Postoperative tunnel enlargement has been frequently reported after anterior cruciate ligament(ACL)reconstruction.Interference screw,as a surgical implant in ACL reconstruction,may influence natural loading transmis...Postoperative tunnel enlargement has been frequently reported after anterior cruciate ligament(ACL)reconstruction.Interference screw,as a surgical implant in ACL reconstruction,may influence natural loading transmission and contribute to tunnel enlargement.The aims of this study are(1)to quantify the alteration of strain energy density(SED)distribution after the anatomic single-bundle ACL reconstruction;and(2)to characterize the influence of screw length and diameter on the degree of the SED alteration.A validated finite element model of human knee joint was used.The screw length ranging from 20 to 30 mm with screw diameter ranging from 7 to 9 mm were investigated.In the post-operative knee,the SED increased steeply at the extra-articular tunnel aperture under compressive and complex loadings,whereas the SED decreased beneath the screw shaft and nearby the intra-articular tunnel aperture.Increasing the screw length could lower the SED deprivation in the proximal part of the bone tunnel;whereas increasing either screw length or diameter could aggravate the SED deprivation in the distal part of the bone tunnel.Decreasing the elastic modulus of the screw could lower the bone SED deprivation around the screw.In consideration of both graft stability and SED alteration,a biodegradable interference screw with a long length is recommended,which could provide a beneficial mechanical environment at the distal part of the tunnel,and meanwhile decrease the bone-graft motion and synovial fluid propagation at the proximal part of the tunnel.These findings together with the clinical and histological factors could help to improve surgical outcome,and serve as a preliminary knowledge for the following study of biodegradable interference screw.展开更多
Based on pseudo strain energy density (PSED) and grey relation coefficient (GRC), an index is proposed to locate the damage of beam-type structures in time-domain. The genetic algorithm (GA) is utilized to identify th...Based on pseudo strain energy density (PSED) and grey relation coefficient (GRC), an index is proposed to locate the damage of beam-type structures in time-domain. The genetic algorithm (GA) is utilized to identify the structural damage severity of confirmed damaged locations. Furthermore, a systematic damage identification program based on GA is developed on MATLAB platform. ANSYS is employed to conduct the finite element analysis of complicated civil engineering structures, which is embedded with interface technique. The two-step damage identification is verified by a finite element model of Xinxingtang Highway Bridge and a laboratory beam model based on polyvinylidens fluoride (PVDF). The bridge model was constructed with 57 girder segments, and simulated with 58 measurement points. The damaged segments were located accurately by GRC index regardless of damage extents and noise levels. With stiffness reduction factors of detected segments as variables, the GA program evolved for 150 generations in 6 h and identified the damage extent with the maximum errors of 1% and 3% corresponding to the noise to signal ratios of 0 and 5%, respectively. In contrast, the common GA-based method without using GRC index evolved for 600 generations in 24 h, but failed to obtain satisfactory results. In the laboratory test, PVDF patches were used as dynamic strain sensors, and the damage locations were identified due to the fact that GRC indexes of points near damaged elements were smaller than 0.6 while those of others were larger than 0.6. The GA-based damage quantification was also consistent with the value of crack depth in the beam model.展开更多
Based on strain signals, a new time-domain methodology for detecting the beam local damage has been developed. The pseudo strain energy density (PSED) is defined and used to build two major damage indexes, the avera...Based on strain signals, a new time-domain methodology for detecting the beam local damage has been developed. The pseudo strain energy density (PSED) is defined and used to build two major damage indexes, the average pseudo strain energy density (APSED) and the average pseudo strain energy density rate (APSEDR). Probability and mathematical statistics are utilized to derive a standardized damage index. Furthermore, by applying the analytic relation between the strain energy release rate and the stress intensity factor, an analytic solution of crack depth is derived. For the dynamic strain signals, the wavelet packet transform is used to pre-process measured data. Finally, a numerical simulation indicates that this method can effectively identify the damage location and its absolute severity.展开更多
