The factors which influence center segregation of continuously cast slabs are obtained through analyzing the database of macrostructrue. It indicates that center segregation becomes severer with the increasing content...The factors which influence center segregation of continuously cast slabs are obtained through analyzing the database of macrostructrue. It indicates that center segregation becomes severer with the increasing content of carbon, phosphorus and sulfur; Center segregation will be reduced obviously if the content of manganese is higher than 1.5% and the ratio of Mn/S is higher than 300; High degree of superheat , high casting speed and increasing width of slabs will increase the degree of center segregation. Since center segregation below class B has little effect on the property of steel, hence, in order to low the ratio of center segregation of class B-1.0 down to 10%, several control strategies are presented as follows: the contents of carbon, phosphorus and sulfur must be focalized in lower range of steel grade demanded, but manganese upper operating range control. The referenced contents of the elements in molten steel are required like this: [C]【0.07%,[P]【0.01%,[S]【0.005%,[Mn]】1.5%,[Mn]/[S]】300; The degree of superheat should be lower than 24℃ and the casting speed should be defined to 1.0-1.1 m·min-1. At the same time, proper secondary cooling system of water distribution should be developed and the precision of continuous caster should be also improved.展开更多
The low-melting phosphate glass was prepared for production of glass binders for protective coating of steel slab. Effects of different O/P ratios on glass structures and properties were analyzed. Differential thermal...The low-melting phosphate glass was prepared for production of glass binders for protective coating of steel slab. Effects of different O/P ratios on glass structures and properties were analyzed. Differential thermal analysis （DTA） and infrared spectroscopy （IR） techniques were applied for low-melting glass binder. It was found that the glass transition temperature（T） was about 300 ℃ and softening temperature（T1） was about 480 ℃. The choice of O/P ratio was very important to the glass transition and softening temperatures. When more P=O bonds existed in the glass networks, P-O-P bond angle was deformed with decreasing of the ratio of O/E The coatings could adhere to the substrates instantaneously at 800 ℃ when the content of binder exceeded 3wt%. The optimal content of glass binder was 5wt%.展开更多
文摘The factors which influence center segregation of continuously cast slabs are obtained through analyzing the database of macrostructrue. It indicates that center segregation becomes severer with the increasing content of carbon, phosphorus and sulfur; Center segregation will be reduced obviously if the content of manganese is higher than 1.5% and the ratio of Mn/S is higher than 300; High degree of superheat , high casting speed and increasing width of slabs will increase the degree of center segregation. Since center segregation below class B has little effect on the property of steel, hence, in order to low the ratio of center segregation of class B-1.0 down to 10%, several control strategies are presented as follows: the contents of carbon, phosphorus and sulfur must be focalized in lower range of steel grade demanded, but manganese upper operating range control. The referenced contents of the elements in molten steel are required like this: [C]【0.07%,[P]【0.01%,[S]【0.005%,[Mn]】1.5%,[Mn]/[S]】300; The degree of superheat should be lower than 24℃ and the casting speed should be defined to 1.0-1.1 m·min-1. At the same time, proper secondary cooling system of water distribution should be developed and the precision of continuous caster should be also improved.
基金Funded by the National Natural Science Foundation of China(No.51202249)the Key Projects in the National Science&Technology Pillar Program in the Twelfth Five-year Plan Period(No.2012BAB08B04)
文摘The low-melting phosphate glass was prepared for production of glass binders for protective coating of steel slab. Effects of different O/P ratios on glass structures and properties were analyzed. Differential thermal analysis （DTA） and infrared spectroscopy （IR） techniques were applied for low-melting glass binder. It was found that the glass transition temperature（T） was about 300 ℃ and softening temperature（T1） was about 480 ℃. The choice of O/P ratio was very important to the glass transition and softening temperatures. When more P=O bonds existed in the glass networks, P-O-P bond angle was deformed with decreasing of the ratio of O/E The coatings could adhere to the substrates instantaneously at 800 ℃ when the content of binder exceeded 3wt%. The optimal content of glass binder was 5wt%.
