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THE ADHESIVE CAPACITY OF STARCH GRAFT COPOLYMERS TO POLYESTER/COTTON FIBER 被引量:10
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作者 祝志峰 周永元 +1 位作者 张文赓 欧石燕 《Journal of China Textile University(English Edition)》 EI CAS 1995年第1期28-35,共8页
The advantages of using starch graft copolymers as warp sizes in textile were briefly discussed, and the factors of affecting adhesive capacity to the fiber were analysed. By using eerie ammonium nitrate as an initiat... The advantages of using starch graft copolymers as warp sizes in textile were briefly discussed, and the factors of affecting adhesive capacity to the fiber were analysed. By using eerie ammonium nitrate as an initiator under nitrogen atomosphere, a number of vinyl and/or acrylic monomers such as acrylic acid, acrylamide, methyl acrylate, ethyl acrylate, butyl acrylate, hydroxyethyl acrylate, methyl methacrylate, butyl methacrylate, vinyl acetate and the combinations among them were graft copolymerized respectively onto granular corn starch in aqueous dispersion. The adhesive capacity of these starch graft copolymers to polyester/cotton fibers was evaluated by a slightly sized rovings according to V. K. Aggarwal’s method which measures the breaking strength and elongation of the rovings impregnated with the size paste. The influences of the monomers and their combinations, the grafting technological processes and the pretreatment methods before graft copolymerization upon adhesive capacity have been 展开更多
关键词 starch mordified starch size graft COPOLYMERIZATION ADHESIVE Capacity
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Starch Grafted Water Resistant Polyvinyl Acetate-Based Wood Adhesive: A Review 被引量:1
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作者 Ravindra Vilas Indubai Gadhave 《Open Journal of Organic Polymer Materials》 CAS 2022年第2期17-30,共14页
Global energy issues and the reliance on hydrocarbon resources have resulted in the reduction of petroleum sources, and the focus of the chemical industries has shifted to substitute raw material sources. The major ra... Global energy issues and the reliance on hydrocarbon resources have resulted in the reduction of petroleum sources, and the focus of the chemical industries has shifted to substitute raw material sources. The major raw materials used in wood adhesives, such as hydrocarbons like polyvinyl acetate, would be gradually replaced by renewable natural polymers. Currently, polyvinyl alcohol has the limitation of petroleum origin, which is non-economical and it will be replaced by biopolymers. Conventionally available wood adhesive emulsions are colloid-like polyvinyl alcohol stabilized. Starch, being a naturally available polymer, has gained interest from researchers for replacing polyvinyl alcohol as a stabilizer. New research on sustainable, economical, biodegradable, renewable, and environmentally friendly starch grafted polyvinyl acetate emulsion that was synthesized by the graft polymerization of vinyl acetate monomer onto starch. However, starch grafted polyvinyl acetate emulsion-based adhesive’s properties, such as poor water resistance, weak adhesion, delayed drying rate and delayed setting speed, have resulted in limitations in its application as a wood adhesive. A detailed review of starch grafting on vinyl acetate and comonomers like acrylamides, and acrylic acid, and the addition of nano-fillers to enhance the water resistance and performance properties of sustainable adhesives has been explained. 展开更多
关键词 starch Water Resistance graftING Polyvinyl Acetate N-Methylol Acrylamide
