We report a systematic study on layered metal SrCu_(4-x)P_(2) single crystals via transport, magnetization, thermodynamic measurements and structural characterization. We find that the crystals show large linear magne...We report a systematic study on layered metal SrCu_(4-x)P_(2) single crystals via transport, magnetization, thermodynamic measurements and structural characterization. We find that the crystals show large linear magnetoresistance without any sign of saturation with a magnetic field up to 30T. We also observe a phase transition with significant anomalies in resistivity and heat capacity at T_(p)~140 K. Thermal expansion measurement reveals a subtle lattice parameter variation near Tp, i.e.,?L_(c)/L_(c)~0.062%. The structural characterization confines that there is no structure transition below and above T_(p). All these results suggest that the nonmagnetic transition of SrCu_(4-x)P_(2) could be associated with structural distortion.展开更多
Aiming at the problem of the surface accuracy and electrical performance of the antenna in space environment are reduced due to thermal deformation caused by temperature load. This paper presents a method to compensat...Aiming at the problem of the surface accuracy and electrical performance of the antenna in space environment are reduced due to thermal deformation caused by temperature load. This paper presents a method to compensate the thermally induced shape distortion of antenna reflector by actively adjusting actuators in order to improve the electrical performance. The adjustment of each actuator is related to the local deformation of the panel. Then, taking a space deployable antenna with a diameter of 5 meters as an example, the finite element model is established. According to the range of the temperature variation in space (<span style="white-space:nowrap;">−</span>180<span style="white-space:nowrap;">°</span>C - 200<span style="white-space:nowrap;">°</span>C), different temperature loads are applied to the antenna. The variation of electrical properties and surface accuracy is analyzed and the worst working condition is determined, and the antenna is compensated based on this condition. Then, four different electrical performance parameters are used as the optimization objectives, and the electromechanical coupling optimization model is established, and the PSO algorithm is used to optimize the actuators adjustments. The results show that the method can effectively improve the electrical performance of the deformed reflector antenna.展开更多
Heat treated steel components often suffer distortion and residual stress effects when cooled to room temperature. A numerical analysis of a vacuum gas quenched die block made of H 13 was carried out utilising a nonli...Heat treated steel components often suffer distortion and residual stress effects when cooled to room temperature. A numerical analysis of a vacuum gas quenched die block made of H 13 was carried out utilising a nonlinear thermoelastic-plastic stress model together with the fluid flow and thermal profiles within the furnace. Simulation procedures for stress behaviour of the die were developed for both direct quench and marquench processes. Results of the initial thermal analysis indicated that the temperature difference between the surface and core of the die during direct quenching (gas pressure is 4 bar) was larger than that due to marquenching ( gas pressure is 4 bar at the beginning and 2 bar near isothermal hold). Simulation of the cooling rates at the surface and core of the die during marquenching correlated well with the experimental data. Further stress simulation indicated that the final thermal distortion and residual stresses in the die after direct quenching were larger than those due to marquenching. The findings of the numerical analysis suggested that marquenching is recommended for this die because it could reduce the temperature difference in the die and thus result in less thermal distortion and residual stresses.展开更多
To prevent buckling distortions of thin-walled elements, Low Stress No Distortion welding techniques have been pioneered and developed for product engineering and component manufacturing of aerospace structures with m...To prevent buckling distortions of thin-walled elements, Low Stress No Distortion welding techniques have been pioneered and developed for product engineering and component manufacturing of aerospace structures with material thickness less than 4 mm. In this paper, the nature of Low Stress No Distortion (LSND) welding techniques using thermal tensioning effects is described and special emphases are given to the mechanism of localized thermal tensioning effect. The fundamental principle of Low Stress No Distortion welding is to create active in-process control of incompatible (inherent) plastic strains and stresses formation during welding to achieve distortion-free results implying that no post weld costly reworking operations for distortion correction is required. Finite element analysis is applied to predict and optimize the localized thermal tensioning technique with a trailing spot heat sink coupled to the welding heat source. Comparisons of the thermal elastic-plastic stress-strain cycles are given between conventional gas tungsten arc welding and GTAW with a trailing spot heat sink.展开更多
