Design of low-alloying and high-performance solid solution-strengthened copper alloys with element substitution for sustainable development

Solid solution-strengthened copper alloys have the advantages of a simple composition and manufacturing process,high mechanical and electrical comprehensive performances,and low cost;thus,they are widely used in high-speed rail contact wires,electronic component connectors,and other devices.Overcoming the contradiction between low alloying and high performance is an important challenge in the development of solid solution-strengthened copper alloys.Taking the typical solid solution-strengthened alloy Cu-4Zn-1Sn as the research object,we proposed using the element In to replace Zn and Sn to achieve low alloying in this work.Two new alloys,Cu-1.5Zn-1Sn-0.4In and Cu-1.5Zn-0.9Sn-0.6In,were designed and prepared.The total weight percentage content of alloying elements decreased by 43%and 41%,respectively,while the product of ultimate tensile strength(UTS)and electrical conductivity(EC)of the annealed state increased by 14%and 15%.After cold rolling with a 90%reduction,the UTS of the two new alloys reached 576 and 627MPa,respectively,the EC was 44.9%IACS and 42.0%IACS,and the product of UTS and EC(UTS×EC)was 97%and 99%higher than that of the annealed state alloy.The dislocations proliferated greatly in cold-rolled alloys,and the strengthening effects of dislocations reached 332 and 356 MPa,respectively,which is the main reason for the considerable improvement in mechanical properties.

A novel immiscible high entropy alloy strengthened via L1_(2)-nanoprecipitate

The low-cost Fe-Cu,Fe-Ni,and Cu-based high-entropy alloys exhibit a widespread utilization prospect.However,these potential applications have been limited by their low strength.In this study,a novel Fe_(31)Cu_(31)Ni_(28)Al_(4)Ti_(3)Co_(3) immiscible high-entropy alloy(HEA)was developed.After vacuum arc melting and copper mold suction casting,this HEA exhibits a unique phase separation microstructure,which consists of striped Cu-rich regions and Fe-rich region.Further magnification of the striped Cu-rich region reveals that it is composed of a Cu-rich dot-like phase and a Fe-rich region.The aging alloy is further strengthened by a L1_(2)-Ni_(3)(AlTi)nanoprecipitates,achieving excellent yield strength(1185 MPa)and uniform ductility(~8.8%).The differential distribution of the L1_(2) nanoprecipitate in the striped Cu-rich region and the external Fe-rich region increased the strength difference between these two regions,which increased the strain gradient and thus improved hetero-deformation induced(HDI)hardening.This work provides a new route to improve the HDI hardening of Fe-Cu alloys.

Strengthening mechanism of T8-aged Al-Cu-Li alloy with increased pre-deformation

The microstructure evolution and mechanical properties of a T8-aged Al-Cu-Li alloy with increased pre-deformation(0-15%) were investigated,revealing the microstructure-strength relationship and the intrinsic strengthening mechanism.The results show that increasing the pre-deformation levels remarkably improves the strength of the alloy but deteriorates its ductility.Dislocations introduced by pre-deformation effectively suppress the formation of Guinier-Preston(GP) zones and provide more nucleation sites for T1 precipitates.This leads to more intensive and finer T1 precipitates in the samples with higher pre-deformation levels.Simultaneously,the enhanced precipitation of T1 precipitates and inhibited formation of GP zones cause the decreases in number and sizes of θ′ precipitates.The quantitative descriptions of the strength contributions from different strengthening mechanisms reveal that strengthening contributions from T1 and θ′ precipitates decrease with increasing pre-deformation.The reduced diameters of T1 precipitates are primarily responsible for their weakened strengthening effects.Therefore,the improved strength of the T8-aged Al-Cu-Li alloy is mainly attributed to the stronger strain hardening from the increased pre-deformation levels.

