In this study, a 600 MPa hot-rolled corrosion-resistant steel plate produced by a specific company is investigated. Edge jagged defects and edge surface defects generated on both sides of the strip during production a...In this study, a 600 MPa hot-rolled corrosion-resistant steel plate produced by a specific company is investigated. Edge jagged defects and edge surface defects generated on both sides of the strip during production are characterized and analyzed. The results indicate that the distribution of reoxidation granules is located underneath the surface peel and that copper-containing granules diffuse along austenite grain boundaries. This phenomenon combined with the chemical composition and production parameters of a strip indicate that copper brittleness leads to edge jagged defects. However,the surface defects should be attributed to inherent defects on the surface of the strip. Measures that prevent surface oxidation and copper segregation at grain boundaries would likely eliminate these two types of edge defects.展开更多
The performance of concrete beams repaired with epoxy mortar was investigated by constructing twelve beam specimens.All the beam specimens were subjected to a constant current for accelerated corrosion.Six specimens w...The performance of concrete beams repaired with epoxy mortar was investigated by constructing twelve beam specimens.All the beam specimens were subjected to a constant current for accelerated corrosion.Six specimens were corroded without subsequent reparation as a control group,and the other six beam specimens were corroded and repaired utilizing epoxy mortar.All specimens were tested to failure.During test process,we focused on the failure pattern of beam specimens,structural cracks,mid-deflections,bearing capacity,and probed into the influence of corrosion degree and repair of epoxy mortar on the performance of beam specimens.It was observed that corrosion-repaired beams in the loading test were in a bending failure pattern.It is obvious that cracking loads and bending stiffness of repaired beams and corrosion-repaired beams were larger than those of unrepaired beams and secondly-corroded beams.When the mass loss of main steel bars was smaller than 10%,the bearing capacity of the repaired beams was similar to that of the unrepaired beams.When the mass loss of main steel bars was larger than 10%,the bearing capacity of the repaired beams increased significantly compared with that of the unrepaired beams.展开更多
The cause of the premature failure of 304 stainless steel tube heat exchanger was investigated.The unique skeleton structure inside the leakage point reveals that this is a new damage mechanism caused by a δ+γ two-p...The cause of the premature failure of 304 stainless steel tube heat exchanger was investigated.The unique skeleton structure inside the leakage point reveals that this is a new damage mechanism caused by a δ+γ two-phase structure and crevice corrosion.The three-dimensional structure of the leakage point was demonstrated using X-ray diffraction topography.The results of scanning electron microscope examination show the microstructure of the weld to be columnar and dendritic.It is found by electron probe microscope analysis and transmission electron microscopy that columnar dendrites consisted of γ-dendrite and an amount of δ-ferrite phases at the dendrite trunk.Simulated corrosion test results confirmed that the corrosion medium was the chloride ion.Crevice corrosion of chloride ions occurred at weld defects on the inner wall thus forming a concentration cell.Grains of columnar dendrites were then corroded by chloride ions and δ-ferrite phases on the grain boundaries were retained,which formed the particular skeleton corrosion structure.As a result,it led to leakage when the corrosion of weld occurred from the inner wall to the outer wall.展开更多
The occurrence and development mechanism of internal local corrosion has always been a controversial topic,and especially under flow conditions.In this paper,an improved high shear force loop was experimentally used,a...The occurrence and development mechanism of internal local corrosion has always been a controversial topic,and especially under flow conditions.In this paper,an improved high shear force loop was experimentally used,and local flow field is induced by simulating corrosion defects on the surface of X80 pipeline steel specimens.The characteristics of corrosion products deposited on the surface of specimens in CO2-saturated NACE solution were investigated by means of electrochemical impedance spectroscopy(EIS),scanning electron microscopy(SEM),X-ray diffraction(XRD),and energy dispersive spectrometry(EDS).The 3D micromorphology of the corrosion test surface after remove the corrosion scale used to measure the size of localized corrosion pit.Under the influence of local defects,the wall shear stress(WSS)and turbulent kinetic energy of local flow fields enhanced significantly,and pressure fluctuations in local flow field were induced.The results showed that the characteristics of surface corrosion products varied with flow velocity.The corrosion scales formed in various regions of specimens with defects exhibited different surface micro-morphologies and chemical compositions.Overall,these data offer new perspectives for better understanding the mechanisms behind local corrosion.展开更多
