Given that fretting wear causes failure in steel wires, we carried out tangential fretting wear tests of steel wires on a self-made fretting wear test rig under contact loads of 9 and 29 N and fretting amplitudes rang...Given that fretting wear causes failure in steel wires, we carried out tangential fretting wear tests of steel wires on a self-made fretting wear test rig under contact loads of 9 and 29 N and fretting amplitudes ranging from 5 to 180 μm. We observed morphologies of fretted steel wire surfaces on an S-3000N scanning electron microscope in order to analyze fretting wear mecha-nisms. The results show that the fretting regime of steel wires transforms from partial slip regime into mixed fretting regime and gross slip regime with an increase in fretting amplitudes under a given contact load. In partial slip regime, the friction coefficient has a relatively low value. Four stages can be defined in mixed fretting and gross slip regimes. The fretting wear of steel wires in-creases obviously with increases in fretting amplitudes. Fretting scars present a typical morphology of annularity, showing slight damage in partial slip regime. However, wear clearly increases in mixed fretting regime where wear mechanism is a combination of plastic deformation, abrasive wear and oxidative wear. In gross slip regime, more severe degradation is present than in the other regimes. The main fretting wear mechanisms of steel wires are abrasive wear, surface fatigue and friction oxidation.展开更多
In this study the process of cladding steel wires with aluminum is investigated experimentally. It is studied how the cladding process and the quality of products are influenced by the aluminum deformation temperature...In this study the process of cladding steel wires with aluminum is investigated experimentally. It is studied how the cladding process and the quality of products are influenced by the aluminum deformation temperature, the wheel speed, the temperature of steel wire, the wire speed and the steel wire tensile force. The relation among the process parameters above is discussed, and the effect of the aluminum deformation temperature on the coating microstructure is analyzed. This paper suggested a reasonable range of process parameters for producing aluminum cladding steel wires.展开更多
Data from a thermodynamic database and the calculation software FactSage were used to investigate the phase diagrams of the MnO?CaO?SiO2?Al2O3 system in cutting-wire steel and the effects of oxide components on the...Data from a thermodynamic database and the calculation software FactSage were used to investigate the phase diagrams of the MnO?CaO?SiO2?Al2O3 system in cutting-wire steel and the effects of oxide components on the low-melting-point (LMP) zone in the cor-responding phase diagrams. Furthermore, the activities of oxide components in the quaternary system at an Al2O3 content of 25wt%were calculated. The contents of dissolved [Al] and [O] in liquid steel in equilibrium with LMP inclusions in the MnO-CaO-SiO2-Al2O3 system were optimized. The results show that the MnO-CaO-SiO2-Al2O3 system possesses the largest LMP zone (below 1400℃) at an Al2O3 content of 25wt%and that the CaO content should be simultaneously controlled in the range of 40wt%to 45wt%. The activities of the oxide components CaO, MnO, and SiO2 should be restricted in the ranges of 0 to 0.05, 0.01 to 0.6, and 0.001 to 0.8, respectively. To obtain LMP inclusions, the [Al] and [O] contents in cutting-wire steel must be controlled within the ranges of 0.5 ×10^-6 to 1.0 ×10^-5 and 3.0 ×10^-6 to 5.0 × 10^-5, respectively.展开更多
A6×19 point-contact hoisting cable was used as our research object to examine the progress of corrosion of steel wires in a laboratory,simulating the actual working conditions in a coalmine.An electrochemical met...A6×19 point-contact hoisting cable was used as our research object to examine the progress of corrosion of steel wires in a laboratory,simulating the actual working conditions in a coalmine.An electrochemical method was used to investigate the corrosion behavior of steel wires with different surface treatments of a corrosive acid solution.The results show that anode activation of steel wire mainly occurs during pre-corrosion,where the anode activation process of bare steel wires is the fastest as is their corresponding corrosion speed,while the anode activation process of oil coated steel wires and their corresponding corrosion speed are the lowest.During the intermediate and late immersion periods, a