this study, the humus produced in the breeding place of Universidad Autonoma de Occidente was thermally characterized. The humus was submitted to a heating program controlled by the Differential Scanning Calor...Through this study, the humus produced in the breeding place of Universidad Autonoma de Occidente was thermally characterized. The humus was submitted to a heating program controlled by the Differential Scanning Calorimetry (DSC) technique to characterize the type of transition, Thermogravimetry (TGA) to study the equilibrium of phasesand Mass Spectrometry (MS) coupled to TGA to identify detached elements in a temperature range. The temperature range used in this study was 30℃ ℃. The energy required for the water desorption in the humus has been found in this study. The humus showed a quick desorption between 30℃ ≤ TDesorption ≤ 110℃ at a heating rate of 10℃/min and presented decomposition around 250℃. Moreover, the kinetics of the desorption of the humus was studied to obtain the activation energy three TGA measures for three different heating rates. The average activation energy was about 26 kJ/Mol. This result was carried out to obtain an estimation of the desorption time of water in the range from room temperature to the decomposition temperature around 350℃.展开更多
The article presents the data of a long-term experience on the reproductive capacity of the soil during the permanent cultivation of cotton, which has been carried out for 96 years at the Institute of Breeding, Seed P...The article presents the data of a long-term experience on the reproductive capacity of the soil during the permanent cultivation of cotton, which has been carried out for 96 years at the Institute of Breeding, Seed Production and Agrotechnology for Growing Cotton in the Kibray district of the Tashkent region. The article presents the results of analyses by determining the content of humus, from which it can be seen that the decrease in humus was more marked on the control variant without fertilizers, and the amount of humus decreased after 20 years compared to the initial indicator by 11.4 t/ha, after 40 years 16 46 t/ha, after 60 years by 19.05 t/ha, after 80 years by 26.29 t/ha and after 96 years by 29.17 t/ha. It was also determined by the decrease in humus content in option 2, where NPK 250:175:125 kg/ha was applied annually, respectively: 6.487 t/ha;9.225 t/ha;10.09 t/ha;16.95 t/ha;19.65 t/ha;with an annual application of 30 t/ha of manure + 25 kg/ha of P<sub>2</sub>O in option 1, respectively: 0.335 t/ha;3.683 t/ha;11.40 t/ha;22.44 t/ha;32.58 t/ha. In addition, the article also provides data on the yield of cotton by options for permanent cultivation. It was determined that in the control variant, the yield decreased from 16.8 centners per hectare to 9.9 centners per hectare;in the variant where NPK was applied every year 250:175:125 kg/ha was 31 - 34 c/ha, where 30 t/ha of manure + 25 kg/ha P<sub>2</sub>O 29 - 32 c/ha were used every year.展开更多
In this paper predecessors′achievements about the division between subtropical zone and warm temperate zone on the south slope of Funiu Mountain are firstly summarized, and the cause why these viewpoints about the di...In this paper predecessors′achievements about the division between subtropical zone and warm temperate zone on the south slope of Funiu Mountain are firstly summarized, and the cause why these viewpoints about the division are different also has been presented. Seven soil profiles at different heights above sea level are dug along the south slope of Funiu Mountain. Many compositions and properties of soil humus have been analyzed in laboratory. A comprehensive study has been made about the division according to the compositions and properties of soil humus with mathematical method. During the analysis process eight indexes have been used, such as altitude, organic carbon, humic acid (HA), fulvic acid (FA), the ratio of humic acid and fulvic acid (HA/FA), two extinction coefficients (E4,E6), and their ratio (E4/E6).The result indicates that the boundary is at about 1000 meters above sea level.展开更多
[Objective] This study aimed to explore the effect of humus fertilizer from fermented branches on pH, total porosity, contents of organic matter, alkaline hy- drolysable nitrogen, available phosphorus, rapidly availab...[Objective] This study aimed to explore the effect of humus fertilizer from fermented branches on pH, total porosity, contents of organic matter, alkaline hy- drolysable nitrogen, available phosphorus, rapidly available potassium, the number of microorganisms and the activity of enzymes in the soil under Dracontomelon duper- reranum trees. [Method] Experiments were carried out to study the physical and chemical properties of soil under Dracontomelon duperreranum trees, and soil with- out any fertilizer treatment was used as control. [Result] The results showed that application of humus fertilizer from fermented branches raised the total porosity of soil, and improved the contents of soil organic matter, available phosphorus, rapidly available potassium, the number of soil microorganisms and the activity of soil en- zymes. In addition, the number of soil microorganisms was positively related to the activity of soil enzymes. [Conclusion] Application of humus fertilizer from fermented branches markedly raised the ratio of the number of bacteria to the number of fungi, and promoted the transformation of fungi-rich soil into bacteria-rich soil, which thus significantly enhanced the soil fertility and improved the soil environment under Dracontomelon duperreranum trees.展开更多
基金Foundation item:This paper was supported by Natural Science Foundation of Fujian Province (B0110025) and Foundation for University Key Teacher by the Ministry of Education.
