Leaching of a copper flotation concentrate with ammonium persulfate in an autoclave system

The leaching behavior of a copper flotation concentrate was investigated using ammonium persulfate （APS） in an autoclave systee. The decomposition products of APS, active oxygen, and acidic medium were used to extract metals from the concentrate. Leaching experiments were performed to compare the availability of APS as an oxidizing agent for leaching of the concentrate under atmospheric conditions and in an autoclave system. Leaching temperature and APS concentration were found to be important parameters in both leaching systems. Atmospheric leaching studies showed that the metal extractions increased with the increase in APS concentration and temperature （up to 333 K）. A similar tendency was determined in the autoclave studies up to 423 K. It was also determined that the metal extractions decreased at temperatures above 423 K due to the passivation of the particle surface by molten elemental sulfur. The results showed that higher copper extractions could be achieved using an autoclave system.

Synthesis and Microstructure Analysis of Autoclaved Aerated Concrete with Carbide Slag Addition

Synthesis of autoclaved aerated concrete （AAC） has been carried out with carbide slag addition, and the carbide slag could be used as a main material to produce the AAC with the compressive strength about 2 MPa and the density below 0.6 g.cm-3. In this study, quartz sand acted as frame structure phase in the matrix, and quartz addition also influenced the Si/Ca of starting material. Tobermorite and CSH gel were formed readily at 62%, which seemed to enhance the compressive strength of samples. Curing time seemed to affect the morphology of phase produced, and specimen with the plate-like tobermorite formed at 10 h appeared to have a better compressive strength development than the fiber-like one at 18 h. The higher curing temperature seemed to favor the tobermorite and CSH gel formation, which also exerted a significant effect on the strength development of the samples. On the micro-scale, the formed CSH gel was filled in the interface of the matrix, and the tobermorite appeared to grow in internal-surface of the pores and interstices. The tobermorite or/and CSH formation seemed to densify the matrix, and therefore enhanced the strength of the samples.

Variation law of gas holdup in an autoclave during the pressure leaching process by using a mixed-flow agitator

The multiphase reaction process of pressure leaching is mainly carried out in the liquid phase. Therefore, gas holdup is essential for the gas–liquid–solid phase reaction and the extraction rate of valuable metals. In this paper, a transparent quartz autoclave, a six blades disc turbine-type agitator, and a high-speed camera were used to investigate the gas holdup of the pressure leaching process. Furthermore, experiments determining the effects of agitation rate, temperature, and oxygen partial pressure on gas holdup were carried out. The results showed that when the agitation rate increased from 350 to 600 r/min, the gas holdup increased from 0.10% to 0.64%. When the temperature increased from 363 to 423 K, the gas holdup increased from 0.14% to 0.20%. When the oxygen partial pressure increased from 0.1 to 0.8 MPa, the gas holdup increased from 0.13% to 0.19%. A similar criteria relationship was established by Homogeneous Principle and Buckingham's theorem. Comprehensively, empirical equation of gas holdup was deduced on the basis of experimental data and the similarity theory, where the criterion equation was determined as ε=4.54×10^(-11)n^(3.65)T^(2.08)P_g^(0.18). It can be seen from the formula that agitation rate made the most important impact on gas holdup in the pressure leaching process using the mixed-flow agitator.

A Review on the Utilization of Waste Material for Autoclaved Aerated Concrete Production

Autoclaved aerated concrete(AAC)has become more attractive due to its excellent and environmental-friendly properties in building construction.AAC is relatively lightweight,possesses lower thermal conductivity,higher heat resistance,lower shrinkage,and fasten construction than normal concrete.AAC is a combination of silica sand,cement,gypsum,lime,water,and an expansion agent.To improve its physical and mechanical properties and reduce its production cost,tremendous innovations where waste materials were utilized as partial replacement of AAC materials were done.This paper is intended to present the literature on the utilization of waste materials as a means of a partial replacement in AAC materials to enhance its physical and mechanical properties and thermal performance.The physical properties such as microstructure and mechanical properties such as density,compressive strength,water absorption are presented to classify the investigation that has been done in such innovations.Apart from that,the discussion on innovations to improve its thermal performance was also presented.Based on the review,an increase of AAC application causes much waste at construction sites and recycling concrete waste powder into wall concrete;particularly,an AAC was not frequently practiced in construction.

