期刊文献+
共找到227篇文章
< 1 2 12 >
每页显示 20 50 100
Achieving gradient heterogeneous structure in Mg alloy for excellent strength-ductility synergy 被引量:2
1
作者 Jing Han Jiapeng Sun +6 位作者 Yuanming Song Bingqian Xu Zhenquan Yang Songsong Xu Ying Han Guosong Wu Jiyun Zhao 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第7期2392-2403,共12页
Most metals including Mg alloys have a longstanding dilemma of strength-ductility trade-off,which is hindering their wider applications.In this study,we propose a gradient heterogeneous grain(GHG)structure for evading... Most metals including Mg alloys have a longstanding dilemma of strength-ductility trade-off,which is hindering their wider applications.In this study,we propose a gradient heterogeneous grain(GHG)structure for evading this trade-off dilemma and ultrasonic severe surface rolling is attempted to construct this novel structure in ZE41 Mg alloy.Here,the GHG structure combine the benefits of gradient structure and heterogeneous grain structure and introduce large microstructural heterogeneities.Compared to the coarse-grain and heterogeneous-grain structured alloys,the GHG structured one exhibits dramatical enhancement in strength,ductility,and strain hardening capability.To the best of our knowledge,its strength becomes much higher than that of common ZE41 Mg alloys at no reduction in ductility.These unique mechanical properties stem from not only the individual contribution of the heterogeneous structure components including the fine/ultrafine grains and deformed coarse grains but also their synergistic effect via hetero-deformation induced strengthening and hardening effects.In summary,our study provides a feasible way to develop new Mg alloys with high strength and good ductility. 展开更多
关键词 Mg alloy ZE41 GRADIENT Heterostructure strength-ductility trade-off
下载PDF
Enhanced strength-ductility synergy in a wire and arc additively manufactured Mg alloy via tuning interlayer dwell time 被引量:1
2
作者 Dong Ma Chunjie Xu +6 位作者 Shang Sui Jun Tian Can Guo Xiangquan Wu Zhongming Zhang Dan Shechtman Sergei Remennik 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第12期4696-4709,共14页
Strength-ductility trade-off is a common issue in Mg alloys. This work proposed that a synergistic enhancement of strength and ductility could be achieved through tuning interlayer dwell time(IDT) in the wire and arc ... Strength-ductility trade-off is a common issue in Mg alloys. This work proposed that a synergistic enhancement of strength and ductility could be achieved through tuning interlayer dwell time(IDT) in the wire and arc additive manufacturing(WAAM) process of Mg alloy.The thermal couples were used to monitor the thermal history during the WAAM process. Additionally, the effect of different IDTs on the microstructure characteristics and resultant mechanical properties of WAAM-processed Mg alloy thin-wall were investigated. The results showed that the stable temperature of the thin-wall component could reach 290 ℃ at IDT=0s, indicating that the thermal accumulation effect was remarkable. Consequently, unimodal coarse grains with an average size of 39.6 μm were generated, and the resultant room-temperature tensile property was poor. With the IDT extended to 60s, the thermal input and thermal dissipation reached a balance, and the stable temperature was only 170 ℃, closing to the initial temperature of the substrate. A refined grain structure with bimodal size distribution was obtained. The remelting zone had fine grains with the size of 15.2 μm, while the arc zone owned coarse grains with the size of 24.5 μm.The alternatively distributed coarse and fine grains lead to the elimination of strength-ductility trade-off. The ultimate tensile strength and elongation of the samples at IDT=60s are increased by 20.6 and 75.0% of those samples at IDT=0s, respectively. The findings will facilitate the development of additive manufacturing processes for advanced Mg alloys. 展开更多
关键词 Wire arc additive manufacturing Interlayer dwell time strength-ductility Magnesium alloys
下载PDF
分离膜的Trade-off效应及其突破研究进展
3
作者 杨誉名 贾子钰 杨春维 《应用化工》 CAS CSCD 北大核心 2024年第6期1466-1468,共3页
综述通过文献调研,对膜材料在水通量与污染物截留效率之间存在的此消彼长的Trade-off效应进行分析,并对近几年国内外突破分离膜Trade-off效应的方法进行了总结。结果表明,膜表面接枝两性离子技术、非溶剂诱导相分离技术、结构改性技术... 综述通过文献调研,对膜材料在水通量与污染物截留效率之间存在的此消彼长的Trade-off效应进行分析,并对近几年国内外突破分离膜Trade-off效应的方法进行了总结。结果表明,膜表面接枝两性离子技术、非溶剂诱导相分离技术、结构改性技术、物理共混技术、表面涂覆技术等可以突破该技术瓶颈。而物理共混技术表现出非常优异的效果,且该技术方法相对简便,无需更新设备,易于实施,制备出的膜材料具有良好的机械性能和产水能力。综述为高效分离膜的开发提供了新的技术思路,为膜技术的应用和推广提供有益的技术借鉴。 展开更多
关键词 trade-off规律 膜材料 表面接枝法 表面涂覆法 掺杂法
下载PDF
The life-history trait trade-offs mediated by reproduction and immunity in the brown planthopper,Nilaparvata lugens Stål
4
作者 Dan Sun Hongfeng Wang +4 位作者 Jiahui Zeng Qiuchen Xu Mingyun Wang Xiaoping Yu Xuping Shentu 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第6期2018-2032,共15页
