[Objective] The study aims to discuss the changes of potential evapotran- spiration and its sensitivity to meteorological factors in Guizhou Province, so as to provide important references for assessment of water reso...[Objective] The study aims to discuss the changes of potential evapotran- spiration and its sensitivity to meteorological factors in Guizhou Province, so as to provide important references for assessment of water resources, research of agri- cultural water conservancy and climate change. [Method] Temporal and spatial dis- tribution characteristics of potential evapotranspiration in Guizhou Province from 1961 to 2010 were analyzed, and the sensitivity of potential evapotranspiration to meteo- rological factors in Guizhou Province was studied through correlation analysis. [Re- sult] On the whole, potential evapotranspiration in Guizhou Province was higher in the southwest and the west compared with the northeast and the east. In various seasons, it was the highest in summer, followed by spring and autumn, while it was the lowest in winter. In recent 40 years, annual potential evapotranspiration showed an obvious decreasing trend in most stations of Guizhou Province. The main meteo- rological factors influencing changes of potential evapotranspiration in Guizhou Province were sunshine duration, daily maximum temperature, and daily average relative humidity. [Conclusion] Daily average temperature was not the main meteoro- logical factor affecting changes of potential evapotranspiration in Guizhou Province, while sunshine duration, daily maximum temperature, and daily average relative hu- midity had important effects on potential evapotranspiration in Guizhou Province.展开更多
By calculating the energy distribution of electrons reaching the photocathode surface and solving the Schrodinger equation that describes the behavior of an electron tunneling through the surface potential barrier,we ...By calculating the energy distribution of electrons reaching the photocathode surface and solving the Schrodinger equation that describes the behavior of an electron tunneling through the surface potential barrier,we obtain an equation to calculate the emitted electron energy distribution of transmission-mode NEA GaAs photocathodes. Accord- ing to the equation,we study the effect of cathode surface potential barrier on the electron energy distribution and find a significant effect of the barrier-Ⅰ thickness or end height,especially the thickness,on the quantum efficiency of the cath- ode. Barrier Ⅱ has an effect on the electron energy spread, and an increase in the vacuum level will lead to a narrower electron energy spread while sacrificing a certain amount of cathode quantum efficiency. The equation is also used to fit the measured electron energy distribution curve of the transmission-mode cathode and the parameters of the surface barri- er are obtained from the fitting. The theoretical curve is in good agreement with the experimental curve.展开更多
Although high resolution can be provided by electrical logging, the measured electrical log range is narrow and is limited to near the well. Borehole-surface electric potential measurements are able to detect a wide e...Although high resolution can be provided by electrical logging, the measured electrical log range is narrow and is limited to near the well. Borehole-surface electric potential measurements are able to detect a wide enough range but its resolution is limited, particularly for reservoirs with complex oil and water distribution or complicated structure. In this study, we attempt to accurately locate the 3-D reservoir water and oil distribution by combining borehole-surface and crosswell electric potentials. First, the distributions of oil and water in both vertical and horizontal directions are detected by the borehole-surface and erosswell electric potential methods, respectively, and then the measured crosswell potential result is used to calibrate the measured borehole-surface electric potential data to improve vertical resolution so that the residual oil distribution is determined in a lower half-space with three dimensions. The evaluation of residual oil distribution is obtained by investigation of differences between the simulation results of the reservoir with and without water flooding. The finite difference numerical simulation results prove that the spatial residual oil distribution can be effectively determined by combining the crosswell and borehole-surface electric potentials.展开更多
Nanobubble flotation technology is an important research topic in the field of fine mineral particle separation.The basic characteristics of nanobubbles,including their size,concentration,surface zeta potential,and st...Nanobubble flotation technology is an important research topic in the field of fine mineral particle separation.The basic characteristics of nanobubbles,including their size,concentration,surface zeta potential,and stability have a significant impact on the nanobubble flotation performance.In this paper,bulk nanobubbles generated based on the principle of hydrodynamic cavitation were investigated to determine the effects of different parameters(e.g.,surfactant(frother)dosage,air flow,air pressure,liquid flow rate,and solution pH value)on their size distribution and zeta potential,as measured using a nanoparticle analyzer.The results demonstrated that the nanobubble size decreased with increasing pH value,surfactant concentration,and cavitation-tube liquid flow rate but increased with increasing air pressure and increasing air flow rate.The magnitude of the negative surface charge of the nanobubbles was positively correlated with the pH value,and a certain relationship was observed between the zeta potential of the nanobubbles and their size.The structural parameters of the cavitation tube also strongly affected the characteristics of the nanobubbles.The results of this study offer certain guidance for optimizing the nanobubble flotation technology.展开更多
We observed the steady-state visually evoked potential(SSVEP) from a healthy subject using a compact quad-channel potassium spin exchange relaxation-free(SERF) optically pumped magnetometer(OPM). To this end, 30 s of ...We observed the steady-state visually evoked potential(SSVEP) from a healthy subject using a compact quad-channel potassium spin exchange relaxation-free(SERF) optically pumped magnetometer(OPM). To this end, 30 s of data were collected, and SSVEP-related magnetic responses with signal intensity ranging from 150 fT to 300 f T were observed for all four channels. The corresponding signal to noise ratio(SNR) was in the range of 3.5–5.5. We then used different channels to operate the sensor as a gradiometer. In the specific case of detecting SSVEP, we noticed that the short channel separation distance led to a strongly diminished gradiometer signal. Although not optimal for the case of SSVEP detection, this set-up can prove to be highly useful for other magnetoencephalography(MEG) paradigms that require good noise cancellation.Considering its compactness, low cost, and good performance, the K-SERF sensor has great potential for biomagnetic field measurements and brain-computer interfaces(BCI).展开更多
The horizontal and vertical distribution characteristics of Pb in urban soil of Shenyang City, China were investigated in this study. The range of Pb concentration in the soil was 22.02-2910.60mg/kg. The standard devi...The horizontal and vertical distribution characteristics of Pb in urban soil of Shenyang City, China were investigated in this study. The range of Pb concentration in the soil was 22.02-2910.60mg/kg. The standard deviation was 443.07mg/kg, and coefficient of variation was 1.64. Tiexi District was seriously contaminated by lead. In general, Pb concentration in the soil decreased with distance from pollution source. Lead concentration varied in different functional areas with the order of industrial area>commercial area>residential area>suburb>reference area. Pb concentration decreased with the depth of soil profile. Both geo-accumulation index and ecological risk index were used to estimate the potential risk of soil Pb pollution in Shenyang City. The results showed that the high potential risk area included Tiexi District and traffic roads.展开更多
