Superabsorbents starch grafted sodium polyacrylate was prepared by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of suspension parameters, ...Superabsorbents starch grafted sodium polyacrylate was prepared by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of suspension parameters, such as volume ratio of continuous phase and dispersed phase, type and dosage of suspending agents, on water absorbency of the starch grafted polymer was studied. Different starch derivatives were also investigated. Superabsorbents made of cationic starch has higher water absorbency than that made of native corn starch.展开更多
Superabsorbents starch grafted sodium polyacrylate was synthesized by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of reaction parameters,...Superabsorbents starch grafted sodium polyacrylate was synthesized by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of reaction parameters, such as starch pretreatment temperature, neutralization degree of monomer, reaction time and temperature, concentration of initiator, molar ratio of monomer and starch, on water absorbency of the starch grafted polymer was studied. The effects of the last two parameters were investigated by uniform design method, and the prediction equation was obtained.展开更多
A super-absorbent polymer is prepared by graft polymerizing acrylamide (AM) onto potato starch using eerie ammonium nitrate (CAN) and N, N'-methylene-bis-acrylamide (bisAM) as an initiator and cross-linking agent ...A super-absorbent polymer is prepared by graft polymerizing acrylamide (AM) onto potato starch using eerie ammonium nitrate (CAN) and N, N'-methylene-bis-acrylamide (bisAM) as an initiator and cross-linking agent respectively, and then subjecting the potato starch- poly(acrylamide) (PAM) graft copolymer (SPAM) to alkaline saponification. The water absorbency (WA) of the sample is nearly 5000 g H2O/g for dry sample in 24 h at room temperature and is far larger than that of reported in the literature([1]). The variables affecting the WA were investigated and optimiz;ed, they were: concentrations of potato starch, AM, CAN and bisAM were 26.3 g/L, 1.14 mol/L, 10.3 mmol/L and 0.53 mmol/L, respectively. The amount of sodium hydroxide was 15 g and the temperatures of graft copolymerization and saponification reactions were 60 degrees C and 95 degrees C. The time of graft copolymerization and saponification reactions was 2 h, respectively.展开更多
文摘Superabsorbents starch grafted sodium polyacrylate was prepared by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of suspension parameters, such as volume ratio of continuous phase and dispersed phase, type and dosage of suspending agents, on water absorbency of the starch grafted polymer was studied. Different starch derivatives were also investigated. Superabsorbents made of cationic starch has higher water absorbency than that made of native corn starch.
文摘Superabsorbents starch grafted sodium polyacrylate was synthesized by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of reaction parameters, such as starch pretreatment temperature, neutralization degree of monomer, reaction time and temperature, concentration of initiator, molar ratio of monomer and starch, on water absorbency of the starch grafted polymer was studied. The effects of the last two parameters were investigated by uniform design method, and the prediction equation was obtained.
文摘A super-absorbent polymer is prepared by graft polymerizing acrylamide (AM) onto potato starch using eerie ammonium nitrate (CAN) and N, N'-methylene-bis-acrylamide (bisAM) as an initiator and cross-linking agent respectively, and then subjecting the potato starch- poly(acrylamide) (PAM) graft copolymer (SPAM) to alkaline saponification. The water absorbency (WA) of the sample is nearly 5000 g H2O/g for dry sample in 24 h at room temperature and is far larger than that of reported in the literature([1]). The variables affecting the WA were investigated and optimiz;ed, they were: concentrations of potato starch, AM, CAN and bisAM were 26.3 g/L, 1.14 mol/L, 10.3 mmol/L and 0.53 mmol/L, respectively. The amount of sodium hydroxide was 15 g and the temperatures of graft copolymerization and saponification reactions were 60 degrees C and 95 degrees C. The time of graft copolymerization and saponification reactions was 2 h, respectively.