Reproduction and immune defense are costly functions,and they are expected to tradeoff with each other to drive evolution.The brown planthopper(BPH),Nilaparvata lugens Stål(Hemiptera,Delphacidae),is a global supe... Reproduction and immune defense are costly functions,and they are expected to tradeoff with each other to drive evolution.The brown planthopper(BPH),Nilaparvata lugens Stål(Hemiptera,Delphacidae),is a global superpest that mostly damages rice crops.Yeast-like symbionts(YLS)exist in the abdominal fat body tissue and are tightly associated with the development,growth,and reproduction of BPH.Our previous research demonstrated that mating behavior promotes the release of YLS from the fat body into the hemolymph in the BPH,thereby triggering an immune response.Additionally,the fitness costs related to life-history traits of BPH(such as survival rate)have a strong dependence on the relative abundance of YLS.However,the possible relationship between reproduction and the immune response in BPH has not been identified.In this study,an omics-based approach was used to analyze the transcriptome of fat body tissues in mated and unmated BPH at 72 h post-eclosion,from which two antimicrobial peptide genes,NlDefensin A(NlDfA)and NlDefensin B(NlDfB),were selected since they were highly expressed in mated BPH.Subsequently,the full-length cDNA sequences of the NlDfA and NlDfB genes were cloned and analyzed.qPCR results showed up-regulation of the NlDfA and NlDfB genes in mated BPH when compared to unmated BPH.Spatial-temporal expression analysis indicated that the NlDfA and NlDfB genes were expressed in all tissues and developmental stages,and they were most highly expressed in the fat body at 24 h post-eclosion.Moreover,the symbionts in BPH were significantly inhibited by the in vitro expression of the NlDfA and NlDfB proteins.Furthermore,RNA interference(RNAi)-mediated suppression of NlDfA and NlDfB dramatically increased the relative abundance of YLS in the fat body,while YLS in the hemolymph decreased significantly.These BPHs also displayed some fitness disadvantages in survival,fecundity,hatchability,and possibly the vertical transmission of YLS from hemolymph to egg.Our results indicated that mating could heighten the immunity of BPH by upregulating the expression of the NlDfA and NlDfB genes,which protect the host from pathogen challenges during reproduction.However,the reduced content of YLS may act as a fitness disadvantage in dictating the life-history traits of BPH.This work has significant theoretical and practical implications for the precise green control technology that involves crucial gene targeting,as well as for the“endosymbionts for pest control”strategy in insects. 展开更多
关键词 Nilaparvata lugens REPRODUCTION immune defense trade-off
下载PDF
Spatiotemporal variations in ecosystem services and their trade-offs and synergies against the background of the gully control and land consolidation project on the Loess Plateau,China
5
作者 WANG Jing WEI Yulu +2 位作者 PENG Biao LIU Siqi LI Jianfeng 《Journal of Arid Land》 SCIE CSCD 2024年第1期131-145,共15页
Studying the spatiotemporal variations in ecosystem services and their interrelationships on the Loess Plateau against the background of the gully control and land consolidation(GCLC)project has significant implicatio... Studying the spatiotemporal variations in ecosystem services and their interrelationships on the Loess Plateau against the background of the gully control and land consolidation(GCLC)project has significant implications for ecological protection and quality development of the Yellow River Basin.Therefore,in this study,we took Yan'an City,Shaanxi Province of China,as the study area,selected four typical ecosystem services,including soil conservation service,water yield service,carbon storage service,and habitat quality service,and quantitatively evaluated the spatiotemporal variation characteristics and trade-offs and synergies of ecosystem services from 2010 to 2018 using the Integrated Valuation of Ecosystem Services and Trade-offs(InVEST)model.We also analysed the relationship between the GCLC project and regional ecosystem service changes in various regions(including 1 city,2 districts,and 10 counties)of Yan'an City and proposed a coordinated development strategy between the GCLC project and the ecological environment.The results showed that,from 2010 to 2018,soil conservation service decreased by 7.76%,while the other three ecosystem services changed relatively little,with water yield service increasing by 0.56% and carbon storage service and habitat quality service decreasing by 0.16% and 0.14%,respectively.The ecological environment of Yan'an City developed in a balanced way between 2010 and 2018,and the four ecosystem services showed synergistic relationships,among which the synergistic relationships between soil conservation service and water yield service and between carbon storage service and habitat quality service were significant.The GCLC project had a negative impact on the ecosystem services of Yan'an City,and the impact on carbon storage service was more significant.This study provides a theoretical basis for the scientific evaluation of the ecological benefits of the GCLC project and the realization of a win-win situation between food security and ecological security. 展开更多
关键词 ecosystem services trade-offs and synergies gully control and land consolidation habitat quality Integrated Valuation of Ecosystem Services and trade-offs(InVEST)model Loess Plateau
下载PDF
Trade-offs and synergies between ecosystem services in Yutian County along the Keriya River Basin,Northwest China
6
作者 ZUBAIDA Muyibul 《Journal of Arid Land》 SCIE CSCD 2024年第7期943-962,共20页
