To overcome the problems of natural decreases in power quality,and to eliminate wind speed fluctuation due to wind shear and tower shadow effect arising from wind turbine structural parameters,an improved prediction m...To overcome the problems of natural decreases in power quality,and to eliminate wind speed fluctuation due to wind shear and tower shadow effect arising from wind turbine structural parameters,an improved prediction model accounting for the dual effect of wind shear and tower shadow is,in this paper,built.Compared to the conventional prediction model,the proposed model contains a new constraint condition,which makes the disturbance term caused by the tower shadow effect always negative so that the prediction result is closer to the actual situation.Furthermore,wind turbine structural parameters such as hub height,rotor diameter,the diameter of the tower top,and rotor overhang on wind shear and tower shadow effect are also explored in detail.The results show that the wind shear effect became weaker with the increase in hub height.The hub height is independent of the tower shadow effect.The rotor diameter is positively correlated with the wind shear and tower shadow effect.The tower shadow effect is positively correlated with the diameter of the tower top and negatively correlated with the rotor overhang.展开更多
The geometry of an inductively coupled plasma (ICP) etcher is usually considered to be an important factor for determining both plasma and process uniformity over a large wafer. During the past few decades, these pa...The geometry of an inductively coupled plasma (ICP) etcher is usually considered to be an important factor for determining both plasma and process uniformity over a large wafer. During the past few decades, these parameters were determined by the "trial and error" method, resulting in wastes of time and funds. In this paper, a new approach of regression orthogonal design with plasma simulation experiments is proposed to investigate the sensitivity of the structural parameters on the uniformity of plasma characteristics. The tool for simulating plasma is CFD-ACE+, which is commercial multi-physical modeling software that has been proven to be accurate for plasma simulation. The simulated experimental results are analyzed to get a regression equation on three structural parameters. Through this equation, engineers can compute the uniformity of the electron number density rapidly without modeling by CFD-ACE+. An optimization performed at the end produces good results.展开更多
In order to improve the strength and stiffness of shield cutterhead, the method of fuzzy mathematics theory in combination with the finite element analysis is adopted. An optimal design model of structural parameters ...In order to improve the strength and stiffness of shield cutterhead, the method of fuzzy mathematics theory in combination with the finite element analysis is adopted. An optimal design model of structural parameters for shield cutterhead is formulated,based on the complex engineering technical requirements. In the model, as the objective function of the model is a composite function of the strength and stiffness, the response surface method is applied to formulate the approximate function of objective function in order to reduce the solution scale of optimal problem. A multi-objective genetic algorithm is used to solve the cutterhead structure design problem and the change rule of the stress-strain with various structural parameters as well as their optimal values were researched under specific geological conditions. The results show that compared with original cutterhead structure scheme, the obtained optimal scheme of the cutterhead structure can greatly improve the strength and stiffness of the cutterhead, which can be seen from the reduction of its maximum equivalent stress by 21.2%, that of its maximum deformation by 0.75%, and that of its mass by 1.04%.展开更多
A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET speci...A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (SBEr), total pore volume (Vr) and average pore diameter (da) were measured and cal- culated as well as process parameters such as yield of char (CY) and burn-off (B). The relationship between the pore structural parameters of the GAC from coal blend (BC-GAC) and the ones of the GACs from corresponding single coals (SC-GACs) was analyzed, in which an index, the relative error (δ), was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with a less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.展开更多
