Experimental Study on Corrosion of Stainless Steel in Low Temperature Multi effect Seawater Desalination

Starting from the corrosion mechanism,this paper analyzes the characteristics of various types of stainless steel and selects the best performance composite plate composite plate stainless steel.Analyze and select the most suitable corrosion detection method based on specific practical multi working conditions,discuss the interference factors that affect metal corrosion during experimental simulation,and the advantages of newly developed sheet metal.The new development of composite board panels,with the substrate and composite materials applying their respective capabilities for MED,will bring breakthrough progress to the scientific research and engineering applica-tion of composite boards.

Effect of Annealing on Fly-Line Microstructure and Properties of Explosively Composited Stainless Steel-Stainless Steel Plates

Effect of annealing on "fly-line"(adiabatic sheer line) microstructure and properties of explosively composited stainless steel-stainless steel plates was studied.Results show that the flyline microstructure will diminish through certain annealing process,while the cracks formed from fly-line microstructure will remain.Therefore,fly-line microstructure can be considered as a plastic deformation microstructure and crack source s meanwhile its formation is considered as a special plastic deformation mechanism of metal under explosive load.

Influence of Non-smooth Surface on Tribological Properties of Glass Fiber-epoxy Resin Composite Sliding against Stainless Steel under Natural Seawater Lubrication

With the development of bionics, the bionic non-smooth surfaces are introduced to the field of tribology. Although non-smooth surface has been studied widely, the studies of non-smooth surface under the natural seawater lubrication are still very fewer, especially experimental research. The influences of smooth and non-smooth surface on the frictional properties of the glass fiber-epoxy resin composite（GF/EPR） coupled with stainless steel 316 L are investigated under natural seawater lubrication in this paper. The tested non-smooth surfaces include the surfaces with semi-spherical pits, the conical pits, the cone-cylinder combined pits, the cylindrical pits and through holes. The friction and wear tests are performed using a ring-on-disc test rig under 60 N load and 1000 r/min rotational speed. The tests results show that GF/EPR with bionic non-smooth surface has quite lower friction coefficient and better wear resistance than GF/EPR with smooth surface without pits. The average friction coefficient of GF/EPR with semi-spherical pits is 0.088, which shows the largest reduction is approximately 63.18% of GF/EPR with smooth surface. In addition, the wear debris on the worn surfaces of GF/EPR are observed by a confocal scanning laser microscope. It is shown that the primary wear mechanism is the abrasive wear. The research results provide some design parameters for non-smooth surface, and the experiment results can serve as a beneficial supplement to non-smooth surface study.

TiC-Maraging stainless steel composite:microstructure, mechanical and wear properties

Particulate TiC reinforced 17-4PH and 465 maraging stainless steel matrix composites were processed by conventional powder metallurgy （P/M）. TiC-maraging stainless steel composites with theoretical density 〉97% were produced using conventional P/M. The microstructure, and mechanical and wear properties of the composites were evaluated. The microstructure of the composites consisted of （core-rim structure） spherical and semi-spherical TiC particles depending on the wettability of the matrix with TiC particles. In TiC-maraging stainless steel composites, 465 stainless steel binder phase showed good wettability with TiC particles. Some microcracks appeared in the composites, indicating the presence of tensile stresses in the composites produced during sintering. The typical properties, hardness, and bend strength were reported for the composites. After heat treatment and aging, an increase in hardness was observed. The increase in hardness was at- tributed to the aging reaction in maraging stainless steel. The specific wear behavior of the composites strongly depends on the content of TiC particles and their interparticle spacing, and on the heat treatment of the maraging stainless steel.