Alien invasive species represent a severe risk to biodiversity and economy, as in the case of fire blight (Erwinia amylovora), a bacterial disease that originated in North America, which may be released into new loc...Alien invasive species represent a severe risk to biodiversity and economy, as in the case of fire blight (Erwinia amylovora), a bacterial disease that originated in North America, which may be released into new locations by means of fruit trade. On the basis of the knowledge of Erwinia amylovora's biophysical characteristics and environmental data, the geographic information system (GIS) has been applied to determine areas where Erwinia amylovora can potentially invade China. Temperature and precipitation, during the blossoming period, are considered to be two critical factors affecting the Erwinia amylovora's suitable climatic zones. This spatial modeling approach was validated from a case study in Europe, where the occurrence of Erwinia amylovora has been proven. The model prediction agreed with the occurrence of the bacteria recorded in Europe, and the same procedure has been applied to produce a potential establishment area in China's two preferential apple cultivation regions, Bohai Bay region and Huangtu Altiplano region. It has been found that areas belonging to the high-risk category are more or less the main apple producing areas, accounting for their great economic importance in China. This methodology provides an initial baseline for assessment, prevention, and management of alien species that may become invasive under certain environmental conditions. In addition, this modeling approach provides a tool for policy makers to use, in making decisions on management practices where alien species are involved.展开更多
Tibetan spruce (Picea smithiana) is an endemic species of the Himalayas,and it distributes only in a re-stricted area with very low number.To address the lack of detailed distributional information,we used maximum en-...Tibetan spruce (Picea smithiana) is an endemic species of the Himalayas,and it distributes only in a re-stricted area with very low number.To address the lack of detailed distributional information,we used maximum en-tropy (Maxent) niche-based model to predict the species' potential distribution from limited occurrence-only records.The location data of P.smithiana,relative bioclimatic variables,vegetation data,digital elevation model (DEM),and the derived data were analyzed in Maxent.The receiver operating characteristic (ROC) curve was applied to assess the prediction accuracy.The Maxent jackknife test was performed to quantify the training gains from data layers and the response of P.smithiana distribution to four typical environmental variables was analyzed.Results show that the model performs well at the regional scale.There is a potential for continued expansion of P.smithiana population numbers and distribution in China.P.smithiana potentially distributes in the lower reaches of Gyirong Zangbo and Poiqu rivers in Gyirong and Nyalam counties in Qomolangma (Mount Everest) National Nature Preserve (QNNP),China.The species prefers warm temperate climate in mountain area and mainly distributes in needle-leaved evergreen closed to open forest and mixed forest along the river valley at relatively low altitudes of about 2000-3000 m.Model simulations suggest that distribution patterns of rare species with few species numbers can be well predicted by Max-ent.展开更多
Bactrocera bryoniae and Bactrocera neohumeralis are highly destructive and major biosecurity/quarantine pests of fruit and vegetable in the tropical and subtropical regions in the South Pacific and Australia.Although ...Bactrocera bryoniae and Bactrocera neohumeralis are highly destructive and major biosecurity/quarantine pests of fruit and vegetable in the tropical and subtropical regions in the South Pacific and Australia.Although these pests have not established in China,precautions must be taken due to their highly destructive nature.Thus,we predicted the potential geographic distribution of B.bryoniae and B.neohumeralis across the world and in particular China by ecological niche modeling of the Maximum Entropy(Max Ent)model with the occurrence records of these two species.Bactrocera bryoniae and B.neohumeralis exhibit similar potential geographic distribution ranges across the world and in China,and each species was predicted to be able to distribute to over 20%of the globe.Globally,the potential geographic distribution ranges for these two fruit fly species included southern Asia,the central and the southeast coast of Africa,southern North America,northern and central South America,and Australia.While within China,most of the southern Yangtze River area was found suitable for these species.Notably,southern China was considered to have the highest risk of B.bryoniae and B.neohumeralis invasions.Our study identifies the regions at high risk for potential establishment of B.bryoniae and B.neohumeralis in the world and in particular China,and informs the development of inspection and biosecurity/quarantine measures to prevent and control their invasions.展开更多
Madagascar,a globally renowned biodiversity hotspot characterized by high rates of endemism,is one of the few remaining refugia for many plants and animal species.However,global climate change has greatly affected the...Madagascar,a globally renowned biodiversity hotspot characterized by high rates of endemism,is one of the few remaining refugia for many plants and animal species.However,global climate change has greatly affected the natural ecosystem and endemic species living in Madagascar,and will likely continue to influence species distribution in the future.Madagascar is home to six endemic baobab(Adansonia spp.,Bombacoideae[Malvaceae])species(Adansonia grandidieri,A.suarezensis,A.madagascariensis,A.perrieri,A.rubrostipa,A.za),which are remarkable and endangered plants.This study aimed to model the current distribution of suitable habitat for each baobab species endemic to Madagascar and determine the effect that climate change will have on suitable baobab habitat by the years 2050 and 2070.The distribution was modeled using MaxEnt based on locality information of 245 occurrence sites of six species from both online database and our own field work.A total of seven climatic variables were used for the modeling process.The present distribution of all six Madagascar's baobabs was largely influenced by temperature-related factors.Although both expansion and contraction of suitable habitat are predicted for all species,loss of original suitable habitat is predicted to be extensive.For the most widespread Madagascar baobab,A.za,more than 40%of its original habitat is predicted to be lost because of climate change.Based on these findings,we recommend that areas predicted to contract in response to climate change should be designated key protection regions for baobab conservation.展开更多
Background: European forests are considered a crucial resource for supplying biomass to a growing bio-economy in Europe. This study aimed to assess the potential availability of forest biomass from European forests an...Background: European forests are considered a crucial resource for supplying biomass to a growing bio-economy in Europe. This study aimed to assess the potential availability of forest biomass from European forests and its spatial distribution. We tried to answer the questions(i) how is the potential forest biomass availability spatially distributed across Europe and(ii) where are hotspots of potential forest biomass availability located?Methods: The spatial distribution of woody biomass potentials was assessed for 2020 for stemwood, residues(branches and harvest losses) and stumps for 39 European countries. Using the European Forest Information SCENario(EFISCEN) model and international forest statistics, we estimated the theoretical amount of biomass that could be available based on the current and future development of the forest age-structure, growing stock and increment and forest management regimes. We combined these estimates with a set of environmental(site productivity, soil and water protection and biodiversity protection) and technical(recovery rate, soil bearing capacity) constraints, which reduced the amount of woody biomass that could potentially be available. We mapped the potential biomass availability at the level of administrative units and at the 10 km × 10 km grid level to gain insight into the spatial distribution of the woody biomass potentials.Results: According to our results, the total availability of forest biomass ranges between 357 and 551 Tg dry matter per year. The largest potential supply of woody biomass per unit of land can be found in northern Europe(southern Finland and Sweden, Estonia and Latvia), central Europe(Austria, Czech Republic, and southern Germany),Slovenia, southwest France and Portugal. However, large parts of these potentials are already used to produce materials and energy. The distribution of biomass potentials that are currently unused only partially coincides with regions that currently have high levels of wood production.Conclusions: Our study shows how the forest biomass potentials are spatially distributed across the European continent, thereby providing insight into where policies could focus on an increase of the supply of woody biomass from forests. Future research on potential biomass availability from European forests should also consider to what extent forest owners would be willing to mobilise additional biomass from their forests and at what costs the estimated potentials could be mobilised.展开更多