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Influence of Reaction Parameters on Water Absorbency of Starch Grafted Superabsorbents
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作者 李明达 周永元 《Journal of Donghua University(English Edition)》 EI CAS 2002年第2期91-94,共4页
Superabsorbents starch grafted sodium polyacrylate was synthesized by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of reaction parameters,... Superabsorbents starch grafted sodium polyacrylate was synthesized by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of reaction parameters, such as starch pretreatment temperature, neutralization degree of monomer, reaction time and temperature, concentration of initiator, molar ratio of monomer and starch, on water absorbency of the starch grafted polymer was studied. The effects of the last two parameters were investigated by uniform design method, and the prediction equation was obtained. 展开更多
关键词 starch grafted sodium polyacrylate SUPERABSORBENT polymer water absorbency UNIFORM design method
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Research on the Sizing Performance of Starch Grafted Poly-hydroxy Alkyl-acid Esters
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作者 郭腊梅 郭良红 《Journal of Donghua University(English Edition)》 EI CAS 2010年第3期316-320,共5页
Starch grafted poly-hydroxy alkyl-acid esters were prepared via graft polymerization.Different characteristics of grafted starches were tested such as viscosity,viscosity stability,adhesion as well as properties of si... Starch grafted poly-hydroxy alkyl-acid esters were prepared via graft polymerization.Different characteristics of grafted starches were tested such as viscosity,viscosity stability,adhesion as well as properties of sized yarns.Sizing performance was analyzed from the aspect of physical and chemical reactions between polymer molecules.It shows that starch grafted poly-hydroxy alkyl-acid esters have excellent sizing performance and could absolutely be used as sizes for polyester-cotton yarns. 展开更多
关键词 grafted 淀粉 hydroxy alkly 酸酉旨 缩放代理人 polylactide (PLA ) 哲学学士
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STUDY ON THE STARCH GRAFTED ACRYLATE MONOMERS AND ITS COMPATIBILITY FOR THE BLEND SYSTEM OF STARCH AND POLYETHYLENE
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作者 于九皋 李新蕊 《Transactions of Tianjin University》 EI CAS 1997年第1期56-61,共6页
研究采用高温和剪切力的作用直接引发淀粉与丙烯酸酯单体的接枝共聚合反应.讨论了各种反应条件对接枝反应的影响,并进一步研究了接枝物在淀粉聚乙烯共混体系中的增容作用.实验结果表明,高温和剪切作用力可以引发淀粉与丙烯酸酯单体... 研究采用高温和剪切力的作用直接引发淀粉与丙烯酸酯单体的接枝共聚合反应.讨论了各种反应条件对接枝反应的影响,并进一步研究了接枝物在淀粉聚乙烯共混体系中的增容作用.实验结果表明,高温和剪切作用力可以引发淀粉与丙烯酸酯单体的接枝共聚合反应。接枝物作为增容剂,对淀粉聚乙烯共混体系的力学性能和流变学性能均有所改善. 展开更多
关键词 淀粉 丙烯酸酯 接枝共聚 相容性
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SYNTHESIS AND SIZING PROPERTIES OF GRAFT STARCHES AS WARP SIZING MATERIALS FOR POLYESTER/COTTON BLEND SPUN YARN 被引量:4
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作者 祝志峰 周永元 张文赓 《Journal of China Textile University(English Edition)》 EI CAS 1994年第1期22-30,共9页
Grafting a number of monomers such as acrylic acid, acrylamide, methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, butyl methacrylate and vinyl acetate onto granular corn starch was carried out resp... Grafting a number of monomers such as acrylic acid, acrylamide, methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, butyl methacrylate and vinyl acetate onto granular corn starch was carried out respectively in aqueous dispersion by using cerie ammonium nitrate as an initiator under nitrogen atmosphere. Conversion of monomer, grafting ratio and grafting efficiency were measured by the method of combining the chemical quantitative analysis with