In order to determine the relationship among energy consumption of rock and its fragmentation, dynamic strength and strain rate, granite, sandstone and limestone specimens were chosen and tested on large-diameter spli...In order to determine the relationship among energy consumption of rock and its fragmentation, dynamic strength and strain rate, granite, sandstone and limestone specimens were chosen and tested on large-diameter split Hopkinson pressure bar (SHPB) equipment with half-sine waveform loading at the strain rates ranging from 40 to 150 s- 1. With recorded signals, the energy consumption, strain rate and dynamic strength were analyzed. And the fragmentation behaviors of specimens were investigated. The experimental results show that the energy consumption density of rock increases linearly with the total incident energy. The energy consumption density is of an exponent relationship with the average size of rock fragments. The higher the energy consumption density, the more serious the fragmentation, and the better the gradation of fragments. The energy consumption density takes a good logarithm relationship with the dynamic strength of rock. The dynamic strength of rock increases with the increase of strain rate, indicating higher strain rate sensitivity.展开更多
In this article,the post-peak softening stage of the constitutive relation and the elastic stiffness degradation of concrete are investigated,and a highly reasonable constitutive relation curve is proposed.At the mate...In this article,the post-peak softening stage of the constitutive relation and the elastic stiffness degradation of concrete are investigated,and a highly reasonable constitutive relation curve is proposed.At the material level,the energy change in the concrete failure process is studied based on the different stress-strain curves of concrete under uniaxial tension and compression.The concrete failure criterion based on elastic strain energy density is deemed suitable and consistent with the experimental phenomena.The hysteresis phenomenon(lags behind the peak strength)is also discussed.At the structure level,the strength reduction method is employed for the stability analysis,the energy change in the failure process of the Long Xi-Kou Dam is examined,and the results show that the dam failure criterion based on elastic strain energy shows a greater significance in practical applications compared with other conventional structural failure criteria in engineering.This criterion is objective and can avoid subjective arbitrariness.展开更多
KVPO_(4)F with excellent structural stability and high operating voltage has been identified as a promising cathode for potassium-ion batteries(PIBs),but limits in sluggish ion transport and severe volume change cause...KVPO_(4)F with excellent structural stability and high operating voltage has been identified as a promising cathode for potassium-ion batteries(PIBs),but limits in sluggish ion transport and severe volume change cause insufficient potassium storage capability.Here,a high-energy and low-strain KVPO_(4)F composite cathode assisted by multifunctional K_(2)C_(4)O_(4)electrode stabilizer is exquisitely designed.Systematical electrochemical investigations demonstrate that this composite cathode can deliver a remarkable energy density up to 530 Wh kg^(-1)with 142.7 mAh g^(-1)of reversible capacity at 25 mA g^(-1),outstanding rate capability of 70.6 mAh g^(-1)at 1000 mA g^(-1),and decent cycling stability.Furthermore,slight volume change(~5%)and increased interfacial stability with thin and even cathode-electrolyte interphase can be observed through in situ and ex situ characterizations,which are attributed to the synergistic effect from in situ potassium compensation and carbon deposition through self-sacrificing K_(2)C_(4)O_(4)additive.Moreover,potassium-ion full cells manifest significant improvement in energy density and cycling stability.This work demonstrates a positive impact of K_(2)C_(4)O_(4)additive on the comprehensive electrochemical enhancement,especially the activation of high-voltage plateau capacity and provides an efficient strategy to enlighten the design of other high-voltage cathodes for advanced high-energy batteries.展开更多
Platinum(Pt)-based noble metal catalysts(PGMs)are the most widely used commercial catalysts,but they have the problems of high cost,low reserves,and susceptibility to small-molecule toxicity.Transition metal oxides(TM...Platinum(Pt)-based noble metal catalysts(PGMs)are the most widely used commercial catalysts,but they have the problems of high cost,low reserves,and susceptibility to small-molecule toxicity.Transition metal oxides(TMOs)are regarded as potential substitutes for PGMs because of their stability in oxidizing environments and excellent catalytic performance.In this study,comprehensive investigation into the influence of elastic strains on the adsorption energies of carbon(C),hydrogen(H)and oxygen(O)on TMOs was conducted.Based on density functional theory(DFT)calculations,these effects in both tetragonal structures(PtO_(2),PdO_(2))and hexagonal structures(ZnO,CdO),along with their respective transition metals were systematically explored.It was identified that the optimal adsorption sites on metal oxides pinpointed the top of oxygen or the top of metal atom,while face-centered cubic(FCC)and hexagonal close-packed(HCP)holes were preferred for the transition metals.Furthermore,under the influence of elastic strains,the results demonstrated significant disparities in the adsorption energies of H and O between oxides and transition metals.Despite these differences,the effect of elastic strains on the adsorption energies of C,H and O on TMOs mirrored those on transition metals:adsorption energies increased under compressive strains,indicating weaker adsorption,and decreased under tension strains,indicating stronger adsorption.This behavior was rationalized based on the d-band model for adsorption atop a metallic atom or the p-band model for adsorption atop an oxygen atom.Consequently,elastic strains present a promising avenue for tailoring the catalytic properties of TMOs.展开更多