Beneficial use of stainless steel EAF slag as composite cement admixture and its heavy metals leaching risk analysis

This study analyzes the feasibility of using stainless steel electric arc furnace （EAF） slag as composite cement admixture and the risk of leaching-out of heavy metals. The results show that the stainless steel EAF slag, mainly made up of Ca2 SiO4, Ca3 Mg （ SiO4 ） 2, some Cr-containing minerals and in small particle size, is easily ground and has cementitious activity. EAF slag, when used as cement admixture, can be added with a maximum percentage of 32%. It can meet the strength requirements of the standard P · C 32.5 cement. When the mixing percentage is decreased to 25 % , the strength of the cement can be increased to that of P · C 42.5 cement. Other main quality indexes of composite cement, such as the setting time and stability, also satisfy standard requirements. The results also show that most of the heavy metals in the stainless steel EAF slag exist in a stable speciation. The concentration of heavy metals that leach out from the stainless steel EAF slag and the composite cement products is far lower than the standard limit of hazardous wastes. The main heavy metal, chromium, exists as less hazardous trivalent chromium. Therefore, the risk of heavy metals leaching out from the stainless steel EAF slag is low. The internal exposure index （IRa） and the external exposure index （Iγ） of the stainless steel EAF slag are both lower than 1.0, satisfying the standard requirements of the state for the radionuclides of building materials. Therefore, stainless steel EAF slag can be safely used as admixture to produce composite cement.

Structure and sliding wear behavior of 321 stainless steel/Al composite coating deposited by high velocity arc spraying technique

A typical 321 stainless steel/aluminum composite coating (321/Al coating) was prepared by high velocity arc spraying technique (HVAS) with 321 stainless steel wire as the anode and aluminum wire as the cathode. The traditional 321 stainless steel coating was also prepared for comparison. Tribological properties of the coatings were evaluated with the ring-block wear tester under different conditions. The structure and worn surface of the coatings were analyzed by scanning electron microscopy(SEM), X-ray diffractometry(XRD) and energy dispersion spectroscopy(EDS). The results show that, except for aluminum phase addition in the 321/Al coating, no other phases are created compared with the 321 coating. However, due to the addition of aluminum, the 321/Al coating forms a type of "ductile/hard phases inter-deposited" structure and performs quite different tribological behavior. Under the dry sliding condition, the anti-wear property of 321/Al coating is about 42% lower than that of 321 coating. But under the oil lubricated conditions with or without 32 h oil-dipping pretreatment, the anti-wear property of 321/Al coating is about 9% and 5% higher than that of 321 coating, respectively. The anti-wear mechanism of the composite coating is mainly relevant to the decrease of oxide impurities and the strengthening action resulted from the "ductile/hard phases inter-deposited" coating structure.

CYCLIC OXIDATION OF Ni-La_2O_3 COMPOSITE COATINGS ELECTRODEPOSITED ON NICKEL AND Fe26Cr STAINLESS STEEL

ＣＹＣＬＩＣＯＸＩＤＡＴＩＯＮＯＦＮｉＬａ２Ｏ３ＣＯＭＰＯＳＩＴＥＣＯＡＴＩＮＧＳＥＬＥＣＴＲＯＤＥＰＯＳＩＴＥＤＯＮＮＩＣＫＥＬＡＮＤＦｅ２６ＣｒＳＴＡＩＮＬＥＳＳＳＴＥＥＬ①ＰｅｎｇＸｉａｏ１，２，ＬｉＴｉｅｆａｎ１，２，ＷｕＷｅｉｔａｏ１Ｓｔ...

Investigation of Sintering Technology for Composite of Stainless Steel and Partially Stabilized Zirconia

The sintering technology for mixed powdered extrusion rods of different proportions of stainless steel to magnesia partially stabilized zirconia (PSZ) was investigated. The effects of some sintering parameters including holding time, atmosphere and protective gas pressure on shrinkage, relative density, microstructure, micro-Vickers hardness and compression strength of sintered samples were mainly researched. The experimental results are as follows: (1) The shrinkage and the relative density of the sintered samples decrease as increasing stainless steel content in the composite, except for the case containing 90 percent of stainless steel; (2) The porosity in PSZ matrix rises as increasing the stainless steel content in the composite; (3) Longer sintering holding time, higher sintering vacuum and gas-pressure sintering process not only enhance the relative density, but also improve microstructure of composite; (4) Micro-Vickers hardness of PSZ matrix decreases as increasing stainless steel content, while that of stainless steel particles in sintered samples varies unnoticeably.

