基于开源Quantum ESPRESSO软件的固体物理教学模式创新与实践

为了解决固体物理课程学习中的难点,授课时引入开源Quantum ESPRESSO软件为学生提供全面的理论学习和实践训练。实践训练分为理论学习和实际操作两个阶段,使学生在理解固体物理的难点的同时获得实际操作经验。通过自主学习、实验报告的撰写和实操演示等分层次的学习方式,学生逐渐提升对固体物理的整体理解水平。学生对这一学习方式的反应良好。Quantum ESPRESSO软件为学生提供了先进的学习工具,有效提高了固体物理课程的学习效果。

Improvement of radiative recombination rate in deep ultraviolet laser diodes with step-like quantum barrier and aluminum-content graded electron blocking layer

The design of the active region structures,including the modifications of structures of the quantum barrier(QB)and electron blocking layer(EBL),in the deep ultraviolet(DUV)Al Ga N laser diode(LD)is investigated numerically with the Crosslight software.The analyses focus on electron and hole injection efficiency,electron leakage,hole diffusion,and radiative recombination rate.Compared with the reference QB structure,the step-like QB structure provides high radiative recombination and maximum output power.Subsequently,a comparative study is conducted on the performance characteristics with four different EBLs.For the EBL with different Al mole fraction layers,the higher Al-content Al Ga N EBL layer is located closely to the active region,leading the electron current leakage to lower,the carrier injection efficiency to increase,and the radiative recombination rate to improve.

Physical Layer Encryption of OFDM-PON Based on Quantum Noise Stream Cipher with Polar Code

Orthogonal frequency division multiplexing passive optical network(OFDM-PON) has superior anti-dispersion property to operate in the C-band of fiber for increased optical power budget. However,the downlink broadcast exposes the physical layer vulnerable to the threat of illegal eavesdropping. Quantum noise stream cipher(QNSC) is a classic physical layer encryption method and well compatible with the OFDM-PON. Meanwhile, it is indispensable to exploit forward error correction(FEC) to control errors in data transmission. However, when QNSC and FEC are jointly coded, the redundant information becomes heavier and thus the code rate of the transmitted signal will be largely reduced. In this work, we propose a physical layer encryption scheme based on polar-code-assisted QNSC. In order to improve the code rate and security of the transmitted signal, we exploit chaotic sequences to yield the redundant bits and utilize the redundant information of the polar code to generate the higher-order encrypted signal in the QNSC scheme with the operation of the interleaver.We experimentally demonstrate the encrypted 16/64-QAM, 16/256-QAM, 16/1024-QAM, 16/4096-QAM QNSC signals transmitted over 30-km standard single mode fiber. For the transmitted 16/4096-QAM QNSC signal, compared with the conventional QNSC method, the proposed method increases the code rate from 0.1 to 0.32 with enhanced security.

Proton‑Prompted Ligand Exchange to Achieve High‑Efficiency CsPbI_(3) Quantum Dot Light‑Emitting Diodes

CsPbI_(3)perovskite quantum dots(QDs)are ideal materials for the next generation of red light-emitting diodes.However,the low phase stability of CsPbI_(3)QDs and long-chain insulating capping ligands hinder the improvement of device performance.Traditional in-situ ligand replacement and ligand exchange after synthesis were often difficult to control.Here,we proposed a new ligand exchange strategy using a proton-prompted insitu exchange of short 5-aminopentanoic acid ligands with long-chain oleic acid and oleylamine ligands to obtain stable small-size CsPbI_(3)QDs.This exchange strategy maintained the size and morphology of CsPbI_(3)QDs and improved the optical properties and the conductivity of CsPbI_(3)QDs films.As a result,high-efficiency red QD-based light-emitting diodes with an emission wavelength of 645 nm demonstrated a record maximum external quantum efficiency of 24.45%and an operational half-life of 10.79 h.