The Keriya River Basin is located in an extremely arid climate zone on the southern edge of the Tarim Basin of Northwest China,exhibiting typical mountain-oasis-desert distribution characteristics.In recent decades,cl... The Keriya River Basin is located in an extremely arid climate zone on the southern edge of the Tarim Basin of Northwest China,exhibiting typical mountain-oasis-desert distribution characteristics.In recent decades,climate change and human activities have exerted significant impacts on the service functions of watershed ecosystems.However,the trade-offs and synergies between ecosystem services(ESs)have not been thoroughly examined.This study aims to reveal the spatiotemporal changes in ESs within the Keriya River Basin from 1995 to 2020 as well as the trade-offs and synergies between ESs.Leveraging the Integrated Valuation of Ecosystem Services and Trade-offs(InVEST)and Revised Wind Erosion Equation(RWEQ)using land use/land cover(LULC),climate,vegetation,soil,and hydrological data,we quantified the spatiotemporal changes in the five principal ESs(carbon storage,water yield,food production,wind and sand prevention,and habitat quality)of the watershed from 1995 to 2020.Spearman correlation coefficients were used to analyze the trade-offs and synergies between ES pairs.The findings reveal that water yield,carbon storage,and habitat quality exhibited relatively high levels in the upstream,while food production and wind and sand prevention dominated the midstream and downstream,respectively.Furthermore,carbon storage,food production,wind and sand prevention,and habitat quality demonstrated an increase at the watershed scale while water yield exhibited a decline from 1995 to 2020.Specifically,carbon storage,wind and sand prevention,and habitat quality presented an upward trend in the upstream but downward trend in the midstream and downstream.Food production in the midstream showed a continuously increasing trend during the study period.Trade-off relationships were identified between water yield and wind and sand prevention,water yield and carbon storage,food production and water yield,and habitat quality and wind and sand prevention.Prominent temporal and spatial synergistic relationships were observed between different ESs,notably between carbon storage and habitat quality,carbon storage and food production,food production and wind and sand prevention,and food production and habitat quality.Water resources emerged as a decisive factor for the sustainable development of the basin,thus highlighting the intricate trade-offs and synergies between water yield and the other four services,particularly the relationship with food production,which warrants further attention.This research is of great significance for the protection and sustainable development of river basins in arid areas. 展开更多
关键词 ecosystem services trade-offs SYNERGIES water yield food production habitat quality wind and sand prevention Tarim Basin
下载PDF
Trade-Offs and Synergie Effects of Regulating Ecosystem Services along an Climatic Gradient in Slovakia
7
作者 Jarmila Makovníková Stanislav Kološta Boris Pálka 《Journal of Geoscience and Environment Protection》 2024年第6期135-150,共16页
This study aims to assess the synergies and trade-offs of regulating ecosystem services. Ecosystem services are non-linearly interconnected and changes in one service can positively or negatively affect another. We ev... This study aims to assess the synergies and trade-offs of regulating ecosystem services. Ecosystem services are non-linearly interconnected and changes in one service can positively or negatively affect another. We evaluated ecosystem services based on biophysical indicators using an expert scoring system that determines the corresponding soil functions and is part of the existing databases available in Slovakia. This methodological combination enabled us to provide unique mapping and assessment of ecosystem services within Slovakia. Correlation analysis between individual regulating ecosystem services and climate regions, slope, texture, and altitude confirm the statistically significant influence of climate and slope in all agricultural land, arable land, and grassland ecosystems. Statistically significant synergistic effects were established between the regulation of the water regime and the regulation of soil erosion within each climate region, apart from the very warm climate region. Only in a very warm climate region was potential of regulating ecosystem services mutually beneficial for soil erosion control and soil cleaning potential (immobilization of inorganic pollutants). 展开更多
关键词 Agroecosystem Services Climatic Zone MAPPING trade-offs SYNERGIES
下载PDF
A rolled Mg-8Al-0.5Zn-0.8Ce alloy with high strength-ductility synergy via engineering high-density low angle boundaries 被引量:1
8
作者 Xiao Ma Min Zha +5 位作者 Siqing Wang Yi Yang Hailong Jia Dan Gao Cheng Wang Huiyuan Wang 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2022年第10期2889-2900,共12页
Developing low-cost rolled Mg alloys with both high strength and ductility is desirable,while the improved strength is generally accompanied with decreased ductility.Here,by using rotated hard-plate rolling(RHPR)with ... Developing low-cost rolled Mg alloys with both high strength and ductility is desirable,while the improved strength is generally accompanied with decreased ductility.Here,by using rotated hard-plate rolling(RHPR)with a total thickness reduction of~85%,we obtained a Mg-8Al-0.5Zn-0.8Ce(wt.%,AZ80-0.8Ce)alloy with a high strength-ductility synergy,i.e.,the yield strength(YS),ultimate tensile strength(UTS)and elongation-to-failure(EF)are~308 MPa,~360 MPa and~13.8%,respectively.It reveals that the high YS is mainly originated from grain boundary strengthening(~212 MPa),followed by dislocation strengthening(~43 MPa)and precipitation hardening(~25 MPa).It is found that a relatively homogeneous fine grain structure containing a large fraction(~62%)of low angle boundaries(LABs)is achieved in the RHPRed alloy,which is benefit for the high tensile EF value.It demonstrates that LABs have important contributions to strengthening and homogenizing tensile deformation process,leading to the simultaneous high strength and high EF.Our work provides a new insight for fabrication of low-cost high performance Mg alloys with an excellent strength-ductility synergy. 展开更多