The welding buckling distortions of thin plated structures were investigated based on finite element methods.An engineering treatment method for predicationg the buckling distortion was proposed.The equivalent applie...The welding buckling distortions of thin plated structures were investigated based on finite element methods.An engineering treatment method for predicationg the buckling distortion was proposed.The equivalent applied thermal load was used to simulate the welding residual stress,thus the calculation of complex welding distortion can be transformed into 3D elastic structural applied load analyses,which can reduce the quantities of calculating work effectively.The validation of the method was verified by comparison of the numerical calculation with experimental results.The prediction of buckling distortion for side walled structures of passenger train was performed and the calculation was in agreement with measuring results in general.It is shown that the main factors for producing the buckling are the intermittent fillet and plug weld during welding the stiffened beams and columns to the panel.展开更多
The steady-state creep behavior of unidirectional C/C(1-D-C/C) composite with pyrolytic carbon matrix was investigated at high temperatures up to 2160℃ and under tensile stress from 133.83 to 213.46MPa. Based on the ...The steady-state creep behavior of unidirectional C/C(1-D-C/C) composite with pyrolytic carbon matrix was investigated at high temperatures up to 2160℃ and under tensile stress from 133.83 to 213.46MPa. Based on the creep experiment of single specimen method, the apparent activation energy and the stress exponent for steadystate creep were determined by the use of a self-made apparatus and an auto-testing system. Value of apparent activation volume is provided and the creep mechanism has also been discussed.展开更多
The effects of carbon distribution on the microstructure and thermal conductivity of ductile iron were investigated in the present study.The microstructure of as-cast and quenched ductile iron were characterized by OM...The effects of carbon distribution on the microstructure and thermal conductivity of ductile iron were investigated in the present study.The microstructure of as-cast and quenched ductile iron were characterized by OM and SEM.Results showed that the microstructure of as-cast ductile iron was composed of spheroidal graphite,ferrite with the volume of 80%,and a small amount of pearlite,and quenched ductile iron was composed of spheroidal graphite,coarse/fine acicular martensite(α_(M)phase)and high-carbon retained austenite(γphase).The volume fraction of retained austensite and its carbon content for direct quenched ductile iron and tepmered ductile iron were quantitatively analysed by XRD.Results revealed that carbon atoms diffused fromα_(M)phase toγphase during tempering at low temperatures,which resulted in carbon content in retainedγphase increasing from 1.2 wt%for the direct quenched sample to about 1.9 wt%for the tempered samples.Consequently,the lattice distortion was significantly reduced and gave rise to an increase of thermal conductivity for ductile iron.展开更多
The connecting rod is one of the most important moving components in an internal combustion engine. The present work determined the possibility of using aluminium alloy 7075 material to design and manufacture a connec...The connecting rod is one of the most important moving components in an internal combustion engine. The present work determined the possibility of using aluminium alloy 7075 material to design and manufacture a connecting rod for weight optimisation without losing the strength of the connecting rod. It considered modal and thermal analyses to investigate the suitability of the material for connecting rod design. The parameters that were considered under the modal analysis were: total deformation, and natural frequency, while the thermal analysis looked at the temperature distribution, total heat flux and directional heat flux of the four connecting rods made with titanium alloy, grey cast iron, structural steel and aluminium 7075 alloy respectively. The connecting rod was modelled using Autodesk inventor2017 software using the calculated parameters. The steady-state thermal analysis was used to determine the induced heat flux and directional heat flux. The study found that Aluminium 7075 alloy deformed more than the remaining three other materials but has superior qualities in terms of vibrational natural frequency, total heat flux and lightweight compared to structural steel, grey cast iron and titanium alloy.展开更多