Thermal Insulation and Strength of Autoclaved Light Concrete

The primary objective of this study was to develop an autoclaved light concrete （ALC） material with ultra-thermal insulation property and to investigate the relationship between its physical characteristics and mechanical properties. Through tests of dry bulk density and compressive strength, relationship of physical characteristics and mechanical properties of samples were studied, resulting in a material with ultra-thermal insulation property. Scanning electron microscope （SEM） and energy-dispersive X-ray spectroscopy （EDX） were applied to analyze the micro-morphology and elemental composition of samples. To identify the product phases, X-ray diffraction （XRD） was engaged. The test results showed that compressive strength and thermal coefficient were reduced with the increasing of aluminum powder within the mixtures. As a result the optimal thermal coefficient and compressive strength of samples were improved to 0.061 W/（m·k） and 1.2 MPa, respectively. SEM, EDX and XRD analyses showed that calcium silicate hydrate and tobermorite crystal were main resultant phases.

A Computer-aided Design System for Framed-mould in Autoclave Processing

The general computer-aided design （CAD） software cannot meet the mould design requirement of the autoclave process for composites, because many parameters such as temperature and pressure should be considered in the mould design process, in addition to the material and geometry of the part. A framed-mould computer-aided design system （FMCAD） used in the autoclave moulding process is proposed in this paper. A function model of the software is presented, in which influence factors such as part structure, mould structure, and process parameters are considered; a design model of the software is established using object oriented （O-O） technology to integrate the stiffness calculation, temperature field calculation, and deformation field calculation of mould in the design, and in the design model, a hybrid model of mould based on calculation feature and form feature is presented to support those calculations. A prototype system is developed, in which a mould design process wizard is built to integrate the input information, calculation, analysis, data storage, display, and design results of mould design. Finally, three design examples are used to verify the prototype.

Development of in-situ Micro-Raman spectroscopy system for autoclave experimental apparatus

We developed a set of in-situ Micro-Raman spectroscopy system for autoclave experimental apparatus because of the scientific significance of in-situ Micro-Raman spectroscopy system under the high-pressure hydrothermal condition.We used this system to measure the Raman spectrum of water-fluid and quartz crystal at the temperature ranging from 125 to 420℃.The signal-tonoise ratio of the Raman signal is good.

Preparation of New Cementitious System using Fly Ash and Dehydrated Autoclaved Aerated Concrete

We experimentally studied the interaction between pozzolanic material（fly ash） and dehydrated autoclaved aerated concrete（DAAC）. The DAAC powder was obtained by grinding aerated concrete waste to particles fi ner than 75μm and was then heated to temperatures up to 900 ℃. New cementitious material was prepared by proportioning fly ash and DAAC, named as AF. X-ray diffraction（XRD） was employed to identify the crystalline phases of DAAC before and after rehydration. The hydration process of AF was analyzed by the heat of hydration and non-evaporable water content（Wn）. The experimental results show that the highest reactivity of DAAC can be obtained by calcining the powder at 700 ℃ and the dehydrated products are mainly β-C2 S and CaO. The cumulative heat of hydration and Wn was found to be strongly dependent on the replacement level of fl y ash, increasing the replacement level of fl y ash lowered them in AF. The strength contribution rates on pozzolanic effect of fl y ash in AF are always negative, showing a contrary tendency of that of cement-fl y ash system.

