Preparation and Characterization of Low-melting Glasses Used as Binder for Protective Coating of Steel Slab

The low-melting phosphate glass was prepared for production of glass binders for protective coating of steel slab. Effects of different O/P ratios on glass structures and properties were analyzed. Differential thermal analysis （DTA） and infrared spectroscopy （IR） techniques were applied for low-melting glass binder. It was found that the glass transition temperature（T） was about 300 ℃ and softening temperature（T1） was about 480 ℃. The choice of O/P ratio was very important to the glass transition and softening temperatures. When more P=O bonds existed in the glass networks, P-O-P bond angle was deformed with decreasing of the ratio of O/E The coatings could adhere to the substrates instantaneously at 800 ℃ when the content of binder exceeded 3wt%. The optimal content of glass binder was 5wt%.

Longitudinal surface cracks on continuous casting slabs of P and Cu containing container steel

The fact that the amount of the mold flux components differs at differentlocations on the cracking surface indicates that the longitudinal surface cracks are initiallyformed in the mold and are enlarged in the secondary cooling zone. Based on the hot ductilitymeasurement of two typical container used steels, it is known that the steels are in severeembrittlement state in the temperature range of 825-775 deg C. By means of increasing Cr/Ni platingthickness on the upper part of the mold, reducing mold heat flux, adopting new secondary coolingpattern, etc., the occurrence of the surface longitudinal cracks on the steel CC (continuouscasting) slabs has been significantly reduced.

Analysis of vibration reduction characteristics and applicability of steel-spring floating-slab track

A coupled dynamics computation model for metro vehicles, along with a steel-spring floating-slab track, is developed based on the theory of vehicle-track coupled dynamics. Using the developed model, the influences of the thickness, length and mass of floating-slab, spring rate and its arrangement space, running speed, etc. on the time and frequency domain characteristics of steel-spring fulcrum force are analyzed. The applicability of steel-spring floatingslab track is discussed through two integrated example cases of metro and buildings possessing distinct natural vibra- tion characteristics. It is concluded that, it is quite significant, in the optimization modular design of the parameters of steel-spring floating-slab track, to take the matching relationship of both the amplitude-frequency characteristics of steel-spring fulcrum force and natural vibration characteristics of integrated structures into comprehensive consideration. In this way the expensive steel-spring floating-slab track can be economically and efficiently utilized according to the site condition, and at the same time, the economic losses and bad social impact resulted from the resonance during usage of steel-spring floating-slab track can be avoided.

Behavior of Liquid Steel in Mold for Thin Slab Caster

The comparison of different submerged entry nozzles(SEN)was made by numerical simulation regarding the influence of liquid steel flow field,heat transfer and mold fluxes,as well as solidification shell stress and surface quality of thin slabs.The optimum internal shape of mold and the SEN were obtained.The foundation for choice of internal shape and casting parameters of mold was built.

Preventing Occurrence of Transverse Corner Cracks on Nb, V and Ti Microalloying Steel CC Slabs

Based on their hot ductilities, Nb, V and Ti microalloying steels can be classified into two groups. The first group includes steels with lower carbon content (≤0.10%). Ductilities of steels of this group recover and rise with decreasing temperature when temperature lowers to below 825℃. Another group includes steels which contain more carbon (>0.12%) or contain more Nb and V. The low ductility temperature Region Ⅲ for steels of mis group extends to temperature as low as 725℃. The occurrence of the transverse corner cracks of the Nb, V and Ti microalloying steel CC slabs has be considerably decreased by stabilizing casting speed, increasing mold steel level automatic control ratio,enhancing caster segment radial alignment and adopting proper secondary cooling patterns to make slab corner temperature at straightening out off the low ductility temperature region.

Carbide and Nitride Precipitation in High Temperature TensiledSpecimens and Hot Ductility of Nb-and Ti-ContainingSteel CC Slabs

Hot ductility of the Nb- and Ti-containing line-pipe steel CC slab specimens were measured under the sirain rate of 1 x 10-3/s. Three types of precipitates were found in the fractured specimens. One was the block-shaped coarse TiN particles precipitated at high temperature. Another type was the fine dynamic precipitation products precipitated at 950～900℃ which caused remarkable ductility reduction of the steel. The third type was the co-existed precipitates formed by fine Nb precipitates nucleating and growing on TiN paricles. Compared with Nb-containing steel which contains no Ti, there was no ductility drop for Nb- and Ti-containing steel at temperature between 850℃ and Ar3 and, the γ→α transformation inside the grain matrixes proceeded faster, which both improved the ductility of the steel in the low ductility temperature Region Ⅲ.