N-doped graphene quantum dot-decorated N-TiO2/P-doped porous hollow g-C_(3)N_(4) nanotube composite photocatalysts for antibiotic photodegradation and H2 production

Exclusive responsiveness to ultraviolet light (~3.2 eV) and high photogenerated charge recombination rate are the two primary drawbacks of pure TiO_(2). We combined N-doped graphene quantum dots (N-GQDs), morphology regulation, and heterojunction construction strategies to synthesize N-GQD/N-doped TiO_(2)/P-doped porous hollow g-C_(3)N_(4) nanotube (PCN) composite photocatalysts (denoted as G-TPCN). The optimal sample (G-TPCN doped with 0.1wt% N-GQD, denoted as 0.1% G-TPCN) exhibits significantly enhanced photoabsorption, which is attributed to the change in bandgap caused by elemental doping (P and N), the improved light-harvesting resulting from the tube structure, and the upconversion effect of N-GQDs. In addition, the internal charge separation and transfer capability of0.1% G-TPCN are dramatically boosted, and its carrier concentration is 3.7, 2.3, and 1.9 times that of N-TiO_(2), PCN, and N-TiO_(2)/PCN(TPCN-1), respectively. This phenomenon is attributed to the formation of Z-scheme heterojunction between N-TiO_(2) and PCNs, the excellent electron conduction ability of N-GQDs, and the short transfer distance caused by the porous nanotube structure. Compared with those of N-TiO_(2), PCNs, and TPCN-1, the H2 production activity of 0.1%G-TPCN under visible light is enhanced by 12.4, 2.3, and 1.4times, respectively, and its ciprofloxacin (CIP) degradation rate is increased by 7.9, 5.7, and 2.9 times, respectively. The optimized performance benefits from excellent photoresponsiveness and improved carrier separation and migration efficiencies. Finally, the photocatalytic mechanism of 0.1% G-TPCN and five possible degradation pathways of CIP are proposed. This study clarifies the mechanism of multiple modification strategies to synergistically improve the photocatalytic performance of 0.1% G-TPCN and provides a potential strategy for rationally designing novel photocatalysts for environmental remediation and solar energy conversion.

Delayed-measurement one-way quantum computing on cloud quantum computer

One-way quantum computation focuses on initially generating an entangled cluster state followed by a sequence of measurements with classical communication of their individual outcomes.Recently,a delayed-measurement approach has been applied to replace classical communication of individual measurement outcomes.In this work,by considering the delayed-measurement approach,we demonstrate a modified one-way CNOT gate using the on-cloud superconducting quantum computing platform:Quafu.The modified protocol for one-way quantum computing requires only three qubits rather than the four used in the standard protocol.Since this modified cluster state decreases the number of physical qubits required to implement one-way computation,both the scalability and complexity of the computing process are improved.Compared to previous work,this modified one-way CNOT gate is superior to the standard one in both fidelity and resource requirements.We have also numerically compared the behavior of standard and modified methods in large-scale one-way quantum computing.Our results suggest that in a noisy intermediate-scale quantum(NISQ)era,the modified method shows a significant advantage for one-way quantum computation.

Detecting the quantum phase transition from the perspective of quantum information in the Aubry–André model

We investigate the effectiveness of entropic uncertainty, entanglement and steering in discerning quantum phase transitions(QPTs). Specifically, we observe significant fluctuations in entropic uncertainty as the driving parameter traverses the phase transition point. It is observed that the entropic uncertainty, entanglement and quantum steering, based on the electron distribution probability, can serve as indicators for detecting QPTs. Notably, we reveal an intriguing anticorrelation relationship between entropic uncertainty and entanglement in the Aubry–André model. Moreover, we explore the feasibility of detecting a QPT when the period parameter is a rational number. These observations open up new and efficient avenues for probing QPTs.

Approximate constructions of counterdiabatic driving withNMR quantum systems

Counterdiabatic driving (CD) offers a fast and robust route to manipulate quantum systems, which has widespreadapplications in quantum technologies. However, for higher-dimensional complex systems, the exact CD term involving thespectral properties of the system is difficult to calculate and generally takes a complicated form, impeding its experimentalrealization. Recently, many approximate methods have been proposed for designing CD passages in many-body systems. Inthis topical review, we focus on the CD formalism and briefly introduce several experimental constructions and applicationsof approximate CD driving in spin-chain models with nuclear magnetic resonance (NMR) systems.