the weight. The adhesive power of the starch graft copolymers to polyester/cotton fiber was evaluated by measuring the breaking strength and elongation of the roving impregnated with the paste. The viscosity change of the size paste before and after grafting was studied. The mechanical properties of polyester/cotton fibre yarn sized by the graft starch were tested. The main conclusions are as follows: (1) monomers which were graft coplymerized onto starch have a significant influence upon the viscosity of the size paste; (2) the adhesive power 展开更多
关键词 starch graft WARP size SIZING Modification
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GRAFT COPOLYMERIZATION OF VINYL MONOMERS ONTO STARCH INITIATED BY TRANSITION METAL-THIOUREA REDOX SYSTEMS 被引量:5
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作者 高建平 田汝川 张黎明 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1996年第2期163-171,共9页
In this paper, the capabilities of grafting acrylonitrile (AN) onto starch initiated by Fe(III)-TU, V(V)-TU, Cr(VI)-TU, Mn(VII)-TU redox systems were compared in the presence of sulfuric acid of different concentratio... In this paper, the capabilities of grafting acrylonitrile (AN) onto starch initiated by Fe(III)-TU, V(V)-TU, Cr(VI)-TU, Mn(VII)-TU redox systems were compared in the presence of sulfuric acid of different concentrations. It was shown that the grafting capability of Mn(VII)-TU is the highest in these initiating systems. Using Mn (VII-TU as initiator, the effects of various acids (HClO4, H2SO4, HNO3, HCl) on the graft copolymerization of acrylonitrile onto starch were discussed, and the capabilities of graft copolymerization of methyl methacrylate (MMA), acrylamide (AM), acrylic acid (AA) onto starch were investigated. The experimental results show that the order of the influences of different acids is HClO4 > H2SO4 > HNO3 > HCl, and the order of grafting capabilities of different monomers grafted onto starch is MMA > AN > AM > AA. The structure and morphology of graft, copolymers were studied with infrared spectroscopy and scanning electron microscopy. The size, shape and roughness of surface of the grafted starch granules are changed after grafting. 展开更多
关键词 transition metal THIOUREA graft copolymerization starch
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The Optimization of Synthesizing Graft Copolymer of Starch with Vinyl Monomers 被引量:1
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作者 王志玉 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2006年第2期83-87,共5页
The graft copolymerization of acrylamide ( AM ) / acrylic acid ( AA ) onto starch ( St- g-pAA and St-g-p(AA-co-AM) ) was carried out using an orthngonal test method. The combined effects of different reaction... The graft copolymerization of acrylamide ( AM ) / acrylic acid ( AA ) onto starch ( St- g-pAA and St-g-p(AA-co-AM) ) was carried out using an orthngonal test method. The combined effects of different reaction conditions on the water absorbency of the graft copolymers were optimized through mathematical statistical methods of range and square variance analysis. The maximum water absorbency was obtained when the ratio of dried starch to distilled water was 1 : 8 ( w/w ), the ratio of starch to monomer 1 : 6 ( w/w ), the initiator concentration 4.40 × 10^-3 mol/L, the crosslinker concentration 10.86 × 10^-2 mol/L, and the basicity to AA 0. 70( mol/mol ). Both the graft copolymers have an excellent water absorption capacity in distilled water aact in 0. 9wt% NaCl solution. It was also found that in distilled water the water absorbency of St-g-pAA was higher than that of St-g-p( AA-co-AM) , while in 0.9wt% NaCl solution, the situation was just the reverse. The correlation between the water absorbeacy anct the nature of the solution anct the properties of the copolymers, which is related to the properties of the monomers, was discussed. The grafting of AA ancl AM onto starch was confirmed by the IR spectra of St-g-pAA and St-g-p( AA-co-AM). 展开更多