Some approaches to measure parallel 6-degree of freedom platform's posturestatically and to calibrate the platform's actual structural parameters by measuring a series of theplatform's varying postures are...Some approaches to measure parallel 6-degree of freedom platform's posturestatically and to calibrate the platform's actual structural parameters by measuring a series of theplatform's varying postures are studied. In the case where high posture accuracy is requiredrelatively, to obtain the platform's actual structural parameters is very important. Threedimensions measurement with 2 theodolites are used to obtain the platform's postures statically andNewton iterative method is adopted to calibrate structural parameters. Some measures taken in themeasurement and the calibration are discussed in detail. And the experiment results of theplatform's posture control before and after the calibration are given. The results show that theplatform's posture control accuracy after the calibration is improved notably.展开更多
Elemental analysis, Fourier transform infrared (FTIR), 1H-NMR, fluorescence spectroscopy, and surface tension methods have been used to characterize the molecular structure and the aggregation behaviors of two aspha...Elemental analysis, Fourier transform infrared (FTIR), 1H-NMR, fluorescence spectroscopy, and surface tension methods have been used to characterize the molecular structure and the aggregation behaviors of two asphaltenic fractions derived, respectively, from an Alge- rian petroleum well and a corresponding storage tank deposit. Elemental analysis, FTIR, ~H-NMR, and fluores- cence spectroscopy were used to investigate the chemical composition and structural parameters of asphaltenes, while the surface tension method was used to measure the critical micelle concentration (CMC) in organic solvents with different solubility parameters and polarities in order to characterize the asphaltenes' aggregation behaviors. Results show that the unstable asphaltenes fraction extracted from the storage tank deposit possesses a higher polarity (higher heteroatoms content) and a lower aro- maticity than stable asphaltenes from the petroleum well. The CMC results indicate that asphaltenes with high polarity and low aromaticity have a high solubility in polar solvents such as nitrobenzene, whereas asphaltenes with low polarity and high aromaticity are more soluble in solvents with weak polarity, like toluene. It is concludedthat the difference of structure of asphaltene samples and polarity of solvents can lead to difference of aggregation behaviors.展开更多
Superconductive properties for oxides were predicted by artificial neural network (ANN) method with structural and chemical parameters as inputs. The predicted properties include superconductivity for oxides, distribu...Superconductive properties for oxides were predicted by artificial neural network (ANN) method with structural and chemical parameters as inputs. The predicted properties include superconductivity for oxides, distributed ranges of the superconductive transition temperature (Tc) for complex oxides, and Tc values for cuprate superconductors. The calculated results indicated that the adjusted ANN can be used to predict superconductive properties for unknown oxides.展开更多
The phase diagrams of microemulsion CTAB/butanol/cyclohexane/aqueous solution of nitrate (or aqueous solution of ammonium salt) were determined and the structural parameters and ΔG*o→i were obtained by means of dilu...The phase diagrams of microemulsion CTAB/butanol/cyclohexane/aqueous solution of nitrate (or aqueous solution of ammonium salt) were determined and the structural parameters and ΔG*o→i were obtained by means of dilution method and theoretical calculation. The effect of different w/s and salt concentration on the stability and structural parameters of microemulsion were investigated. The result shows that with the increase of w/s, the area of microemulsion and Nd decrease, Rw, l and n increase; with the increase of salt concentration, the area of microemulsion, l and Nd decrease, ΔG*o→I, Rw and n increase. Theoretical basis of preparing size-controlled long afterglow luminescence materials and study of the relationship between fluorescence properties and particle size are provided.展开更多
Two body centered tetragonal (bet) crystal structures of α'-Fe_(16)N_2 with x=0.25, z=0.3125 (Jack-1) and x=0.222, z=0.306 (Jack-2) respectively, were analyzed theoretically with EMS software package. The simulat...Two body centered tetragonal (bet) crystal structures of α'-Fe_(16)N_2 with x=0.25, z=0.3125 (Jack-1) and x=0.222, z=0.306 (Jack-2) respectively, were analyzed theoretically with EMS software package. The simulation of diffraction patterns indicates that both diffraction patterns of the same axis in these two structures obey bcc extinction rule. The conclusion is also obtained from the analyses of the diffracted waves. α'-Fe_(16)N_2 precipitates in the diffusion layer of ion-nitrided α-iron have been studied with transmission electron microscope (TEM). We have distinctly observed the electron diffraction patterns of α'-Fe_(16)N_2 in [100], [111], [110], [011], [210], [021], [311], [113], [331] and [133] zone axes with perfect symmetry, which indicate the parallel orientation relationship with α matrix:<001>α'//<001>α'// {100}.α'// {100}tα. The analyses of diffraction patterns, which obey bcc extinction rule, verify the bct structure of α'-Fe_(16)N_2 discovered by X-ray diffraction.展开更多