The electronic structures of (CdSe)n/(ZnSe)m strained-lager soperfattice (SLS) were investigated by the recursion method in the tight-bindiop opproximation. The total,local, and partial density of states were calculat...The electronic structures of (CdSe)n/(ZnSe)m strained-lager soperfattice (SLS) were investigated by the recursion method in the tight-bindiop opproximation. The total,local, and partial density of states were calculated for n=1, m=5.The total density of states (TDOS) for bulk CdSe, ZnSe and n=1, 3, m=1, 3, 5, for SLS were investigated.Fermi energy, the band gap, the valence of an atom, and the ionization potential and the electron affinity were discassed.展开更多
In this paper the conception of theoretical determine the relations between material experimental characteristics is presented. On the base of stress-strain relations for nonlinear elastic anisotropic material and geo...In this paper the conception of theoretical determine the relations between material experimental characteristics is presented. On the base of stress-strain relations for nonlinear elastic anisotropic material and geometrical interpretation of deformation state, the general form of strain energy density function was introduced. Using this function and variational methods the relations between material characteristics were achieved. All considerations are illustrated by a short theoretical example.展开更多
The objective of this paper was to study low temperature crack resistance mechanism of steel slag asphalt mixture(SAM).Thermal stress restrained specimen test(TSRST)and three-point bending test were carried out to eva...The objective of this paper was to study low temperature crack resistance mechanism of steel slag asphalt mixture(SAM).Thermal stress restrained specimen test(TSRST)and three-point bending test were carried out to evaluate the low-temperature crack resistance of SAM and basalt asphalt mixture(BAM).Based on the digital image correlation technique(DIC),the strain field distribution and crack propagation of SAM were analyzed from the microscopic point of view,and a new index,crack length factor(C),was proposed to evaluate the crack resistance of the asphalt mixture.The crystal phase composition and microstructure of steel slag aggregate(SA)and basalt aggregate(BA)were studied by X-ray diffraction(XRD)and scanning electron microscopy(SEM)to explore the low-temperature crack resistance mechanism of SAM.Results show that the low-temperature crack resistance of SAM is better than that of BAM;SAM has good integrity and persistent elastic deformation,and its bending failure mode is a hysteretic quasi-brittle failure;The SA surface is evenly distributed with pores and has surface roughness.SA has the composition phase of alkaline aggregate-calcite(CaCO3),so it has good adhesion to asphalt,which reveals the mechanism of excellent low-temperature crack resistance of SAM.展开更多
基金supported by the National Science & Technology Pillar Program of China(2012BAI18B07 and 2012BAI22B02)the National Natural Science Foundation of China(10925208 and 11120101001)the National Key Lab of Virtual Reality Technology
文摘Postoperative tunnel enlargement has been frequently reported after anterior cruciate ligament(ACL)reconstruction.Interference screw,as a surgical implant in ACL reconstruction,may influence natural loading transmission and contribute to tunnel enlargement.The aims of this study are(1)to quantify the alteration of strain energy density(SED)distribution after the anatomic single-bundle ACL reconstruction;and(2)to characterize the influence of screw length and diameter on the degree of the SED alteration.A validated finite element model of human knee joint was used.The screw length ranging from 20 to 30 mm with screw diameter ranging from 7 to 9 mm were investigated.In the post-operative knee,the SED increased steeply at the extra-articular tunnel aperture under compressive and complex loadings,whereas the SED decreased beneath the screw shaft and nearby the intra-articular tunnel aperture.Increasing the screw length could lower the SED deprivation in the proximal part of the bone tunnel;whereas increasing either screw length or diameter could aggravate the SED deprivation in the distal part of the bone tunnel.Decreasing the elastic modulus of the screw could lower the bone SED deprivation around the screw.In consideration of both graft stability and SED alteration,a biodegradable interference screw with a long length is recommended,which could provide a beneficial mechanical environment at the distal part of the tunnel,and meanwhile decrease the bone-graft motion and synovial fluid propagation at the proximal part of the tunnel.These findings together with the clinical and histological factors could help to improve surgical outcome,and serve as a preliminary knowledge for the following study of biodegradable interference screw.
