1 Scope This standard specifies the classification, technical requirements, test methods, quality appraisal procedures, packing, marking, transportation, storage and quality certificate of castables for steel rolling...1 Scope This standard specifies the classification, technical requirements, test methods, quality appraisal procedures, packing, marking, transportation, storage and quality certificate of castables for steel rolling reheating furnace.展开更多
The workability and durability of a type of sustainable concrete made with steel slag powder were investigated. The hydrated products of cement paste with ground granulated blast furnace slag(GGBFS) alone or with a ...The workability and durability of a type of sustainable concrete made with steel slag powder were investigated. The hydrated products of cement paste with ground granulated blast furnace slag(GGBFS) alone or with a combined admixture of GGBFS-steel slag powder were investigated by X-ray diffraction(XRD). Furthermore, the mechanism of chemically activated steel slag powder was also studied. The experimental results showed that when steel slag powder was added to concrete, the slumps through the same time were lower. The initial and fi nal setting times were slightly retarded. The dry shrinkages were lower, and the abrasion resistance was better. The chemically activated steel slag powder could improve compressive strengths, resistance to chloride permeation and water permeation, as well as carbonization resistance. XRD patterns indicated that the activators enhanced the formation of calcium silicate hydrate(C-S-H) gel and ettringite(AFt). This research contributes to sustainable disposal of wastes and has the potential to provide several important environmental benefi ts.展开更多
Accurate control of slab temperature and heating rate is an important significance to improve product performance and reduce carbon emissions for steel rolling reheating furnace(SRRF).Firstly,a spatial temporal distri...Accurate control of slab temperature and heating rate is an important significance to improve product performance and reduce carbon emissions for steel rolling reheating furnace(SRRF).Firstly,a spatial temporal distributed-nonlinear autoregressive with exogenous inputs correlation model(STD-NARXCM)to spatial temporal distributed-autoregressive with exogenous inputs correlation model(STD-ARXCM)in working point is established.Secondly,a new coordinated time-sharing control architecture in different time periods is proposed,which is along the length of the SRRF to improve the control performance.Thirdly,a hybrid control algorithm of expert-fuzzy is proposed to improve the dynamic of the temperature and the heating rate during time period 0 to t_(1).A hybrid control algorithm of expert-fuzzy-PID is proposed to enhance the control accuracy and the heating rate during time period t_(1) to t_(2).A hybrid control algorithm of expert-active disturbance rejection control(ADRC)is proposed to boost the anti-interference and the heating rate during time period t_(2) to t_(3).Finally,the experimental results show that the coordinated time-sharing algorithm can meet the process requirements,the maximum deviation of temperature value is 8-13.5℃.展开更多
Cr25Ni35Nb and Cr35Ni45Nb alloys are usually used in the ethylene cracking furnaces. However, premature failure of furnace tubes often occurs ahead of design life due to elevated temperature exposure conditions (1050...Cr25Ni35Nb and Cr35Ni45Nb alloys are usually used in the ethylene cracking furnaces. However, premature failure of furnace tubes often occurs ahead of design life due to elevated temperature exposure conditions (1050-1100 ℃) and aggressive service environment. Effects of exposure temperature and time on microstructure and mechanical properties of Cr25Ni35Nb and Cr35Ni45Nb steel at aging temperature (1200 ℃) with various exposure time were simulated different service times at 1050 ℃. Change of mechanical properties at room temperature and elevated temperature (900 ℃) of the aged Cr25Ni35Nb and Cr35Ni45Nb steel were investigated. Under exposure at 1200 ℃, ultimate tensile and yield strength, elongation of Cr35Ni45Nb steel increase initially and then decrease, however, strength and ductility of Cr25Ni35Nb steel decrease with aging time increasing. Large amount of fine secondary carbide particles precipitated and dispersed in matrix of Cr35Ni45Nb steel, which increased strength and ductility for dispersion strengthening. However, the effect of the dispersion strengthening is weakened by needle-like secondary carbides. Strength and ductility decreased with fine secondary carbide particles growing. For Cr25Ni35Nb steel, few fine secondary carbide particles precipitated and dispersed in the matrix, and needle-like secondary carbides generated in the matrix, which causes strength and ductility decreased with aging time increasing.展开更多