Enhanced mechanical properties of molybdenum alloy originating from composite strengthening of Re and CeO_(2)

To enhance the mechanical properties of molybdenum alloys at both room and high temperatures,Mo-14Re-1CeO_(2)alloy was synthesized using the powder metallurgy method,and the corresponding microstructure and mechanical properties were characterized.The results indicate that the ultimate tensile strength of Mo-14Re-1CeO_(2)reaches 657 MPa,with a total elongation of 35.2%,significantly higher than those of pure molybdenum(453 MPa,and 7.01%).Furthermore,the compression strength of Mo-14Re-1CeO_(2)at high temperature(1200℃)achieves 355 MPa,which is still larger than that of pure molybdenum(221 MPa).It is revealed that there is a coherent interface between CeO_(2)and the Mo-14Re matrix with CeO_(2)particles uniformly distributed in both intergranular and intragranular regions.The improvements in mechanical properties are primarily attributed to the formation of Mo-Re solid solution,grain refinement,and dispersion strengthening effect of CeO_(2).

Experimental investigation of engineered geopolymer composite for structural strengthening against blast loads

The recent increase in blast/bombing incidents all over the world has pushed the development of effective strengthening approaches to enhance the blast resistance of existing civil infrastructures.Engineered geopolymer composite(EGC)is a promising material featured by eco-friendly,fast-setting and strain-hardening characteristics for emergent strengthening and construction.However,the fiber optimization for preparing EGC and its protective effect on structural elements under blast scenarios are uncertain.In this study,laboratory tests were firstly conducted to evaluate the effects of fiber types on the properties of EGC in terms of workability,dry shrinkage,and mechanical properties in compression,tension and flexure.The experimental results showed that EGC containing PE fiber exhibited suitable workability,acceptable dry shrinkage and superior mechanical properties compared with other types of fibers.After that,a series of field tests were carried out to evaluate the effectiveness of EGC retrofitting layer on the enhancement of blast performance of typical elements.The tests include autoclaved aerated concrete(AAC)masonry walls subjected to vented gas explosion,reinforced AAC panels subjected to TNT explosion and plain concrete slabs subjected to contact explosion.It was found that EGC could effectively enhance the blast resistance of structural elements in different scenarios.For AAC masonry walls and panels,with the existence of EGC,the integrity of specimens could be maintained,and their deflections and damage were significantly reduced.For plain concrete slabs,the EGC overlay could reduce the diameter and depth of the crater and spallation of specimens.

Strengthened US-Japan Cooperation in the South China Sea in the Context of the“Indo-Pacific Strategy”:Measures,Motivations and Effects

In recent years,the US-Japan alliance has been greatly strengthened,and the South China Sea issue has gradually become an important tool for the two countries to jointly promote the“Indo-Pacific strategy”and attract regional countries to deter China.The US and Japan,in mutual support,have engaged in the South China Sea issue at various levels,in various fi elds and by various means,not only strengthening their military presence in the South China Sea,but also increasing support to the Philippines’provocation against China,which has become important factors for the current heating up of the situation in the South China Sea.

Striving Continuously to Strengthen Oneself

As the largest developing country,China not only develops itself in the spirit of self-strengthening,but also actively embraces the world and contributes to global development.

Investigation of the Micro-Mechanics of an Extruded Precipitation-Strengthened Magnesium Alloy under Cyclic Loading

Precipitation strengthening is a crucial microscopic mechanism for enhancing the strength of magnesium alloys. In order to elucidate the influence of precipitation on the microscopic deformation mechanisms and macroscopic mechanical response of magnesium alloys under cyclic loading conditions, we employed a crystal plasticity model to analyze the stress-strain curves, specific crystal plane diffraction intensities, and the temporal evolution of various microscopic deformation mechanisms and twinning volume fractions for an extruded magnesium alloy, AXM10304, containing coherent precipitates. The research findings indicate that precipitation does not fundamentally alter the microscopic mechanisms of this alloy. However, it hinders twinning during the compression stage, mildly promotes detwinning during the tension stage, and enhances tension secondary hardening by elevating the difficulty of activation of the prismatic slip.

Selective Laser Melting of Novel SiC and TiC Strengthen 7075 Aluminum Powders for Anti-Cracks Application

The aerospace and military sectors have widely used AA7075, a type of 7075 aluminum alloy, due to its exceptional mechanical performance. Selective laser melting (SLM) is a highly effective method for producing intricate metallic components, particularly in the case of aluminum alloys like Al-Si-Mg. Nevertheless, the production of high-strength AA7075 by SLM is challenging because of its susceptibility to heat cracking and elemental vaporization. In this study, AA7075 powders were mechanically mixed with SiC and TiC particles. Subsequently, this new type of AA7075 powder was effectively utilized in green laser printing to create solid components with fine-grain strengthening microstructures consisting of equiaxial grains. These as-printed parts exhibit a tensile strength of up to 350 MPa and a ductility exceeding 2.1%. Hardness also increases with the increasing content of mixed powder, highlighting the essential role of SiC and TiC in SLM for improved hardness and tensile strength performance. .