A quantum-enhanced magnetometer using a single high-spin nucleus in silicon

Quantum enhanced metrology has the potential to go beyond the standard quantum limit and eventually to the ultimate Heisenberg bound.In particular,quantum probes prepared in nonclassical coherent states have recently been recognized as a useful resource for metrology.Hence,there has been considerable interest in constructing magnetic quantum sensors that combine high resolution and high sensitivity.Here,we explore a nanoscale magnetometer with quantum-enhanced sensitivity,based on 123Sb(I=7/2)nuclear spin doped in silicon,that takes advantage of techniques of spin-squeezing and coherent control.With the optimal squeezed initial state,the magnetic field sensitivity may be expected to approach 6 aT·Hz^(−1/2)·cm^(−3/2) and 603 nT·Hz^(−1/2) at the single-spin level.This magnetic sensor may provide a novel sensitive and high-resolution route to microscopic mapping of magnetic fields as well as other applications.

Variational data encoding and correlations in quantum-enhanced machine learning

Leveraging the extraordinary phenomena of quantum superposition and quantum correlation,quantum computing offers unprecedented potential for addressing challenges beyond the reach of classical computers.This paper tackles two pivotal challenges in the realm of quantum computing:firstly,the development of an effective encoding protocol for translating classical data into quantum states,a critical step for any quantum computation.Different encoding strategies can significantly influence quantum computer performance.Secondly,we address the need to counteract the inevitable noise that can hinder quantum acceleration.Our primary contribution is the introduction of a novel variational data encoding method,grounded in quantum regression algorithm models.By adapting the learning concept from machine learning,we render data encoding a learnable process.This allowed us to study the role of quantum correlation in data encoding.Through numerical simulations of various regression tasks,we demonstrate the efficacy of our variational data encoding,particularly post-learning from instructional data.Moreover,we delve into the role of quantum correlation in enhancing task performance,especially in noisy environments.Our findings underscore the critical role of quantum correlation in not only bolstering performance but also in mitigating noise interference,thus advancing the frontier of quantum computing.

Quantum confinement of carriers in the type-I quantum wells structure

Quantum confinement is recognized to be an inherent property in low-dimensional structures.Traditionally,it is believed that the carriers trapped within the well cannot escape due to the discrete energy levels.However,our previous research has revealed efficient carrier escape in low-dimensional structures,contradicting this conventional understanding.In this study,we review the energy band structure of quantum wells along the growth direction considering it as a superposition of the bulk material dispersion and quantization energy dispersion resulting from the quantum confinement across the whole Brillouin zone.By accounting for all wave vectors,we obtain a certain distribution of carrier energy at each quantized energy level,giving rise to the energy subbands.These results enable carriers to escape from the well under the influence of an electric field.Additionally,we have compiled a comprehensive summary of various energy band scenarios in quantum well structures relevant to carrier transport.Such a new interpretation holds significant value in deepening our comprehension of low-dimensional energy bands,discovering new physical phenomena,and designing novel devices with superior performance.

Quantum circuit-based proxy blind signatures:A novel approach and experimental evaluation on the IBM quantum cloud platform

This paper presents a novel approach to proxy blind signatures in the realm of quantum circuits,aiming to enhance security while safeguarding sensitive information.The main objective of this research is to introduce a quantum proxy blind signature(QPBS)protocol that utilizes quantum logical gates and quantum measurement techniques.The QPBS protocol is constructed by the initial phase,proximal blinding message phase,remote authorization and signature phase,remote validation,and de-blinding phase.This innovative design ensures a secure mechanism for signing documents without revealing the content to the proxy signer,providing practical security authentication in a quantum environment under the assumption that the CNOT gates are securely implemented.Unlike existing approaches,our proposed QPBS protocol eliminates the need for quantum entanglement preparation,thus simplifying the implementation process.To assess the effectiveness and robustness of the QPBS protocol,we conduct comprehensive simulation studies in both ideal and noisy quantum environments on the IBM quantum cloud platform.The results demonstrate the superior performance of the QPBS algorithm,highlighting its resilience against repudiation and forgeability,which are key security concerns in the realm of proxy blind signatures.Furthermore,we have established authentic security thresholds(82.102%)in the presence of real noise,thereby emphasizing the practicality of our proposed solution.

