Superior energy storage efficiency through tailoring relaxor behavior and band energy gap in KNN-based ferroelectric ceramic capacitors

With the increasing demand of high-power and pulsed power electronic devices,environmental-friendly potassium sodium niobate((Na_(0.5)K_(0.5))NbO_(3),KNN)ceramic-based capacitors have attracted much attention in recent years owning to the boosted energy storage density(W_(rec)).Nevertheless,the dielectric loss also increases as the external electric field increases,which will generate much dissipated energy and raise the temperature of ceramic capacitors.Thus,an effective strategy is proposed to enhance the energy storage efficiency(η)via tailoring relaxor behavior and bad gap energy in the ferroelectric 0.9(Na_(0.5)K_(0.5))-NbO_(3)-0.1Bi(Zn_(2/3)(Nb_(x)Ta_(1−x))1/3)O_(3) ceramics.On the one hand,the more diverse ions in the B-sites owing to introducing the Ta could further disturb the long-range ferroelectric polar order to form the short−range polar nanoregions(PNRs),resulting in the highη.On the other hand,the introduction of Ta ions could boost the intrinsic band energy gap and thus improve the Eb.As a result,high Wrec of 3.29 J/cm^(3) and ultrahighηof 90.1%at the high external electric field of 310 kV/cm are achieved in x=0.5 sample.These results reveal that the KNN-based ceramics are promising lead-free candidate for high-power electronic devices.

Fine root litter quality regulates soil carbon storage efficiency in subtropical forest soils

●High-quality and low-quality root litter had contrasting patterns of mass loss.●Greater litter-derived C was incorporated into soils under high-quality root litter.●Root litter decay rate or litter-derived C were related to soil microbial diversity.●Root litter quality had little effect on soil physicochemical properties.●High root litter quality was the main driver of enhanced soil C storage efficiency.Decomposing root litter is a major contributor to soil carbon(C)storage in forest soils.During decomposition,the quality of root litter could play a critical role in soil C storage.However,it is unclear whether root litter quality influences soil C storage efficiency.We conducted a two-year greenhouse decomposition experiment using 13C-labeled fine root litter of two tree species to investigate how root litter quality,represented by C to nitrogen(C/N)ratios,regulates decomposition and C storage efficiency in subtropical forest soils in China.‘High-quality’root litter(C/N ratio=26)decayed faster during the first year(0−410 days),whereas‘low-quality’root litter(C/N ratio=46)decomposed faster toward the end of the two-year period(598−767 days).However,over the two years of the study,mass loss from high-quality root litter(29.14±1.42%)was lower than‘low-quality’root litter(33.01±0.54%).Nonetheless,root litter C storage efficiency(i.e.,the ratio of new root litter-derived soil C to total mineralized root litter C)was significantly greater for high-quality root litter,with twice as much litter-derived C stored in soils compared to low-quality root litter at the end of the experiment.Root litter quality likely influenced soil C storage via changes in microbial diversity,as the decomposition of high-quality litter declined with increasing bacterial diversity,whereas the amount of litter-derived soil C from low-quality litter increased with fungal diversity.Our results thus reveal that root litter quality mediates decomposition and C storage in subtropical forest soils in China and future work should consider the links between root litter quality and soil microbial diversity.

Recent Progress and Future Trends on the State of Charge Estimation Methods to Improve Battery-storage Efficiency: A Review

Battery storage systems are subject to frequent charging/discharging cycles,which reduce the operational life of the battery and reduce system reliability in the long run.As such,several Battery Management Systems(BMS)have been developed to maintain system reliability and extend the battery’s operative life.Accurate estimation of the battery’s State of Charge(SOC)is a key challenge in the BMS due to its non-linear characteristics.This paper presents a comprehensive review on the most recent classifications and mathematical models for SOC estimation.Future trends for SOC estimation methods are also presented.

Sodium bismuth titanate-based perovskite ceramics with high energy storage efficiency and discharge performance

Designing dielectric materials with the tremendous energy storage density is fundamentally important for developing pulse power capacitors.An effective approach was proposed to favorably modify the dielectric energy storage properties(ESP)of Bi_(0.5)Na_(0.5)TiO_(3) ceramics using CaTiO_(3) incorporation.The dielectric breakdown strength was effectively enhanced,and simultaneously the relaxor behavior was optimized to lower the remnant polarization,which is resulted from the decreased grains size with the introduction of Ca^(2+)ion.Remarkably,at a CaTiO_(3) doping level of 0.2,a 0.8Bi_(0.5)Na_(0.5)TiO_(3)-0.2CaTiO_(3)(0.8BNT-0.2CT)ceramic obtained both high energy storage density(Wtotal)of~1.38 J/cm^(3) together with excellent efficiency(h)of~91.3%.Furthermore,an ultrafast discharge response speed(t0:9)~94 ns was achieved in 0.8BNT-0.2CT ceramic,as well as tremendous current density(C_(D)~1520 A/cm2)and power density(P_(D)~115 MW/cm^(3)).This study not only revealed the superior ESP mechanism as regards Bi_(0.5)Na_(0.5)TiO_(3) based ceramics but also provided candidate materials in pulse power capacitor devices.