passive film is generated on the surface of steel wires,which are gradually damaged with the passage of time.Local pitting corrosion occurs easily on the surface of steel wires with a high-polarization potential. Suitable equivalent circuits were chosen to fit the electrochemical impedance spectroscopy(EIS)of steel wires over various corrosive times and different surface treatments,which indicate good fitting results. The double electrical layer charge-transfer resistance increases in the sequence:bare steel wire, untreated steel wire and oil coated steel wire and their corrosion resistance decreases in turn,which is consistent with their polarization curves.The oil layer provides a certain protective effect on untreated steel wires,but its effect is not entirely clear.展开更多
The characteristic of near-surface microstructure and its effects on the torsion performance of cold-drawn pearlitic steel wires for bridge cables were investigated by focused ion beam-scanning electron microscope,tra...The characteristic of near-surface microstructure and its effects on the torsion performance of cold-drawn pearlitic steel wires for bridge cables were investigated by focused ion beam-scanning electron microscope,transmission electron microscopy and differential scanning calorimetry.The samples with similar tensile strength before and after hot-dip galvanizing process are,respectively,characterized as delaminated and non-delaminated in torsion test which indicates that the tensile strength is independent of the toughness value(i e,reduction area and torsion ability).It is interesting to find that there exists submicron granular ferrite on near-surface of the wires,which can be attributed to dislocation rearrangement and sub-grains rotation during cold drawing and hot-dip galvanizing process.And their distribution can suggest homogeneousness of deformation degree to a certain extent:the closer to the surface of their distribution,the more homogeneous deformation of the wires.There is a close relationship between the thermal stability of the cementite layer and distribution of granular ferrite:differential scanning calorimetry(DSC)analysis shows that the sample is accompanied by submicron granular ferrite which is located closer to the surface has higher thermal stability under galvanizing temperature(450°C).A new mechanism of the torsion delamination of pearlitic steel wires is discussed in terms of the thermal stability of the cementite layer and distribution of granular ferrite.展开更多
It was shown by the study of TEM that the fine lamellar pearlite becomes a ductile phase dur- ing cold drawing.There exist many ledges to emit dislocations at Fe_3C/Fe interface.It is one of the reasons that high dens...It was shown by the study of TEM that the fine lamellar pearlite becomes a ductile phase dur- ing cold drawing.There exist many ledges to emit dislocations at Fe_3C/Fe interface.It is one of the reasons that high density of dislocations emerges at the Fe_3C/Fe interface. Furthermore,there are some evidences to support that dislocation cuts through Fe_3C.There- fore,it is necessary to consider the contribution of cementite being sheared strengthening.展开更多
The force feed lubrication method is used for drawing aluminum clad steel wire. It is studied how deformation of wire and aspect of the lubricant film are influenced by the die angle, the reduction, the drawing spee...The force feed lubrication method is used for drawing aluminum clad steel wire. It is studied how deformation of wire and aspect of the lubricant film are influenced by the die angle, the reduction, the drawing speed and the gap between pressure die and wire. It has been concluded that when the factors above mentioned promote to thicken lubricant film, the drawing force is reduced and this favors the homogenous deformation of aluminum coating and steel core.展开更多