长波红外差分干涉仪在低温工况下会因光学元件受到非均匀应力作用产生干涉条纹的畸变,从而降低干涉仪系统性能。本文为解决低温工况干涉条纹弯曲畸变问题,基于长波红外差分干涉仪光机系统进行了干涉条纹畸变影响因素分析,结合光-机-热...长波红外差分干涉仪在低温工况下会因光学元件受到非均匀应力作用产生干涉条纹的畸变,从而降低干涉仪系统性能。本文为解决低温工况干涉条纹弯曲畸变问题,基于长波红外差分干涉仪光机系统进行了干涉条纹畸变影响因素分析,结合光-机-热耦合分析方法,对干涉仪系统低温工作状态进行仿真。随后设计了针对影响条纹畸变的关键元件——光栅元件的低温微应力动态稳定支撑安装结构,结构优化后的光栅表面面形均方根(Root Mean Square,RMS)值为3.89×10^(-2) nm,面形峰谷值(Peak to Valley,PV)值为2.21×10^(-1) nm,分别较优化前初始系统的分析结果减小了5个数量级,系统仿真干涉条纹畸变小于1个探测器像元。全系统低温验证试验表明,优化结构可有效抑制干涉条纹畸变,畸变量小于2个探测器像元,试验与仿真计算结果一致性较好,验证了优化分析方法的有效性。该优化方案对提升反射式光学系统结构低温稳定性,提高系统工作能力有较大意义和价值。展开更多
Polyhedral distortion,associated closely with the atomic arrangement and interatomic interactions,drives many unique behaviors in solids,such as phase transition and negative thermal expansion.In thermoelectric hetero...Polyhedral distortion,associated closely with the atomic arrangement and interatomic interactions,drives many unique behaviors in solids,such as phase transition and negative thermal expansion.In thermoelectric heteroanionic oxides,the anionic polyhedra are widely present,but their effect on thermal transport is rarely investigated.Here,we report an anomalous thermal conduction induced by local symmetry distortion in layered oxyselenides via solving the Boltzmann transport equation based on first-principles calculations.We found interestingly that lighter BiCuSeO exhibits lower thermal conductivity than heavier BiAgSeO.Due to the different distorted degrees of CuSe4 and AgSe4 tetrahedrons,Cu prefers the in-plane vibration,while Ag has more tendency of out-of-plane vibration.Thus,the heat-carrying phonons dominated by the rattling-like vibration of Cu are significantly suppressed,resulting in lower thermal conductivity of BiCuSeO.This study highlights the importance of polyhedral distortion in regulating thermal conduction in layered heteroanionic materials.展开更多
Metal additive manufacturing,especially laser powder bed fusion(L-PBF),is increasingly being used to fabricate complex parts with fine features.Emerging L-PBF systems have large build volumes and several lasers that o...Metal additive manufacturing,especially laser powder bed fusion(L-PBF),is increasingly being used to fabricate complex parts with fine features.Emerging L-PBF systems have large build volumes and several lasers that op-erate simultaneously.Hence,they can produce large and complex parts at reduced costs and short build times.However,the thermal distortion remains a critical challenge.Hence,a thorough understanding of the impact of multiple lasers on part distortion in multi-laser PBF(ML-PBF)is imperative.Although experimental investigation is possible,a more conducive approach is to design and create suitable predictive models to understand the impact of multiple lasers consolidating a part into layers.To fulfill this goal,in this study,a commercially available and widely used thermo-mechanical model,Netfabb,was used to investigate the effects of multiple lasers for com-plex scan patterns such as raster,spiral,and Hilbert on the temperature distribution and thermal distortion.The results show that the thermal distortion is minimal for the spiral scan pattern.Additionally,multiple lasers were found to decrease the build time(as expected)while maintaining or reducing the thermal distortion compared with their single-laser counterparts for all scan patterns(except Hilbert).Therefore,the newly developed ML-PBF predictive model is capable of providing critical insights into the effects of using multiple lasers,thereby opening new possibilities for the faster production of complex parts.In the future,small-scale computational models will be expanded to include large-scale parts,and probabilistic models will be developed to establish correlations.展开更多
In recent years,bamboo,as a green building material,has attracted more and more attention worldwide.Inspired by the investigation of cross-laminated timber in structural systems,a new engineered cross-laminated bamboo...In recent years,bamboo,as a green building material,has attracted more and more attention worldwide.Inspired by the investigation of cross-laminated timber in structural systems,a new engineered cross-laminated bamboo(CLB)consisting of the cross lamination of bamboo scrimber plates is proposed in this paper.To evaluate its potential in structural applications,the thermal insulation performances of the CLB walls and CLB walls with the EPS foam plate were studied and evaluated by the temperature-controlled box-heat flow meter method.Test results indicated that the thermal insulation performance improved with the increase of thickness,but different wall configurations had little effect on the thermal insulation performance under the same thickness of the CLB wall.The thermal insulation performance of EPS-CLB composite wall was much better than that of CLB wall.In addition,a relatively acceptable accuracy of the theoretical calculations was proved.Finally,the influence of different locations of the EPS foam plate on heat transfer coefficient can be neglected as it was studied based on the validated numerical models.展开更多