关键词 starch acrylic acid ACRYLAMIDE graft copolymerization water absorbency orhogonal test
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Starch Modification by Graft Copolymerization of Acrylonitrile
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作者 刘瑞贤 李莉 +3 位作者 茹宗玲 张黎明 高建平 田汝川 《Transactions of Tianjin University》 EI CAS 2003年第3期231-234,共4页
The graft copolymerization of acrylonitrile (AN) onto starch under the initiation of potassium permanganate was investigated. The effect of various reaction conditions on the graft copolymerization was studied. The re... The graft copolymerization of acrylonitrile (AN) onto starch under the initiation of potassium permanganate was investigated. The effect of various reaction conditions on the graft copolymerization was studied. The relationships between the grafting rate and the initiator concentration of potassium permanganate, monomer acrylonitrile and backbone starch, as well as reaction temperature were established. The oxidation reaction of starch with manganic ions and valence changes of manganic ions during the graft copolymerization were discussed. The results show that manganic ion Mn 7+ underwent a series of valence changes during the graft copolymerization: Mn(Ⅶ) → Mn(Ⅳ) → Mn(Ⅲ) → Mn(Ⅱ). The grafting rate of the graft copolymerization of acrylonitrile onto starch is also given. 展开更多
关键词 淀粉 丙烯腈 接枝共聚作用 接枝率 高锰酸钾
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A NEW METHOD TO SYNTHESIZE THE CATIONIC GRAFT STARCH
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作者 LinLi BingyueLiu YafengCao 《天津科技大学学报》 CAS 2004年第A01期220-224,共5页
The cationic graft copolymer was synthesized by reversed phase emulsion copolymerization of starch with diallydimethyl ammoniumlchlorid (DADMAC) and acrylamide(AM). The copolymerization was carried out using (NH4)2S2O... The cationic graft copolymer was synthesized by reversed phase emulsion copolymerization of starch with diallydimethyl ammoniumlchlorid (DADMAC) and acrylamide(AM). The copolymerization was carried out using (NH4)2S2O8-NH2CONH2 redox as initiator and selecting Span-20 as emulsifier. The effects of emulsifier content in oil phase, volume ratio of oil to water, initiator concentration and mole ratio of DADMAC to AM on the graft copolymerization were discussed. The optimum condition of synthetics was found with the orthogonal test method. 展开更多
关键词 接枝共聚物 阳离子淀粉 倒相乳胶 丙烯酰胺 粘性
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Graft Copolymerization of Modified Oxidized Starch and Its ER Effect
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作者 Liu Xueqing Yan Changhao +3 位作者 Wu Liping Wu Defeng Qiu Guanming Zhang Ming 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第5期548-548,共1页
关键词 electrorheological fluid graft copolymerization starch rare earths
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Studies on the Graft Copolymerization of Methyl Acrylate and Ethyl Acrylate onto Corn Starch Using Potassium Persulfate-Sodium Thiosulphatc as Initiation System
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作者 Wu Gongsheng (Department of Chemistry, Quigdao University, Qingdao)Wang Bin (Department of Chemistry,Daqing Oil College,Daqing) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1990年第2期149-154,共6页
