Stretchable,Transparent,and Ultra-Broadband Terahertz Shielding Thin Films Based on Wrinkled MXene Architectures

With the increasing demand for terahertz(THz)technology in security inspection,medical imaging,and flexible electronics,there is a significant need for stretchable and transparent THz electromagnetic interference(EMI)shielding materials.Existing EMI shielding materials,like opaque metals and carbon-based films,face challenges in achieving both high transparency and high shielding efficiency(SE).Here,a wrinkled structure strategy was proposed to construct ultra-thin,stretchable,and transparent terahertz shielding MXene films,which possesses both isotropous wrinkles(height about 50 nm)and periodic wrinkles(height about 500 nm).Compared to flat film,the wrinkled MXene film(8 nm)demonstrates a remarkable 36.5%increase in SE within the THz band.The wrinkled MXene film exhibits an EMI SE of 21.1 dB at the thickness of 100 nm,and an average EMI SE/t of 700 dBμm^(−1)over the 0.1-10 THz.Theoretical calculations suggest that the wrinkled structure enhances the film’s conductivity and surface plasmon resonances,resulting in an improved THz wave absorption.Additionally,the wrinkled structure enhances the MXene films’stretchability and stability.After bending and stretching(at 30%strain)cycles,the average THz transmittance of the wrinkled film is only 0.5%and 2.4%,respectively.The outstanding performances of the wrinkled MXene film make it a promising THz electromagnetic shielding materials for future smart windows and wearable electronics.

A new horizon for neuroscience:terahertz biotechnology in brain research

Terahertz biotechnology has been increasingly applied in various biomedical fields and has especially shown great potential for application in brain sciences.In this article,we review the development of terahertz biotechnology and its applications in the field of neuropsychiatry.Available evidence indicates promising prospects for the use of terahertz spectroscopy and terahertz imaging techniques in the diagnosis of amyloid disease,cerebrovascular disease,glioma,psychiatric disease,traumatic brain injury,and myelin deficit.In vitro and animal experiments have also demonstrated the potential therapeutic value of terahertz technology in some neuropsychiatric diseases.Although the precise underlying mechanism of the interactions between terahertz electromagnetic waves and the biosystem is not yet fully understood,the research progress in this field shows great potential for biomedical noninvasive diagnostic and therapeutic applications.However,the biosafety of terahertz radiation requires further exploration regarding its two-sided efficacy in practical applications.This review demonstrates that terahertz biotechnology has the potential to be a promising method in the field of neuropsychiatry based on its unique advantages.

Terahertz toroidal dipole metamaterial sensors for detection of aflatoxin B1

Terahertz metamaterial biosensors have attracted significant attention in the biological field due to their advantages of label-free,real-time and in situ detection.In this paper,a highly sensitive metamaterial sensor with semi-ring mirror symmetry based on toroidal dipole resonance is designed for a new metamaterial biosensor.It is shown that a refractive index sensitivity of 337.5 GHz per refractive index unit can be achieved under an analyte of saturated thickness near a 1.33 THz transmission dip.For biosensor samples where aflatoxin B1 is dropped on the metamaterial surface in our experiment,dip amplitudes of transmission varying from 0.1904 to 0.203 and 0.2093 are observed as aflatoxin B1 concentrations are altered from 0 to 0.001μg·ml-1 and to 0.01μg·ml-1,respectively.Furthermore,when aflatoxin B1 concentrations are 0.1μg·ml-1,1μg·ml-1,10μg·ml-1 and 100μg·ml-1,dip amplitudes of 0.2179,0.226,0.2384 and 0.2527 and dip redshifts of 10.1 GHz,20.1 GHz,27.7 GHz and 37.6 GHz are respectively observed.These results illustrate high-sensitivity,label-free detection of aflatoxin B1,enriching the applications of sensors in the terahertz domain.