In this paper, the structural parameters, and density of the states of TaB2 compound have been calculated, and investigated in hexagonal phase with P6/mmm space group. The calculations have been performed with ultra-s...In this paper, the structural parameters, and density of the states of TaB2 compound have been calculated, and investigated in hexagonal phase with P6/mmm space group. The calculations have been performed with ultra-soft pseudo-potential in the frame work of Density Functional Theory (DFT) by using the Quantum Espresso package. With respect to high quantity of bulk modulus, and low quantity of the volume it is being understood that this compound has a very hard structure. The figure of density of states shows that this compound is a kind of metal. The obtained results from this research have good accord with experimental results, and with the same researches.展开更多
Random dynamic responses caused by the uncertainty of structural parameters of the coupled train-ballasted track-subgrade system under train loading can pose safety concerns to the train operation.This paper introduce...Random dynamic responses caused by the uncertainty of structural parameters of the coupled train-ballasted track-subgrade system under train loading can pose safety concerns to the train operation.This paper introduced a computational model for analyzing probabilistic dynamic responses of three-dimensional(3D)coupled train-ballasted track-subgrade system(TBTSS),where the coupling effects of uncertain rail irregularities,stiffness and damping properties of ballast and subgrade layers were simultaneously considered.The number theoretical method(NTM)was employed to design discrete points for the multi-dimensional stochastic parameters.The time-histories of stochastic dynamic vibrations of the TBSS with systematically uncertain structural parameters were calculated accurately and efficiently by employing the probability density evolution method(PDEM).The model-predicted results were consistent with those by the Monte Carlo simulation method.A sensitivity study was performed to assess the relative importance of those uncertain structural parameters,based on which a case study was presented to explore the stochastic probability evolution mechanism of such train-ballasted track-subgrade system.展开更多
Inert anode has been a hot issue in the aluminum industry for many decades. With the help of FEA (finite element analysis) software ANSYS, a model was developed to simulate the thermal stress distribution working co...Inert anode has been a hot issue in the aluminum industry for many decades. With the help of FEA (finite element analysis) software ANSYS, a model was developed to simulate the thermal stress distribution working condition of an inert anode. To reduce its thermal stress, the effect of some parameters on the thermal stress distribution was investigated, including the anode height, the anode radius, the hole depth, the hole radius, and the radius of inner chamfer and outer chamfer. The results showed that in the actual working condition of an inert anode, there existed a large axial tensile stress near the tangent interface between the anode and bath, which was the major cause of anode breaking. Increasing the anode height and reducing the hole depth properly seemed to be beneficial for the stress distribution. With the increase of anode radius, the stress distribution became better first and then deteriorated, the reasonable value was between 0.045 to 0.06m. The hole radius had a significant effect on the stress and a smaller radius would reduce the thermal stress. The effect of the radius of the inner chamfer and the outer chamfer was less than other parameters.展开更多
The structure parameters in an actual industrial production have a great influence on the coefficient of supercharger floating bearing dynamic characteristics,but there has been little systematic study so far.In this ...The structure parameters in an actual industrial production have a great influence on the coefficient of supercharger floating bearing dynamic characteristics,but there has been little systematic study so far.In this paper,the influence of structural parameters of the turbocharger floating bearing on its dynamic characteristic coefficientsis systematically investigated based on the theories of hydrodynamic lubrication and tribology.The influence of clearance ratio on eccentricity and the influence of internal to external radius ratios,and Sommerfeld number were analyzed.A new formula of responding characteristics of the oil film force caused by the displacement or velocity disturbance was deduced near an equilibrium in the steady state.Applying the newly developed formula,the dynamic characteristic was studied for floating bearings.Regularity for change of oil film stiffness and damping was analyzed with the structural parameters of floating bearing such as radius ratios and eccentricity.It has been found that the clearance ratio increases with eccentricity when the radius ratio is unchanged.The eccentricity decreases with the internal to external radius ratio of floating rings when the clearance ratio is constant.The absolute value of total principal stiffness and total main damping decrease with the clearance ratio and radius ratio of floating rings when the total cross damping is stable.The results and findings in this paper can contribute to nonlinear dynamics designs of turbocharger rotor-bearing systems.展开更多