Global food security is threatened by the impacts of the spread of crop pests and changes in the complex interactions between crops and pests under climate change.Schrankia costaestrigalis is a newly-reported potato p...Global food security is threatened by the impacts of the spread of crop pests and changes in the complex interactions between crops and pests under climate change.Schrankia costaestrigalis is a newly-reported potato pest in southern China.Early-warning monitoring of this insect pest could protect domestic agriculture as it has already caused regional yield reduction and/or quality decline in potato production.Our research aimed to confirm the potential geographical distributions(PGDs)of S.costaestrigalis in China under different climate scenarios using an optimal MaxEnt model,and to provide baseline data for preventing agricultural damage by S.costaestrigalis.Our findings indicated that the accuracy of the optimal MaxEnt model was better than the default-setting model,and the minimum temperature of the coldest month,precipitation of the driest month,precipitation of the coldest quarter,and the human influence index were the variables significantly affecting the PGDs of S.costaestrigalis.The highly-and moderately-suitable habitats of S.costaestrigalis were mainly located in eastern and southern China.The PGDs of S.costaestrigalis in China will decrease under climate change.The conversion of the highly-to moderately-suitable habitat will also be significant under climate change.The centroid of the suitable habitat area of S.costaestrigalis under the current climate showed a general tendency to move northeast and to the middle-high latitudes in the 2030s.The agricultural practice of plastic film mulching in potato fields will provide a favorable microclimate for S.costaestrigalis in the suitable areas.More attention should be paid to the early warning and monitoring of S.costaestrigalis in order to prevent its further spread in the main areas in China’s winter potato planting regions.展开更多
Talinopsis frutescens(Anacampserotaceae,a family that is close related to Cactaceae)is a succulent species endemic to North America.The aim of this study was to explore,using Ecological Niche Modeling(ENM),changes in ...Talinopsis frutescens(Anacampserotaceae,a family that is close related to Cactaceae)is a succulent species endemic to North America.The aim of this study was to explore,using Ecological Niche Modeling(ENM),changes in potential distribution ranges considering different climate scenarios:past conditions during the Last Inter Glacial(LIG)and the Last Glacial Maximum(LGM),the present and projections for 2070(RCP 2.6 to 8.5).A pattern of contraction is observed during the LIG,which agrees with other studies focused in species from arid environments.This pattern was followed by a migration towards the south during the LGM and a possible recent expansion to the north as is observed in the present scenario.All future projections show the same contraction and fragmentation patterns,resulting in three discontinuous areas:the northern part of the Chihuahuan Desert,the southern-central part of the Mexican Plateau,and the smallest one in the Tehuacán-Cuicatlán Valley.Our projections for future scenarios agree with other studies and support that global climate change tends to alter the current distribution of arid environment species.展开更多
Due to the influence of human activities such as cultivation and urban construction,the ecosystem of the Yellow River Basin(YRB)is subjected to increased vulnerability and even potential risk of destruction.Ecological...Due to the influence of human activities such as cultivation and urban construction,the ecosystem of the Yellow River Basin(YRB)is subjected to increased vulnerability and even potential risk of destruction.Ecological restoration has led to an increase in vegetation,but excessive afforestation conversely results in low survival rate of trees,water shortages,and biodiversity loss.It is of great significance for achieving sustainable development of forests to reasonable revegetation in the region.At present,the potential distribution pattern of dominant species and their mixed forms in the basin has not been effectively studied.This study simulated the potential distribution of dominant vegetation in the YRB based on Maximum Entropy(Max Ent)and Genetic Algorithm for Rule-Set Prediction(GARP)and explored the impact of human interference on it by employing land use as the environmental filter to distinguish the regions of human activities.We further predicted the potential distribution of typically mixed forests and discussed their human interference.The main results are as follows:(1)Except for Caragana korshinskii,all models had good above performance(0.7<the mean AUC<1).Except for Caragana korshinskii,the area under the curve(AUC)for 90%of the models indicated that Max Ent performed better than GARP,and Max Ent easily lead to over-fitting while GARP predicted a wider range.(2)Except for Nitraria tangutorum,the dominant types of vegetation such as Pinus tabulaeformis,Platycladus orientalis,and Hippophae rhamnoides mainly distributed in southern Gansu,Shaanxi,and south-central Shanxi.Among them,the largest suitable area of Artemisia gmelinii and Stipa bungeana(High suitable area)were approximately 56.7×104 km2(38.8%)and 54.7×104 km2(28.5%)with the area occupied by large-scale cultivation being 17.5×104 km2(39.4%)and 18.9×104 km2(48%),respectively,which indicated human activities caused great damage to the core growth regions of these vegetation.(3)Mean temperature of coldest quarter or month mainly constrained the growth of most vegetation in the YRB in terms of temperature,while precipitation of wettest/driest month is one of the dominant factors.However,some vegetation responded differently to other meteorological factors due to niche differences.(4)Most of the mixed forests were distributed in southern Gansu,Shaanxi,and Shanxi provinces;its middle and high suitable areas were mainly concentrated in Shaanxi and southern and central Shanxi,where the cultivated land had occupied most of them.Therefore,the results showed that the restoration of herbaceous vegetation such as Artemisia gmelinii and Stipa bungeana has a high potential and it is appropriate that the measures for afforestation should be concentrated in the areas like the lower reaches of the Weihe,Jinghe,and Beiluo rivers and Luliang Mountain,where the cultivated land overlaps with the high suitable areas of the corresponding vegetation and the mixed forests with less water consumption and wide distribution,such as Caragana korshinskii-Hippophae rhamnoides,Pinus tabulaeformis-Quercus liaotungensis,and Ostryopsis davidiana-Stipa bungeana-Hippophae rhamnoides.The results of this study can provide effective guidance for mixed forest plantations and vegetation conservation in the YRB.展开更多
Antarctic krill is the key species of ecological system in the Amundsen Sea.At present,the suitable distribution is unobtainable by scientifi c surveys or data from the fi shery.In this paper,the maximum entropy algor...Antarctic krill is the key species of ecological system in the Amundsen Sea.At present,the suitable distribution is unobtainable by scientifi c surveys or data from the fi shery.In this paper,the maximum entropy algorithm(Maxent)was used to obtain the potential distribution of adult Antarctic krill in order to provide useful information and reasonable reference for the policy on protecting potential krill habitats around the Amundsen Sea.Occurrence points and 17 environmental variables were used to simulate the distributions.Results show that the high and moderate suitable habitats lie between 65°S and 72°S in the Amundsen Sea.The high suitable habitat accounts for 8.1%of the total area of the Amundsen Sea.The sea ice persistence(ICE),total phytoplankton(PHYC),and the minimum value of dissolved iron(Fe_min)are the three dominant contributors to the model.Results from the response curves show that Antarctic krill preferred habitats with ICE of 0.42-0.93,PHYC of 2.48-2.77 mmol/m^(3) and Fe_min of(7.10×10^(-5))-(9.45×10^(-5))mmol/m 3.Positive trends existed in the PHYC of the high and moderate suitable habitat,and a positive trend existed in the Fe_min of moderate suitable habitat.However,the probability of presence of Antarctic krill will decrease if the increase of the PHYC and Fe_min continues.展开更多