High photoelectric conversion efficiency and fast relaxation time of FA_(0.4)MA_(0.6)PbI_(3) applied in ultrafast modulation of terahertz waves

Active control of terahertz(THz)waves is attracting tremendous attentions in terahertz communications and active photonic devices.Perovskite,due to its excellent photoelectric conversion performance and simple manufacturing process,has emerged as a promising candidate for optoelectronic applications.However,the exploration of perovskites in optically controlled THz modulators is still limited.In this work,the photoelectric properties and carrier dynamics of FA_(0.4)MA_(0.6)PbI_(3)perovskite films were investigated by optical pumped terahertz probe(OPTP)system.The ultrafast carrier dynamics reveal that FA_(0.4)MA_(0.6)PbI_(3)thin film exhibits rapid switching and relaxation time within picosecond level,suggesting that FA_(0.4)MA_(0.6)PbI_(3)is an ideal candidate for active THz devices with ultrafast response.Furthermore,as a proof of concept,a FA_(0.4)MA_(0.6)PbI_(3)-based metadevice with integrating plasma-induced transparency(PIT)effect was fabricated to achieve ultrafast modulation of THz wave.The experimental results demonstrated that the switching time of FA_(0.4)MA_(0.6)PbI_(3)-based THz modulator is near to 3.5 ps,and the threshold of optical pump is as low as 12.7μJ cm^(-2).The simulation results attribute the mechanism of ultrafast THz modulation to photo-induced free carriers in the FA_(0.4)MA_(0.6)PbI_(3)layer,which progressively shorten the capacitive gap of PIT resonator.This study not only illuminates the potential of FA_(0.4)MA_(0.6)PbI_(3)in THz modulation,but also contributes to the field of ultrafast photonic devices.

Polarimeter–interferometer diagnostic using terahertz solid-state sources for fluctuation measurements on Keda Torus e Xperiment(KTX)

A multi-channel polarimeter-interferometer has been developed on the Keda Torus eXperiment(KTX)for the study of equilibrium dynamics and internal magnetic fluctuations.A three-wave technique based on terahertz solid-state sources(-650 GHz)is applied for simultaneous measurements of electron density and Faraday rotation angle.The output power of the microwave source is 2 mW.Faraday rotation effect using a rotating wave plate is tested with phase noise less than 0.8°,and the density phase noise is less than 0.9°.Measurement of Faraday rotation angle and density for discharges on KTX have demonstrated high sensitivity to internal MHD activities.

Enhanced picosecond terahertz wave generation based on cascade effects in a terahertz parametric generator

Enhanced terahertz wave generation via a Stokes cascade process has been demonstrated using picosecond pulse pumped terahertz parametric generation at 1 kHz repetition rate.Clear cascade saturation of terahertz output was observed,and the corresponding cascade-Stokes spectra were analyzed.The maximum terahertz wave average power was 22μW under a pump power of 30 W,whereas the maximum power conversion efficiency was 8×10^(-7)under a pump power of 21 W.The THz power fluctuation was measured to be about 1%in 20 min.This THz parametric source with a relatively stable output is suitable for a variety of practical applications.

Phase-locked single-mode terahertz quantum cascade lasers array

We demonstrated a scheme of phase-locked terahertz quantum cascade lasers(THz QCLs)array,with a single-mode pulse power of 108 mW at 13 K.The device utilizes a Talbot cavity to achieve phase locking among five ridge lasers with first-order buried distributed feedback(DFB)grating,resulting in nearly five times amplification of the single-mode power.Due to the optimum length of Talbot cavity depends on wavelength,the combination of Talbot cavity with the DFB grating leads to better power amplification than the combination with multimode Fabry-Perot(F-P)cavities.The Talbot cavity facet reflects light back to the ridge array direction and achieves self-imaging in the array,enabling phase-locked operation of ridges.We set the spacing between adjacent elements to be 220μm,much larger than the free-space wavelength,ensuring the operation of the fundamental supermode throughout the laser's dynamic range and obtaining a high-brightness far-field distribution.This scheme provides a new approach for enhancing the single-mode power of THz QCLs.

Terahertz quasi-perfect vortex beam with integer-order and fractional-order generated by spiral spherical harmonic axicon

We propose a new method to generate terahertz perfect vortex beam with integer-order and fractional-order. A new optical diffractive element composed of the phase combination of a spherical harmonic axicon and a spiral phase plate is designed and called spiral spherical harmonic axicon. A terahertz Gaussian beam passes through the spiral spherical harmonic axicon to generate a terahertz vortex beam. When only the topological charge number carried by spiral spherical harmonic axicon increases, the ring radius of terahertz vortex beam increases slightly, so the beam is shaped into a terahertz quasi-perfect vortex beam. Importantly, the terahertz quasi-perfect vortex beam can carry not only integer-order topological charge number but also fractional-order topological charge number. This is the first time that vortex beam and quasi-perfect vortex beam with fractional-order have been successfully realized in terahertz domain and experiment.