Grafting copolymerizations of methyl acrylate(MA) and ethyl acrylate(EA) onto corn starch, respectively, initiated by potassium persulfate-sodium thiosulphate (KPS-STS) redox system, were studied. The structures of po... Grafting copolymerizations of methyl acrylate(MA) and ethyl acrylate(EA) onto corn starch, respectively, initiated by potassium persulfate-sodium thiosulphate (KPS-STS) redox system, were studied. The structures of poly(MA)-g-starch and poly(EA)-g-starch were characterized by IR, SEM and X-ray diffraction. Experimental results show that KPS-STS is an efficient initiation system for grafting of MA and EA onto corn starch. The maximum percent grafting was obtained at [KPS] of 6.0× 10~3 mol/L, [STS] of 1.8× 10 5 mol/L, [M] of 6. 0× 101 mol/L, S:L=4:100 at 40℃ for 6 h. The reactivity order is MA>EA. 展开更多
关键词 Methyl acrylate Ethyl acrylatc. graft copolymerization starch
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The Optimized Synthesis of Starch-g-Lactic Acid Copolymer with High Grafting Degree Catalyzed by Sulfuric Acid
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作者 胡志颖 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2014年第6期1187-1190,共4页
The starch-g-lactic acid copolymer was synthesized with catalysis of sulfuric acid by onestep process, and the structure of starch-g-lactic acid copolymer was characterized by means of IR, 13C-NMR, HMBC, XRD, and SEM.... The starch-g-lactic acid copolymer was synthesized with catalysis of sulfuric acid by onestep process, and the structure of starch-g-lactic acid copolymer was characterized by means of IR, 13C-NMR, HMBC, XRD, and SEM. The experimental results show that the maximum grafting degree of starch can reach 75% when the starch-g-lactic acid copolymer is activated at 80 ℃ for 2 h and reacted with lactic acid at 90 ℃ for 4 h in vacuum. 展开更多
关键词 corn starch lactic acid sulfuric acid starch-g-lactic acid copolymer graft copolymerization
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Preparation of superabsorbent by graft copolymerization of acrylic acid onto corn starch using K_2S_2O_8 and rare earths as initiators
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作者 白永平 李卫东 +1 位作者 冯立群 赵超 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2008年第6期831-834,共4页
K2S2O8 and rare earths(RE)were used as initiators to prepare superabsorbents by graft copolymerization of acrylic acid(AA)onto corn starch.The effects of monomer concentration,initiator K2S2O8 concentration,cross-link... K2S2O8 and rare earths(RE)were used as initiators to prepare superabsorbents by graft copolymerization of acrylic acid(AA)onto corn starch.The effects of monomer concentration,initiator K2S2O8 concentration,cross-linker concentration,reaction temperature and the concentration ratio of RE and K2S2O8 on the graft copolymerization were studied in terms of the water absorption capacity of superabsorbents.Results indicate that the optimum conditions obtained for the grafting of AA onto 5g starch are as follows:AA of 75.773 g/L,K2S2O8 of 0.437 g/L,RE of 0.874 g/L,cross-linker of 0.381 g/L and temperature of 70 ℃.The maximum water absorption capacity obtained is 740 g/g.The new method of graft polymerization is easily proceeded and controlled.The graft copolymers were characterized by infra-red spectroscopy,scanning electron microscopy and TG.Results characterized by IR and SEM give strong evidence for grafting of AA onto corn starch,and those characterized by TG reveal that the grafting of AA improves the thermostability of corn starch. 展开更多
关键词 超吸收剂 共聚合 淀粉 丙烯酸
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STUDIES ON GRAFT COPOLYMERIZATION OF DL-LACTIDE ON CORN STARCH AND BIODEGRADABILITY OF THE COPOLYMERS