The variety,inner quality and surface quality of low-alloy spring steel wire rod for domestic automobile is summarized in detail.And according to commercial low-alloy spring steel wire rod variety, product quality lev...The variety,inner quality and surface quality of low-alloy spring steel wire rod for domestic automobile is summarized in detail.And according to commercial low-alloy spring steel wire rod variety, product quality level and its actual application situation on automobile supplied by present industrially developed country metallurgy enterprises,it is pointed that the variety of low-alloy spring steel wire rod for domestic automobile can't satisfy the requirements of automobile industry development,compare with overseas advanced technology,product quality has the following gaps:the first is that steel purity is low,the control level of non-metallic inclusions is not steady,there is often large grain difficult deforming non-deformation inclusions existing,the control level of steel purity has big difference,the level of large steel factory is high,but its steady has a large gap compare with foreign advanced level,not to mention small steel factory which research and development powder is low.The second is surface complete decarburization can' t be avoided completely.The third is that surface defects are more.The fourth is that composition segregation and structure segregation are not steady,steel wire can't be drawn normally when the segregation is serious. In all,the segregation of 55SiCrA is superior to 60Si2MnA obviously.The industrialization of domestic high level low-alloy spring steel wire rod can't seek quick success and instant benefits,independent innovation perseveringly must be adopted,the success may be reached after master core technologies and adopt the science way of step by step.展开更多
To investigate the fretting wear of steel wires in hoisting ropes, specimenswere made of 6X19 point contact ropes. A model for the fretting ear was developed and a frettingwear test rig was deigned in laboratory. A se...To investigate the fretting wear of steel wires in hoisting ropes, specimenswere made of 6X19 point contact ropes. A model for the fretting ear was developed and a frettingwear test rig was deigned in laboratory. A series of experiments were performed on this test rig.The wear volume was taken as a characteristic parameter to describe the fretting wear in relation tothe contact load, reciprocating cycles and amplitude. Moreover, the wear mechanisms were discussedin the fretting process.展开更多
ZnO thin films were prepared by electrophoretic deposition on stainless steel wire sieve, using zinc acetate as a precursor. The film was sintered and characterised by Scanning Electron Microscopy (SEM), X-Ray Diffr...ZnO thin films were prepared by electrophoretic deposition on stainless steel wire sieve, using zinc acetate as a precursor. The film was sintered and characterised by Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) and chemisorption of oxygen. A culture bacterial consortium composed by gram negative rod-shaped microbes was prepared in a liquid agar in a flask. It was transported by air through a reactor equipped with a UV lamp with 3 and 5 sieves of a stainless steel wire coated with ZnO film. It was exposed in continuous in five experiments to photocatalytic advanced oxidation. The experiments showed a total efficiency for colony forming unit reduction of a maximum of 99.66% for a residence time of 20 seconds with 5 stainless steel wire where exposed in continuous to UV. Also they were evaluated at 7.5 seconds, observing that the contribution of residence time and amount of catalytic for the CFU reduction was quite similar. Variance analysis showed that the efficiency was significant with the no parametric Kruskal-Wallis test with P 〈 0.05. This technology could be used to clean indoor air of closed environments such as hospitals, crowded buildings or public transportation systems where airborne bacteria has been documented.展开更多
This paper analyzes the influence of fatigue loading on the residual stress profile in high strength steel wires. To this end, different sinusoidal loads with diverse values of maximum loading level and number of cycl...This paper analyzes the influence of fatigue loading on the residual stress profile in high strength steel wires. To this end, different sinusoidal loads with diverse values of maximum loading level and number of cycles were simulated on wires in which several residual stress profiles had been previously introduced, some of them with a tensile state and others with a compressive state. An analysis was made of the evolution with time of such residual stress laws by comparing them at key instants of loading, that is, at initial instant, at maximum load, at minimum load and at final instant. Numerical results show only a minor influence of fatigue loading on the residual stress profile.展开更多