Oxygen vacancies have a profound effect on the magnetic,electronic,and transport properties of transition metal oxides but little is known about their effect on thermal expansion.Herein we report the effect of oxygen ...Oxygen vacancies have a profound effect on the magnetic,electronic,and transport properties of transition metal oxides but little is known about their effect on thermal expansion.Herein we report the effect of oxygen defects on the structure formation and thermal expansion properties of the layered perovskite Ca2RuO4(CRO).It is shown that the CRO containing excess oxygen crystallizes in a metallic L-CRO phase without structure transition from 100 K to 500 K and displays a normal thermal expansion behavior,whereas those with oxygen vacancies adopt at room temperature an insulating S-CRO phase and exhibit an enormous negative thermal expansion(NTE)from 100 K to about 360 K,from where they undergo a structure transition to a high temperature metallic L-CRO phase.Compared to the L-CRO containing excess oxygen,the S-CRO structure has increasingly large orthorhombic strain and distinctive in-plane distortion upon cooling.The in-plane distortion of the RuO6 octahedra reaches a maximum across 260 K and then relaxes monotonically,providing a structure evidence for the appearance of an antiferromagnetic orbital ordering in the paramagnetic phase and the A_g phonon mode suppression and phase flip across the same temperature found recently.Both the L-and S-CRO display an antiferromagnetic ordering at about 150-110 K,with ferromagnetic ordering components at lower temperature.The NTE in S-CRO is a result of a complex interplay among the spin,orbital,and lattice.展开更多
Finite element (FE) modelling methods were implemented to perform a weakly-coupled weld simulation activity on a series of simple plate welds, to determine the effects of altering the frequency of saving the thermal t...Finite element (FE) modelling methods were implemented to perform a weakly-coupled weld simulation activity on a series of simple plate welds, to determine the effects of altering the frequency of saving the thermal time-step result upon the mechanical results. By definition, the thermal results will be unaffected, but the mechanical results are calculated from the saved thermal results, hence can be changed when the frequency of saving thermal time-steps is altered. By default, most weakly-coupled thermal-mechanical solvers will save every single thermal time-step, for accuracy. Results indicated that during the welding operation, the thermal time-steps could be reduced to saving 1-in-every-2 thermal time-steps with minimal loss in mechanical accuracy. However, during the cooling operation, every time-step was required to be saved. Whilst this seems almost counter-intuitive that the time-step during the cooling operation is in some way more critical than during welding, it must be stated that the FE software employed for this exercise has a setting allowing the time-steps to become progressively large during cooling, when thermal gradients are much lower and as such both thermal and mechanical calculations are easier to converge.展开更多
By placing a sample between a heated and a cooled rod, a thermal conductivity of the sample can be evaluated easily with the assumption of a one-dimensional heat flow. However, a three-dimensional constriction/spreadi...By placing a sample between a heated and a cooled rod, a thermal conductivity of the sample can be evaluated easily with the assumption of a one-dimensional heat flow. However, a three-dimensional constriction/spreading heat flow may occur inside the rods when the sample is a composite having different thermal conductivities. In order to investigate the thermal resistance due to the constriction/spreading heat flow, the three-dimensional numerical analyses were conducted on the heat transfer characteristics of the rods. In the present analyses, a polymer-based composite board having thermal vias was sandwiched between the rods. From the numerical results, it was confirmed that the constriction/spreading resistance of the rods was strongly affected by the thermal conductivity of the rods as well as the number and size of the thermal vias. A simple equation was also proposed to evaluate the constriction/spreading resistance of the rods. Fairly good agreements were obtained between the numerical results and the calculated ones by the simple equation. Moreover, the discussion was also made on an effective thermal conductivity of the composite board evaluated with the heated and the cooled rod.展开更多
We study the long-time average of the reduced density matrix(RDM)of a two-level system as the central system,which is locally coupled to a many-body quantum chaotic system as the environment,under an overall Schr?ding...We study the long-time average of the reduced density matrix(RDM)of a two-level system as the central system,which is locally coupled to a many-body quantum chaotic system as the environment,under an overall Schr?dinger evolution.A phenomenological relation among elements of the RDM is proposed for a dissipative interaction in the strong coupling regime and is tested numerically with the environment as a defect Ising chain,as well as a mixed-field Ising chain.展开更多