X65 low carbon steel was exposed to Co-60 radiation source with 1.25 MeV gamma rays, and cumulatively absorbed gamma irradiation doses（1, 2, and 3 Mgy） were obtained after different exposure time（333, 667, and 100...X65 low carbon steel was exposed to Co-60 radiation source with 1.25 MeV gamma rays, and cumulatively absorbed gamma irradiation doses（1, 2, and 3 Mgy） were obtained after different exposure time（333, 667, and 1000 h）. The effect of cumulative gamma irradiation on microstructure and corrosion behaviour of the carbon steel in unirradiated aerobic Beishan groundwater at 25℃ was investigated by using positron annihilation, scanning vibrating electrode, and electrochemical techniques. Cumulative gamma irradiation increases vacancy intensity and decreases open circuit potential（OCP） of carbon steel. They indicate that the irradiated carbon steel is activated. Measured current density distribution above the irradiated carbon steel shows that cumulative gamma irradiation accelerates localized corrosion after 0.5 h of immersion. In contrast, the analysis of electrochemical impedance spectroscopy of the irradiated carbon steel indicates that localized corrosion is transformed into general corrosion after 12 h of immersion, which is also accelerated by cumulative gamma irradiation.展开更多
Steel bar corrosion on electrolytes and the influence of cation were investigated. Three electrolytes of Ca（OH）2, NaOH and KOH with pH levels of 12.5, 11.5, 10.5, 9.5, 8.5 were prepared, meanwhile, the methods of fr...Steel bar corrosion on electrolytes and the influence of cation were investigated. Three electrolytes of Ca（OH）2, NaOH and KOH with pH levels of 12.5, 11.5, 10.5, 9.5, 8.5 were prepared, meanwhile, the methods of free corrosion potential and electrochemical impedance spectra （EIS） were used to evaluate the influence of cations on the depassivation of the steel bar in electrolytes. The experimental results indicate that the initial corrosion pH value of the steel bar is influenced by the cation in electrolyte and the influence of K＋ in electrolyte is the most remarkable, followed by Na＋ and Ca2＋. The initial corrosion pH values are 10.5 in KOH electrolyte, 9.5 in NaOH electrolyte and lower than 8.5 in Ca（OH）2 electrolyte.展开更多
文摘In this study, a 600 MPa hot-rolled corrosion-resistant steel plate produced by a specific company is investigated. Edge jagged defects and edge surface defects generated on both sides of the strip during production are characterized and analyzed. The results indicate that the distribution of reoxidation granules is located underneath the surface peel and that copper-containing granules diffuse along austenite grain boundaries. This phenomenon combined with the chemical composition and production parameters of a strip indicate that copper brittleness leads to edge jagged defects. However,the surface defects should be attributed to inherent defects on the surface of the strip. Measures that prevent surface oxidation and copper segregation at grain boundaries would likely eliminate these two types of edge defects.
基金supported by the National Natural Science Foundation of China(No.51279074)the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘The performance of concrete beams repaired with epoxy mortar was investigated by constructing twelve beam specimens.All the beam specimens were subjected to a constant current for accelerated corrosion.Six specimens were corroded without subsequent reparation as a control group,and the other six beam specimens were corroded and repaired utilizing epoxy mortar.All specimens were tested to failure.During test process,we focused on the failure pattern of beam specimens,structural cracks,mid-deflections,bearing capacity,and probed into the influence of corrosion degree and repair of epoxy mortar on the performance of beam specimens.It was observed that corrosion-repaired beams in the loading test were in a bending failure pattern.It is obvious that cracking loads and bending stiffness of repaired beams and corrosion-repaired beams were larger than those of unrepaired beams and secondly-corroded beams.When the mass loss of main steel bars was smaller than 10%,the bearing capacity of the repaired beams was similar to that of the unrepaired beams.When the mass loss of main steel bars was larger than 10%,the bearing capacity of the repaired beams increased significantly compared with that of the unrepaired beams.