Efficient cache replacement framework based on access hotness for spacecraft processors

A notable portion of cachelines in real-world workloads exhibits inner non-uniform access behaviors.However,modern cache management rarely considers this fine-grained feature,which impacts the effective cache capacity of contemporary high-performance spacecraft processors.To harness these non-uniform access behaviors,an efficient cache replacement framework featuring an auxiliary cache specifically designed to retain evicted hot data was proposed.This framework reconstructs the cache replacement policy,facilitating data migration between the main cache and the auxiliary cache.Unlike traditional cacheline-granularity policies,the approach excels at identifying and evicting infrequently used data,thereby optimizing cache utilization.The evaluation shows impressive performance improvement,especially on workloads with irregular access patterns.Benefiting from fine granularity,the proposal achieves superior storage efficiency compared with commonly used cache management schemes,providing a potential optimization opportunity for modern resource-constrained processors,such as spacecraft processors.Furthermore,the framework complements existing modern cache replacement policies and can be seamlessly integrated with minimal modifications,enhancing their overall efficacy.

Storage-efficient reconstruction framework for planar contours

A storage-efficient reconstruction framework for cartographic planar contours is developed.With a smaller number of control points,we aim to calculate the area and perimeter as well as to reconstruct a smooth curve.The input data forms an oriented contour,each control point of which consists of three values:the Cartesian coordinates(x,y)and tangent angleθ.Two types of interpolation methods are developed,one of which is based on an arc spline while the other one is on a cubic Hermite spline.The arc spline-based method reconstructs a G1 continuous curve,with which the exact area and perimeter can be calculated.The benefit of using the Hermite spline-based method is that it can achieve G2 continuity on most control points and can obtain the exact area,whereas the resulting perimeter is approximate.In a numerical experiment for analytically defined curves,more accurate computation of the area and perimeter was achieved with a smaller number of control points.In another experiment using a digital elevation model data,the reconstructed contours were smoother than those by a conventional method.

Rational construction of densely packed Si/MXene composite microspheres enables favorable sodium storage

The fast and reversible sodiation/desodiation of anode materials remains an indelible yet fascinating target.Herein, a class of the densely packed Si/MXene composite microspheres is constructed and prepared, taking advantages of the synergistic effects of the activated Si nanoparticles and conductive flower-like MXene microspheres with ample ion-diffusion pathways. Consequently,the intrinsic MXene nanosheets with intelligently regulated interlayer spacing can accommodate the volume change induced strain during cycling, and the strong interaction between the Si and MXene matrix greatly contributes to the robust structural stability. As expected, the Si/MXene composite architecture exhibits boosted sodium storage performance, in terms of an inspiring reversible capacity of 751 mAh·g^(-1)at 0.1 A·g^(-1), remarkable long-term cycling stability of 376 mAh·g^(-1)at 0.1 A·g^(-1) over 500 cycles, and outstanding rate capability(after one consecutive current density changing from 0.1 to 2.0 A·g^(-1), a large capacity of 275 mAh·g^(-1) is regained after suddenly returning the initial current density back to 0.1 A·g^(-1) and in the subsequent 200 cycles this composite architecture anode still delivers a capacity of 332 mAh·g^(-1)). The kinetics analysis indicates superior pseudocapacitive property, high electronic conductivity, and favorable sodium-ion adsorption and diffusion capability,confirming fast sodium storage performance. Impressively, ex-situ X-ray diffraction and selected area electron diffraction characterizations corroborate the formation of NaSi;as the main sodiation products during the reversible evolutions of cycled proceeding with sodium-ion insertion. This work sheds light on the elaborate design of silicon-based nanostructured anodes towards advanced high-performance sodium-ion batteries.

Effects of the buried straw layer on soil water and nitrogen distribution under different irrigation limits

At present,water and fertilizer use efficiency is low in many cultivation areas in southern China.Studies show that the buried straw layer can effectively conserve water and fertilizer.To investigate the optimal irrigation upper limit above the straw barrier and its effect on soil moisture and nitrogen distribution,an indoor soil column experiment was conducted.Six treatments were designed consisting of two levels of straw layer i.e.,(with and without buried straw layer at 25 cm depth),and three irrigation water upper limits i.e.,(saturated moisture content(s),field water holding capacity(f),and 80%of field water holding capacity(0.8f)as the upper limit of irrigation).The result revealed that the buried straw layer can inhibit water infiltration and significantly increase the water storage capacity and water storage efficiency of 0-25 cm soil depth.Under the condition of no evaporation,when the upper limit of irrigation water does not exceed the field water holding capacity,the storage efficiency of 0-25 cm soil water reaches 89%-91%after 6 d.Moreover,a buried straw layer can inhibit the deep percolation of nitrate nitrogen and increase the amount of nitrate-nitrogen in 0-25 cm soil.The 80%field water holding capacity irrigation upper limit combined with straw interlayer treatment had a higher nitrate-nitrogen content in the 0-25 cm soil layer than other treatments.Therefore,80%of field water holding capacity as the upper limit of irrigation combined with buried straw layer is the optimal strategy to conserve soil water and nitrogen in the upper soil profile.