文摘This study was conducted in Xinkou Experimental Forestry Farm of Fujian Agricultural and Forestry University, Sanming, Fujian Province in January 1999. Taking pure stand of Chinese fir as control, the authors measured and studied the content of organic carbon, content of humic acid (HA), ratio of HA to fulvic acid (FA), and the characteristics of infrared light spectrum and visible light spectrum of soil humus in the mixed forest of Chinese fir and Tsoong?tree. Compared to humus composition in the pure stand of Chinese fir, the content of soil organic C, HA content, and the E4 value of HA for different layers of soil, except for the ratio of HA to FA, showed a significant increase in the mixed forest, while the ratios of E4 to E6 had a little decrease. The infrared light spectrum of humic acid had an absorptive peak at 1650 cm-1. It is concluded that the levels of humification and aromaticity of soil humus are higher in the mixed forest, which is favorable for the improvement of soil structure and nutrient supply, thus improving the soil fertility to a certain degree.
文摘This paper deals with the development of a sequential extraction method to separate the Ca-bound and Fe-and Al-bound humus from soils.First,comparative analyses were carried out on dissolution of synthetic organo-mineral complexes by different extractants,i.e.0.1M Na4P2O7,0.1M NaOH+0.1M Na4P2O7 mixture,0.1M NaOH,0.5M (NaPO3)6 and 0.5M neutral Na2SO4.Among the five extractants,0.1M NaOH+0.1M Na4P2O7 mixture was the most efficient in extracting humus from various complexes.0.5M Na2SO4 had a better specificity to Ca than 0.5M (NaPO3)6,by only extracting Ca-bound humus without destorying Fe-and Al-bound organo-mineral complexes.Then sequential extractions first with 0.5M Na2SO4 and then with 0.1M NaOH+0.1M Na4P2O7 mixture were applied to a series of soil samples with different degrees of base saturation.The cations were dominated by Ca in the 0.5M Na2SO4 extract and by Al in the 0.1M NaOH+0.1M Na4P2O7 mixture.The sequential extraction method can efficiently separate or isolate Ca-bound and Fe-and Al-bound humus from each other.
基金Project supported by the National High Technology Research and Development Program of China (863 Program) (No. 2004AA246020) the National Natural Science Foundation for Distinguished Young Scholars, China(No. 20225722).
文摘The sorption-desorption behavior of dicyandiamide (DCD) is an importantchemical process that affects DCD fate and mobility in soils. Therefore, this study quantified DCDsorption-desorption on a phaeozem (Mollisol), a burozem (Alfisol), a soil with organicmatter-removed and peat humus using the batch-equilibration procedure, and identified soilproperties that influenced DCD sorption. The sorption on peat humus was higher than that on thephaeozem and the burozem, with much lower sorption observed on the soil with organic matter-removed,indicating that soil organic matter was the main carrier of DCD sorption. Due to its amphipathicproperty the DCD molecule sorption on the phaeozem and the burozem decreased as pH increased fromabout 2 to 5, but a further increase in pH led to a rise in DCD sorption. The DCD desorptionhysteretic effect for peat humus was greater than that for the phaeozem and the burozem using 0.01mol L^(-1) CaCl_2 as the background electrolyte, suggesting that the hydrophobic domains of organicmatter may play an important role in DCD sorption.