To improve the quality of high carbon wire rods,combined electromagnetic stirring was introduced in the continuous casting of round billets with a diameter of 250mm at Tianjin Rockcheck Steel Group Co.In this paper,th...To improve the quality of high carbon wire rods,combined electromagnetic stirring was introduced in the continuous casting of round billets with a diameter of 250mm at Tianjin Rockcheck Steel Group Co.In this paper,the positioning of final electromagnetic stirring(F-EMS)was determined by nail-shooting method.Furthermore,the effect of mold electromagnetic stirring(M-EMS)on the macrostructure and internal defects in the round billets was investigated to find out the optimal operating parameters for continuous casting of SWRH 82B round billets.The results show the desirable positioning of F-EMS locates 9.7m below the mold level where the molten steel can be effectively driven by electromagnetic force and disperse central composition segregation.The shrinkage cavity is totally eliminated with the rotational M-EMS.The ratio and index of central composition segregation and center porosity can be reduced significantly. Furthermore,the equiaxed crystal ratio is considerably increased to 64%under 480A/3Hz M-EMS and 500A/10Hz F-EMS. Fine microstructure and mechanical property of wire rod are presented after optimization of combined electromagnetic stirring.Accordingly,the probability of occurrence of cup-cone fracture of wire rod is reduced dramatically.展开更多
基金supported by the National Natural Science Foundation of China (No 50875252)the Program for New Century Excellent Talents in Universities (NoNCET-06-0479)the Natural Science Foundation of Jiangsu Province (NoBK2008005)
文摘Given that fretting wear causes failure in steel wires, we carried out tangential fretting wear tests of steel wires on a self-made fretting wear test rig under contact loads of 9 and 29 N and fretting amplitudes ranging from 5 to 180 μm. We observed morphologies of fretted steel wire surfaces on an S-3000N scanning electron microscope in order to analyze fretting wear mecha-nisms. The results show that the fretting regime of steel wires transforms from partial slip regime into mixed fretting regime and gross slip regime with an increase in fretting amplitudes under a given contact load. In partial slip regime, the friction coefficient has a relatively low value. Four stages can be defined in mixed fretting and gross slip regimes. The fretting wear of steel wires in-creases obviously with increases in fretting amplitudes. Fretting scars present a typical morphology of annularity, showing slight damage in partial slip regime. However, wear clearly increases in mixed fretting regime where wear mechanism is a combination of plastic deformation, abrasive wear and oxidative wear. In gross slip regime, more severe degradation is present than in the other regimes. The main fretting wear mechanisms of steel wires are abrasive wear, surface fatigue and friction oxidation.
文摘In this study the process of cladding steel wires with aluminum is investigated experimentally. It is studied how the cladding process and the quality of products are influenced by the aluminum deformation temperature, the wheel speed, the temperature of steel wire, the wire speed and the steel wire tensile force. The relation among the process parameters above is discussed, and the effect of the aluminum deformation temperature on the coating microstructure is analyzed. This paper suggested a reasonable range of process parameters for producing aluminum cladding steel wires.
文摘Data from a thermodynamic database and the calculation software FactSage were used to investigate the phase diagrams of the MnO?CaO?SiO2?Al2O3 system in cutting-wire steel and the effects of oxide components on the low-melting-point (LMP) zone in the cor-responding phase diagrams. Furthermore, the activities of oxide components in the quaternary system at an Al2O3 content of 25wt%were calculated. The contents of dissolved [Al] and [O] in liquid steel in equilibrium with LMP inclusions in the MnO-CaO-SiO2-Al2O3 system were optimized. The results show that the MnO-CaO-SiO2-Al2O3 system possesses the largest LMP zone (below 1400℃) at an Al2O3 content of 25wt%and that the CaO content should be simultaneously controlled in the range of 40wt%to 45wt%. The activities of the oxide components CaO, MnO, and SiO2 should be restricted in the ranges of 0 to 0.05, 0.01 to 0.6, and 0.001 to 0.8, respectively. To obtain LMP inclusions, the [Al] and [O] contents in cutting-wire steel must be controlled within the ranges of 0.5 ×10^-6 to 1.0 ×10^-5 and 3.0 ×10^-6 to 5.0 × 10^-5, respectively.
基金supported by the National Natural Science Foundation of China(No.50875252)the Program for New Century Excellent Talents in University(No.NCET-06-0479).