The atomic structural parameter P-i = (Z(i)*/n(i)*) (1 + n(i)*/n(i)) (1 + m(i)/Z) and the molecular structural parameter [GRAPHICS] are defined. The standard formation enthalpies (Delta(f)H(m)(phi)) of 74 species of r...The atomic structural parameter P-i = (Z(i)*/n(i)*) (1 + n(i)*/n(i)) (1 + m(i)/Z) and the molecular structural parameter [GRAPHICS] are defined. The standard formation enthalpies (Delta(f)H(m)(phi)) of 74 species of rare earth compounds were studied with P, and the correlation coefficient is R > 0.94. The structural factors and the properties of rare earth compounds are influenced by the Z(i)*, n(i)*, n(i), m(i), Z. This study has special referential value to predict the properties of rare earth compounds.展开更多
In order to improve the performance of vehicle radiators, a two-dimensional heat transfer steady-state model of the radiator was set up. The influence of the structural parameters (axial ratio) of the heat exchange tu...In order to improve the performance of vehicle radiators, a two-dimensional heat transfer steady-state model of the radiator was set up. The influence of the structural parameters (axial ratio) of the heat exchange tube on the windward side on the heat transfer performance of the radiator was studied. With the increase of the axial ratio of the heat exchange tube on the windward side, the heat exchange capacity of the heat exchange tube surface slightly decreases. The heat exchange area increases significantly, which increases the total heat exchange of the radiator and improves the heat transfer performance of the radiator. When the axial ratio increases from 1.0 to 2.0, the average surface heat transfer capacity decreases from 5664.16</span><span style="font-family:""> </span><span style="font-family:Verdana;">W/m<sup>2</sup> to 5623.57</span><span style="font-family:""> </span><span style="font-family:Verdana;">W/m<sup>2</sup>.展开更多
In order to study the influence mechanism of structural type and size on the hydrodynamic performance of vertical curved V-type otter board,this paper based on the computational fluid dynamics method,a three-dimension...In order to study the influence mechanism of structural type and size on the hydrodynamic performance of vertical curved V-type otter board,this paper based on the computational fluid dynamics method,a three-dimensional numerical model of vertical curved V-type otter board is established to calculate and analyze its hydrodynamic performance,and the validity of the numerical simulation results is verified by designing and constructing a scaled model for dynamic flume experiments.On this basis,the effects of different structural parameters,such as the deflector angle,camber,and spacing,on the hydrodynamic performance of the vertical curved V-Type otter board are investigated and the optimal structural design scheme is determined.The results demonstrate that single or synchronous changes of the angle,camber,and spacing of the two deflectors have varying degrees of impact on the hydrodynamic performance of the vertical curved V-Type otter board.To improve the expansion effect of the otter board,setting the angle of the deflector A to 40◦and that of the deflector B to 30◦,or setting the camber of deflectors A and B to 18%,or setting the spacing between deflectors A and B to 380 mm and that between the deflector and the main panel to 670 mm can increase the lift coefficient of the vertical curved V-Type otter board to its maximum value.Considering the overall performance of the otter board,when the angle of the deflector A is set to 25◦and that of the deflector B is set to 30◦,or the camber of the deflector A is set to 6% and that of the deflector B is set to 9%,or the spacing between deflectors A and B is set to 340 mm and that between the deflector and the main panel is set to 610 mm,the lift-to-drag ratio of the otter board can be increased to its maximum value.展开更多