基金Supported by National Natural Science Foundation of China (No. 50778077 and No. 50608036)
文摘Based on pseudo strain energy density (PSED) and grey relation coefficient (GRC), an index is proposed to locate the damage of beam-type structures in time-domain. The genetic algorithm (GA) is utilized to identify the structural damage severity of confirmed damaged locations. Furthermore, a systematic damage identification program based on GA is developed on MATLAB platform. ANSYS is employed to conduct the finite element analysis of complicated civil engineering structures, which is embedded with interface technique. The two-step damage identification is verified by a finite element model of Xinxingtang Highway Bridge and a laboratory beam model based on polyvinylidens fluoride (PVDF). The bridge model was constructed with 57 girder segments, and simulated with 58 measurement points. The damaged segments were located accurately by GRC index regardless of damage extents and noise levels. With stiffness reduction factors of detected segments as variables, the GA program evolved for 150 generations in 6 h and identified the damage extent with the maximum errors of 1% and 3% corresponding to the noise to signal ratios of 0 and 5%, respectively. In contrast, the common GA-based method without using GRC index evolved for 600 generations in 24 h, but failed to obtain satisfactory results. In the laboratory test, PVDF patches were used as dynamic strain sensors, and the damage locations were identified due to the fact that GRC indexes of points near damaged elements were smaller than 0.6 while those of others were larger than 0.6. The GA-based damage quantification was also consistent with the value of crack depth in the beam model.
基金The National Natural Science Foundation of China (Nos.50778077 and 50608036)
文摘Based on strain signals, a new time-domain methodology for detecting the beam local damage has been developed. The pseudo strain energy density (PSED) is defined and used to build two major damage indexes, the average pseudo strain energy density (APSED) and the average pseudo strain energy density rate (APSEDR). Probability and mathematical statistics are utilized to derive a standardized damage index. Furthermore, by applying the analytic relation between the strain energy release rate and the stress intensity factor, an analytic solution of crack depth is derived. For the dynamic strain signals, the wavelet packet transform is used to pre-process measured data. Finally, a numerical simulation indicates that this method can effectively identify the damage location and its absolute severity.
基金Projects(50674107, 10472134, 50490274) supported by the National Natural Science Foundation of China
文摘In order to determine the relationship among energy consumption of rock and its fragmentation, dynamic strength and strain rate, granite, sandstone and limestone specimens were chosen and tested on large-diameter split Hopkinson pressure bar (SHPB) equipment with half-sine waveform loading at the strain rates ranging from 40 to 150 s- 1. With recorded signals, the energy consumption, strain rate and dynamic strength were analyzed. And the fragmentation behaviors of specimens were investigated. The experimental results show that the energy consumption density of rock increases linearly with the total incident energy. The energy consumption density is of an exponent relationship with the average size of rock fragments. The higher the energy consumption density, the more serious the fragmentation, and the better the gradation of fragments. The energy consumption density takes a good logarithm relationship with the dynamic strength of rock. The dynamic strength of rock increases with the increase of strain rate, indicating higher strain rate sensitivity.
基金supported by The National Natural Science Foundation of China(No.51739006,11132003).
文摘In this article,the post-peak softening stage of the constitutive relation and the elastic stiffness degradation of concrete are investigated,and a highly reasonable constitutive relation curve is proposed.At the material level,the energy change in the concrete failure process is studied based on the different stress-strain curves of concrete under uniaxial tension and compression.The concrete failure criterion based on elastic strain energy density is deemed suitable and consistent with the experimental phenomena.The hysteresis phenomenon(lags behind the peak strength)is also discussed.At the structure level,the strength reduction method is employed for the stability analysis,the energy change in the failure process of the Long Xi-Kou Dam is examined,and the results show that the dam failure criterion based on elastic strain energy shows a greater significance in practical applications compared with other conventional structural failure criteria in engineering.This criterion is objective and can avoid subjective arbitrariness.