Oxidation Behavior of Fe26Cr1Mo Stainless Steel in the Presence of Ni-La_2O_3 Electrodeposited Composite Film

The oxidation behaviors of Fe26Cr1Mo with and without the Ni La 2O 3 electrodeposited composite film have been investigated by thermogravimetric analysis (TGA) and a scanning electron microscope equipped with an energy dispersive analytical X ray system(SEM/EDAX). The experimental results show that the oxide scale growing on Fe26Cr1Mo exposed at 900 ℃ spalled severely during cooling, while after the stainless steel was coated with the Ni La 2O 3 electrodeposited composite film, its high temperature cyclic oxidation resistance was significantly improved. The reason is that a La 2O 3 modified NiO scale, which has a superior adhesion to the substrate, was formed on the Fe26Cr1Mo stainless steel coated with Ni La 2O 3 composite film.

Pulsed TIG welding-brazing butt joints of aluminum-stainless steel thin plates with different fillers

Aluminum and stainless steel plates with 1.5 mm thickness are joined by pulsed TIG welding-brazing process with ER1100, ER4043 and ER2319 fillers, separately. Good weld formation can be obtained by adjusting appropriate pulse parameters. The effects of the fillers on that the thickness of the intermetallic compound （ IMC ） and tensile strength of the joints are investigated. SEM results indicate layer with ER2319 filler is about 2 ~m, which is thinner than 2. 5 p^m of ER1100 filler and 3.5 txm of ER4043 filler. Moreover, the element distribution in both IMCs and welded seams with three fillers are different because of the different compositions of fillers. The results of mechanical property tests suggest that the joint strength with ER2319 filler is the highest, while the joint impact energy is the lowest. The joint with ERllOO filler exhibits the best comprehensive mechanical pet.formanee.

Microstructure and properties of composite of stainless steel and partially stabilized zirconia

To fabricate the metal-ceramics multi-layer hollow functionally gradient materials(FGMs) that might meet the requirement of repeated service and long working time of high temperature burners, such as spacecraft engine, the microstructure and properties of composite of stainless steel and partially stabilized zirconia were investigated. Samples of different proportions of stainless steel to partially yttria-stabilized zirconia were fabricated by powder extrusion and sintering method. Shrinkage, relative density, microstructure, micro-Vickers hardness, compression strength, bending strength, fractography morphology and electrical resistivity of sintered samples with different proportions of stainless steel were measured. The results show that threshold of metallic matrix composite(MMC) is approximately equal to 60%(volume fraction) stainless steel. The samples with 0 to 50%(volume fraction) stainless steel indicate ceramic brittleness and non-cutability, and the samples with 70% to 100%(volume fraction) stainless steel indicate metallic plasticity and cutability.

Ti/(Ti,Cr)N/CrN multilayer coated 316L stainless steel by arc ion plating as bipolar plates for proton exchange membrane fuel cells

Arc ion plating (AIP) is applied to form Ti/(Ti,Cr)N/CrN multilayer coating on the surface of 316L stainless steel (SS316L) as bipolar plates for proton exchange membrane fuel cells (PEMFCs). The characterizations of the coating are analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). Interfacial contact resistance (ICR) between the coated sample and carbon paper is 4.9 m Omega cm(2) under 150 N/cm(2), which is much lower than that of the SS316L substrate. Potentiodynamic and potentiostatic tests are performed in the simulated PEMFC working conditions to investigate the corrosion behaviors of the coated sample. Superior anticorrosion performance is observed for the coated sample, whose corrosion current density is 0.12 mu A/cm(2). Surface morphology results after corrosion tests indicate that the substrate is well protected by the multilayer coating. Performances of the single cell with the multilayer coated SS316L bipolar plate are improved significantly compared with that of the cell with the uncoated SS316L bipolar plate, presenting a great potential for PEMFC application. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.