扶正补土皮内针法联合康复训练治疗脑卒中后肩手综合征Ⅰ期临床观察

目的研究扶正补土皮内针法联合康复训练对缺血性脑卒中后肩手综合征(SHS)Ⅰ期的影响。方法选取62例卒中后SHSⅠ期患者,随机分为试验组和对照组,每组31例;对照组实施康复训练,试验组则实施扶正补土皮内针治疗联合康复训练。运用简式Fugl-Meyer评分、视觉模拟量表(VAS)评分、手部水肿评分评估两组患者的上肢运动功能、疼痛情况及手部水肿程度,并比较临床疗效。结果治疗后,试验组患者简式Fugl-Meyer评分、VAS评分、水肿评分均优于对照组(P<0.05)。试验组治疗总有效率为90.32%(28/31),高于对照组的67.74%(21/31)(P<0.05)。结论扶正补土皮内针法联合康复训练可改善缺血性脑卒中后SHSⅠ期患者的肩部疼痛及水肿程度并促进上肢运动功能的恢复。

种芽生物营养强化机的设计与试验

针对营养功能性农产品供给不足和生物营养强化技术装备落后等问题,设计了种芽生物营养强化机。采取提高组分浓度差、压力差,以及透水交变真空等快速催芽技术,解决营养组分向种芽内高效传质问题。经绿豆芽富叶酸营养强化试验和发芽糙米富钙营养强化试验研究,结果表明:种芽生物营养强化机可生产高营养价值农产品,其生产的绿豆芽中叶酸含量可达1.486 mg/kg,发芽糙米中钙含量可达757 mg/kg,营养强化效果良好。

Formability and strengthening mechanism of AA6061 tubular components under solid granule medium internal high pressure forming

A new technological process of tube forming was developed, namely solution treatment → granule medium internal high pressure forming → artificial aging. During this process, the mechanical properties of AA6061 tube can be adjusted by heat treatment to satisfy the process requirements and the processing method can also be realized by granule medium internal high pressure forming technology with the features of convenient implementation, low requirement to equipment and flexible design in product. Results show that, at a solution temperature of 560 ℃ and time of 120 min, the elongation of AA6061 increases by 313%, but the strength and the hardness dramatically decrease. At an aging temperature of 180 ℃ and time of 360 min, the strength and hardness of AA6061 alloy are recovered to the values of the as-received alloy. The maximum expansion ratio（MER） of AA6061 tube increases by 25.5% and the material properties of formed tube reach the performances of raw material.

Microstructure evolution of alumina dispersion strengthened copper alloy deformed under different conditions

Microstructure and texture evolution of Cu-0.23%Al2O3 dispersion strengthened copper alloy, deformed at room temperature or cryogenic temperature, were investigated. The main textures in hot-extruded specimen were Brass {011} 〈211〉 and Cube {100} 〈100〉. Textures of Brass {011} 〈211〉 and Goss {011} 〈100〉 were observed in specimen after deformation at room temperature; while textures of Brass {011} 〈211〉, Goss {011} 〈100〉 and S {123} 〈634〉 were detected after deformation at cryogenic temperature. It is believed that the additional Al2O3 nanoparticles can result in dislocation pinning effect, which can further lead to the suppression of dislocations cross-slip. While in the specimen deformed at cryogenic temperature, both pinning effect and cryogenic temperature are responsible for the formation of Brass, Goss and S textures.