基金supported by Government Order of the Ministry of Education and Science of the Republic of Kazakhstan (0106 RK)
文摘The organic carbon and humus content in oil polluted brown and grey-brown soils in Mangyshlak,Pre-Caspian Sea Region,was analyzed from 2000 to 2008.The results indicated that bitumen substances from crude oil pollution deteriorated the soil property,however,the organic carbon content increased significantly.The products of oil pollution changed the composition of car-bonaceous substances which formed soil humus,and changed the ratios of the humus components.Residual insoluble carbon increased with the rise of oil organic carbon.The mobility of humus components was significantly increased because of the high oxidation-reduction process in the topsoil,and the humus content and microorganism activity increased.The organic carbon content increased significantly,while it decreased with the distance away from the oil well.The rearrangement of physical,physical-chemical and chemical properties of the polluted soils was significant.
文摘14C-tracer technique and closed incubation method were used to study straw 14C decomposition and distribution in different fractions of newly formed humus under different moisture regimes. Decomposition of straw 14C was faster during the initial days, and slower thereafter. Decay rate constants of straw 14C varied from 3.29x10-3 d-1 to 7.06x10-3 d-1. After 112 d incubation, the amount of straw 14C mineralized was 1.17~1.46 times greater in submerged soils than in upland soils. of the soil residual 14C, 9.08%~15.73%was present in humic acid (HA) and 31.01%~37.62% in fulvic acid (FA). Submerged condition favored the formation of HA, and HA/FA ratio of newly formed humus (labelled) was greater in submerged soils than in upland soils. Clay minerals affected the distribution of straw 14C in different humus fractions. Proportion of 14C present in HA to 14C remaining in soil was greater in Vertisol than in Ultisol.
基金Project (No. 970601) supported by the State Education Commission, China.
文摘Effects of humus fractions (fulvic acid, brown humic acid and grey humic acid) on the leachability and transferring activity of five types of mineral-bound Hg were investigated. Under the acid leaching condition: fulvic acid could promote leachability and vertical transference of all the mineral-bound Hg. Brown humic acid could retard the leaching and transferring processes of CaCO3-Hg, Fe2O3-Hg, MnO2-Hg and kaolinite Hg but not bentonite-Hg. Grey humic acid could greatly enhance residing ability of the mineral-bound Hg in the soil column and restrain them from vertical transferring. The effect of humus on leachability and transferring activity on the mineral-bound Hg was closely related to its ability to convert the mineral-bound Hg into organic-bound form and the transferability of the latter in the soil column. The characteristics of the mineral-bound Hg in speciation were the internal factors that determined the extent and rate of the influence of the humus.
文摘In this paper, author will report on the process of rice cultivation in paddy fields using treated water which treated domestic sewage wastewater. Odor problems from sewage treatment plants have been solved by confinement and ventilation, but reducing the color and odor of treated water is economically difficult and is a subject of recycling of discharged water. Humus pellet bioreactors can be attached to existing sewage treatment plants to suppress the odor of the sewage treatment plants as a whole and to prevent sludge from deteriorating and to improve the quality of treated water. The odor and color of the treated water discharged from the sewage treatment plant was reduced. In addition, we were able to obtain performance of treated water with nitrogen 3 mg/L, phosphorus 1 mg/L or less throughout the year. On the other hand, there are many cases of results that cannot be used for paddy rice cultivation and vegetable production etc. by ignoring plant growth and physiology (fertilizer). For that reason, laws and guidance such as having to dilute more than 50 times in order to use processed water for agriculture are being conducted without learning. It is a case of using humus pellets in sewage treatment system and using deodorized wastewater of sewage by adjusting fertilizer when used in paddy field rice production.
基金supported by the National Natural Science Foundation of China(49971049).