Impermeability Research of Autoclaved Propylene Oxide Sludge Shell-aggregate Concrete

We aimed to reuse the propylene oxide sludge(POS).Propylene oxide sludge shell-aggregate(POSS-A)and propylene oxide sludge gradient shell-aggregate(POSGS-A)whose main hydrated phase is tobermorite were successfully manufactured by the hydrothermal synthesis of POS and silica materials under the condition of autoclaved(180℃,1.0 MPa)curing.Influences of pre-wetting time of coarse aggregate and pressure application mode on the different concretes were investigated.The experimental results show that the concrete with POSS-A as coarse aggregate(POSS-A concrete),the concrete with POS gradient shell-aggregate as coarse aggregate(POSGS-A concrete),sintered aggregate concrete and common concrete,all have excellent impermeability performance whatever the pre-wetting time of coarse aggregate is 0.5 h or 24 h,and the pre-wetting time of coarse aggregate has a negligible influence on the concrete.The influence degree of pressure application mode on the impermeability performance of the sintered aggregate concrete is the greatest among three kinds of concrete,which has a negligible influence on impermeability performance of the other concretes.POSGS-A can be used as a green building light aggregate in hydraulic concrete.

Kinetics of Autoclave Curing Process on Autoclaved Aerated Concrete with Magnetite Tailings

Lightweight and energy saving autoclaved aerated concrete(AAC) acting as a newbuilding material were prepared by using magnetite tailings from iron ore as main rawmaterials,and the purpose of comprehensive utilization of tailings resources was to improve their utilization efficiency.The effects of curing system on AAC product performance were discussed.The autoclave curing reaction kinetics was studied as well as the generated amount of hydration product trends over autoclave curing temperature and time were analyzed.The results indicated that the properties of AAC was in accordance with Chinese national standard the A3.5 B06 class of GB/T11968-2006 by prepared from magnetite tailing as the main rawmaterials.Meanwhile,autoclave curing process was controlled by the diffusion velocity through the products ' layers of reactants,and the apparent activation energy of autoclave curing process was 19.269 k J/mol.Compressive strength of aerated concrete is improved by mutual cementation between the appropriate amount of calcium silicate hydrate and tobermorite crystal.

Relationship between Structural Characteristics of Fly Ash and Reactivity under Autoclave Curing

The reactivity of autoclaved materials is conventionally estimated by their chemical composition. In this paper, after determining the chemical composition of various types of fly ash, a series of new tests which included X-ray Diffraction (XRD), infrared spectral analysis (IR) and bound water testing, were applied to investigate the performance of autoclaved fly ash products. The relationship between the infrared spectral analysis of Si-O wavenumber (about 1 100 cm-1) and its autoclaved chemical reactivity, and compressive strength of its autoclaved samples, is analyzed. The results show that fly ash with a lower wavenumber will have stronger autoclaved chemical reactivity and higher compressive strength for its autoclaved sample. Thus, the Si-O stretching vibration wavelength can be used to estimate autoclaved chemical reactivity of fly ash, so as to control the quality of fly ash to be autoclaved, and to predict the compressive strength of autoclaved fly ash products.

Research on Preparation and Influencing Fctors of High Calcium High Sulfate Ash to Autoclaved Aerated Concrete

In this paper, a high calcium high sulfate ash as the main material, adding fly ash, lime, cement, gypsum and some modifiers to prepare autoclaved aerated concrete. The products complies with the technical requirements of GB/T11968-2006. This paper also studies the influence of the physical methods and water ratio on autoclaved aerated concrete by high calcium high sulfate ash aerated concrete. The best ratio of water and Grinding time were found in practice study.

Experimental Study on Improving Seismic Behavior of Load-Bearing Masonry Wall Made of Autoclaved Aerated Concrete

To investigate the seismic behavior of autoclaved aerated concrete load-bearing masonry wall(AACLMW), a piece of control block wall without constructional measures and five pieces of block walls with different constructional measures were tested under low reversed cyclic loading which imitated low to moderate earthquake force. The seismic behavior of AACLMW with different constructional measures in terms of failure mode, hysteretic curve, deformation capacity and displacement ductility was studied and compared with that without constructional measures. The experimental results indicate that the constructional measures comprising constructional columns and horizontal concrete strips are effective for improving the seismic behavior of AACLMW. The study in this paper can provide a reliable experimental basis for further analysis and engineering application of AACLMW in the future.