Terahertz high-sensitivity SIS mixer based on Nb–AlN–NbN hybrid superconducting tunnel junctions

The terahertz band,a unique segment of the electromagnetic spectrum,is crucial for observing the cold,dark universe and plays a pivotal role in cutting-edge scientific research,including the study of cosmic environments that support life and imaging black holes.High-sensitivity superconductor–insulator–superconductor(SIS)mixers are essential detectors for terahertz astronomical telescopes and interferometric arrays.Compared to the commonly used classical Nb/AlO_(x)/Nb superconducting tunnel junction,the Nb/AlN/NbN hybrid superconducting tunnel junction has a higher energy gap voltage and can achieve a higher critical current density.This makes it particularly promising for the development of ultra-wideband,high-sensitivity coherent detectors or mixers in various scientific research fields.In this paper,we present a superconducting SIS mixer based on Nb/AlN/NbN parallel-connected twin junctions(PCTJ),which has a bandwidth extending up to490 GHz–720 GHz.The best achieved double-sideband(DSB)noise temperature(sensitivity)is below three times the quantum noise level.

High-Order Spatial FDTD Solver of Maxwell’s Equations for Terahertz Radiation Production

We applied a spatial high-order finite-difference-time-domain (HO-FDTD) scheme to solve 2D Maxwell’s equations in order to develop a fluid model employed to study the production of terahertz radiation by the filamentation of two femtosecond lasers in air plasma. We examined the performance of the applied scheme, in this context, we implemented the developed model to study selected phenomena in terahertz radiation production, such as the excitation energy and conversion efficiency of the produced THz radiation, in addition to the influence of the pulse chirping on properties of the produced radiation. The obtained numerical results have clarified that the applied HO-FDTD scheme is precisely accurate to solve Maxwell’s equations and sufficiently valid to study the production of terahertz radiation by the filamentation of two femtosecond lasers in air plasma.

Terahertz Spectroscopic Study of Standard Substances for Bituminous Coal and Anthracite

This study underscores the significance of online monitoring of standard substances for bituminous coal and anthracite,two commonly used fossil fuels.Terahertz technology emerges as a powerful non-destructive detection method capable of revealing the physical and chemical properties of measured objects.In this research,terahertz time-domain spectroscopy technology was employed to investigate the spectral characteristics of four distinct types of bituminous coal and anthracite samples.The refractive index and absorption coefficient spectra of these samples were calculated across a frequency range of 0.5 THz to 2.5 THz.Furthermore,principal component analysis was conducted using all refractive index and absorption coefficient data within this frequency band.Through the analysis and comparison with known parameters of coal standard materials,it was established that carbon content primarily influences the refractive index of bituminous coal and anthracite,while ash content predominantly affects the absorption effect.These findings underscore the potential of terahertz spectroscopy in conjunction with principal component analysis to qualitatively assess the similarities and differences between coal samples,thus offering novel insights for the online monitoring of diverse coal types and qualities.

Research on Detection of Food additives Based on Terahertz Spectroscopy and Analytic Hierarchy Process

Terahertz time-domain spectroscopy is a kind of far-infrared spectroscopy technology,and its spectrum reflects the internal properties of substances with rich physical and chemical information,so the use of terahertz waves can be used to qualitatively identify food additives containing nitrogen elements.Analytic hierarchy process(AHP)was originally used to solve evaluation-type problems,and this paper introduces it into the field of terahertz spectral qualitative analysis,proposes a terahertz time-domain spectral qualitative identification method combined with analytic hierarchy process,and verifies the feasibility of the method by taking four common food additives(xylitol,L-alanine,sorbic acid,and benzoic acid)and two illegal additives(melamine,and Sudan Red No.I)as the objects of study.Firstly,the collected terahertz time-domain spectral data were pre-processed and transformed into a data set consisting of peaks,peak positions,peak numbers and overall trends;then,the data were divided into comparison and test sets,and a qualitative additive identification model incorporating analytic hierarchy process was constructed and parameter optimisation was performed.The results showed that the qualitative identification accuracies of additives based on single factors,i.e.,overall trend,peak value,peak position,and peak number,were 80.23%,70.93%,67.44%,and 40.70%,respectively,whereas the identification accuracy of the analytic hierarchy process qualitative identification method based on multi-factors could be improved to 92.44%.In addition,the fuzzy characterisation of the absorption spectrum data was binarised in the data pre-processing stage and used as the base data for the overall trend,and the recognition accuracy was improved to 94.19%by combining the fuzzy characterisation method of such data with the hierarchical analysis qualitative recognition model.The results show that it is feasible to use terahertz technology to identify different varieties of additives,and this paper constructs a hierarchical analytical qualitative model with better effect,which provides a new means for food additives detection,and the method is simple in steps,with a small demand for samples,which is suitable for the rapid detection of small samples.