文摘The radioactive isotope tracer and ion exchange balanced method was used to study the stability of 109Cd, 65 Zn complexes with humus acids. In the 109Cd and 65 Zn single existing system with humic acids, the stability constants of the humic-109Cd(65Zn) complex compound was higher than the fulvic-109 Cd(65Zn) complex compound. The stability constant of the humic (fulvic) -65Zn was higher than that of the humic (ful-vic)-109Cd. In the 109Cd and 65 Zn coexisting system, the stability constant and the co-ordination number of the humic (fulvic)-65Zn complex obviously increased, but the stability constant and the co-ordination number of the humic (fulvic)-109Cd complex obviously decreased as compared with its respectively single existing system . The result showed that the humus matter with higher molecular weight could more effectively reduce plant availability of heavy metals than that with lower molecular weight in polluted soil by heavy metals. The humus matter could more effectively reduce plant availability of Zn than that of Cd. Application of humus-acid increased the harm of Cd and decreased the harm of Zn to plants in Cd-Zn coexisting system.
文摘A systematic study concerning the effects of a long-term stationary fertilization on content and property of soil humus in fluvo-aquic soil sampled from Malan Farm, Xinji City, Hebei, and arid red soil and paddy red soil sampled from the Institute of Red Soil, Jinxian County, Jiangxi was conducted. The results showed that long-term fertilization had effects not only on the content and composition of soil humus, but also on the physico-chemical property of humus. With applying organic manure or combined application of organic manure and chemical fertilizer, E4 and E6 values of humic acid decreased in fluvo-aquic soil and arid red soil, but increased in paddy red soil. In paddy red soil, E4 and E6 values of humic acid increased also with a single application of chemical fertilizer, but E4 and E6 values had less change of humic acid in fluvo-aquic soil and arid red soil. The effects on the visible spectroscopic property of f ulvic acid were different from that of humic acid. Long-term application of organic manure or combined application of organic manure and chemical fertilizer could increase E4 and E6 values of f ulvic acid in three types of soil. Single application of chemical fertilizer had less effect on the E4 and E6. Long-term fertilization could also influence the ultraviolet spectroscopic property of humus. With a single application of organic manure or combined application of organic manure and chemical fertilizer, the ultraviolet absorbance of humic acid and f ulvic acid increased in the three types of soil. But this effect was obvious only in short wave length, and the effect could decrease if the wave length increased. With a single application of chemical fertilizer the ultraviolet absorbance of fulvic acid could increase, but it of humic acid increased only in fluvo-aquic soil. Long-term application of organic manure or combined application of organic manure and chemical fertilizer could increase the content of total acidic groups, carboxy groups and phenolic hydroxy groups of humic acid and fuvic acid in the three types of soil. Single application of chemical fertilizer had less effect on the content of total acidic groups, carboxy groups and phenolic hydroxy groups of humic acid and fuvic acid in the three types of soil.
文摘Calcium-bound and iron-and aluminium-bound humus extracted from different soils collected from north to south of China were characterized by chemical and spectroscopic methods. Meaningful differences in the composition and structure between them were revealed by (13)C NMR, visible spectroscopy and elemental analysis. Results showed that the contents of carbon, hydrogen and nitrogen were higher in iron-and aluminium-bound humus than in calcium-bound humus while oxygen content in calcium-bound humus was shown to be higher. The calcium-bound humus had hasher C/N and O/C ratios than iron- and aluminumbound humus. The calcium-bound humic acid (HA1) showed higher E4/E6 ratios than iron- and aluminumbound humic acid (HA2) while iron- and aluminum-bound pulvic acid (FA2) showed higher E4/E6 ratios than calcium-bound fulvic acid (PA1). An inverse relationship between E4/E6 ratios and aromaticity as determined by (13)C NMR spectra was observed for HA and FA from black soil. The (13)C NMR spectroscopy revealed that HA2 was more aromatic than HA1. On the other hand, FA1 exhibited a higher aromaticitythan FA2.