关键词 Mg-Al-Zn alloys Rolling Strengthening mechanism Microstructure strength-ductility synergy
下载PDF
Spatiotemporal Characteristics and Future Scenario Simulation of the Trade-offs and Synergies of Mountain Ecosystem Services: A Case Study of the Dabie Mountains Area, China 被引量:3
9
作者 FANG Lin LIU Yanxiao +1 位作者 LI Canfeng CAI Jun 《Chinese Geographical Science》 SCIE CSCD 2023年第1期144-160,共17页
Mountain ecosystems play an essential role in supporting regional sustainable development and improving local ecological environments. However, economic development in mountainous areas has long been lagging, and mult... Mountain ecosystems play an essential role in supporting regional sustainable development and improving local ecological environments. However, economic development in mountainous areas has long been lagging, and multiple conflicts related to resource assurance, ecological protection, and economic development have emerged. An accurate grasp of the current status and evolutionary trends of mountain ecosystems is essential to enhance the overall benefits of ecosystem services and maintain regional ecological security. Based on the In VEST(Integrated Valuation of Ecosystem Services and Trade-offs) model, this study analyzed the spatiotemporal evolution patterns and the trade-offs and synergies among ecosystem services(ES) in the Dabie Mountains Area(DMA) of eastern China. The Markov-PLUS(Patch-generating Land Use Simulation) model was used to conduct a multi-scenario simulation of the area's future development. Water yield(WY) and soil conservation(SC) had overall increasing trends during 2000-2020, carbon storage(CS)decreased overall but slowed with time, and habitat quality(HQ) increased and then decreased. The ecological protection scenario is the best scenario for improving ES in the DMA by 2030;compared to 2020, the total WY would decrease by 3.77 × 10^(8) m^(3), SC would increase by 0.65 × 10^(6) t, CS would increase by 1.33 × 10^(6) t, and HQ would increase by 0.06%. The comprehensive development scenario is the second-most effective scenario for ecological improvement, while the natural development scenario did not have a significant effect. However, as the comprehensive development scenario considers both environmental protection and economic development, which are both vital for the sustainable development of the mountainous areas, this scenario is considered the most suitable path for future development. There are trade-offs between WY, CS, and HQ, while there are synergies between SC, CS, and HQ. Spatially, the DMA's central core district is the main strong synergistic area, the marginal zone is the weak synergistic area, and trade-offs are mainly distributed in the transition zone. 展开更多
关键词 ecosystem services trade-offs InVEST(Integrated Valuation of Ecosystem Services and trade-offs)model PLUS(Patchgenerating Land Use Simulation)model scenario projection Dabie Mountains China
下载PDF
Trade-offs between ion-conducting and mechanical properties: The case of polyacrylate electrolytes 被引量:2
10
作者 Guoli Lu Yaojian Zhang +7 位作者 Jianjun Zhang Xiaofan Du Zhaolin Lv Junzhe Du Zhiming Zhao Yue Tang Jingwen Zhao Guanglei Cui 《Carbon Energy》 SCIE CSCD 2023年第2期24-60,共37页
Polymer electrolytes(PEs)have been long recognized as the key materials to enable energy-dense batteries and render flexible energy devices practically viable,owing to their chemical and mechanical reliability.However... Polymer electrolytes(PEs)have been long recognized as the key materials to enable energy-dense batteries and render flexible energy devices practically viable,owing to their chemical and mechanical reliability.However,much of their promise is yet to be realized.The roomtemperature ion conductivity of existing PEs still falls short of the implementation criterion of 10^(-4) S cm^(-1) on the promise of acceptable mechanical properties,thereby precluding their practical application.The twin but inversely related duties of polymers,that is,functioning as both an ion-conducting medium and a structural backbone,underlie this issue but are less elucidated systematically.The polyacrylate(PA)family is among promising polymer matrices on account of ester polarity,electrode compatibility,chemical tunability,and mechanical durability.The extensive applicability of PA in plasticized gels,dry solids,and emerging composites makes PA-based PEs representative to illustrate the trade-off between ion conduction and mechanical strength.We herein seek to outline the stated long-standing conflict exemplified by PA-based PEs,focusing on crucial strategies toward balancing and reconciling the two mutually exclusive properties,with the intention of offering designing guidelines for next-generation PEs. 展开更多
关键词 ionic conductivity lithium batteries mechanical properties POLYACRYLATE polymer electrolytes trade-offs
下载PDF
Trade-off and Synergy of Rural Functions Under County Depopulation in the Typical Black Soil Region of Northeast China 被引量:1
11
作者 LI Dongmei WEN Qing +1 位作者 QI Yue ZHANG Pingyu 《Chinese Geographical Science》 SCIE CSCD 2023年第4期616-633,共18页