Threshold-independent method for single-shot readout of spin qubits in semiconductor quantum dots

The single-shot readout data process is essential for the realization of high-fidelity qubits and fault-tolerant quantum algorithms in semiconductor quantum dots. However, the fidelity and visibility of the readout process are sensitive to the choice of the thresholds and limited by the experimental hardware. By demonstrating the linear dependence between the measured spin state probabilities and readout visibilities along with dark counts, we describe an alternative threshold-independent method for the single-shot readout of spin qubits in semiconductor quantum dots. We can obtain the extrapolated spin state probabilities of the prepared probabilities of the excited spin state through the threshold-independent method. We then analyze the corresponding errors of the method, finding that errors of the extrapolated probabilities cannot be neglected with no constraints on the readout time and threshold voltage. Therefore, by limiting the readout time and threshold voltage, we ensure the accuracy of the extrapolated probability. We then prove that the efficiency and robustness of this method are 60 times larger than those of the most commonly used method. Moreover, we discuss the influence of the electron temperature on the effective area with a fixed external magnetic field and provide a preliminary demonstration for a single-shot readout of up to 0.7K/1.5T in the future.

Balancing the minimum error rate and minimum copy consumption in quantum state discrimination

Extracting more information and saving quantum resources are two main aims for quantum measurements.However,the optimization of strategies for these two objectives varies when discriminating between quantum states■and■through multiple measurements.In this study,we introduce a novel state discrimination model that reveals the intricate relationship between the average error rate and average copy consumption.By integrating these two crucial metrics and minimizing their weighted sum for any given weight value,our research underscores the infeasibility of simultaneously minimizing these metrics through local measurements with one-way communication.Our findings present a compelling trade-off curve,highlighting the advantages of achieving a balance between error rate and copy consumption in quantum discrimination tasks,offering valuable insights into the optimization of quantum resources while ensuring the accuracy of quantum state discrimination.

QBIoT:A Quantum Blockchain Framework for IoT with an Improved Proof-of-Authority Consensus Algorithm and a Public-Key Quantum Signature

The Internet of Things(IoT)is a network system that connects physical devices through the Internet,allowing them to interact.Nowadays,IoT has become an integral part of our lives,offering convenience and smart functionality.However,the growing number of IoT devices has brought about a corresponding increase in cybersecurity threats,such as device vulnerabilities,data privacy concerns,and network susceptibilities.Integrating blockchain technology with IoT has proven to be a promising approach to enhance IoT security.Nevertheless,the emergence of quantum computing poses a significant challenge to the security of traditional classical cryptography used in blockchain,potentially exposing it to quantum cyber-attacks.To support the growth of the IoT industry,mitigate quantum threats,and safeguard IoT data,this study proposes a robust blockchain solution for IoT that incorporates both classical and post-quantum security measures.Firstly,we present the Quantum-Enhanced Blockchain Architecture for IoT(QBIoT)to ensure secure data sharing and integrity protection.Secondly,we propose an improved Proof of Authority consensus algorithm called“Proof of Authority with Random Election”(PoARE),implemented within QBIoT for leader selection and new block creation.Thirdly,we develop a publickey quantum signature protocol for transaction verification in the blockchain.Finally,a comprehensive security analysis of QBIoT demonstrates its resilience against cyber threats from both classical and quantum adversaries.In summary,this research introduces an innovative quantum-enhanced blockchain solution to address quantum security concernswithin the realmof IoT.The proposedQBIoT framework contributes to the ongoing development of quantum blockchain technology and offers valuable insights for future research on IoT security.