DC magnetic biasing problem,caused by the DC grounding electrode, threatened the safe operation of AC power grid. In this paper, the characteristics of the soil stratification near DC grounding electrode was researche...DC magnetic biasing problem,caused by the DC grounding electrode, threatened the safe operation of AC power grid. In this paper, the characteristics of the soil stratification near DC grounding electrode was researched. The AC-DC interconnected large-scale system model under the monopole operation mode was established. The earth surface potential and DC current distribution in various stations under the different surface thickness was calculated. Some useful conclusions are drawn from the analyzed results.展开更多
Climate change has affected and will continue to affect the spatial distribution patterns of marine organisms.To understand the impact of climate change on the distribution patterns and species richness of the Sciaeni...Climate change has affected and will continue to affect the spatial distribution patterns of marine organisms.To understand the impact of climate change on the distribution patterns and species richness of the Sciaenidae in China’s coastal waters,the maximum entropy model was used to combine six environmental factors and predict the potential distribution of 12 major species of Sciaenidae by 2050s under Representative Concentration Pathways(RCPs)2.6 and 8.5.The results showed that the average area under the receiver operating characteristic curve of the model was 0.917,indicating that the model predictions were accurate and reliable.The main driving factors affecting the potential distribution of these fishes were dissolved oxygen,salinity,and sea surface temperature(SST).There was an overall northward shift in the potential habitat areas of these fishes under the two climate scenarios.The total potential habitat areas of Larimichthys polyactis,Pennahia argentata,and Pennahia pawak decreased under both climate scenarios,while the total habitat area of Johnius belengerii,Pennahia anea,Miichthys miiuy,Collichthys lucidus,and Collichthys niveatus increased,suggesting that these might be loser and winner species,respectively.The expansion rate,contraction rate,degree of centroid change,and species richness in the potential habitats were generally more significant under RCP8.5 than RCP2.6.The mean shift rates of the potential distribution were 41.50 km/(10 a) and 29.20 km/(10 a) under RCP8.5 and RCP2.6,respectively.The changes in Sciaenidae species richness under climate change were bounded by the Changjiang River Estuary waters,with obvious north-south differences.Some waters with increased species richness may become refuges for Sciaenidae fishes under climate change.The richness and habitat area change rate of some aquatic germplasm resources will decrease,meanings that these reserves are more sensitive to climate change,and more attention should be paid to the potential challenges and opportunities for fishery managers.This study may provide a scientific basis for the management and conservation of Sciaenidae in China under climate change.展开更多
The adsorption isotherms of four activated carbons (Norit Rill, Chemviron BPL, Monolit, and Ambersorb-572) have been examined by nitrogen adsorption at 77.5 K. A method for adsorption potential distribution calculat...The adsorption isotherms of four activated carbons (Norit Rill, Chemviron BPL, Monolit, and Ambersorb-572) have been examined by nitrogen adsorption at 77.5 K. A method for adsorption potential distribution calculation has been proposed based on the adsorption isotherms. This distribution provides information about possible changes in the Gibbs free energy caused by the energetic and geometrical heterogeneities of an activated carbon as well as by the adsorbate-related entropic effects. The general character of the adsorption potential distribution is clearly visible by its simple relation to the micropore and mesopore distribution,展开更多
The interfacial electrical potentials and charge distributions of two manganite-based heterojunctions, i.e.,La_(0.67)Ca_(0.33)MnO_3/SrTiO_3:0.05 wt% Nb(LCMO/STON) and La_(0.67)Ca_(0.33)MnO_3/LaMnO_3/SrTiO_3:0.05 wt% N...The interfacial electrical potentials and charge distributions of two manganite-based heterojunctions, i.e.,La_(0.67)Ca_(0.33)MnO_3/SrTiO_3:0.05 wt% Nb(LCMO/STON) and La_(0.67)Ca_(0.33)MnO_3/LaMnO_3/SrTiO_3:0.05 wt% Nb(simplified as LCMO/LMO/STON), are studied by means of off-axis electron holography in a transmission electron microscope.The influences of buffer layer on the microstructure and magnetic properties of the LCMO films are explored. The results show that when a buffer layer of LaMnO_3 is introduced, the tensile strain between the STON substrate and LCMO film reduces, misfit dislocation density decreases near the interfaces of the heterojunctions, and a positive magnetoresistance is observed. For the LCMO/STON junction, positive and negative charges accumulate near the interface between the substrate and the film. For the LCMO/LMO/STON junction, a complex charge distribution takes place across the interface, where notable negative charges accumulate. The difference between the charge distributions near the interface may shed light on the observed generation of positive magnetoresistance in the junction with a buffer layer.展开更多
In this paper the charge transfer and variation of potential distribution upon formation of 4, 4'-bipyridine molecular junction have been investigated by applying hybrid density-functional theory (B3LYP) at ab init...In this paper the charge transfer and variation of potential distribution upon formation of 4, 4'-bipyridine molecular junction have been investigated by applying hybrid density-functional theory (B3LYP) at ab initio level. The numerical results show that there exist charge-accumulation and charge-depletion regions located at respective inside and outside of interfaces. The variation of potential distribution is obvious at interfaces. When distance between electrodes is changed, the charge transfer and variation of potential distribution clearly have distance-dependent performance. It is demonstrated that the contact structure between the molecule and electrodes is another key factor for dominating the properties of molecular junction. The qualitative explanation for experimental results is suggested.展开更多
基金Supported by the National Natural Science Foundation of China(41365008)Science and Technology Foundation of Guizhou Province,China(QKHJZ[2013]2187)+1 种基金Forestry Research Project of Guizhou ProvinceChina(QLKHJZ[2013]05)~~
文摘[Objective] The study aims to discuss the changes of potential evapotran- spiration and its sensitivity to meteorological factors in Guizhou Province, so as to provide important references for assessment of water resources, research of agri- cultural water conservancy and climate change. [Method] Temporal and spatial dis- tribution characteristics of potential evapotranspiration in Guizhou Province from 1961 to 2010 were analyzed, and the sensitivity of potential evapotranspiration to meteo- rological factors in Guizhou Province was studied through correlation analysis. [Re- sult] On the whole, potential evapotranspiration in Guizhou Province was higher in the southwest and the west compared with the northeast and the east. In various seasons, it was the highest in summer, followed by spring and autumn, while it was the lowest in winter. In recent 40 years, annual potential evapotranspiration showed an obvious decreasing trend in most stations of Guizhou Province. The main meteo- rological factors influencing changes of potential evapotranspiration in Guizhou Province were sunshine duration, daily maximum temperature, and daily average relative humidity. [Conclusion] Daily average temperature was not the main meteoro- logical factor affecting changes of potential evapotranspiration in Guizhou Province, while sunshine duration, daily maximum temperature, and daily average relative hu- midity had important effects on potential evapotranspiration in Guizhou Province.