As the population continues to shrink in the black soil region of Northeast China since 2000,it is critical to master the impact of population shrinkage on rural functions to realize rural revitalization and sustainab... As the population continues to shrink in the black soil region of Northeast China since 2000,it is critical to master the impact of population shrinkage on rural functions to realize rural revitalization and sustainable development.In this study,we focused on the impacts of depopulation on the evolution and interrelationship of rural subfunctions.Based on the rural function indexes system,the TOPSIS(Technique for Order Preference by Similarity to an Ideal Solution)method,spatial analysis method,and mathematical statistics analysis method were used to summarize the spatial and temporal characteristics of rural function development,as well as the effect of population shrinkage in the typical black soil region of Northeast China.The results showed that depopulation varied in the extent and duration between the forested region and plain areas,which both impacted the trajectories of rural subfunctions evolution.For the economic development function and ecological conservation function,the effect of continuous slight depopulation was beneficial,while the effect of rapid depopulation was adverse,which was exactly opposite to the agricultural production function.All forms of population shrinkage were conducive to the development of the social security function.With the deepening population shrinkage,depopulation mainly promoted the collaborative development between subfunctions in this study,except the relationship between agricultural production and social security function.But effects of depopulation on the interrelationship of rural subfunctions varied between the forested region and plain areas in some cases.The results provided evidence for the cognition that population shrinkage had complicated effects on rural subfunctions. 展开更多
关键词 rural function depopulation trade-off and synergy typical black soil region Northeast China
下载PDF
Synergies and trade-offs of climate-smart agriculture(CSA)practices selected by smallholder farmers in Geshy watershed,Southwest Ethiopia
12
作者 Girma TILAHUN Amare BANTIDER Desalegn YAYEH 《Regional Sustainability》 2023年第2期129-138,共10页
Studies on mainstreaming climate-smart agriculture(CSA)practices can increase smallholder farmers’capacity and awareness to improve food security and establish sustainable livelihoods through resilient agricultural s... Studies on mainstreaming climate-smart agriculture(CSA)practices can increase smallholder farmers’capacity and awareness to improve food security and establish sustainable livelihoods through resilient agricultural systems,while achieving adaptation and mitigation benefits.Hence,valuable insights can be obtained from smallholder farmers in responding to present and forthcoming challenges of climate change impacts.However,there is little research work on trade-off and synergy assessments.Taking Geshy watershed in Southwest Ethiopia as a case study area,both quantitative and qualitative data analysis were undertaken in this study.The data were collected from 15 key informant interviews,6 focus group discussions,and 384 households to answer the following questions:(1)what are the top 5 preferred CSA practices for smallholder farmers in Geshy watershed when coping with the impacts of climate change?(2)What is the performance of the preferred CSA practices?And(3)which trade-offs and synergies are experienced upon the implementation of CSA practices?The study came up with the most preferred CSA practices such as the use of improved crop varieties,small-scale irrigation,improved animal husbandry,the use of efficient inorganic fertilizers,and crop rotation with legumes.The selected CSA practices showed that the productivity goal exhibit the best synergy,while the mitigation goal has trade-offs.The study also indicated that the use of improved crop varieties causes high synergies in all 3 goals of CSA practices;small-scale irrigation provides a medium synergy on productivity goal but high synergy for adaptation and mitigation goals;improved animal husbandry shows a high synergy with the adaptation goal,a relatively lower synergy with the productivity goal,and a trade-off with the mitigation goal;the use of efficient inorganic fertilizers shows maximum synergy for the productivity and adaptation goals;and crop rotation with legumes exhibits high synergy with the productivity and mitigation goals but a relatively lower synergy with the adaptation goal.These results can provide evidence to various stakeholder farmers in the value chain that the impacts of climate change can be addressed by the adoption of CSA practices.In general,CSA practices are considered indispensable.Smallholder farmers prefer CSA practices that help to increase crop productivity and household resilience to climate change impacts.The results generate a vital foundation for recommendations to smallholder farming decision-makers.It also sensitizes actions for innovative and sustainable methods that are able to upscale the preferred CSA practices in the agricultural system in Geshy watershed of Southwest Ethiopia and other regions. 展开更多
关键词 Climate-smart agriculture(CSA) Climate change SYNERGIES trade-offs Productivity Adaptation Mitigation Geshy watershed
下载PDF
Pocket Modification of x-Amine Transaminase AtATA for Overcoming the Trade-Off Between Activity and Stability Toward 1-Acetonaphthone
13
作者 Jiaren Cao Fangfang Fan +6 位作者 Changjiang Lyu Sheng Hu Weirui Zhao Jiaqi Mei Shuai Qiu Lehe Mei Jun Huang 《Engineering》 SCIE EI CAS CSCD 2023年第11期203-214,共12页