Quantum synchronization with correlated baths

We study quantum synchronization under the nonequilibrium reservoirs.We consider a two-qubit XXZ chain coupled independently to their own reservoirs modeled by the collisional model.Two reservoir particles,initially prepared in a thermal state or a state with coherence,are correlated through a unitary transformation and afterward interact locally with the two quantum subsystems.We study the quantum effect of reservoir on synchronous dynamics of system.By preparing different reservoir initial states or manipulating the reservoir particles coupling and the temperature gradient,we find that quantum entanglement of reservoir is the key to control quantum synchronization of system qubits.

Design of a novel hybrid quantum deep neural network in INEQR images classification

We redesign the parameterized quantum circuit in the quantum deep neural network, construct a three-layer structure as the hidden layer, and then use classical optimization algorithms to train the parameterized quantum circuit, thereby propose a novel hybrid quantum deep neural network(HQDNN) used for image classification. After bilinear interpolation reduces the original image to a suitable size, an improved novel enhanced quantum representation(INEQR) is used to encode it into quantum states as the input of the HQDNN. Multi-layer parameterized quantum circuits are used as the main structure to implement feature extraction and classification. The output results of parameterized quantum circuits are converted into classical data through quantum measurements and then optimized on a classical computer. To verify the performance of the HQDNN, we conduct binary classification and three classification experiments on the MNIST(Modified National Institute of Standards and Technology) data set. In the first binary classification, the accuracy of 0 and 4 exceeds98%. Then we compare the performance of three classification with other algorithms, the results on two datasets show that the classification accuracy is higher than that of quantum deep neural network and general quantum convolutional neural network.

Quafu-RL:The cloud quantum computers based quantum reinforcement learning

With the rapid advancement of quantum computing,hybrid quantum–classical machine learning has shown numerous potential applications at the current stage,with expectations of being achievable in the noisy intermediate-scale quantum(NISQ)era.Quantum reinforcement learning,as an indispensable study,has recently demonstrated its ability to solve standard benchmark environments with formally provable theoretical advantages over classical counterparts.However,despite the progress of quantum processors and the emergence of quantum computing clouds,implementing quantum reinforcement learning algorithms utilizing parameterized quantum circuits(PQCs)on NISQ devices remains infrequent.In this work,we take the first step towards executing benchmark quantum reinforcement problems on real devices equipped with at most 136 qubits on the BAQIS Quafu quantum computing cloud.The experimental results demonstrate that the policy agents can successfully accomplish objectives under modified conditions in both the training and inference phases.Moreover,we design hardware-efficient PQC architectures in the quantum model using a multi-objective evolutionary algorithm and develop a learning algorithm that is adaptable to quantum devices.We hope that the Quafu-RL can be a guiding example to show how to realize machine learning tasks by taking advantage of quantum computers on the quantum cloud platform.

Quantum block coherence with respect to projective measurements

Quantum coherence serves as a defining characteristic of quantum mechanics,finding extensive applications in quantum computing and quantum communication processing.This study explores quantum block coherence in the context of projective measurements,focusing on the quantification of such coherence.Firstly,we define the correlation function between the two general projective measurements P and Q,and analyze the connection between sets of block incoherent states related to two compatible projective measurements P and Q.Secondly,we discuss the measure of quantum block coherence with respect to projective measurements.Based on a given measure of quantum block coherence,we characterize the existence of maximal block coherent states through projective measurements.This research integrates the compatibility of projective measurements with the framework of quantum block coherence,contributing to the advancement of block coherence measurement theory.

Single-photon scattering and quantum entanglement of two giant atoms with azimuthal angle differences in a waveguide system

We theoretically investigate coherent scattering of single photons and quantum entanglement of two giant atoms with azimuthal angle differences in a waveguide system.Using the real-space Hamiltonian,analytical expressions are derived for the transport spectra scattered by these two giant atoms with four azimuthal angles.Fano-like resonance can be exhibited in the scattering spectra by adjusting the azimuthal angle difference.High concurrence of the entangled state for two atoms can be implemented in a wide angle-difference range,and the entanglement of the atomic states can be switched on/off by modulating the additional azimuthal angle differences from the giant atoms.This suggests a novel handle to effectively control the single-photon scattering and quantum entanglement.