文摘By calculating the energy distribution of electrons reaching the photocathode surface and solving the Schrodinger equation that describes the behavior of an electron tunneling through the surface potential barrier,we obtain an equation to calculate the emitted electron energy distribution of transmission-mode NEA GaAs photocathodes. Accord- ing to the equation,we study the effect of cathode surface potential barrier on the electron energy distribution and find a significant effect of the barrier-Ⅰ thickness or end height,especially the thickness,on the quantum efficiency of the cath- ode. Barrier Ⅱ has an effect on the electron energy spread, and an increase in the vacuum level will lead to a narrower electron energy spread while sacrificing a certain amount of cathode quantum efficiency. The equation is also used to fit the measured electron energy distribution curve of the transmission-mode cathode and the parameters of the surface barri- er are obtained from the fitting. The theoretical curve is in good agreement with the experimental curve.
文摘Although high resolution can be provided by electrical logging, the measured electrical log range is narrow and is limited to near the well. Borehole-surface electric potential measurements are able to detect a wide enough range but its resolution is limited, particularly for reservoirs with complex oil and water distribution or complicated structure. In this study, we attempt to accurately locate the 3-D reservoir water and oil distribution by combining borehole-surface and crosswell electric potentials. First, the distributions of oil and water in both vertical and horizontal directions are detected by the borehole-surface and erosswell electric potential methods, respectively, and then the measured crosswell potential result is used to calibrate the measured borehole-surface electric potential data to improve vertical resolution so that the residual oil distribution is determined in a lower half-space with three dimensions. The evaluation of residual oil distribution is obtained by investigation of differences between the simulation results of the reservoir with and without water flooding. The finite difference numerical simulation results prove that the spatial residual oil distribution can be effectively determined by combining the crosswell and borehole-surface electric potentials.
文摘Nanobubble flotation technology is an important research topic in the field of fine mineral particle separation.The basic characteristics of nanobubbles,including their size,concentration,surface zeta potential,and stability have a significant impact on the nanobubble flotation performance.In this paper,bulk nanobubbles generated based on the principle of hydrodynamic cavitation were investigated to determine the effects of different parameters(e.g.,surfactant(frother)dosage,air flow,air pressure,liquid flow rate,and solution pH value)on their size distribution and zeta potential,as measured using a nanoparticle analyzer.The results demonstrated that the nanobubble size decreased with increasing pH value,surfactant concentration,and cavitation-tube liquid flow rate but increased with increasing air pressure and increasing air flow rate.The magnitude of the negative surface charge of the nanobubbles was positively correlated with the pH value,and a certain relationship was observed between the zeta potential of the nanobubbles and their size.The structural parameters of the cavitation tube also strongly affected the characteristics of the nanobubbles.The results of this study offer certain guidance for optimizing the nanobubble flotation technology.
基金Project supported by the National Key Research and Development Program of China(Grant Nos.2016YFA0300600 and 2016YFA0301500)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant Nos.XDB07030000 and XDBS32000000)+1 种基金the National Natural Science Foundation of China(Grant Nos.11474347 and 31730039)the Fund from the Ministry of Science and Technology of China(Grant No.2015CB351701)
文摘We observed the steady-state visually evoked potential(SSVEP) from a healthy subject using a compact quad-channel potassium spin exchange relaxation-free(SERF) optically pumped magnetometer(OPM). To this end, 30 s of data were collected, and SSVEP-related magnetic responses with signal intensity ranging from 150 fT to 300 f T were observed for all four channels. The corresponding signal to noise ratio(SNR) was in the range of 3.5–5.5. We then used different channels to operate the sensor as a gradiometer. In the specific case of detecting SSVEP, we noticed that the short channel separation distance led to a strongly diminished gradiometer signal. Although not optimal for the case of SSVEP detection, this set-up can prove to be highly useful for other magnetoencephalography(MEG) paradigms that require good noise cancellation.Considering its compactness, low cost, and good performance, the K-SERF sensor has great potential for biomagnetic field measurements and brain-computer interfaces(BCI).
基金Under the auspices of the National Natural Science Foundation of China (No. 40171089), Knowledge InnovationProgram of Chinese Academy of Sciences (No. KZCX1-SW-19-4-01) and National Basic Research Program of China (No.2004CB418507)
文摘The horizontal and vertical distribution characteristics of Pb in urban soil of Shenyang City, China were investigated in this study. The range of Pb concentration in the soil was 22.02-2910.60mg/kg. The standard deviation was 443.07mg/kg, and coefficient of variation was 1.64. Tiexi District was seriously contaminated by lead. In general, Pb concentration in the soil decreased with distance from pollution source. Lead concentration varied in different functional areas with the order of industrial area>commercial area>residential area>suburb>reference area. Pb concentration decreased with the depth of soil profile. Both geo-accumulation index and ecological risk index were used to estimate the potential risk of soil Pb pollution in Shenyang City. The results showed that the high potential risk area included Tiexi District and traffic roads.