Amine transaminases(ATAs)catalyze the asymmetric amination of prochiral ketones or aldehydes to their corresponding chiral amines.However,the trade-off between activity and stability in enzyme engineering represents a... Amine transaminases(ATAs)catalyze the asymmetric amination of prochiral ketones or aldehydes to their corresponding chiral amines.However,the trade-off between activity and stability in enzyme engineering represents a major obstacle to the practical application of ATAs.Overcoming this trade-off is important for developing robustly engineered enzymes and a universal approach for ATAs.Herein,we modified the binding pocket of co-ATA from Aspergillus terreus(AtATA)to identify the key amino acid residues controlling the activity and stability of AtATA toward 1-acetonaphthone.We discovered a structural switch comprising four key amino acid sites(R128,V149,L182,and L187),as well as the"best"mutant(AtATAD224K/V149A/L182 F/L187F;termed M4).Compared to the parent enzyme AtATAD224K(AtATAPa),M4 increased the catalytic efficiency(k_(cat)/K_(m)^(1-acetonaphthone),where kcatis the constant of catalytic activities and is 10.1 min^(-1),K_(m)^(1-acetonaphthoneis) Michaelis-Menten constant and is 1.7 mmol·L^(-1))and half-life(t1/2)by 59-fold to 5.9 L·min^(-1)·mmol-1and by 1.6-fold to 46.9 min,respectively.Moreover,using M4 as the biocatalyst,we converted a 20 mmol·L^(-1)aliquot of 1-acetonaphthone in a 50 mL scaled-up system to the desired product,(R)-(+)-1(1-naphthyl)ethylamine((R)-NEA),with 78%yield and high enantiomeric purity(R>99.5%)within 10 h.M4 also displayed significantly enhanced activity toward various 1-acetonaphthone analogs.The related structural properties derived by analyzing structure and sequence information of robust ATAs illustrated their enhanced activity and thermostability.Strengthening of intramolecular interactions and expansion of the angle between the substratebinding pocket and the pyridoxal 5’-phosphate(PLP)-binding pocket contributed to synchronous enhancement of ATA thermostability and activity.Moreover,this pocket engineering strategy successfully transferred enhanced activity and thermostability to three other ATAs,which exhibited 8%-22%sequence similarity with AtATA.This research has important implications for overcoming the trade-off between ATA activity and thermostability. 展开更多
关键词 trade-off CO-EVOLUTION Amine transaminase (R)-(+)-1(1-naphthyl)ethylamine
下载PDF
双凝固浴条件下TiO_(2)/PVDF-g-PEGMA/PVDF膜的制备及性能
14
作者 张献坤 唐玉兰 +3 位作者 周东锐 何亚婷 孙先源 齐琬羽 《净水技术》 2024年第1期140-150,共11页
将TiO_(2)和两亲聚合物PVDF-g-PEGMA一起加入铸膜液中,以乙醇溶液为第1凝固浴,利用其较高的成孔能力使改性膜表面生成大量孔洞,之后将改性膜放入第2凝固浴中,利用NaCl溶液对膜孔生长的抑制作用,制备孔隙率高、孔洞较小的亲水性TiO_(2)/P... 将TiO_(2)和两亲聚合物PVDF-g-PEGMA一起加入铸膜液中,以乙醇溶液为第1凝固浴,利用其较高的成孔能力使改性膜表面生成大量孔洞,之后将改性膜放入第2凝固浴中,利用NaCl溶液对膜孔生长的抑制作用,制备孔隙率高、孔洞较小的亲水性TiO_(2)/PVDF-g-PEGMA/PVDF超滤膜。试验结果表明,第1凝固浴乙醇溶液质量分数为20%时,随着第2凝固浴NaCl溶液浓度的升高,α晶相的生长受到抑制,β晶相数量占比增大,表面粗糙度出现下降,改性膜的抗污染性能增强。试验中,m^(2)凝固浴条件(20%乙醇溶液,20 g/L NaCl溶液)下制备的改性膜性能最好,孔隙率达到1.94%,海藻酸钠截留试验中膜通量和截留率分别为288 L/(m^(2)·h)和68.08%;跨膜压力为10 psi(0.07 MPa)时的纯水通量和通量恢复率分别为1862 L/(m^(2)·h)和76.25%,较M0(仅20%乙醇溶液)均有所提高,trade-off效应得以缓解,牛血清蛋白吸附量下降到961.56μg/cm^(2),抗污染性能升高。 展开更多
关键词 双凝固浴 聚偏氟乙烯(PVDF) 超滤膜 PVDF-g-PEGMA trade-off 效应 无机-有机杂化膜
下载PDF
Gradient microstructure and superior strength-ductility synergy of AZ61 magnesium alloy bars processed by radial forging with different deformation temperatures
15
作者 Jingfeng Zou Lifeng Ma +2 位作者 Yanchun Zhu Ling Qin Yuan Yuan 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第3期65-77,共13页
Gradient microstructure modification is a cost-efficient strategy for high strength without compromising ductility,which is urgently needed in the fundamental science of engineering materials.In this study,heterogeneo... Gradient microstructure modification is a cost-efficient strategy for high strength without compromising ductility,which is urgently needed in the fundamental science of engineering materials.In this study,heterogeneous structures of AZ61 alloy bars with anisotropic gradients(with different grain size distributions from the surface to the center)were observed to exhibit strong strength-ductility synergies under different deformation tem peratures.The results reveal that the grain refinement process under mediumlow temperature deformation conditions(≤350℃)consists of four transition stages along the radial direction,i.e.,twin activations and deformation band formations,dislocation cells and pile-ups,ultrafine sub-grains,and randomly orientated quasi-micron grains.Different deformation temperatures have a great influence on twin activations and deformation band formations,and the high temperature can easily provoke the initiation of non-basal slip.The deformation bands were determined as a primary nucleation site due to their highly unstable dislocation hindrance ability.Analysis in combination with the Radial forging(RF)deformation process,the differences of dynamic precipitates can be attributed to microstructural difference and solubility limit of Al at different tem peratures.By summarizing the tensile test results,the sample forged at 350℃exhibited the best strength-ductility synergy,exhibiting the highest elongation(EL)of 23.2%with a 251 MPa yield strength(YS)and 394 MPa ultimate tensile strength(UTS)in center region,and combined with the highest strength value of 256 MPa YS and 420 MPa UTS in the center region,while the EL was slightly degraded to 19.8%. 展开更多
关键词 Gradient microstructure Radial forging strength-ductility synergy Magnesium alloy Strengthening mechanism
原文传递
Understory seedlings of Quercus mongolica survive by phenological escape