Strengthening effects of BFRP on reinforced concrete beams

Reinforced concrete （RC） beams externally bonded with basalt fiber reinforced polymer （BFRP） are experimentally investigated by using different numbers of bonding plies, transverse anchorages as well as the initial conditions of strengthened beams. The performances of the BFRP strengthening are compared with those of the carbon fiber reinforced polymer （CFRP） and the glass fiber reinforced polymer （GFRP） under the same experimental condition. Experimental results indicate that the strength and ductility of the strengthened beam with two plies of the BFRP are improved remarkably than those with one ply. The strengthening effects of the BFRP lie between those of the CFRP and the GFRP. The BFRP strengthening is little influenced by pre-cracks of concrete. Most failures are caused by interfaciai debonding induced by flexural cracks in the experiment. Clamping of Uwraps along the whole beam is less efficient than endpoint anchorage for increasing the ultimate load of the strengthened beam. Finally, the models suggested by the five guidelines for predicting the debonding strain of the CFRP are extended to the BFRP and the conservative estimates of the debonding strain of the BFRP are given as well.

Experiments and modeling of double-peak precipitation hardening and strengthening mechanisms in Al-Zn-Mg alloy

The aim of the present work is to develop a model for simulating double-peak precipitation hardening kinetics in Al-Zn-Mg alloy with the simultaneous formation of different types of precipitates at elevated temperatures based on the modified Langer-Schwartz approach. The double aging peaks are present in the long time age-hardening curves of Al-Zn-Mg alloys. The physically-based model, while taking explicitly into account nucleation, growth, coarsening of the new phase precipitations and two strengthening mechanisms associated with particle-dislocation interaction （shearing and bypassing）, was used for the analysis of precipitates evolution and precipitation hardening during aging of Al-Zn-Mg alloy. Model predictions were compared with the measurements of Al-Zn-Mg alloy. The systematic and quantitative results show that the predicted hardness profiles of double peaks via adding a shape dependent parameter in the growth equation for growth and coarsening generally agree well with the measured ones. Two strengthening mechanisms associated with particle-dislocation interaction （shearing and bypassing） were considered operating simultaneously in view of the particle size-distribution. The transition from shearing to bypassing strengthening mechanism was found to occur at rather early stage of the particle growth. The bypassing was found to be the prevailing strengthening mechanism in the investigated alloys.

杂交兰双艺金龙根状茎增殖、分化及生根壮苗研究

杂交兰双艺金龙(Cymbidium‘Shuangyi Jinlong’)是福建百秾生态科技有限公司从杂交兰栽培品种黄金龙的无性系变异单株中选育出的新品种,集花艺和叶艺于一身,发芽性好,易开花,抗性较强,有较高的市场需求。为提高杂交兰种苗繁殖效率,提升种苗品质,建立标准化生产体系,以双艺金龙的根状茎为材料,对其根状茎增殖与分化、生根壮苗、炼苗移栽等各阶段影响因素进行正交试验。结果表明:(1)适宜根状茎增殖生长的培养基是MS+1.00 mg/L NAA+0.10 mg/L 6-BA+20.00 g/L蔗糖+1.00 g/L活性炭+6.30 g/L琼脂+1.00 g/L蛋白胨,根状茎数量和鲜质量增殖系数分别为3.57和4.63。(2)适宜根状茎芽分化的培养基是1/2MS+1.50 mg/L NAA+0.90 mg/L TDZ+100.00 g/L香蕉泥+25.00 g/L蔗糖+6.30 g/L琼脂,芽分化率为97.78%,分化系数达6.87。(3)生根壮苗效果较好的培养基是1/2MS+1.00 mg/L IBA+100.00 g/L香蕉泥+0.17 g/L KH_(2)PO_(4)+1.00 g/L蛋白胨+30.00 g/L蔗糖+6.30 g/L琼脂+1.00 g/L活性炭,培养90 d植株平均生根数5条,根长5.40 cm,假鳞茎厚度4.35 mm,株高12.95 cm,每株苗鲜质量2.42 g。(4)炼苗21 d后选用水苔∶松树皮(V∶V=1∶1)为基质进行移栽,移栽60 d存活率为83.33%。本研究综合考虑各因素的影响效应,最终确定了各阶段的最佳培养基配方和炼苗移栽方案,为双艺金龙标准化生产体系的建立提供参考。

Experimental study on aseismic behaviors of Chinese ancient tenon-mortise joint strengthened by CFRP