Corner crack mechanism of boron-containing LCAK steel slabs

At Baoshan Iron ＆ Steel Co., Ltd., comer cracks of boron containing LCAK steel slabs had caused remarkable quality loss and mass flow disorder. With the help of fractography and thermodynamics analysis, the embrittlement mechanism of this steel grade was studied and the results are as follows： 1 The transformation from 3＇ to a starts at the austenite grain boundaries and a layer of thin ferrite film gradually forms around the austenite grains. Strain concentration will preferentially start inside the ferrite phase when the stress accumulates to a certain level. 2 The coarse BN particles acceleratedly precipitated at the γ/α interfaces further deteriorate the ductility of the ferrite film, and brittleness results in strain concentration and microvoid coalescence inside the ferrite film. Therefore the austenite grain boundaries are prone to intergranular failure. 3 The stoichiometry among Al, N and B is a very important factor influencing the hot ductility of this steel grade. By controling the B-to-N atomic ratio to above 1, all N can be fixed by B instead of A1. Thus coarsegrained steel is available and fewer grain boundaries and higher ductility can reduce the risk of comer cracks. （4） By adjusting the B-to-N atomic ratio,Baoshan Iron ＆ Steel Co.,Ltd. successfully reduced the number of cracks to nearly one tenth of that in the past and the hot tensile tests confirmed remarkable improvement in the hot ductility of this steel.

Effects of electromagnetic stirring on surface purity of IF steel slabs

In order to analyze the effect of electromagnetic stirring on the slab＇ s surface purity, the continuously cast slab surface inclusions and subsurface blisters have been investigated. The results indicate that the mold electromagnetic stirrer （M -EMS） is useful for the improvement of IF steel slabs＇ surface quality. The continuously cast slab surface inclusions and subsurface blisters have been significantly reduced. The distribution of bubbles in the slab is non-homogeneous in terms of both width and depth. The continuously cast slab surface inclusions tend to miniaturization through M-EMS and most of the inclusions are less than 10 μm in size.

Simulation of thermal behavior during peritectic steel solidification in slab continuous casting mold

Thermal behavior of the solidifying shell in continuous casting mold is very important to final steel products.In the present work,one two-dimension transient thermal-mechanical finite element model was developed to simulate the thermal behavior of peritectic steel solidifying in slab continuous casting mold by using the sequential coupling method.In this model,the steel physical properties at high temperature was gotten from the micro-segregation model withδ/γtransformation in mushy zone,and the heat flux was obtained according to the displacement between the surface of solidifying shell and the hot face of mold as solidification contraction,the liquid-solid structure and distribution of mold flux,and the temperature distribution of slab surface and mold hot face,in addition,the rate-dependent elastic-viscoplastic constitutive equation was applied to account for the evolution of shell stress in the mold.With this model,the variation characteristics of surface temperature,heat flux, and growth of the solidifying shell corner,as well as the thickness distribution of the liquid flux,solidified flux,air gap and the corresponding thermal resistance were described.

Hot Ductility of Vanadium Micro-alloying Steel Continuous Casting Slabs

The hot ductility of the V-containing micro-alloying steel CC (continuouscasting) slabs and precipitation of vanadium carbide in the tensile specimens were investigated. Theresults indicate that the precipitation ratio and precipitation rate of vanadium in the specimensreach maximum respectively at 900, -825 and 825 deg C. There is still l0 percent-l7 percent ofvanadium precipitated when the deformation temperature decreases to 800-700 deg C. Vanadium largelyaffects the ductility of the steel in the low ductility temperature Region III. Embrittlement ofsteel with higher V content is severer in the region and the embrittlement extends to lowertemperature.