Highly efficient vectorial field manipulation using a transmitted tri-layer metasurface in the terahertz band

Polarization is a basic characteristic of electromagnetic waves that conveys much optical information owing to its many states.The polarization state is manipulated and controlled for optical information security,optical encryption,and optical communication.Metasurface devices provide a new way to manipulate wave-fronts of light.A single ultrathin metasurface device can generate and modulate several differently polarized light fields,and thus carries optical information in several different channels.Terahertz(THz)waves have become widely used as carrier waves for wireless communication.Compact and functional metasurface devices are in high demand for THz elements and systems.This paper proposes a tri-layer metallic THz metasurface for multi-channel polarization generation and phase modulation with a high efficiency of approximately 80%.An azimuthally polarized THz vectorial beam generator is realized and characterized for use as a THz polarization analyzer.The incident polarization angle can be observed graphically with high accuracy.Moreover,a vectorial hologram with eight channels for different linear polarization states is demonstrated experimentally.The information in different holograms can be hidden by choosing the polarization channel for detection.This work contributes to achieving multi-functional metasurface in the THz band and can benefit THz communication and optical information security.

Maximizing Terahertz Energy Absorption with MXene Absorber

Achieving high absorption in broad terahertz bands has long been challenging for terahertz electromagnetic wave absorbers.Recently in Nature Photonics,Xiao et al.reported the high absorption approaching the theoretical upper limit across the whole terahertz band of MXene-based terahertz absorbers and,on this basis,constructed an applicable,updated alternating current impedance matching model.

Hybrid bound states in the continuum in terahertz metasurfaces

Bound states in the continuum(BICs)have exhibited extraordinary properties in photonics for enhanced light-matter interactions that enable appealing applications in nonlinear optics,biosensors,and ultrafast optical switches.The most common strategy to apply BICs in a metasurface is by breaking symmetry of resonators in the uniform array that leaks the otherwise uncoupled mode to free space and exhibits an inverse quadratic relationship between quality factor(Q)and asymmetry.Here,we propose a scheme to further reduce scattering losses and improve the robustness of symmetry-protected BICs by decreasing the radiation density with a hybrid BIC lattice.We observe a significant increase of radiative Q in the hybrid lattice compared to the uniform lattice with a factor larger than 14.6.In the hybrid BIC lattice,modes are transferred toГpoint inherited from high symmetric X,Y,and M points in the Brillouin zone that reveal as multiple Fano resonances in the far field and would find applications in hyperspectral sensing.This work initiates a novel and generalized path toward reducing scattering losses and improving the robustness of BICs in terms of lattice engineering that would release the rigid requirements of fabrication accuracy and benefit applications of photonics and optoelectronic devices.

Graphene metasurface-based switchable terahertz half-/quarter-wave plate with a broad bandwidth

Metasurfaces incorporating graphene hold great promise for the active manipulation of terahertz waves. However,it remains challenging to design a broadband graphene-based terahertz metasurface with switchable functionality of half-wave plate(HWP) and quarter-wave plate(QWP). Here, we propose a graphene–metal hybrid metasurface for achieving broadband switchable HWP/QWP in the terahertz regime. Simulation results show that, by varying the Fermi energy of graphene from 0 eV to 1 eV, the function of the reflective metasurface can be switched from an HWP with polarization conversion ratio exceeding 97% over a wide band ranging from 0.7 THz to 1.3 THz, to a QWP with ellipticity above 0.92over 0.78 THz–1.33 THz. The sharing bandwidth reaches up to 0.52 THz and the relative bandwidth is as high as 50%.We expect this broadband and dynamically switchable terahertz HWP/QWP will find applications in terahertz sensing,imaging, and telecommunications.