基金Project supported by the National Key Research and Development Program of China (Grant Nos.2023YFA1607403,2021YFA1600201,and 2022YFA1602603)the Natural Science Foundation of China (Grant Nos.U19A2093,U2032214,and U2032163)+5 种基金the Collaborative Innovation Program of Hefei Science Center,CAS (Grant No.2019HSC-CIP 001)the Youth Innovation Promotion Association of CAS (Grant No.2021117)the Natural Science Foundation of Anhui Province (No.1908085QA15)the HFIPS Director’s Fund (Grant No.YZJJQY202304)the CASHIPS Director’s Fund (Grant No.YZJJ2022QN36)supported by the High Magnetic Field Laboratory of Anhui Province。
文摘We report a systematic study on layered metal SrCu_(4-x)P_(2) single crystals via transport, magnetization, thermodynamic measurements and structural characterization. We find that the crystals show large linear magnetoresistance without any sign of saturation with a magnetic field up to 30T. We also observe a phase transition with significant anomalies in resistivity and heat capacity at T_(p)~140 K. Thermal expansion measurement reveals a subtle lattice parameter variation near Tp, i.e.,?L_(c)/L_(c)~0.062%. The structural characterization confines that there is no structure transition below and above T_(p). All these results suggest that the nonmagnetic transition of SrCu_(4-x)P_(2) could be associated with structural distortion.
文摘Aiming at the problem of the surface accuracy and electrical performance of the antenna in space environment are reduced due to thermal deformation caused by temperature load. This paper presents a method to compensate the thermally induced shape distortion of antenna reflector by actively adjusting actuators in order to improve the electrical performance. The adjustment of each actuator is related to the local deformation of the panel. Then, taking a space deployable antenna with a diameter of 5 meters as an example, the finite element model is established. According to the range of the temperature variation in space (<span style="white-space:nowrap;">−</span>180<span style="white-space:nowrap;">°</span>C - 200<span style="white-space:nowrap;">°</span>C), different temperature loads are applied to the antenna. The variation of electrical properties and surface accuracy is analyzed and the worst working condition is determined, and the antenna is compensated based on this condition. Then, four different electrical performance parameters are used as the optimization objectives, and the electromechanical coupling optimization model is established, and the PSO algorithm is used to optimize the actuators adjustments. The results show that the method can effectively improve the electrical performance of the deformed reflector antenna.
文摘Heat treated steel components often suffer distortion and residual stress effects when cooled to room temperature. A numerical analysis of a vacuum gas quenched die block made of H 13 was carried out utilising a nonlinear thermoelastic-plastic stress model together with the fluid flow and thermal profiles within the furnace. Simulation procedures for stress behaviour of the die were developed for both direct quench and marquench processes. Results of the initial thermal analysis indicated that the temperature difference between the surface and core of the die during direct quenching (gas pressure is 4 bar) was larger than that due to marquenching ( gas pressure is 4 bar at the beginning and 2 bar near isothermal hold). Simulation of the cooling rates at the surface and core of the die during marquenching correlated well with the experimental data. Further stress simulation indicated that the final thermal distortion and residual stresses in the die after direct quenching were larger than those due to marquenching. The findings of the numerical analysis suggested that marquenching is recommended for this die because it could reduce the temperature difference in the die and thus result in less thermal distortion and residual stresses.
文摘To prevent buckling distortions of thin-walled elements, Low Stress No Distortion welding techniques have been pioneered and developed for product engineering and component manufacturing of aerospace structures with material thickness less than 4 mm. In this paper, the nature of Low Stress No Distortion (LSND) welding techniques using thermal tensioning effects is described and special emphases are given to the mechanism of localized thermal tensioning effect. The fundamental principle of Low Stress No Distortion welding is to create active in-process control of incompatible (inherent) plastic strains and stresses formation during welding to achieve distortion-free results implying that no post weld costly reworking operations for distortion correction is required. Finite element analysis is applied to predict and optimize the localized thermal tensioning technique with a trailing spot heat sink coupled to the welding heat source. Comparisons of the thermal elastic-plastic stress-strain cycles are given between conventional gas tungsten arc welding and GTAW with a trailing spot heat sink.