Effect of Autoclave Sterilisation on the Dimensional Stability and Tear Strength of Three Silicone Impression Materials

Objectives: There is a risk of spreading infectious material via non-sterile impressions. The aim of this study was to compare the effect of autoclave sterilisation on dimensional stability and tear strength of impression materials. Methods: Twenty-four specimens were produced using a standard ruled test block for each of three impression materials (Affinis, Aquasil and Speedex) to test dimensional stability. Thirty tear strips for each material were prepared for the tear test (ISO 34-1). Specimens were randomly allocated to 3 different groups (autoclaved, disinfected or untreated). A non-contact scanner was used to analyse dimensional change and a universal testing machine was used to determine tear strengths. Results: There were no significant differences in the test dimensions measured for any of the three impression materials following autoclave treatment compared to the disinfected or untreated control groups. The tear strengths were not adversely affected by autoclave sterilisation at 134°C. Conclusion: These addition and condensation-cured silicone impression materials can be steam autoclaved without adverse effects on dimensional accuracy or tear strength.

Influence of Polycarboxylic-type Admixture on the Strength of Autoclaved Aerated Concrete

The influence of polycarboxylic-type admixture on the strength of autoclaved aerated concrete（AAC） was investigated. The flexural strength and compressive strength of AAC with polycarboxylic admixture（PA） were tested. The microstructure of AAC reinforced by PA was analyzed using scanning electron microscopic（SEM） methods. The crystal structure analysis of AAC with PA was also carried out using X-ray diffraction（XRD）. The results showed that the compressive strength and flexural strength of AAC were increased by 43.9% and 42.8%, respectively, when 1.5wt% of PA was mixed. In addition, the dosage of admixture influenced the reinforcing effect. Admixture affected pore structure and surface characteristic of the products in autoclaved curing process and improved the formation of high crystallite tobermorite which led to the enhancement of the compressive and flexural strength of AAC.

Experiment and Numerical Simulation on Axial Compressive Performance of Autoclaved Fly Ash Solid Brick Masonry Columns

To study the influence of slenderness on the axial compressive performance of autoclaved fly ash solid brick masonry columns, compression experiments were conducted on 12 samples of autoclaved fly ash solid brick masonry column and 4 samples of fired clay brick masonry column. The damage patterns and compressive performance were compared and analyzed. The experimental results indicate that the compressive bearing capacity decreases as slenderness increases from 3 to 18, and the compressive bearing capacity of the autoclaved fly ash solid brick masonry columns is lower than that of the fired clay brick masonry columns. The formulae for the axial compressive bearing capacity of autoclaved fly ash solid brick masonry columns were derived based on the experiments. The nonlinear FEA program ANSYS was adopted to simulate the behaviors of masonry columns. By comparing the simulation results and experimental results, it is shown that the simulation results agree well with the experimental ones. The rationality and applicability of the simulation results were verified.

Nano-treatment of Autoclaved Aerated Concrete Waste and Its Usage in Cleaner Building Materials

Autoclaved aerated concrete waste(AACW)was used as a raw material to prepare nucleation seed for acceleration of Portland cement.Nano AACW seed with median particle size of 324 nm was prepared by wet grinding method.Both the electrical conductivity and pH value of nano AACW suspension were obviously improved.Both the setting times and intensity of the main hydration heat peak were promoted by nano AACW,indicating the possibility of AACW suspension as nucleation seed.The early age compressive strength before 3 days was also clearly improved by nano AACW,with no negative effect on the late age strength.Furthermore,the reduced CH content with dosage of nano AACW indicates that nano AACW not only plays a role of nucleation seed in cement hydration,but also has a certain pozzolanic reaction.