Operating condition and service results of several tested bricks in slagline area of the VOD vessel are described. It has been shown that the fully co-clinkered magnesite chrome brick is superior, followed by two-stag...Operating condition and service results of several tested bricks in slagline area of the VOD vessel are described. It has been shown that the fully co-clinkered magnesite chrome brick is superior, followed by two-stage calcined magnesite-dolomite brick , prereacted magnesite-chrome brick and one-stage calcined magnesite-dolomite brick. Chemical and petrological examination were carried out by conventional analysis and optical microscope respectively. The reason of damage of the tested bricks are discussed and described as follows : (1) MgO in brick is erased and dissolved by slag to destroy structure of the direct bond ; (2) slag penetrating into the brick and then reacting with it to form various belts leading to spatting ; (3 ) reducing action of reducing agents ; (4) vaporization of some composition in the brick at high temperature under vacuum causes reducing weight and increasing porosity and (5 ) serious ma-chanic abrasion. Therefore, some opinions on increasing lining life of VOD vessels are suggested.展开更多
Air quenched basic oxygen furnace steel slag (BOF-SS) is processed at very high cooling rate, which is expected to have different cementitious properties from conventional slowly cooled BOF-SS. For this purpose, the...Air quenched basic oxygen furnace steel slag (BOF-SS) is processed at very high cooling rate, which is expected to have different cementitious properties from conventional slowly cooled BOF-SS. For this purpose, the strength activity indexes of air quenched and slowly cooled BOF-SS are investigated. The results reveal that, under the specific surface area (S) of 490 m^2/kg, the compressive strength activity index reaches 1.24 after 28 days with replacement of 15% air quenched BOF-SS and reaches 1.05 after 28 days with replacement of 20% air quenched BOF-SS and 30%granulated blast furnace slag (GBFS). The cementitious activity of air quenched BOF-SS is obviously higher than that of slowly cooled BOF-SS, mainly because it contains more C3 S and glassy phases.展开更多
文摘1 Scope This standard specifies the classification, technical requirements, test methods, quality appraisal procedures, packing, marking, transportation, storage and quality certificate of castables for steel rolling reheating furnace.
基金Funded by the National Natural Science Foundation of China(Nos.51208370,51172164)the Fundamental Research Funds for the Central Universities(No.0500219170)
文摘The workability and durability of a type of sustainable concrete made with steel slag powder were investigated. The hydrated products of cement paste with ground granulated blast furnace slag(GGBFS) alone or with a combined admixture of GGBFS-steel slag powder were investigated by X-ray diffraction(XRD). Furthermore, the mechanism of chemically activated steel slag powder was also studied. The experimental results showed that when steel slag powder was added to concrete, the slumps through the same time were lower. The initial and fi nal setting times were slightly retarded. The dry shrinkages were lower, and the abrasion resistance was better. The chemically activated steel slag powder could improve compressive strengths, resistance to chloride permeation and water permeation, as well as carbonization resistance. XRD patterns indicated that the activators enhanced the formation of calcium silicate hydrate(C-S-H) gel and ettringite(AFt). This research contributes to sustainable disposal of wastes and has the potential to provide several important environmental benefi ts.
基金This work was supported by the National Natural Science Foundation of China(Nos.62173032 and 62003038).