文摘The welding buckling distortions of thin plated structures were investigated based on finite element methods.An engineering treatment method for predicationg the buckling distortion was proposed.The equivalent applied thermal load was used to simulate the welding residual stress,thus the calculation of complex welding distortion can be transformed into 3D elastic structural applied load analyses,which can reduce the quantities of calculating work effectively.The validation of the method was verified by comparison of the numerical calculation with experimental results.The prediction of buckling distortion for side walled structures of passenger train was performed and the calculation was in agreement with measuring results in general.It is shown that the main factors for producing the buckling are the intermittent fillet and plug weld during welding the stiffened beams and columns to the panel.
文摘The steady-state creep behavior of unidirectional C/C(1-D-C/C) composite with pyrolytic carbon matrix was investigated at high temperatures up to 2160℃ and under tensile stress from 133.83 to 213.46MPa. Based on the creep experiment of single specimen method, the apparent activation energy and the stress exponent for steadystate creep were determined by the use of a self-made apparatus and an auto-testing system. Value of apparent activation volume is provided and the creep mechanism has also been discussed.
基金Funded by China Postdoctoral Science Foundation(Nos.2019M653703 and 2020T130523)Xi’an University of Technology Youth Nova Fund(No.101-451320005)。
文摘The effects of carbon distribution on the microstructure and thermal conductivity of ductile iron were investigated in the present study.The microstructure of as-cast and quenched ductile iron were characterized by OM and SEM.Results showed that the microstructure of as-cast ductile iron was composed of spheroidal graphite,ferrite with the volume of 80%,and a small amount of pearlite,and quenched ductile iron was composed of spheroidal graphite,coarse/fine acicular martensite(α_(M)phase)and high-carbon retained austenite(γphase).The volume fraction of retained austensite and its carbon content for direct quenched ductile iron and tepmered ductile iron were quantitatively analysed by XRD.Results revealed that carbon atoms diffused fromα_(M)phase toγphase during tempering at low temperatures,which resulted in carbon content in retainedγphase increasing from 1.2 wt%for the direct quenched sample to about 1.9 wt%for the tempered samples.Consequently,the lattice distortion was significantly reduced and gave rise to an increase of thermal conductivity for ductile iron.
文摘The connecting rod is one of the most important moving components in an internal combustion engine. The present work determined the possibility of using aluminium alloy 7075 material to design and manufacture a connecting rod for weight optimisation without losing the strength of the connecting rod. It considered modal and thermal analyses to investigate the suitability of the material for connecting rod design. The parameters that were considered under the modal analysis were: total deformation, and natural frequency, while the thermal analysis looked at the temperature distribution, total heat flux and directional heat flux of the four connecting rods made with titanium alloy, grey cast iron, structural steel and aluminium 7075 alloy respectively. The connecting rod was modelled using Autodesk inventor2017 software using the calculated parameters. The steady-state thermal analysis was used to determine the induced heat flux and directional heat flux. The study found that Aluminium 7075 alloy deformed more than the remaining three other materials but has superior qualities in terms of vibrational natural frequency, total heat flux and lightweight compared to structural steel, grey cast iron and titanium alloy.
文摘长波红外差分干涉仪在低温工况下会因光学元件受到非均匀应力作用产生干涉条纹的畸变,从而降低干涉仪系统性能。本文为解决低温工况干涉条纹弯曲畸变问题,基于长波红外差分干涉仪光机系统进行了干涉条纹畸变影响因素分析,结合光-机-热耦合分析方法,对干涉仪系统低温工作状态进行仿真。随后设计了针对影响条纹畸变的关键元件——光栅元件的低温微应力动态稳定支撑安装结构,结构优化后的光栅表面面形均方根(Root Mean Square,RMS)值为3.89×10^(-2) nm,面形峰谷值(Peak to Valley,PV)值为2.21×10^(-1) nm,分别较优化前初始系统的分析结果减小了5个数量级,系统仿真干涉条纹畸变小于1个探测器像元。全系统低温验证试验表明,优化结构可有效抑制干涉条纹畸变,畸变量小于2个探测器像元,试验与仿真计算结果一致性较好,验证了优化分析方法的有效性。该优化方案对提升反射式光学系统结构低温稳定性,提高系统工作能力有较大意义和价值。
基金This work was financially supported by Basic Science Center Project of National Natural Science Foundation of China under grant No.51788104National Science Foundation of China under grant No.52172211+2 种基金The work at Henan Polytechnic University is supported by the Doctoral Foundation of Henan Polytechnic University(in Natural and Science)(NO.B202112)the Fundamental Research Funds for the Universities of Henan Province(NO.NSFRF220421)B.W.was partially supported by the postgraduate research opportunities program of HZWTECH(HZWTECH-PROP).