16
作者 Shixiong Wu Ying Liu +2 位作者 Lulu He Wei Zeng Qijing Liu 《Forest Ecosystems》 SCIE CSCD 2024年第2期236-246,共11页
Understanding understory seedling regeneration mechanisms is important for the sustainable development of temperate primary forests in the context of increasingly intense climate warming events.The poor regeneration o... Understanding understory seedling regeneration mechanisms is important for the sustainable development of temperate primary forests in the context of increasingly intense climate warming events.The poor regeneration of dominant tree species,however,is one of the biggest challenges it faces at the moment.Especially,the regeneration of the shade-intolerant Quercus mongolica seedling is difficult in primary forests,which contrasts with the extreme abundance of understory seedlings in secondary forests.The mechanism behind the interesting phenomenon is still unknown.This study used in-situ monitoring and nursery-controlled experiment to investigate the survival rate,growth performance,as well as nonstructural carbohydrate (NSC) concentrations and pools of various organ tissues of seedlings for two consecutive years,further analyze the understory light availability and simulate the foliage carbon (C) gain in the secondary and primary forest.Results suggested that seedlings in the secondary forest had greater biomass allocation aboveground,height and specific leaf area (SLA) in summer,which allowed the seedling to survive longer in the canopy closure period.High light availability and positive C gain in early spring and late autumn are key factors affecting the growth and survival of understory seedlings in the secondary forest,whereas seedlings in the primary forest had annual negative carbon gain.Through the growing season,the total NSC concentrations of seedlings gradually decreased,whereas those of seedlings in the secondary forest increased significantly in autumn,and were mainly stored in roots for winter consumption and the following year's summer shade period,which was verified by the nursery-controlled experiment that simulated autumn enhanced light availability improved seedling survival rate and NSC pools.In conclusion,our results revealed the survival trade-off strategies of Quercus mongolica seedlings and highlighted the necessity of high light availability during the spring and autumn phenological periods for shade-intolerant tree seedling recruitment. 展开更多
关键词 Carbon gain Nonstructural carbohydrate RECRUITMENT trade-off Biomass allocation
下载PDF
Sexual Dimorphism and Female Reproductive Characteristics in the Hainan Water Skink(Tropidophorus hainanus)from Hainan,South China
17
作者 Yu DU Xiaming ZHU +2 位作者 Chixian LIN Yuntao YAO Xiang JI 《Asian Herpetological Research》 SCIE CSCD 2024年第1期49-58,共10页
We studied sexual dimorphism in body size and shape and female reproductive characteristics in the Hainan Water Skink(Tropidophorus hainanus)from Hainan,South China.In our sample the largest female and male were 61.1 ... We studied sexual dimorphism in body size and shape and female reproductive characteristics in the Hainan Water Skink(Tropidophorus hainanus)from Hainan,South China.In our sample the largest female and male were 61.1 and 55.2 mm snout-vent length(SVL),respectively.The mean SVL was larger in adult females(52.0 mm)than in adult males(48.3 mm).Juveniles were sexually dimorphic in head length but not in other examined morphological variables.Adult males were longer in head length and shorter in abdomen length and fore-limb length than adult females of the same SVL.Ontogenetic shifts in sexual dimorphism in body shape were evident,as revealed by the fact that morphological differences between the sexes were more pronounced in adults than in juveniles.Females produced a single litter of 3–6 offspring per season from early August to early September.Litter size,litter mass and offspring(neonate)mass were positively related to female SVL.Neonate mass was independent of relative fecundity.From the above findings we draw three main conclusions.First,females are the larger sex in T.hainanus,and sexual dimorphism in body shape is more pronounced in adults than in juveniles.Second,larger female T.hainanus produce more and larger offspring and thus heavier litters than smaller ones.Third,the offspring size-number trade-off does is not evident in T.hainanus. 展开更多
关键词 FECUNDITY morphology offspring size-number trade-off REPRODUCTION SCINCIDAE sexual dimorphism
下载PDF
Exploring social-ecological system resilience in South China Karst:Quantification,interaction and policy implication
18
作者 Tiantian Chen Yuxi Wang Li Peng 《Geography and Sustainability》 CSCD 2024年第2期289-301,共13页
China’s Grain to Green Program(GTGP),which is one of the largest payments for ecosystem services(PES)in the world,has made significant ecological improvements to the environment.However,current understanding of its o... China’s Grain to Green Program(GTGP),which is one of the largest payments for ecosystem services(PES)in the world,has made significant ecological improvements to the environment.However,current understanding of its outcomes on the social-ecological system(SES)remains limited.Therefore,taking the South China Karst as an example,a SES resilience evaluation index system was constructed followed by an exploratory spatial analysis,root mean square error,and Self-Organizing Feature Map to clarify the spatiotemporal changes and relationship of SES resilience,achieve the zoning of SES resilience and provide restoration measures.The