Process and challenges of stainless steel based bipolar plates for proton exchange membrane fuel cells

Proton exchange membrane fuel cell(PEMFC)powered automobiles have been recognized to be the ultimate solution to replace traditional fuel automobiles because of their advantages of PEMFCs such as no pollution,low temperature start-up,high energy density,and low noise.As one of the core components,the bipolar plates(BPs)play an important role in the PEMFC stack.Traditional graphite BPs and composite BPs have been criticized for their shortcomings such as low strength,high brittleness,and high processing cost.In contrast,stainless steel BPs(SSBPs)have recently attracted much attention of domestic and foreign researchers because of their excellent comprehensive performance,low cost,and diverse options for automobile applications.However,the SSBPs are prone to corrosion and passivation in the PEMFC working environment,which lead to reduced output power or premature failure.This review is aimed to summarize the corrosion and passivation mechanisms,characterizations and evaluation,and the surface modification technologies in the current SSBPs research.The non-coating and coating technical routes of SSBPs are demonstrated,such as substrate component regulation,thermal nitriding,electroplating,ion plating,chemical vapor deposition,and physical vapor deposition,etc.Alternative coating materials for SSBPs are metal coatings,metal nitride coatings,conductive polymer coatings,and polymer/carbon coatings,etc.Both the surface modification technologies can solve the corrosion resistance problem of stainless steel without affecting the contact resistance,however still facing restraints such as long-time stability,feasibility of low-cost,and mass production process.This paper is believed to enrich the knowledge of high-performance and long-life BPs applied for PEMFC automobiles.

Microstructure,strength and welding window of aluminum alloy-stainless steel explosive cladding with different interlayers

Aluminum 5052(Al 5052)-stainless steel 316(SS 316)plates were explosively cladded with Al 1100,pure copper and SS 304 interlayers.The operational parameters viz.,standoff distance,explosive mass ratio(mass ratio of the explosive to the flyer plate)and inclination angle were varied and the results were presented.The advent of interlayer relocates the lower boundary of the welding window,and enhances the welding regime by 40%.A triaxial welding window,considering the influence of the third operational parameter,was developed as well.Use of interlayer transforms the continuous molten layer formed in the traditional Al 5052-SS 316 explosive clad interfaces into a smooth interface devoid or with a slender presence of intermetallic compounds.The microhardness,ram tensile and shear strengths of the interlayered clads are higher than those of the traditional explosive clads,and the maximum values are witnessed for stainless steel interlaced Al 5052-SS 316 explosive clads.

Improving pulsed laser weldability of duplex stainless steel to 5456 aluminum alloy via friction stir process reinforcing of aluminum by BNi-2 brazing alloy

Effects of laser pulse distance and reinforcing of 5456 aluminum alloy were investigated on laser weldability of Al alloy to duplex stainless steel (DSS) plates. The aluminum alloy plate was reinforced by nickel-base BNi-2 brazing powder via friction stir processing. The DSS plates were laser welded to the Al5456/BNi-2 composite and also to the Al5456 alloy plates. The welding zones were studied by scanning electron microscopy, X-ray diffractometry, micro-hardness and shear tests. The weld interface layer became thinner from 23 to 5 μm, as the laser pulse distance was increased from 0.2 to 0.5 mm. Reinforcing of the Al alloy modified the phases at interface layer from Al-Fe intermetallic compounds (IMCs) in the DSS/Al alloy weld, to Al-Ni-Fe IMCs in the DSS/Al composite one, since more nickel was injected in the weld pool by BNi-2 reinforcements. This led to a remarkable reduction in crack tendency of the welds and decreased the hardness of the interface layer from ~950 HV to ~600 HV. Shear strengths of the DSS/Al composite welds were significantly increased by ~150%, from 46 to 114 MPa, in comparison to the DSS/Al alloy ones.