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作者 YOU Yingcai ZHU Changying SHEN Xin JIAO Jingliang Department of Chemistry, Nankai University, Tianjin 300071, China 《Chinese Journal of Reactive Polymers》 2000年第2期138-144,共7页
The starch/D,L-lactide graft copolymers were synthesized by reacting D,L-lactide with corn starch in N,N-dimethylacetamide (DMAM) in the presence of triethylamine (NEt3) and anhydrous lithium chloride. The effect of r... The starch/D,L-lactide graft copolymers were synthesized by reacting D,L-lactide with corn starch in N,N-dimethylacetamide (DMAM) in the presence of triethylamine (NEt3) and anhydrous lithium chloride. The effect of reaction time and the molar ratio of D,L-lactide to glucose structural unit of starch on monomer conversion(C%), graft (G%) and graft efficiency (GE%) were studied. The C%, G% and GE% could approach 37.3%,179.7% and 68.0%, respectively when the molar ratio of D,L-lactide to glucose structural unit of starch is 10:1 and the graft copolymerization was carried out at 80-85℃ for 4 hours under nitrogen atmosphere. The Fourier transforms infra-red (FTIR) spectroscopy, differential scanning calorimetry (DSC) and X-ray diffraction (XRD) spectroscopy were used in order to characterize the graft copolymers. FTIR spectra show that absorption band at 1740 cm-1 confirmed the formation of ester bond, indicating the starch /D,L-lactide graft copolymers were produced, the DSC characteristic results show the melting temperature of the graft copolymer were elevated slightly as the molar ratio of D,L-lactide to glucose structural units of starch increased and the X-ray diffraction spectra show the synthesized graft copolymers were amorphous. The degradability of graft copolymer was tested with the aid of acid, alkali and microbe such as bacillus subtilis and staphylococcus aureus. The results of water resistance show the graft copolymer produced can be used as a component of impermeable coating for cardboard. 展开更多
关键词 聚合物 生物降解 玉米淀粉
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TBE EFFIGIENGIES OF THREE INITIATORS OF Fe^(2+)—H_2O_2, K_2S_2O_8, KMnO_4 AND TBE KINETIC EQUATION IN THE GRAFTING OF AGRYLAMIDE ONTO STARCH
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作者 Guang Zhong YAHG Wen Hua GUO +4 位作者 Quan Sheng LI Shao Jie LU Xi Hai CUI Shu Cheng MO Yin Hun SHI 《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第12期913-916,共4页
A comparative study is made on the efficiencies of three initiators of Fe^(2+)-H_2O_2, K_2S_2O_8 and KMnO_4 in the grafting of acrylamide onto starch. Of the three initiators the best one is KMnO_4. Moreover, the kine... A comparative study is made on the efficiencies of three initiators of Fe^(2+)-H_2O_2, K_2S_2O_8 and KMnO_4 in the grafting of acrylamide onto starch. Of the three initiators the best one is KMnO_4. Moreover, the kinetic equation is also studied. 展开更多
关键词 St TBE EFFIGIENGIES OF THREE INITIATORS OF Fe AM IV KMnO4 AND TBE KINETIC EQUATION IN THE graftING OF AGRYLAMIDE ONTO starch K2S2O8 H2O2 FE
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RADICAL GRAFTING REACTIONS ONTO STARCH AND OTHER WATER-SOLUBLE COPOLYMERS IN ISOLATED GEL DROPLETS
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作者 张连生 A.F.Johnson 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1993年第2期144-152,共9页