The“state of the art”slab caster for stainless steel in ThyssenKrupp Acciai Speciali Terni

On April 23,2009,a new single strand slab caster at ThyssenKrupp Acciai Speciali Terni(TKAST) was successfully started up with the first cast of AISI 304 grade in Terni plant,central Italy.TKAST is the Italian company of ThyssenKrupp Stainless group. The new caster is designed for a total capacity of approx.900.000 tpy of stainless steel slabs covering the complete range of stainless grades,including AISI 300 and 400 families(austenitic,ferritic and martensitic grades).This state of the art caster for the production of 215 mm thick slabs replaced an existing thin slab caster. This paper resumes the reasons of the installation of the new plant designed,manufactured erected and commissioned by Danieli and describes the technological solution,main features as well as the excellent results of this state of the art caster.

The optimization of mold fluxes used for casting the peritectic steel of heavy slabs at Baosteel

In order to solve the problem of the high surface longitudinal crack ratio of heavy peritectic steel slabs produced by the No. 3 continuous caster at Baosteel,the physical properties of the original mold flux and the optimized mold flux were compared in a comprehensive way by using analytical measures, such as a slag film heat-flow simulator, a thermowire molten flux crystallization tester and an X-ray diffractometer in the laboratory. The results reveal that one of the major reasons for the cracks is the poor heat transfer ability of the original mold flux. However, the optimized mold flux with a high basicity features a high crystallizing rate,low crystallization temperature and low heat-flow density. Therefore, the optimized mold flux is more suitable for casting peritectic steel by the heavy slab continuous caster. The test results show that the slabs produced by using the optimized mold flux had no surface longitudinal crack in four test casts, while the surface longitudinal crack ratio of the slabs produced by using the original mold flux was 5%. The optimized mold flux can effectively prevent slab surface longitudinal cracks from occurring.

钢板混凝土墙-钢筋混凝土楼板连接节点抗剪性能

模块化技术正在推动新一代核电厂的设计和发展,兼具优良工作性能和工业化施工性能的钢板混凝土(SC)结构在模块化结构具有广泛应用前景。SC墙-RC楼板连接节点作为SC模块结构与RC结构之间的典型传力构件,其结构设计必须既要保证荷载的有效传递,又要考虑模块化施工的可行性。为研究SC墙-RC楼板连接节点抗剪性能,设计并完成了2个“薄墙厚板型”SC墙-RC楼板连接节点循环加载试验,包括GB/T 51340—2018建议的钢筋连接器连接、附加抗剪键等两种连接方式。试验结果表明:在剪跨比1.50下试件均发生RC楼板弯剪破坏,节点主要传力破坏路径为加载端至楼板根部的斜压杆区域,说明节点结合面不配置抗剪键仍满足抗剪要求;试验过程中,直螺纹钢筋套筒无滑脱、未发生钢筋或焊缝拉断,延性系数均大于4,说明钢筋连接器连接的传力性能良好,可作为SC墙-RC楼板连接节点的有效连接方式;该节点核心区仍属于抗剪薄弱区域,若要满足“全强度连接”设计准则,核心区对拉筋体积含钢率应不低于0.59%。

薄板坯结晶器内中锰钢流动与凝固行为数值模拟

采用数值模拟方法对断面尺寸为1500 mm×90 mm的中锰钢薄板坯连铸结晶器内钢液流动与凝固特征进行了研究,分析了反应性保护渣的熔化与混合行为。研究结果表明,在拉速为5 m/min、浸入深度为300 mm的案例下,中锰钢在结晶器中下部约宽面四分之一附近的温度波动较大,因坯壳传热慢导致在结晶器出口处窄面的坯壳较薄,厚度仅为7.73 mm。对比低碳钢渣圈形状发现,中锰钢连铸过程中形成的渣圈尺寸略小,并以初始层成分为主,固态渣膜经不同阶段的反应层与初始层混合形成,结晶器上部因保护渣成分变化易导致坯壳初始凝固不均匀。

Longitudinal surface cracks of thin slabs

Based on the production practice of medium carbon thin slabs in the CSP plant,the reasons and influencing factors for the formation of longitudinal cracks were investigated,and some industrial measures were taken to eliminate the cracks.The results show that the efficient solutions to reduce longitudinal cracks are improving the performance of the mold powder,stabilizing the mold heat flux,and maintaining a proper taper of the mold during casting.Proper pouring temperature and secondary cooling also play important roles in preventing longitudinal surface cracks.