文摘Polyhedral distortion,associated closely with the atomic arrangement and interatomic interactions,drives many unique behaviors in solids,such as phase transition and negative thermal expansion.In thermoelectric heteroanionic oxides,the anionic polyhedra are widely present,but their effect on thermal transport is rarely investigated.Here,we report an anomalous thermal conduction induced by local symmetry distortion in layered oxyselenides via solving the Boltzmann transport equation based on first-principles calculations.We found interestingly that lighter BiCuSeO exhibits lower thermal conductivity than heavier BiAgSeO.Due to the different distorted degrees of CuSe4 and AgSe4 tetrahedrons,Cu prefers the in-plane vibration,while Ag has more tendency of out-of-plane vibration.Thus,the heat-carrying phonons dominated by the rattling-like vibration of Cu are significantly suppressed,resulting in lower thermal conductivity of BiCuSeO.This study highlights the importance of polyhedral distortion in regulating thermal conduction in layered heteroanionic materials.
基金supported by Defense Advanced Research Projects Agency of USA(Grant.No.D22AP00147-00).
文摘Metal additive manufacturing,especially laser powder bed fusion(L-PBF),is increasingly being used to fabricate complex parts with fine features.Emerging L-PBF systems have large build volumes and several lasers that op-erate simultaneously.Hence,they can produce large and complex parts at reduced costs and short build times.However,the thermal distortion remains a critical challenge.Hence,a thorough understanding of the impact of multiple lasers on part distortion in multi-laser PBF(ML-PBF)is imperative.Although experimental investigation is possible,a more conducive approach is to design and create suitable predictive models to understand the impact of multiple lasers consolidating a part into layers.To fulfill this goal,in this study,a commercially available and widely used thermo-mechanical model,Netfabb,was used to investigate the effects of multiple lasers for com-plex scan patterns such as raster,spiral,and Hilbert on the temperature distribution and thermal distortion.The results show that the thermal distortion is minimal for the spiral scan pattern.Additionally,multiple lasers were found to decrease the build time(as expected)while maintaining or reducing the thermal distortion compared with their single-laser counterparts for all scan patterns(except Hilbert).Therefore,the newly developed ML-PBF predictive model is capable of providing critical insights into the effects of using multiple lasers,thereby opening new possibilities for the faster production of complex parts.In the future,small-scale computational models will be expanded to include large-scale parts,and probabilistic models will be developed to establish correlations.
基金from the National Natural Research and Development Fund(9Z05000049D0)Integrated Key Precast Components and New Wood-bamboo Composite Structure(2017YFC0703502).
文摘In recent years,bamboo,as a green building material,has attracted more and more attention worldwide.Inspired by the investigation of cross-laminated timber in structural systems,a new engineered cross-laminated bamboo(CLB)consisting of the cross lamination of bamboo scrimber plates is proposed in this paper.To evaluate its potential in structural applications,the thermal insulation performances of the CLB walls and CLB walls with the EPS foam plate were studied and evaluated by the temperature-controlled box-heat flow meter method.Test results indicated that the thermal insulation performance improved with the increase of thickness,but different wall configurations had little effect on the thermal insulation performance under the same thickness of the CLB wall.The thermal insulation performance of EPS-CLB composite wall was much better than that of CLB wall.In addition,a relatively acceptable accuracy of the theoretical calculations was proved.Finally,the influence of different locations of the EPS foam plate on heat transfer coefficient can be neglected as it was studied based on the validated numerical models.