Electrochemical Behavior of Niobium Electrodeposited 316 Stainless Steel Bipolar Plate for PEMFC in Choline Chloride Based Ionic Liquids

Niobium was electrodeposited on 316 stainless steel bipolar plates of a fuel cell in water and air-stable choline chloride based ionic liquids. The electrochemical corruption property of bipolar plates in simulated PEMFC environment was investigated. It was showed that the plating film was distributed on the surface of 316 stainless steel like isolated islands with height less than 50 nm. The XPS, XRD results showed that a smooth and strong chemical inert film of Nb O and Nb2O5 was formed on the surface of 316 stainless steel. In simulated cathodic condition, the corrosion potential of Nb coated stainless steel was improved by 244 m V, whilst in an anodic condition, it was improved by 105 m V. The current densities for the coated 316 stainless steel were decreased to 2.479 4 μA·cm-2 from 14.810 μA·cm-2 at-0.1 V and to 0.576 μA·cm-2 from 13.417 μA/·cm-2 at 0.6 V, respectively. It was implied that the niobium coating effectively decreased the corrosion rate. The results of the electrochemical tests indicated that the corrosion resistance of stainless steel was greatly improved after coated with niobium.

Effects of Ni on microstructure and properties of aluminum- stainless steel TIG welding-brazing joint with AI-Si filler

Effects of Ni on microstructure and properties of aluminum-stainless steel TIG welding-brazing joint with Al-Si filler were studied. Different mass percentage of Ni powder was added in the flux separately. Results of tensile tests show that a significant improvement on mechanical properties of the butt joint is obtained using the modified flux. Moreover, obvious differences on microstructures of the interfaces were observed with Ni addition, that two intermetallic compound （IMC） layers at the interface change to one layer and the IMC thickness also decreases. Finally, effect mechanism of Ni was analyzed and discussed. Ni addition leads to an enrichment of element Si at the brazing interface, and furthermore suppresses the formation of intermetaUic compound. The reduction of IMC thickness is the main reason for the improvement of joint properties.

INFLUENCE OF PHASE COMPOSITION ON PITTING CORROSION RESISTANCE OF SPUTTERED COATING OF 1Cr18Ni9Ti STAINLESS STEEL

A series of single bcc,bcc plus fcc duplex and single fcc microcrystalline coatings of 1Cr18Ni9Ti stainless steel were prepared by using sputtering technique.The resistance against pitting corrosion was studied by measurements of pitting corrosion potentials and electrochemical noise during initiation of corrosion pits.The results show that the sputtered coatings with single bcc phase or single fcc structure are more resistant to pitting corrosion than those with bcc plus fcc duplex phase structure.

Experimental study on dissimilar TIG welding-brazing of 5A06 aluminum alloy to SUS321 stainless steel

Dissimilar metals TIG welding-brazing of 5A06 aluminum alloy to SUS321 stainless steel has been carried out with Al-Sil2 eutectic filler metal and modified non-corrosive flux. The surface appearance and microstructures of the joint were analyzed and the average tensile strength of the joint was estimated. The results show that a sound dissimilar metals joint is obtained by TIG welding-brazing. Slag and residual flux on steel surface can be removed by sanding easily. The joint has dual characteristics： in aluminum alloy side, it is a welded joint, while in stainless steel side, it is a brazed joint. The whole interface layer, unequal in thickness at different position, ranges from 5 μm to 25 μm. The average tensile strength of the butt joint reaches 120 MPa and the fracture occurs at the interface layer.

Composition and corrosion resistance of palladium film on 316L stainless steel by brush plating

Palladium films with good adhesive strength were deposited on 316L stainless steel by brush plating. Scanning electronic microscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy （XPS）, mass loss tests and electrochemical methods were used to study the properties of the films. The brush plated palladium film mainly consisted of palladium. XPS analysis indicated that palladium was present in the films as metal state. The palladium plated stainless steel samples showed excellent corrosion resistance in boiling 20% H2SO4 solution and boiling acetic/formic acids with 0.005 mol/L Br- ions added. The corrosion rates of the palladium plated 316L stainless steel samples were about two orders of magnitude lower than those of the original 316L stainless steel samples. This method provides a possibility to prepare protective palladium films on stainless steel facilities with large areas in industrial sites.