In order to well protect Chinese ancient buildings, aseismic behaviors of Chinese ancient tenon-mortise joints strengthened by carbon fibre reinforced plastic （CFRP） are studied by experiments. Based on the actual size of an ancient building, a wooden frame model with a scale of 1 ： 8 of the prototype structure is built considering the swallow-tail type of tenon-mortise connections. Low cyclic reversed loading tests are carried out including three groups of unstrengthened structures and two groups of structures strengthened with CFRP. Based on experimental data, moment-rotation angle hysteretic curves and skeleton curves for each joint are obtained. The energy dissipation capability, stiffness degradation and deformation performance of the joints before and after being strengthened are also analyzed. Results show that after being strengthened with CFRP, the tenon value pulled out of the mortise is reduced; the bending strength and the energy dissipation capabilities of the joint are enhanced; stiffness degradation of the joint is not obvious; and the deformation performance of the joint remains good. Thus, the CFRP has good effects on strengthening the tenon-mortise joints of Chinese ancient buildings.

Fatigue behavior of crane beam strengthened with CFRP

In order to study the fatigue behavior of the damaged reinforced concrete （RC） beams strengthened by carbon fiber reinforced polymer （CFRP） laminate, three T-shaped beams strengthened by CFRP and one contrasting beam are tested under fatigue loading, with the parameters of different modes of strengthening and different fatigue load levels considered. The main results obtained from the tests are： the width of the crack decreases 50. 2% to 66%, and the development of the crack is limited; the stress of steel decreases 24. 1% to 28. 2%, and the stiffness increases 14.9% to 16. 1% after being strengthened. Based on the technical specification for strengthening concrete structures with CFRP and the conclusions from the tests, a calculating scheme of the flexure stiffness is given, which can be used for reference in engineering design. Finally, some suggestions are given for design in fatigue strengthening.

Flexural behaviors of FRP strengthened corroded RC beams

The flexural behavior of eight FRP （ fiber reinforced polymer） strengthened RC （reinforced concrete） beams with different steel corrosion rates are numerically studied by Ansys finite element software. The influences of the corrosion rate on crack pattern, failure mechanism, ultimate strength, ductility and deformation capacity are also analyzed. Modeling results show that the beams with low corrosion rates fail by the crushing of the concrete in the compression zone. For the beams with medium corrosion rates, the bond slip between the concrete and the longitudinal reinforcement occurs after steel yielding, and the beams finally fail by the debonding of the FRP plates. For the beams with high corrosion rates, the bond slip occurs before steel yielding, and the beams finally fail by the crushing of the concrete in the compression zone. The higher the corrosion rates of the longitudinal reinforcement, the more the carrying capacity of FRP strengthened RC beams reduces. The carrying capacity of RCB-1 （the corrosion rate is 0） is 115 kN, and the carrying capacity of RCB-7 （the corrosion rate is 20% ） is 42 kN. The deformation capacity of FRP strengthened corroded RC beams is higher than that of FRP strengthened uucorroded RC beams. The ultimate deflection of RCB-1 and RCB-7 are 20 mm and 35 nun, respectively, and the ultimate deflection of RCB-5 （the corrosion rate is 10% ） reaches 60 ilUn.

Physiological Mechanism for Anthocyanins to Strengthen the Drought Tolerance of Plants

This paper summarized the possible physiological mechanism by which anthocyanins strengthen the tolerance of plants to drought. Drought stress can in-duce plant cel s to synthesize and accumulate anthocyanins. The photochemical properties, subcel ular accumulation sites and spatial distributions in plant organs and tissues of anthocyanins determine their function of strengthening plant tolerance, which is realized by three possible physiological mechanisms： （1） anthocyanins and their chelated metal ions can optimize the osmoregulation ability of the plant cel s by directly acting as the osmoregulation substances of the cel s, （2） anthocyanins with suitable spatial locations can reduce the photoinhibition of the plants under drought stresses, （3） anthocyanins can effectively maintain and improve the active oxygen-scavenging capacity of the plant cel s under drought conditions. Therein, that the anthocyanins enhance the antioxidant capacity of the plant cel s under drought stresses is probably the main reason for the anthocyanins to strengthen the drought tolerance of plants. This review could provide a reference for the mechanism re-search of the drought resistance and the breeding of the drought-resistant cultivars for the plants holding the ability to synthesize and accumulate anthocyanins.