文摘A6×19 point-contact hoisting cable was used as our research object to examine the progress of corrosion of steel wires in a laboratory,simulating the actual working conditions in a coalmine.An electrochemical method was used to investigate the corrosion behavior of steel wires with different surface treatments of a corrosive acid solution.The results show that anode activation of steel wire mainly occurs during pre-corrosion,where the anode activation process of bare steel wires is the fastest as is their corresponding corrosion speed,while the anode activation process of oil coated steel wires and their corresponding corrosion speed are the lowest.During the intermediate and late immersion periods, a passive film is generated on the surface of steel wires,which are gradually damaged with the passage of time.Local pitting corrosion occurs easily on the surface of steel wires with a high-polarization potential. Suitable equivalent circuits were chosen to fit the electrochemical impedance spectroscopy(EIS)of steel wires over various corrosive times and different surface treatments,which indicate good fitting results. The double electrical layer charge-transfer resistance increases in the sequence:bare steel wire, untreated steel wire and oil coated steel wire and their corrosion resistance decreases in turn,which is consistent with their polarization curves.The oil layer provides a certain protective effect on untreated steel wires,but its effect is not entirely clear.
基金Funded by the National Key R&D Program of China(No.2017YFB0304801)。
文摘The characteristic of near-surface microstructure and its effects on the torsion performance of cold-drawn pearlitic steel wires for bridge cables were investigated by focused ion beam-scanning electron microscope,transmission electron microscopy and differential scanning calorimetry.The samples with similar tensile strength before and after hot-dip galvanizing process are,respectively,characterized as delaminated and non-delaminated in torsion test which indicates that the tensile strength is independent of the toughness value(i e,reduction area and torsion ability).It is interesting to find that there exists submicron granular ferrite on near-surface of the wires,which can be attributed to dislocation rearrangement and sub-grains rotation during cold drawing and hot-dip galvanizing process.And their distribution can suggest homogeneousness of deformation degree to a certain extent:the closer to the surface of their distribution,the more homogeneous deformation of the wires.There is a close relationship between the thermal stability of the cementite layer and distribution of granular ferrite:differential scanning calorimetry(DSC)analysis shows that the sample is accompanied by submicron granular ferrite which is located closer to the surface has higher thermal stability under galvanizing temperature(450°C).A new mechanism of the torsion delamination of pearlitic steel wires is discussed in terms of the thermal stability of the cementite layer and distribution of granular ferrite.
文摘It was shown by the study of TEM that the fine lamellar pearlite becomes a ductile phase dur- ing cold drawing.There exist many ledges to emit dislocations at Fe_3C/Fe interface.It is one of the reasons that high density of dislocations emerges at the Fe_3C/Fe interface. Furthermore,there are some evidences to support that dislocation cuts through Fe_3C.There- fore,it is necessary to consider the contribution of cementite being sheared strengthening.
文摘The force feed lubrication method is used for drawing aluminum clad steel wire. It is studied how deformation of wire and aspect of the lubricant film are influenced by the die angle, the reduction, the drawing speed and the gap between pressure die and wire. It has been concluded that when the factors above mentioned promote to thicken lubricant film, the drawing force is reduced and this favors the homogenous deformation of aluminum coating and steel core.
文摘The variety,inner quality and surface quality of low-alloy spring steel wire rod for domestic automobile is summarized in detail.And according to commercial low-alloy spring steel wire rod variety, product quality level and its actual application situation on automobile supplied by present industrially developed country metallurgy enterprises,it is pointed that the variety of low-alloy spring steel wire rod for domestic automobile can't satisfy the requirements of automobile industry development,compare with overseas advanced technology,product quality has the following gaps:the first is that steel purity is low,the control level of non-metallic inclusions is not steady,there is often large grain difficult deforming non-deformation inclusions existing,the control level of steel purity has big difference,the level of large steel factory is high,but its steady has a large gap compare with foreign advanced level,not to mention small steel factory which research and development powder is low.The second is surface complete decarburization can' t be avoided completely.The third is that surface defects are more.The fourth is that composition segregation and structure segregation are not steady,steel wire can't be drawn normally when the segregation is serious. In all,the segregation of 55SiCrA is superior to 60Si2MnA obviously.The industrialization of domestic high level low-alloy spring steel wire rod can't seek quick success and instant benefits,independent innovation perseveringly must be adopted,the success may be reached after master core technologies and adopt the science way of step by step.