基金the National Natural Science Foundation of China(Grant Nos.11874328 and 11574276)The SXRD experiments were performed at the BL02B2 and BL04B2 of SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute(JASRI+1 种基金proposal Nos.2019A1167,2019A1095,and 2019A1340)We also acknowledge the help of Beamline Scientists Dr.Lirong Zheng(BSRF),Dr.Shogo Kawaguchi,and Dr.Koji Ohara(SPring-8).
文摘Oxygen vacancies have a profound effect on the magnetic,electronic,and transport properties of transition metal oxides but little is known about their effect on thermal expansion.Herein we report the effect of oxygen defects on the structure formation and thermal expansion properties of the layered perovskite Ca2RuO4(CRO).It is shown that the CRO containing excess oxygen crystallizes in a metallic L-CRO phase without structure transition from 100 K to 500 K and displays a normal thermal expansion behavior,whereas those with oxygen vacancies adopt at room temperature an insulating S-CRO phase and exhibit an enormous negative thermal expansion(NTE)from 100 K to about 360 K,from where they undergo a structure transition to a high temperature metallic L-CRO phase.Compared to the L-CRO containing excess oxygen,the S-CRO structure has increasingly large orthorhombic strain and distinctive in-plane distortion upon cooling.The in-plane distortion of the RuO6 octahedra reaches a maximum across 260 K and then relaxes monotonically,providing a structure evidence for the appearance of an antiferromagnetic orbital ordering in the paramagnetic phase and the A_g phonon mode suppression and phase flip across the same temperature found recently.Both the L-and S-CRO display an antiferromagnetic ordering at about 150-110 K,with ferromagnetic ordering components at lower temperature.The NTE in S-CRO is a result of a complex interplay among the spin,orbital,and lattice.
文摘Finite element (FE) modelling methods were implemented to perform a weakly-coupled weld simulation activity on a series of simple plate welds, to determine the effects of altering the frequency of saving the thermal time-step result upon the mechanical results. By definition, the thermal results will be unaffected, but the mechanical results are calculated from the saved thermal results, hence can be changed when the frequency of saving thermal time-steps is altered. By default, most weakly-coupled thermal-mechanical solvers will save every single thermal time-step, for accuracy. Results indicated that during the welding operation, the thermal time-steps could be reduced to saving 1-in-every-2 thermal time-steps with minimal loss in mechanical accuracy. However, during the cooling operation, every time-step was required to be saved. Whilst this seems almost counter-intuitive that the time-step during the cooling operation is in some way more critical than during welding, it must be stated that the FE software employed for this exercise has a setting allowing the time-steps to become progressively large during cooling, when thermal gradients are much lower and as such both thermal and mechanical calculations are easier to converge.
文摘By placing a sample between a heated and a cooled rod, a thermal conductivity of the sample can be evaluated easily with the assumption of a one-dimensional heat flow. However, a three-dimensional constriction/spreading heat flow may occur inside the rods when the sample is a composite having different thermal conductivities. In order to investigate the thermal resistance due to the constriction/spreading heat flow, the three-dimensional numerical analyses were conducted on the heat transfer characteristics of the rods. In the present analyses, a polymer-based composite board having thermal vias was sandwiched between the rods. From the numerical results, it was confirmed that the constriction/spreading resistance of the rods was strongly affected by the thermal conductivity of the rods as well as the number and size of the thermal vias. A simple equation was also proposed to evaluate the constriction/spreading resistance of the rods. Fairly good agreements were obtained between the numerical results and the calculated ones by the simple equation. Moreover, the discussion was also made on an effective thermal conductivity of the composite board evaluated with the heated and the cooled rod.
基金the Natural Science Foundation of China under Grant Nos.11275179,11535011 and 11775210the Deutsche Forschungsgemeinschaft(DFG)within the Research Unit FOR 2692 under Grant No.397107022(GE 1657/3-2)
文摘We study the long-time average of the reduced density matrix(RDM)of a two-level system as the central system,which is locally coupled to a many-body quantum chaotic system as the environment,under an overall Schr?dinger evolution.A phenomenological relation among elements of the RDM is proposed for a dissipative interaction in the strong coupling regime and is tested numerically with the environment as a defect Ising chain,as well as a mixed-field Ising chain.