A novel radical grafting copolymerization process has been designed for water-soluble polymers which avoids the problems of conducting grafting reactions in highly viscous polymerization media. A variety of water-solu... A novel radical grafting copolymerization process has been designed for water-soluble polymers which avoids the problems of conducting grafting reactions in highly viscous polymerization media. A variety of water-soluble graft copolymers having starch or dextran as the backbone chain with grafted side chains of polyacrylamide (—AM—), poly (acrylic acid ) (—AA—), poly (acrylamide-co-acrylic acid) (—AM—NH_4AA—) or poly ( acrylamide-co-2-acryiamido-2-methyl-l-propanesulphinic acid) (—AM—AMPS—) have been synthesized in gel droplets using aceric sulphate redox initiator, and their properties compared. The reaction conditions were optimized taking into account reaction kinetic data and the observed properties of the products produced under different reaction conditions. The effects of the ratios of [backbone]/[graft monomer], [ AM]/[ AA]/[AMPS] , [Ce^(4+)]/[ S_2O_8=] and pH value on the reaction rate , conversion, grafting degree, grafted chain length and the product molecular weight have been investigated. 展开更多
关键词 Radical grafting copolymerization Isolated gel droplets Acrylamide starch Kinetics
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淀粉接枝丙烯酰胺与聚丙烯酰胺对高岭土动态絮凝差异的研究
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作者 高博 刘新辉 +4 位作者 姚雷 袁雪 谢永鑫 卜祥宁 沙杰 《矿产保护与利用》 2024年第1期24-32,共9页
高岭土等黏土矿的存在是煤泥水沉降效果差的主要原因,目前尚未有关于难沉降煤泥水动态絮凝过程的研究。相较于聚丙烯酰胺(PAM)合成单体的毒性,淀粉接枝丙烯酰胺(SAM)合成的单体可降解性好。为此,以高岭土为研究对象,系统对比了SAM与PAM... 高岭土等黏土矿的存在是煤泥水沉降效果差的主要原因,目前尚未有关于难沉降煤泥水动态絮凝过程的研究。相较于聚丙烯酰胺(PAM)合成单体的毒性,淀粉接枝丙烯酰胺(SAM)合成的单体可降解性好。为此,以高岭土为研究对象,系统对比了SAM与PAM对高岭土动态絮凝过程的影响。首先,考察了不同SAM与PAM用量下的沉降速度和絮凝效果。随后,通过聚焦光束反射测量(FBRM)和颗粒录影显微镜(PVM)技术研究了高岭土悬浮液在SAM和PAM作用下的不同粒级颗粒数量变化。沉降实验和FBRM-PVM测试结果表明,PAM能够形成更多的+100μm大絮团,使得PAM具有更好的沉降效果;SAM形成的絮团更稳定,对细颗粒的絮凝效果更好。最后,通过FBRM获得的数据,基于Smoluchowski模型计算了PAM和SAM作用下高岭土的絮凝动力学参数,发现PAM作用下的絮凝指数明显高于SAM,同时-30μm和30~60μm颗粒数量的动态变化主导了絮凝动力学中絮团的形成过程。总体而言,PAM可以形成更多的、松散的大絮团,有利于高岭土的快速沉降,但对微细颗粒絮凝效果不佳。相较于PAM,SAM独特的多链立体网状结构,有利于微细颗粒絮凝和形成稳定的絮团,从而避免选煤厂洗水系统中细泥的循环积聚。 展开更多
关键词 淀粉 接枝共聚 聚丙烯酰胺 FBRM-PVM 絮凝动力学 高岭土
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ε-聚赖氨酸盐酸盐接枝淀粉薄膜的制备及性质研究
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作者 刘勇 马文雅 +2 位作者 刘孝芳 陈霄汉 李立 《包装工程》 CAS 北大核心 2024年第13期35-41,共7页
目的对淀粉接枝抑菌肽,得到抑菌淀粉,并挤出成膜,表征其性质,为淀粉的应用提供参考。方法借助偶联剂,将ε-聚赖氨酸盐酸盐(ε-polylysine-HCl,ε-PLH)接枝到玉米淀粉上,分析其化学结构、微观结构、热性能及抑菌性。通过熔融挤出法将接... 目的对淀粉接枝抑菌肽,得到抑菌淀粉,并挤出成膜,表征其性质,为淀粉的应用提供参考。方法借助偶联剂,将ε-聚赖氨酸盐酸盐(ε-polylysine-HCl,ε-PLH)接枝到玉米淀粉上,分析其化学结构、微观结构、热性能及抑菌性。通过熔融挤出法将接枝淀粉与聚乳酸(Polylactic acid,PLA)、聚己二酸/对苯二甲酸丁二酯(Poly butyleneadipate-co-terephthalate,PBAT)共混改性成膜,表征其力学性能、抑菌性能。结果FTIR显示,ε-PLH被成功接枝到淀粉分子上;热重分析(TGA)结果显示,接枝淀粉的起始分解温度有所下降;含有30%接枝淀粉的PBAT/PLA薄膜具有更高的拉伸强度。此外,接枝淀粉添加量为30%的薄膜对大肠杆菌、金黄色葡萄球菌的抑制率分别达到了46.53%、68.81%。结论接枝ε-聚赖氨酸盐酸盐是一种有效的淀粉改性途径,接枝淀粉/PBAT/PLA薄膜具有良好的应用前景。 展开更多
关键词 玉米淀粉 ε-聚赖氨酸盐酸盐 接枝 改性 淀粉膜
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木薯淀粉-丙烯酰胺接枝共聚物的结构与性能
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作者 蔡海鹏 汪进文 +3 位作者 董春雷 朱刚 杜官本 邓书端 《林业工程学报》 CSCD 北大核心 2024年第4期79-86,共8页
为消除传统人造板的甲醛释放对人体健康和环境造成的危害,将木薯淀粉(CS)降解后与丙烯酰胺(AM)接枝共聚,制备木薯淀粉-丙烯酰胺接枝共聚物(CS-AAGC)胶黏剂,并对其外观、黏度、固含量等基本性能进行测定。通过傅里叶变换红外光谱(FT-IR)... 为消除传统人造板的甲醛释放对人体健康和环境造成的危害,将木薯淀粉(CS)降解后与丙烯酰胺(AM)接枝共聚,制备木薯淀粉-丙烯酰胺接枝共聚物(CS-AAGC)胶黏剂,并对其外观、黏度、固含量等基本性能进行测定。通过傅里叶变换红外光谱(FT-IR)、核磁共振碳谱(13C NMR)及X射线光电子能谱(XPS)对其结构进行分析,采用差式扫描量热分析(DSC)及扫描电镜(SEM)分析其固化性能,探究木薯淀粉与丙烯酰胺(AM)的物质的量比对木薯淀粉-丙烯酰胺接枝共聚物胶黏剂胶合强度的影响。结果表明:合成的木薯淀粉-丙烯酰胺接枝共聚物胶黏剂外观为乳白色均一液体,随着丙烯酰胺添加量的增加,共聚物的黏度也随之增加;丙烯酰胺上的双键与淀粉中的羟基发生了反应;当n(淀粉基本单元)∶n(AM)=1∶5时,相应的木薯淀粉-丙烯酰胺接枝共聚物的胶合性能相对最好,以其制备的胶合板干状剪切强度为1.46 MPa、(23±2)℃冷水浸泡24 h后的剪切强度为0.87 MPa、(63±1)℃热水浸泡3 h后的剪切强度为0.84 MPa,符合GB/T 9846—2015《普通胶合板》对Ⅱ类胶合板的要求。 展开更多
关键词 木薯淀粉 丙烯酰胺 木材胶黏剂 接枝共聚 胶合板
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