文摘Accurate control of slab temperature and heating rate is an important significance to improve product performance and reduce carbon emissions for steel rolling reheating furnace(SRRF).Firstly,a spatial temporal distributed-nonlinear autoregressive with exogenous inputs correlation model(STD-NARXCM)to spatial temporal distributed-autoregressive with exogenous inputs correlation model(STD-ARXCM)in working point is established.Secondly,a new coordinated time-sharing control architecture in different time periods is proposed,which is along the length of the SRRF to improve the control performance.Thirdly,a hybrid control algorithm of expert-fuzzy is proposed to improve the dynamic of the temperature and the heating rate during time period 0 to t_(1).A hybrid control algorithm of expert-fuzzy-PID is proposed to enhance the control accuracy and the heating rate during time period t_(1) to t_(2).A hybrid control algorithm of expert-active disturbance rejection control(ADRC)is proposed to boost the anti-interference and the heating rate during time period t_(2) to t_(3).Finally,the experimental results show that the coordinated time-sharing algorithm can meet the process requirements,the maximum deviation of temperature value is 8-13.5℃.
基金supported by the National Natural Science Foundation of China(No.50775107)National High Technical Research and Development Program of China (No.2007AA04Z407)Innovation Program for Graduate Students in Nanjing University of Technology (No.BSCX200816)
文摘Cr25Ni35Nb and Cr35Ni45Nb alloys are usually used in the ethylene cracking furnaces. However, premature failure of furnace tubes often occurs ahead of design life due to elevated temperature exposure conditions (1050-1100 ℃) and aggressive service environment. Effects of exposure temperature and time on microstructure and mechanical properties of Cr25Ni35Nb and Cr35Ni45Nb steel at aging temperature (1200 ℃) with various exposure time were simulated different service times at 1050 ℃. Change of mechanical properties at room temperature and elevated temperature (900 ℃) of the aged Cr25Ni35Nb and Cr35Ni45Nb steel were investigated. Under exposure at 1200 ℃, ultimate tensile and yield strength, elongation of Cr35Ni45Nb steel increase initially and then decrease, however, strength and ductility of Cr25Ni35Nb steel decrease with aging time increasing. Large amount of fine secondary carbide particles precipitated and dispersed in matrix of Cr35Ni45Nb steel, which increased strength and ductility for dispersion strengthening. However, the effect of the dispersion strengthening is weakened by needle-like secondary carbides. Strength and ductility decreased with fine secondary carbide particles growing. For Cr25Ni35Nb steel, few fine secondary carbide particles precipitated and dispersed in the matrix, and needle-like secondary carbides generated in the matrix, which causes strength and ductility decreased with aging time increasing.
文摘Operating condition and service results of several tested bricks in slagline area of the VOD vessel are described. It has been shown that the fully co-clinkered magnesite chrome brick is superior, followed by two-stage calcined magnesite-dolomite brick , prereacted magnesite-chrome brick and one-stage calcined magnesite-dolomite brick. Chemical and petrological examination were carried out by conventional analysis and optical microscope respectively. The reason of damage of the tested bricks are discussed and described as follows : (1) MgO in brick is erased and dissolved by slag to destroy structure of the direct bond ; (2) slag penetrating into the brick and then reacting with it to form various belts leading to spatting ; (3 ) reducing action of reducing agents ; (4) vaporization of some composition in the brick at high temperature under vacuum causes reducing weight and increasing porosity and (5 ) serious ma-chanic abrasion. Therefore, some opinions on increasing lining life of VOD vessels are suggested.
基金Item Sponsored by National Natural Science Foundation of China(51234003)
文摘Air quenched basic oxygen furnace steel slag (BOF-SS) is processed at very high cooling rate, which is expected to have different cementitious properties from conventional slowly cooled BOF-SS. For this purpose, the strength activity indexes of air quenched and slowly cooled BOF-SS are investigated. The results reveal that, under the specific surface area (S) of 490 m^2/kg, the compressive strength activity index reaches 1.24 after 28 days with replacement of 15% air quenched BOF-SS and reaches 1.05 after 28 days with replacement of 20% air quenched BOF-SS and 30%granulated blast furnace slag (GBFS). The cementitious activity of air quenched BOF-SS is obviously higher than that of slowly cooled BOF-SS, mainly because it contains more C3 S and glassy phases.