Numerical Evaluation of Two k-εTurbulence Model for Predicting Flow and Solidification in Continuous Casting Slab

A steady three-dimensional fluid flow and solidification model was built based on CFD software by high-Reynolds-number and Lam-Bremhorst low-Reynolds-number k-ε model.During the simulation,the fixed-grid enthalpy-porosity technique was used to represent the solidification,and Darcy law was adopted to simulate the flow in mushy region.The prediction for steel flow and solidification was evaluated by the comparison of two turbulence models.It is found that both Lam-Bremhorst low-Reynolds-number and high-Reynolds-number k-ε models predict the same trend of the steel flow and temperature distribution.However,due to the effect of turbulent flow on heat transfer,the low-Reynolds-number turbulence model predicts longer penetration depth of molten steel in sub-mold region,less shell growth and higher shell surface temperature at the narrow face compared with standard k-ε model.

Flexural behaviour of SFRRAC two-way composite slab with different shapes

To promote the application of green renewable materials in concrete composite slabs(CCSs)and study the flexural behavior of CCSs with different shapes,the bending performances of three CCSs with a SFRRAC base plate,one cast-in-site concrete slab of ordinary concrete and one CCS of ordinary concrete by steel bar truss(as recommended in the technical specification for precast concrete structures in Chinese)were compared through experiments.The carrying capacity,flexural behaviour and bi-directional mechanical properties of the specimens were systematically analyzed from the failure modes,load-deflection curves,load-bar strain curves,load-slip curves and crack distributions.Results show that the bending failure process of CCSs with a SFRRAC base plate is similar to that of the cast-in-site concrete slab of ordinary concrete and CCS of ordinary concrete by steel bar truss,as all of them went through the plastic phase,elastic plastic phase and failure phase with fully developed cracks and deflection.No sudden breakage or horizontal cracking of the connecting interface between the base plate and concrete topping was observed.The shape of the base plate has a major impact on the bearing capacity of the CCS with the SFRRAC base plate.When calculating the ultimate bearing capacity with the plastic yield line theory,the influence of the base plate shape on the plastic yield line position should be taken into account.

Development of Tailored Structure and Tensile Properties of Thermomechanical Treated Micro Alloyed Low Carbon Dual Phase Steel

Direct hot rolled dual phase steel production represents a challenging route, compared with cold rolled and intercritical annealing process, due to complex and sophisticated control of the hot strip mill processing parameters. Instead, high technology compact slab production plant offers economic advantages, adequate control and prompt use of the advanced thermomechanical controlled rolling. The current work aims to obtain different structures and tensile properties by physical simulation of direct hot rolled niobium micro alloyed dual phase low carbon steel by varying the metallurgical temperatures of hot strip mill plant. This starts with adaptation of the chemical analysis of a low carbon content to fall far from the undesired peritectic region to avoid slab cracking during casting. Thermodynamic and kinetics calculations by Thermo-Calc 2020 and JMat pro software are used to define the transformation’s temperatures Ae1 and Ae3 as well as processing temperatures;namely of reheating, finishing rolling, step cooling and coiling temperatures. The results show that the increase of finishing rolling temperature from 780°C to 840°C or decreasing either of step cooling duration at ferrite bay from 7 to 4 seconds, enhances yield and tensile strengths, all due to more martensite volume fraction formation. The yield and tensile strengths also increase with decreasing coiling temperature from 330°C to 180°C, which is explained due to the increase of dislocation densities resulted from the sudden shape change during martensite formation at the lower coiling temperature in additional to the self-tempering of martensite formed at higher coiling temperatures which soften the dual phase steel.

Research on the trajectory of non-metal inclusions with the flow in the mold during the solidification of continuous casting slabs

By means of the numerical simulation method,the mathematical model of inclusions movement in the mold is established under the condition of austenitic and fen-itic stainless steel slab production. According to the simulation results, the main zones for inclusion particles accumulation were found and many factors that affected floating-up probability of inclusion particles were identified. These factors include the inclusion particle size, the casting speed and the slab width, etc. It is believed that the inclusion particle size is the key one among these factors.

New Argon Stopper Technology for Slab Casting

Argon addition into the casting channel reduces the amount of clogging on the refractory wall to allow long sequence casting of aluminium-killed steel grades.The key to minimum surface defects on the final product is to establish the optimum quantity by optimising the gas distribution below the stopper nose.This is achieved by new argon stopper technology which supports low gas quantities with homogeneous gas and bubble distributions to float non-metallic inclusions(NMI)in the continuous casting mould.