文摘Through this study, the humus produced in the breeding place of Universidad Autonoma de Occidente was thermally characterized. The humus was submitted to a heating program controlled by the Differential Scanning Calorimetry (DSC) technique to characterize the type of transition, Thermogravimetry (TGA) to study the equilibrium of phasesand Mass Spectrometry (MS) coupled to TGA to identify detached elements in a temperature range. The temperature range used in this study was 30℃ ℃. The energy required for the water desorption in the humus has been found in this study. The humus showed a quick desorption between 30℃ ≤ TDesorption ≤ 110℃ at a heating rate of 10℃/min and presented decomposition around 250℃. Moreover, the kinetics of the desorption of the humus was studied to obtain the activation energy three TGA measures for three different heating rates. The average activation energy was about 26 kJ/Mol. This result was carried out to obtain an estimation of the desorption time of water in the range from room temperature to the decomposition temperature around 350℃.
文摘The article presents the data of a long-term experience on the reproductive capacity of the soil during the permanent cultivation of cotton, which has been carried out for 96 years at the Institute of Breeding, Seed Production and Agrotechnology for Growing Cotton in the Kibray district of the Tashkent region. The article presents the results of analyses by determining the content of humus, from which it can be seen that the decrease in humus was more marked on the control variant without fertilizers, and the amount of humus decreased after 20 years compared to the initial indicator by 11.4 t/ha, after 40 years 16 46 t/ha, after 60 years by 19.05 t/ha, after 80 years by 26.29 t/ha and after 96 years by 29.17 t/ha. It was also determined by the decrease in humus content in option 2, where NPK 250:175:125 kg/ha was applied annually, respectively: 6.487 t/ha;9.225 t/ha;10.09 t/ha;16.95 t/ha;19.65 t/ha;with an annual application of 30 t/ha of manure + 25 kg/ha of P<sub>2</sub>O in option 1, respectively: 0.335 t/ha;3.683 t/ha;11.40 t/ha;22.44 t/ha;32.58 t/ha. In addition, the article also provides data on the yield of cotton by options for permanent cultivation. It was determined that in the control variant, the yield decreased from 16.8 centners per hectare to 9.9 centners per hectare;in the variant where NPK was applied every year 250:175:125 kg/ha was 31 - 34 c/ha, where 30 t/ha of manure + 25 kg/ha P<sub>2</sub>O 29 - 32 c/ha were used every year.
文摘In this paper predecessors′achievements about the division between subtropical zone and warm temperate zone on the south slope of Funiu Mountain are firstly summarized, and the cause why these viewpoints about the division are different also has been presented. Seven soil profiles at different heights above sea level are dug along the south slope of Funiu Mountain. Many compositions and properties of soil humus have been analyzed in laboratory. A comprehensive study has been made about the division according to the compositions and properties of soil humus with mathematical method. During the analysis process eight indexes have been used, such as altitude, organic carbon, humic acid (HA), fulvic acid (FA), the ratio of humic acid and fulvic acid (HA/FA), two extinction coefficients (E4,E6), and their ratio (E4/E6).The result indicates that the boundary is at about 1000 meters above sea level.
文摘[Objective] This study aimed to explore the effect of humus fertilizer from fermented branches on pH, total porosity, contents of organic matter, alkaline hy- drolysable nitrogen, available phosphorus, rapidly available potassium, the number of microorganisms and the activity of enzymes in the soil under Dracontomelon duper- reranum trees. [Method] Experiments were carried out to study the physical and chemical properties of soil under Dracontomelon duperreranum trees, and soil with- out any fertilizer treatment was used as control. [Result] The results showed that application of humus fertilizer from fermented branches raised the total porosity of soil, and improved the contents of soil organic matter, available phosphorus, rapidly available potassium, the number of soil microorganisms and the activity of soil en- zymes. In addition, the number of soil microorganisms was positively related to the activity of soil enzymes. [Conclusion] Application of humus fertilizer from fermented branches markedly raised the ratio of the number of bacteria to the number of fungi, and promoted the transformation of fungi-rich soil into bacteria-rich soil, which thus significantly enhanced the soil fertility and improved the soil environment under Dracontomelon duperreranum trees.