文摘Alien invasive species represent a severe risk to biodiversity and economy, as in the case of fire blight (Erwinia amylovora), a bacterial disease that originated in North America, which may be released into new locations by means of fruit trade. On the basis of the knowledge of Erwinia amylovora's biophysical characteristics and environmental data, the geographic information system (GIS) has been applied to determine areas where Erwinia amylovora can potentially invade China. Temperature and precipitation, during the blossoming period, are considered to be two critical factors affecting the Erwinia amylovora's suitable climatic zones. This spatial modeling approach was validated from a case study in Europe, where the occurrence of Erwinia amylovora has been proven. The model prediction agreed with the occurrence of the bacteria recorded in Europe, and the same procedure has been applied to produce a potential establishment area in China's two preferential apple cultivation regions, Bohai Bay region and Huangtu Altiplano region. It has been found that areas belonging to the high-risk category are more or less the main apple producing areas, accounting for their great economic importance in China. This methodology provides an initial baseline for assessment, prevention, and management of alien species that may become invasive under certain environmental conditions. In addition, this modeling approach provides a tool for policy makers to use, in making decisions on management practices where alien species are involved.
基金Under the auspices of National Basic Research Program of China (No.2010CB951704)Institutional Consolidation for Coordinated and Integrated Monitoring of Natural Resources towards Sustainable Development and Environmental Conservation in the Hindu Kush-Karakoram-Himalaya Mountain Complex (No.76444-000)External Cooperation Program of Chinese Academy of Sciences (No.GJHZ0954)
文摘Tibetan spruce (Picea smithiana) is an endemic species of the Himalayas,and it distributes only in a re-stricted area with very low number.To address the lack of detailed distributional information,we used maximum en-tropy (Maxent) niche-based model to predict the species' potential distribution from limited occurrence-only records.The location data of P.smithiana,relative bioclimatic variables,vegetation data,digital elevation model (DEM),and the derived data were analyzed in Maxent.The receiver operating characteristic (ROC) curve was applied to assess the prediction accuracy.The Maxent jackknife test was performed to quantify the training gains from data layers and the response of P.smithiana distribution to four typical environmental variables was analyzed.Results show that the model performs well at the regional scale.There is a potential for continued expansion of P.smithiana population numbers and distribution in China.P.smithiana potentially distributes in the lower reaches of Gyirong Zangbo and Poiqu rivers in Gyirong and Nyalam counties in Qomolangma (Mount Everest) National Nature Preserve (QNNP),China.The species prefers warm temperate climate in mountain area and mainly distributes in needle-leaved evergreen closed to open forest and mixed forest along the river valley at relatively low altitudes of about 2000-3000 m.Model simulations suggest that distribution patterns of rare species with few species numbers can be well predicted by Max-ent.
基金supported by the National Key R&D Program of China(2017YFC1200600 and 2016YFC1202104)the Innovation Team of Modern Agricultural Industry Generic Key Technology R&D of Guangdong Province,China(2019KJ134)+1 种基金the Open Fund of the Guangxi Key Laboratory of Biology for Crop Diseases and Insect Pests,China(2016-KF-3)A student scholarship was provided by the Harry Butler Institute,Murdoch University,Australia。
文摘Bactrocera bryoniae and Bactrocera neohumeralis are highly destructive and major biosecurity/quarantine pests of fruit and vegetable in the tropical and subtropical regions in the South Pacific and Australia.Although these pests have not established in China,precautions must be taken due to their highly destructive nature.Thus,we predicted the potential geographic distribution of B.bryoniae and B.neohumeralis across the world and in particular China by ecological niche modeling of the Maximum Entropy(Max Ent)model with the occurrence records of these two species.Bactrocera bryoniae and B.neohumeralis exhibit similar potential geographic distribution ranges across the world and in China,and each species was predicted to be able to distribute to over 20%of the globe.Globally,the potential geographic distribution ranges for these two fruit fly species included southern Asia,the central and the southeast coast of Africa,southern North America,northern and central South America,and Australia.While within China,most of the southern Yangtze River area was found suitable for these species.Notably,southern China was considered to have the highest risk of B.bryoniae and B.neohumeralis invasions.Our study identifies the regions at high risk for potential establishment of B.bryoniae and B.neohumeralis in the world and in particular China,and informs the development of inspection and biosecurity/quarantine measures to prevent and control their invasions.
基金This study was supported by the funds from Sino-Africa Joint Research Center,CAS,China(Y323771W07 and SAJC201322)National Natural Science Foundation of China(31800176).
文摘Madagascar,a globally renowned biodiversity hotspot characterized by high rates of endemism,is one of the few remaining refugia for many plants and animal species.However,global climate change has greatly affected the natural ecosystem and endemic species living in Madagascar,and will likely continue to influence species distribution in the future.Madagascar is home to six endemic baobab(Adansonia spp.,Bombacoideae[Malvaceae])species(Adansonia grandidieri,A.suarezensis,A.madagascariensis,A.perrieri,A.rubrostipa,A.za),which are remarkable and endangered plants.This study aimed to model the current distribution of suitable habitat for each baobab species endemic to Madagascar and determine the effect that climate change will have on suitable baobab habitat by the years 2050 and 2070.The distribution was modeled using MaxEnt based on locality information of 245 occurrence sites of six species from both online database and our own field work.A total of seven climatic variables were used for the modeling process.The present distribution of all six Madagascar's baobabs was largely influenced by temperature-related factors.Although both expansion and contraction of suitable habitat are predicted for all species,loss of original suitable habitat is predicted to be extensive.For the most widespread Madagascar baobab,A.za,more than 40%of its original habitat is predicted to be lost because of climate change.Based on these findings,we recommend that areas predicted to contract in response to climate change should be designated key protection regions for baobab conservation.
基金funded through the EU 7th framework projects S2BIOM(grant agreement 608622)Trees4Future(grant agreement 284181)+1 种基金OPERAs(grant agreement 308393)the Bio Based Industries Joint Undertaking under the EU's H2020 through the TECH4EFFECT project(grant agreement 720757)
文摘Background: European forests are considered a crucial resource for supplying biomass to a growing bio-economy in Europe. This study aimed to assess the potential availability of forest biomass from European forests and its spatial distribution. We tried to answer the questions(i) how is the potential forest biomass availability spatially distributed across Europe and(ii) where are hotspots of potential forest biomass availability located?Methods: The spatial distribution of woody biomass potentials was assessed for 2020 for stemwood, residues(branches and harvest losses) and stumps for 39 European countries. Using the European Forest Information SCENario(EFISCEN) model and international forest statistics, we estimated the theoretical amount of biomass that could be available based on the current and future development of the forest age-structure, growing stock and increment and forest management regimes. We combined these estimates with a set of environmental(site productivity, soil and water protection and biodiversity protection) and technical(recovery rate, soil bearing capacity) constraints, which reduced the amount of woody biomass that could potentially be available. We mapped the potential biomass availability at the level of administrative units and at the 10 km × 10 km grid level to gain insight into the spatial distribution of the woody biomass potentials.Results: According to our results, the total availability of forest biomass ranges between 357 and 551 Tg dry matter per year. The largest potential supply of woody biomass per unit of land can be found in northern Europe(southern Finland and Sweden, Estonia and Latvia), central Europe(Austria, Czech Republic, and southern Germany),Slovenia, southwest France and Portugal. However, large parts of these potentials are already used to produce materials and energy. The distribution of biomass potentials that are currently unused only partially coincides with regions that currently have high levels of wood production.Conclusions: Our study shows how the forest biomass potentials are spatially distributed across the European continent, thereby providing insight into where policies could focus on an increase of the supply of woody biomass from forests. Future research on potential biomass availability from European forests should also consider to what extent forest owners would be willing to mobilise additional biomass from their forests and at what costs the estimated potentials could be mobilised.