基金the financial support from the National Key R&D Program of China(Grant No.2023YFE0202000)the National Natural Science Foundation of China(Grant No.52102213)+1 种基金Natural Science Foundation of Jilin Province(Grant No.20230101128JC)Double-Thousand Talents Plan of Jiangxi Province(jxsq2023102005)
文摘KVPO_(4)F with excellent structural stability and high operating voltage has been identified as a promising cathode for potassium-ion batteries(PIBs),but limits in sluggish ion transport and severe volume change cause insufficient potassium storage capability.Here,a high-energy and low-strain KVPO_(4)F composite cathode assisted by multifunctional K_(2)C_(4)O_(4)electrode stabilizer is exquisitely designed.Systematical electrochemical investigations demonstrate that this composite cathode can deliver a remarkable energy density up to 530 Wh kg^(-1)with 142.7 mAh g^(-1)of reversible capacity at 25 mA g^(-1),outstanding rate capability of 70.6 mAh g^(-1)at 1000 mA g^(-1),and decent cycling stability.Furthermore,slight volume change(~5%)and increased interfacial stability with thin and even cathode-electrolyte interphase can be observed through in situ and ex situ characterizations,which are attributed to the synergistic effect from in situ potassium compensation and carbon deposition through self-sacrificing K_(2)C_(4)O_(4)additive.Moreover,potassium-ion full cells manifest significant improvement in energy density and cycling stability.This work demonstrates a positive impact of K_(2)C_(4)O_(4)additive on the comprehensive electrochemical enhancement,especially the activation of high-voltage plateau capacity and provides an efficient strategy to enlighten the design of other high-voltage cathodes for advanced high-energy batteries.
基金Science and Technology Commission of Shanghai Municipality(21ZR1472900,22ZR1471600)。
文摘Platinum(Pt)-based noble metal catalysts(PGMs)are the most widely used commercial catalysts,but they have the problems of high cost,low reserves,and susceptibility to small-molecule toxicity.Transition metal oxides(TMOs)are regarded as potential substitutes for PGMs because of their stability in oxidizing environments and excellent catalytic performance.In this study,comprehensive investigation into the influence of elastic strains on the adsorption energies of carbon(C),hydrogen(H)and oxygen(O)on TMOs was conducted.Based on density functional theory(DFT)calculations,these effects in both tetragonal structures(PtO_(2),PdO_(2))and hexagonal structures(ZnO,CdO),along with their respective transition metals were systematically explored.It was identified that the optimal adsorption sites on metal oxides pinpointed the top of oxygen or the top of metal atom,while face-centered cubic(FCC)and hexagonal close-packed(HCP)holes were preferred for the transition metals.Furthermore,under the influence of elastic strains,the results demonstrated significant disparities in the adsorption energies of H and O between oxides and transition metals.Despite these differences,the effect of elastic strains on the adsorption energies of C,H and O on TMOs mirrored those on transition metals:adsorption energies increased under compressive strains,indicating weaker adsorption,and decreased under tension strains,indicating stronger adsorption.This behavior was rationalized based on the d-band model for adsorption atop a metallic atom or the p-band model for adsorption atop an oxygen atom.Consequently,elastic strains present a promising avenue for tailoring the catalytic properties of TMOs.
文摘The electronic structures of (CdSe)n/(ZnSe)m strained-lager soperfattice (SLS) were investigated by the recursion method in the tight-bindiop opproximation. The total,local, and partial density of states were calculated for n=1, m=5.The total density of states (TDOS) for bulk CdSe, ZnSe and n=1, 3, m=1, 3, 5, for SLS were investigated.Fermi energy, the band gap, the valence of an atom, and the ionization potential and the electron affinity were discassed.
文摘In this paper the conception of theoretical determine the relations between material experimental characteristics is presented. On the base of stress-strain relations for nonlinear elastic anisotropic material and geometrical interpretation of deformation state, the general form of strain energy density function was introduced. Using this function and variational methods the relations between material characteristics were achieved. All considerations are illustrated by a short theoretical example.
基金Funded by the National Natural Science Foundation of China(No.11962024)Key Technology Project of Inner Mongolia Autonomous Region(No.2019GG031)。
文摘The objective of this paper was to study low temperature crack resistance mechanism of steel slag asphalt mixture(SAM).Thermal stress restrained specimen test(TSRST)and three-point bending test were carried out to evaluate the low-temperature crack resistance of SAM and basalt asphalt mixture(BAM).Based on the digital image correlation technique(DIC),the strain field distribution and crack propagation of SAM were analyzed from the microscopic point of view,and a new index,crack length factor(C),was proposed to evaluate the crack resistance of the asphalt mixture.The crystal phase composition and microstructure of steel slag aggregate(SA)and basalt aggregate(BA)were studied by X-ray diffraction(XRD)and scanning electron microscopy(SEM)to explore the low-temperature crack resistance mechanism of SAM.Results show that the low-temperature crack resistance of SAM is better than that of BAM;SAM has good integrity and persistent elastic deformation,and its bending failure mode is a hysteretic quasi-brittle failure;The SA surface is evenly distributed with pores and has surface roughness.SA has the composition phase of alkaline aggregate-calcite(CaCO3),so it has good adhesion to asphalt,which reveals the mechanism of excellent low-temperature crack resistance of SAM.