Probing photocarrier dynamics of pressurized graphene using time-resolved terahertz spectroscopy

Graphene hosts intriguing photocarrier dynamics such as negative transient terahertz(THz) photoconductivity, high electron temperature, benefiting from the unique linear Dirac dispersion. In this work, the pressure effects of photocarrier dynamics of graphene have been investigated using in situ time-resolved THz spectroscopy in combination with diamond anvil cell exceeding 9 GPa. We find that the negative THz conductivity maintains in our studied pressure range both for monolayer and bilayer graphene. In particular, the amplitude of THz photoconductivity in monolayer graphene manifests an extraordinary dropping with pressure, compared with that from the counterparts such as bulk silicon and bilayer graphene.Concomitantly, the time constant is reduced with increasing pressure, highlighting the pressure-induced hot carrier cooling.The pressure dependence of photocarrier dynamics in monolayer graphene is likely related with the enhancement of the interfacial coupling between diamond surface and sample, allowing for the activity of new electron–phonon scattering. Our work is expected to provide an impetus for the studies of high-pressure THz spectroscopy of two-dimensional materials.

High efficiency of broadband transmissive metasurface terahertz polarization converter

Terahertz wave is between microwave and infrared bands in the electromagnetic spectrum with the frequency range from 0.1 THz to 10 THz. Controlling and processing of the polarization state in terahertz wave are the focus due to its great influence on the characteristics. In this paper, a transmissive metasurface terahertz polarization converter is designed in 3D structure with an upper surface of ruler-like rectangular, an intermediate dielectric layer and a lower surface of metal grid wires. Numerical simulations of the converter show that the polarization conversion ratio(PCR) is above 99.9% at 0.288 THz–1.6 THz, the polarization rotation angle(PRA) is close to 90° at 0.06 THz–1.4 THz, and the ellipticity angle(EA) is close to 0° at 0.531 THz–1.49 THz. The origin of the efficient polarization conversion is explained by analyzing the electric field intensity, magnetic field intensity, surface current, electric field energy density, and magnetic field energy density distributions of the converter at 1.19 THz and 0.87 THz, which are consistent with the energy transmittance and transmittance coefficient. In addition, the effects of different thickness and material of intermediate layer, thickness of upper surface material, polarized wave incidence angle, and metasurface materials on the performance of the polarization converter are discussed, and how they affect the conversion performance of the polarization converter are also explained.Our results provide a strong theoretical basis and technical support to develop high performance transmission-type terahertz polarization converters, and play an important role to promote the development of terahertz science and technology.

Multi-channel terahertz focused beam generator based on shared-aperture metasurface

Most of existing metasurfaces usually have limited channel behavior,which seriouslyhinders their development and application.In this paper,we propose a multi-channel terahertz focused beam generator based on shared-aperture metasurface,and the generator consists of a top square metal strip,a middle layer of silica and a metal bottom plate.By changing the position and size of the shared-aperture array,the designed metasurface can generate any number of multi-channel focusing beams at different predicted positions.In addition,the energy intensity of focusing beams can be controlled.The full-wave simulation results show that the metasurface achieves four-channel vortex focused beam generation with different topological charges,and five-,six-,eight-channel focused beam generation with different energy intensities at a frequency of 1 THz,which are in good agreement with the theoretically calculated predictions.This work can provide a new idea for designing the terahertz multichannel devices.

2D MXene Ti_(3)C_(2)T_(x)Enhanced Plasmonic Absorption in Metasurface for Terahertz Shielding

With the advancement of technology,shielding for terahertz(THz)electronic and communication equipment is increasingly important.The metamaterial absorption technique is mostly used to shield electromagnetic interference(EMI)in THz sensing technologies.The most widely used THz metamaterial absorbers suffer from their narrowband properties and the involvement of complex fabrication techniques.Materials with multifunctional properties,such as adjustable conductivity,broad bandwidth,high flexibility,and robustness,are driving future development to meet THz shielding applications.In this article,a theoretical simulation approach based on finite difference time domain(FDTD)is utilized to study the absorption and shielding characteristics of a two-dimensional(2D)MXene Ti_(3)C_(2)T_(x) metasurface absorber in the THz band.The proposed metamaterial structure is made up of a square-shaped array of MXene that is 50 nmthick and is placed on top of a silicon substrate.The bottom surface of the silicon is metalized with gold to reduce the transmission and ultimately enhance the absorption at 1–3 THz.The symmetric adjacent space between theMXene array results in a widening of bandwidth.The proposed metasurface achieves 96%absorption under normal illumination of the incident source and acquires an average of 25 dB shielding at 1 THz bandwidth,with the peak shielding reaching 65 dB.The results show that 2D MXene-based stacked metasurfaces can be proven in the realization of low-cost devices for THz shielding and sensing applications.