基金supported by the National Key R&D Program of China(2021YFC2600400 and 2021YFD1400100)。
文摘Global food security is threatened by the impacts of the spread of crop pests and changes in the complex interactions between crops and pests under climate change.Schrankia costaestrigalis is a newly-reported potato pest in southern China.Early-warning monitoring of this insect pest could protect domestic agriculture as it has already caused regional yield reduction and/or quality decline in potato production.Our research aimed to confirm the potential geographical distributions(PGDs)of S.costaestrigalis in China under different climate scenarios using an optimal MaxEnt model,and to provide baseline data for preventing agricultural damage by S.costaestrigalis.Our findings indicated that the accuracy of the optimal MaxEnt model was better than the default-setting model,and the minimum temperature of the coldest month,precipitation of the driest month,precipitation of the coldest quarter,and the human influence index were the variables significantly affecting the PGDs of S.costaestrigalis.The highly-and moderately-suitable habitats of S.costaestrigalis were mainly located in eastern and southern China.The PGDs of S.costaestrigalis in China will decrease under climate change.The conversion of the highly-to moderately-suitable habitat will also be significant under climate change.The centroid of the suitable habitat area of S.costaestrigalis under the current climate showed a general tendency to move northeast and to the middle-high latitudes in the 2030s.The agricultural practice of plastic film mulching in potato fields will provide a favorable microclimate for S.costaestrigalis in the suitable areas.More attention should be paid to the early warning and monitoring of S.costaestrigalis in order to prevent its further spread in the main areas in China’s winter potato planting regions.
基金partially funded by the National Council of Science and Technology, Mexico (PhD scholarship 436041)the Cactus and Succulent Society of America grantsupported by the Educational Professional Development Program (#UAA-PTC-169) granted to the corresponding author by the Public Education Department and the Autonomous University of Aguascalientes, Mexico
文摘Talinopsis frutescens(Anacampserotaceae,a family that is close related to Cactaceae)is a succulent species endemic to North America.The aim of this study was to explore,using Ecological Niche Modeling(ENM),changes in potential distribution ranges considering different climate scenarios:past conditions during the Last Inter Glacial(LIG)and the Last Glacial Maximum(LGM),the present and projections for 2070(RCP 2.6 to 8.5).A pattern of contraction is observed during the LIG,which agrees with other studies focused in species from arid environments.This pattern was followed by a migration towards the south during the LGM and a possible recent expansion to the north as is observed in the present scenario.All future projections show the same contraction and fragmentation patterns,resulting in three discontinuous areas:the northern part of the Chihuahuan Desert,the southern-central part of the Mexican Plateau,and the smallest one in the Tehuacán-Cuicatlán Valley.Our projections for future scenarios agree with other studies and support that global climate change tends to alter the current distribution of arid environment species.
基金performed in the framework of the National Science Fund for Distinguished Young Scholars(31700370)。
文摘Due to the influence of human activities such as cultivation and urban construction,the ecosystem of the Yellow River Basin(YRB)is subjected to increased vulnerability and even potential risk of destruction.Ecological restoration has led to an increase in vegetation,but excessive afforestation conversely results in low survival rate of trees,water shortages,and biodiversity loss.It is of great significance for achieving sustainable development of forests to reasonable revegetation in the region.At present,the potential distribution pattern of dominant species and their mixed forms in the basin has not been effectively studied.This study simulated the potential distribution of dominant vegetation in the YRB based on Maximum Entropy(Max Ent)and Genetic Algorithm for Rule-Set Prediction(GARP)and explored the impact of human interference on it by employing land use as the environmental filter to distinguish the regions of human activities.We further predicted the potential distribution of typically mixed forests and discussed their human interference.The main results are as follows:(1)Except for Caragana korshinskii,all models had good above performance(0.7<the mean AUC<1).Except for Caragana korshinskii,the area under the curve(AUC)for 90%of the models indicated that Max Ent performed better than GARP,and Max Ent easily lead to over-fitting while GARP predicted a wider range.(2)Except for Nitraria tangutorum,the dominant types of vegetation such as Pinus tabulaeformis,Platycladus orientalis,and Hippophae rhamnoides mainly distributed in southern Gansu,Shaanxi,and south-central Shanxi.Among them,the largest suitable area of Artemisia gmelinii and Stipa bungeana(High suitable area)were approximately 56.7×104 km2(38.8%)and 54.7×104 km2(28.5%)with the area occupied by large-scale cultivation being 17.5×104 km2(39.4%)and 18.9×104 km2(48%),respectively,which indicated human activities caused great damage to the core growth regions of these vegetation.(3)Mean temperature of coldest quarter or month mainly constrained the growth of most vegetation in the YRB in terms of temperature,while precipitation of wettest/driest month is one of the dominant factors.However,some vegetation responded differently to other meteorological factors due to niche differences.(4)Most of the mixed forests were distributed in southern Gansu,Shaanxi,and Shanxi provinces;its middle and high suitable areas were mainly concentrated in Shaanxi and southern and central Shanxi,where the cultivated land had occupied most of them.Therefore,the results showed that the restoration of herbaceous vegetation such as Artemisia gmelinii and Stipa bungeana has a high potential and it is appropriate that the measures for afforestation should be concentrated in the areas like the lower reaches of the Weihe,Jinghe,and Beiluo rivers and Luliang Mountain,where the cultivated land overlaps with the high suitable areas of the corresponding vegetation and the mixed forests with less water consumption and wide distribution,such as Caragana korshinskii-Hippophae rhamnoides,Pinus tabulaeformis-Quercus liaotungensis,and Ostryopsis davidiana-Stipa bungeana-Hippophae rhamnoides.The results of this study can provide effective guidance for mixed forest plantations and vegetation conservation in the YRB.