results showed an upward trend in social resilience from 2000 to 2020,especially its subsystem of social development.Regional ecological resilience was stable,owing to a slightly declined ecosystem services and increased landscape pattern.Spatially,nearly half of the counties exhibited a distribution mismatch in SES resilience.There was an obvious inverted U-shaped relationship of SES resilience,indicating a clear threshold effect,and the constraint relation-ship of SES resilience eased over time,demonstrating the effectiveness of the ecological restoration program.GTGP played a positive role in reducing regional SES trade-off,but this positive effect was limited,reflecting the limitations of overemphasizing the conversion from farmland to forest and grassland.Regional SES resilience can be divided into four clusters,which were the key optimization zone for social system,the SES resilience safety zone,the key restoration zone for SES resilience,and the key optimization zone for ecological system.Adaptive adjustments for the GTGP in these zones should be taken to achieve maximum SES benefits in the future. 展开更多
关键词 SES resilience trade-off CLUSTERING GTGP South China Karst
下载PDF
Extremely thin but very robust:Surprising cryptogam trait combinations at the end of the leaf economics spectrum
19
作者 Tana Wuyun Lu Zhang +6 位作者 Tiina Tosens Bin Liu Kristiina Mark JoséÁngel Morales-Sanchez Jesamine Jöneva Rikisahedew Vivian Kuusk Ülo Niinemets 《Plant Diversity》 SCIE CAS CSCD 2024年第5期621-629,共9页
Leaf economics spectrum(LES)describes the fundamental trade-offs between leaf structural,chemical,and physiological investments.Generally,structurally robust thick leaves with high leaf dry mass per unit area(LMA)exhi... Leaf economics spectrum(LES)describes the fundamental trade-offs between leaf structural,chemical,and physiological investments.Generally,structurally robust thick leaves with high leaf dry mass per unit area(LMA)exhibit lower photosynthetic capacity per dry mass(Amass).Paradoxically,“soft and thinleaved”mosses and spikemosses have very low Amass,but due to minute-size foliage elements,their LMA and its components,leaf thickness(LT)and density(LD),have not been systematically estimated.Here,we characterized LES and associated traits in cryptogams in unprecedented details,covering five evolutionarily different lineages.We found that mosses and spikemosses had the lowest LMA and LT values ever measured for terrestrial plants.Across a broad range of species from different lineages,Amass and LD were negatively correlated.In contrast,Amass was only related to LMA when LMA was greater than 14 g cm^(-2).In fact,low Amass reflected high LD and cell wall thickness in the studied cryptogams.We conclude that evolutionarily old plant lineages attained poorly differentiated,ultrathin mesophyll by increasing LD.Across plant lineages,LD,not LMA,is the trait that represents the trade-off between leaf robustness and physiology in the LES. 展开更多
关键词 Investment strategy Leaf density Leaf structural traits LMA estimation bias Non-seed plants Trait trade-offs
下载PDF
Spatial-temporal heterogeneity of ecological quality changes across the Qinghai-Tibet Plateau under the influence of climate factors and human activities
20
作者 ZiPing Zhang YuWei Cui +1 位作者 WenJia Tang Sen Li 《Research in Cold and Arid Regions》 CSCD 2024年第3期129-140,共12页
Over the last few decades,the ecological quality of the Qinghai–Tibet Plateau(QTP)has significantly changed due to climate warming,humidification,and increasing human activities.Thus,evaluating this region's ecol... Over the last few decades,the ecological quality of the Qinghai–Tibet Plateau(QTP)has significantly changed due to climate warming,humidification,and increasing human activities.Thus,evaluating this region's ecological quality and dominant factors is crucial for sustainable development.In this study,the changes in the ecological quality on the QTP from 2000 to 2020 were evaluated based on aggregated indices and Sen–MK trend analyses,and the dominant factors affecting the ecological quality of the QTP were quantitatively analyzed using decision tree classification.The results revealed that(1)the ecological quality of the QTP exhibited an overall high trend in the east and a low pattern in the west;(2)the ecological quality of the QTP significantly increased from 2000 to 2020,and human activities were the dominant factors causing this change;and(3)the changes in the ecological quality and dominant factors exhibited obvious spatiotemporal heterogeneity.The area with an improved ecological quality occurred mainly in the northern QTP region.It was governed by human activities and precipitation.In contrast,the area with a deteriorated ecological quality occurred largely in the southern QTP region and was dominated by human activities and temperature.The 2000–2010 period was the most significant period of heterogeneity regarding of ecological quality and its driving factors.(4)The change in the ecological quality was mainly affected by the synergistic relationship between human activities and climate change in this region,which encompassed multiple dominant factors.This study provides important information on the spatiotemporal heterogeneity of ecological quality change and its dominant factors on the QTP and offers systematic guidance for the planning and implementation of ecological protection projects. 展开更多
关键词 Remote sensing-based ecological index(RSEI) Dominant factors Synergies and trade-offs Qinghai‒Tibet Plateau
下载PDF
上一页 1 2 12 下一页 到第
使用帮助 返回顶部