文摘The cause of the premature failure of 304 stainless steel tube heat exchanger was investigated.The unique skeleton structure inside the leakage point reveals that this is a new damage mechanism caused by a δ+γ two-phase structure and crevice corrosion.The three-dimensional structure of the leakage point was demonstrated using X-ray diffraction topography.The results of scanning electron microscope examination show the microstructure of the weld to be columnar and dendritic.It is found by electron probe microscope analysis and transmission electron microscopy that columnar dendrites consisted of γ-dendrite and an amount of δ-ferrite phases at the dendrite trunk.Simulated corrosion test results confirmed that the corrosion medium was the chloride ion.Crevice corrosion of chloride ions occurred at weld defects on the inner wall thus forming a concentration cell.Grains of columnar dendrites were then corroded by chloride ions and δ-ferrite phases on the grain boundaries were retained,which formed the particular skeleton corrosion structure.As a result,it led to leakage when the corrosion of weld occurred from the inner wall to the outer wall.
基金supported by the National Natural Science Foundation of China with(No.51774314)Natural Science Foundation of Shandong Province with grant number(No.ZR2018MEM002)the Fundamental Research Funds for the Central Universities(No.19CX05001A)for financial support。
文摘The occurrence and development mechanism of internal local corrosion has always been a controversial topic,and especially under flow conditions.In this paper,an improved high shear force loop was experimentally used,and local flow field is induced by simulating corrosion defects on the surface of X80 pipeline steel specimens.The characteristics of corrosion products deposited on the surface of specimens in CO2-saturated NACE solution were investigated by means of electrochemical impedance spectroscopy(EIS),scanning electron microscopy(SEM),X-ray diffraction(XRD),and energy dispersive spectrometry(EDS).The 3D micromorphology of the corrosion test surface after remove the corrosion scale used to measure the size of localized corrosion pit.Under the influence of local defects,the wall shear stress(WSS)and turbulent kinetic energy of local flow fields enhanced significantly,and pressure fluctuations in local flow field were induced.The results showed that the characteristics of surface corrosion products varied with flow velocity.The corrosion scales formed in various regions of specimens with defects exhibited different surface micro-morphologies and chemical compositions.Overall,these data offer new perspectives for better understanding the mechanisms behind local corrosion.
基金supported by Key Research Program of Frontier Sciences,Chinese Academy of Sciences[QYZDY-SSWJSC012]National Natural Science Foundation[No.51771211]+1 种基金the National Key Research and Development Program of China[2017YFB0702100,2016YFE0105200]Key Program of the Chinese Academy of Sciences[ZDRW-CN-2017-1]
文摘X65 low carbon steel was exposed to Co-60 radiation source with 1.25 MeV gamma rays, and cumulatively absorbed gamma irradiation doses（1, 2, and 3 Mgy） were obtained after different exposure time（333, 667, and 1000 h）. The effect of cumulative gamma irradiation on microstructure and corrosion behaviour of the carbon steel in unirradiated aerobic Beishan groundwater at 25℃ was investigated by using positron annihilation, scanning vibrating electrode, and electrochemical techniques. Cumulative gamma irradiation increases vacancy intensity and decreases open circuit potential（OCP） of carbon steel. They indicate that the irradiated carbon steel is activated. Measured current density distribution above the irradiated carbon steel shows that cumulative gamma irradiation accelerates localized corrosion after 0.5 h of immersion. In contrast, the analysis of electrochemical impedance spectroscopy of the irradiated carbon steel indicates that localized corrosion is transformed into general corrosion after 12 h of immersion, which is also accelerated by cumulative gamma irradiation.
基金Funded by the National Natural Science Foundation of China(No.50978085 and 50808066)the Six Talent Peak Project (Class A) of Jiangsu Provincethe Research Funds of Hohai University for the Central Universities(No. 2010B07514)
文摘Steel bar corrosion on electrolytes and the influence of cation were investigated. Three electrolytes of Ca（OH）2, NaOH and KOH with pH levels of 12.5, 11.5, 10.5, 9.5, 8.5 were prepared, meanwhile, the methods of free corrosion potential and electrochemical impedance spectra （EIS） were used to evaluate the influence of cations on the depassivation of the steel bar in electrolytes. The experimental results indicate that the initial corrosion pH value of the steel bar is influenced by the cation in electrolyte and the influence of K＋ in electrolyte is the most remarkable, followed by Na＋ and Ca2＋. The initial corrosion pH values are 10.5 in KOH electrolyte, 9.5 in NaOH electrolyte and lower than 8.5 in Ca（OH）2 electrolyte.