基金Supported by the Impact and Response of Antarctic Seas to Climate Change from Polar Research Institute of China(No.RFSOCC2020-2022-No.18)the National Science Foundation of Tianjin(No.19JCZDJC40600)the National Natural Science Foundation of China(No.42176198)。
文摘Antarctic krill is the key species of ecological system in the Amundsen Sea.At present,the suitable distribution is unobtainable by scientifi c surveys or data from the fi shery.In this paper,the maximum entropy algorithm(Maxent)was used to obtain the potential distribution of adult Antarctic krill in order to provide useful information and reasonable reference for the policy on protecting potential krill habitats around the Amundsen Sea.Occurrence points and 17 environmental variables were used to simulate the distributions.Results show that the high and moderate suitable habitats lie between 65°S and 72°S in the Amundsen Sea.The high suitable habitat accounts for 8.1%of the total area of the Amundsen Sea.The sea ice persistence(ICE),total phytoplankton(PHYC),and the minimum value of dissolved iron(Fe_min)are the three dominant contributors to the model.Results from the response curves show that Antarctic krill preferred habitats with ICE of 0.42-0.93,PHYC of 2.48-2.77 mmol/m^(3) and Fe_min of(7.10×10^(-5))-(9.45×10^(-5))mmol/m 3.Positive trends existed in the PHYC of the high and moderate suitable habitat,and a positive trend existed in the Fe_min of moderate suitable habitat.However,the probability of presence of Antarctic krill will decrease if the increase of the PHYC and Fe_min continues.
文摘DC magnetic biasing problem,caused by the DC grounding electrode, threatened the safe operation of AC power grid. In this paper, the characteristics of the soil stratification near DC grounding electrode was researched. The AC-DC interconnected large-scale system model under the monopole operation mode was established. The earth surface potential and DC current distribution in various stations under the different surface thickness was calculated. Some useful conclusions are drawn from the analyzed results.
基金The Xiamen Youth Innovation Fund under contract No.3502Z20206096the National Key Research and Development Program of China under contract No.2019YFE0124700+1 种基金the National Natural Science Foundation of China under contract Nos 42176153,41906127,and 42076163the National Program on Global Change and Air-Sea Interaction under contract No.HR01-200701.
文摘Climate change has affected and will continue to affect the spatial distribution patterns of marine organisms.To understand the impact of climate change on the distribution patterns and species richness of the Sciaenidae in China’s coastal waters,the maximum entropy model was used to combine six environmental factors and predict the potential distribution of 12 major species of Sciaenidae by 2050s under Representative Concentration Pathways(RCPs)2.6 and 8.5.The results showed that the average area under the receiver operating characteristic curve of the model was 0.917,indicating that the model predictions were accurate and reliable.The main driving factors affecting the potential distribution of these fishes were dissolved oxygen,salinity,and sea surface temperature(SST).There was an overall northward shift in the potential habitat areas of these fishes under the two climate scenarios.The total potential habitat areas of Larimichthys polyactis,Pennahia argentata,and Pennahia pawak decreased under both climate scenarios,while the total habitat area of Johnius belengerii,Pennahia anea,Miichthys miiuy,Collichthys lucidus,and Collichthys niveatus increased,suggesting that these might be loser and winner species,respectively.The expansion rate,contraction rate,degree of centroid change,and species richness in the potential habitats were generally more significant under RCP8.5 than RCP2.6.The mean shift rates of the potential distribution were 41.50 km/(10 a) and 29.20 km/(10 a) under RCP8.5 and RCP2.6,respectively.The changes in Sciaenidae species richness under climate change were bounded by the Changjiang River Estuary waters,with obvious north-south differences.Some waters with increased species richness may become refuges for Sciaenidae fishes under climate change.The richness and habitat area change rate of some aquatic germplasm resources will decrease,meanings that these reserves are more sensitive to climate change,and more attention should be paid to the potential challenges and opportunities for fishery managers.This study may provide a scientific basis for the management and conservation of Sciaenidae in China under climate change.
基金Natural Science Foundation of Guangdong Province (No. 36566)
文摘The adsorption isotherms of four activated carbons (Norit Rill, Chemviron BPL, Monolit, and Ambersorb-572) have been examined by nitrogen adsorption at 77.5 K. A method for adsorption potential distribution calculation has been proposed based on the adsorption isotherms. This distribution provides information about possible changes in the Gibbs free energy caused by the energetic and geometrical heterogeneities of an activated carbon as well as by the adsorbate-related entropic effects. The general character of the adsorption potential distribution is clearly visible by its simple relation to the micropore and mesopore distribution,
基金Project supported by the National Natural Science Foundation of China(Grant No.10974105)the High-end Foreign Experts Recruitment Programs,China(Grant Nos.GDW20173500154 and GDW20163500110)+3 种基金the Taishan Scholar Program of Shandong ProvinceShandong Province "Double–Hundred Talent Plan" on 100 Foreign Experts and 100 Foreign Expert Teams Introduction Projectthe Top-notch Innovative Talent Program of Qingdao City,China(Grant No.13-CX-08)the Qingdao International Center for Semiconductor Photoelectric Nanomaterials,and Shandong Provincial University Key Laboratory of Optoelectrical Material Physics and Devices
文摘The interfacial electrical potentials and charge distributions of two manganite-based heterojunctions, i.e.,La_(0.67)Ca_(0.33)MnO_3/SrTiO_3:0.05 wt% Nb(LCMO/STON) and La_(0.67)Ca_(0.33)MnO_3/LaMnO_3/SrTiO_3:0.05 wt% Nb(simplified as LCMO/LMO/STON), are studied by means of off-axis electron holography in a transmission electron microscope.The influences of buffer layer on the microstructure and magnetic properties of the LCMO films are explored. The results show that when a buffer layer of LaMnO_3 is introduced, the tensile strain between the STON substrate and LCMO film reduces, misfit dislocation density decreases near the interfaces of the heterojunctions, and a positive magnetoresistance is observed. For the LCMO/STON junction, positive and negative charges accumulate near the interface between the substrate and the film. For the LCMO/LMO/STON junction, a complex charge distribution takes place across the interface, where notable negative charges accumulate. The difference between the charge distributions near the interface may shed light on the observed generation of positive magnetoresistance in the junction with a buffer layer.
基金Project supported by the National Natural Science Foundation of China (Grant No 10674084), the Natural Science Foundation of Shandong Province, China (Grant No Y2004A08) and the Doctorate Foundation of the State Education Ministry of China (Grant No 20040445001).
文摘In this paper the charge transfer and variation of potential distribution upon formation of 4, 4'-bipyridine molecular junction have been investigated by applying hybrid density-functional theory (B3LYP) at ab initio level. The numerical results show that there exist charge-accumulation and charge-depletion regions located at respective inside and outside of interfaces. The variation of potential distribution is obvious at interfaces. When distance between electrodes is changed, the charge transfer and variation of potential distribution clearly have distance-dependent performance. It is demonstrated that the contact structure between the molecule and electrodes is another key factor for dominating the properties of molecular junction. The qualitative explanation for experimental results is suggested.