基金This work was financially supported by the Ministry of Coal Industry, China(the Research Foundation of Mining Science) and the L
文摘To investigate the fretting wear of steel wires in hoisting ropes, specimenswere made of 6X19 point contact ropes. A model for the fretting ear was developed and a frettingwear test rig was deigned in laboratory. A series of experiments were performed on this test rig.The wear volume was taken as a characteristic parameter to describe the fretting wear in relation tothe contact load, reciprocating cycles and amplitude. Moreover, the wear mechanisms were discussedin the fretting process.
文摘ZnO thin films were prepared by electrophoretic deposition on stainless steel wire sieve, using zinc acetate as a precursor. The film was sintered and characterised by Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) and chemisorption of oxygen. A culture bacterial consortium composed by gram negative rod-shaped microbes was prepared in a liquid agar in a flask. It was transported by air through a reactor equipped with a UV lamp with 3 and 5 sieves of a stainless steel wire coated with ZnO film. It was exposed in continuous in five experiments to photocatalytic advanced oxidation. The experiments showed a total efficiency for colony forming unit reduction of a maximum of 99.66% for a residence time of 20 seconds with 5 stainless steel wire where exposed in continuous to UV. Also they were evaluated at 7.5 seconds, observing that the contribution of residence time and amount of catalytic for the CFU reduction was quite similar. Variance analysis showed that the efficiency was significant with the no parametric Kruskal-Wallis test with P 〈 0.05. This technology could be used to clean indoor air of closed environments such as hospitals, crowded buildings or public transportation systems where airborne bacteria has been documented.
文摘This paper analyzes the influence of fatigue loading on the residual stress profile in high strength steel wires. To this end, different sinusoidal loads with diverse values of maximum loading level and number of cycles were simulated on wires in which several residual stress profiles had been previously introduced, some of them with a tensile state and others with a compressive state. An analysis was made of the evolution with time of such residual stress laws by comparing them at key instants of loading, that is, at initial instant, at maximum load, at minimum load and at final instant. Numerical results show only a minor influence of fatigue loading on the residual stress profile.
基金Item Sponsored by National Natural Science Foundation of China[No.50834009]the National Natural Science Foundation of China[No.51004038]+1 种基金Key Grant Project of China Ministry of Education(No.311014)the 111 Project of China(No.B07015)
文摘To improve the quality of high carbon wire rods,combined electromagnetic stirring was introduced in the continuous casting of round billets with a diameter of 250mm at Tianjin Rockcheck Steel Group Co.In this paper,the positioning of final electromagnetic stirring(F-EMS)was determined by nail-shooting method.Furthermore,the effect of mold electromagnetic stirring(M-EMS)on the macrostructure and internal defects in the round billets was investigated to find out the optimal operating parameters for continuous casting of SWRH 82B round billets.The results show the desirable positioning of F-EMS locates 9.7m below the mold level where the molten steel can be effectively driven by electromagnetic force and disperse central composition segregation.The shrinkage cavity is totally eliminated with the rotational M-EMS.The ratio and index of central composition segregation and center porosity can be reduced significantly. Furthermore,the equiaxed crystal ratio is considerably increased to 64%under 480A/3Hz M-EMS and 500A/10Hz F-EMS. Fine microstructure and mechanical property of wire rod are presented after optimization of combined electromagnetic stirring.Accordingly,the probability of occurrence of cup-cone fracture of wire rod is reduced dramatically.