Utilization of Dredged River Sediment in Preparing Autoclaved Aerated Concrete Blocks

In this study,the dredged river sediment,soft texture and fine particles,is mixed with other materials and transformed into eco-friendly autoclaved aerated concrete(hereinafter referred to as AAC)blocks.The results indicated the bricks produced under the conditions of 30%–34%dredged river sediment,24%cement,10%quick lime,30%fly ash,2%gypsum and 0.09%aluminum powder with 0.5 water to material ratio,2.2 MPa autoclave pressure and 6 h autoclave time,the average compressive strength of 4.5 MPa and average dry density of 716.56 kg/m³were obtained,the two parameters(strength&density)both met the requirement of national industry standard.At the same time,the contents of dredged river sediment,cement,lime,fly ash,gypsum and aluminum powder were 15%,48%,20%,15%,2%and 0.09%,respectively,and the non-AAC block made of 0.5 water to material ratio,the average compressive strength of 3.1 MPa and average dry density of 924.19 kg/m³were obtained,the two parameters(strength&density)also met the requirement of national industry standard.In addition,the AAC block’s phase composition and morphology were micro-analyzed by SEM and XRD,the main substances in AAC block were found to be tobermorite and CSH,Among them,the chemical bond between Si-O-Si and Al-O-Al is broken,Al-O-Si is regenerated,Al substituted tobermorite with better strength is formed,and the compressive strength of AAC is further improved.

Improvement of Interlaminar Fracture Properties of Out of Autoclave Manufactured Carbon Fiber Reinforced Polymers Using Multi-Walled Carbon Nanotubes

The present study aims to the development of Out of Autoclave (OoA) Carbon Fiber Reinforced Polymers (CFRPs) with increased interlaminar fracture toughness by using MWCNTs. The introduction of MWCNTs into the structure of CFRPs has been succeeded by using carbon nanotube-enriched sizing agent for the pretreatment of the fiber preform using an in-house developed methodology that can be easily scaled up. The positive effect of the proposed methodology on the interlaminar fracture toughness of the CFRP laminate was assessed by the increase of Mode I and Mode II interlaminar fracture toughness of the composites. Different wt% MWCNTs concentrations were used (namely 0.5%, 1%, 1.5% and 2.5%). It was found that the nanomodified composites exhibit a significant increase of the interlaminar critical strain energy release rate GIC and GIIC of the order of 103% and 62% respectively, in the case of 1.5 wt% MWCNTs weight content. Scanning Electron Microscopy (SEM) of the fracture surfaces of CFRP samples revealed the contribution and the associated synergistic mechanisms of MWCNTs to the increase of the crack propagation resistance in the case of nano-modified CFRPs compared to the reference material.

A Study of Compressive, Flexural, Heat Humidity and Heat Transfer of Autoclaved Aerated Concrete Mixed Polypropylene Fiber under Climate of Bangkok

This paper presents the experimental results of study on mechanical properties, heat and humidity transfer through AAC （autoclaved aerated concrete） mixed with PP （polypropylene fiber）. The performance of AAC-PP is investigated in terms of compressive strength, flexural strength, splitting tensile strength, porosity, heat and humidity capacity. The results are compared with control specimen made of autoclaved aerated concrete only （Non-AAC-PP）. Results showed that ultimate compressive strength, flexural strength and splitting tensile strength can be obtained when the content of polypropylene fiber added at 0.75% by volume while porosity of specimens rapidly decreased when content of fiber addition increased above 1% of its volume. Additional, a comparison study of heat and humidity transfer properties on AAC-PP walls showed that the AAC-PP house had lower indoor air and moisture content than （Non-AAC-PP） house. Therefore, addition PP fiber on AAC increased mechanical properties, enhanced hygrothermal performance and reducing moisture content under tropical climate of Bangkok.