For combined sensible-latent heat storage system(CSLHS)(termed as the hybrid configuration),macro encapsulation can effectively solve the leakage problem of PCMs.However,due to the poor thermal conductivity of PCMs,th...For combined sensible-latent heat storage system(CSLHS)(termed as the hybrid configuration),macro encapsulation can effectively solve the leakage problem of PCMs.However,due to the poor thermal conductivity of PCMs,the charging performance of the hybrid configuration slightly increases compared to the solid structure(with only sensible materials).Meanwhile,the natural convection in the PCMs zone could improve the charging performance.So,how to improve natural convection intensity is a key issue for the CSLHS by macro encapsulating.It is found that adding fins can significantly enhance natural convection and accelerate the melting of PCM.In this paper,we proposed the hybrid configuration with fins built-in by macro encapsulation,and analyzed its charging performance with different fin structural parameters in the PCM zone by CFD simulation.In the case,the sensible heat storage material is high-temperature concrete and the PCM is a low-melting-point mixed molten salt.We analyzed the effects of fin number,fin length and fin thickness on the charging performance of the hybrid configuration respectively.From the result,the charging performance increases with the fin number,but the increase rate gradually decreases.When the fin number is 6,the charging performance increases by 20.18%compared to the situation without fin.The charging performance increases gradually with the fin length.Compared with the hybrid configuration without fin,for each 10 mm increase in fin length,its charging performances increase by 4.09%,5.26%,7.02%,8.77%,11.70%,and 15.79%,respectively.Different from number and length of fins,the effect of thickness on the charging performance is very small.When the fin thickness increased from 1 mm to 4 mm,the charging performance only increased by 2.3%.It indicates that the main reason for the improving the charging performance is to increase the natural convection intensity by dividing the PCM zone through fins.These results show that the charging performance of the CSLHS with macro encapsulation can be improved by optimizing fin structural parameters.展开更多
Nitrogen-rich heterocyclic energetic compounds(NRHECs)and their salts have witnessed widespread synthesis in recent years.The substantial energy-density content within these compounds can lead to potentially dangerous...Nitrogen-rich heterocyclic energetic compounds(NRHECs)and their salts have witnessed widespread synthesis in recent years.The substantial energy-density content within these compounds can lead to potentially dangerous explosive reactions when subjected to external stimuli such as electrical discharge.Therefore,developing a reliable model for predicting their electrostatic discharge sensitivity(ESD)becomes imperative.This study proposes a novel and straightforward model based on the presence of specific groups(-NH_(2) or-NH-,-N=N^(+)-O^(-)and-NNO_(2),-ONO_(2) or-NO_(2))under certain conditions to assess the ESD of NRHECs and their salts,employing interpretable structural parameters.Utilizing a comprehensive dataset comprising 54 ESD measurements of NRHECs and their salts,divided into 49/5 training/test sets,the model achieves promising results.The Root Mean Square Error(RMSE),Mean Absolute Error(MAE),and Maximum Error for the training set are reported as 0.16 J,0.12 J,and 0.5 J,respectively.Notably,the ratios RMSE(training)/RMSE(test),MAE(training)/MAE(test),and Max Error(training)/Max Error(test)are all greater than 1.0,indicating the robust predictive capabilities of the model.The presented model demonstrates its efficacy in providing a reliable assessment of ESD for the targeted NRHECs and their salts,without the need for intricate computer codes or expert involvement.展开更多
The effects of double shielded TIG (tungsten inert gas) torch's structural parameters, including the flow rate ratio between the inner and outer layers of gas and the extended length of the electrode (abbreviated ...The effects of double shielded TIG (tungsten inert gas) torch's structural parameters, including the flow rate ratio between the inner and outer layers of gas and the extended length of the electrode (abbreviated as ELE in this work), on the fusion zone profile have been investigated for OCrl3NiSMo martensitic stainless steel. Results show that the double shielded TIG process yields relatively high penetration of the weld pool in a broad range of the structural parameters. ELE over 3 mm is too large and causes adverse reactions on the protection of electrode. The outer gas with relatively high flow rate or the outer layer with high oxygen content is conducive to the oxygen dissolved into the arc, which results in the oxidation of the weld pool surface and the electrode tip. The double shielded TIG welded metal was tested and presented good impact property.展开更多
The effect of structural parameters of TiO2 nanotube arrays (TNAs) upon their photocatalytic/photoelectro- catalytic performance is studied by comparing the morphological characteristics and physicochemical properti...The effect of structural parameters of TiO2 nanotube arrays (TNAs) upon their photocatalytic/photoelectro- catalytic performance is studied by comparing the morphological characteristics and physicochemical properties with different tube lengths prepared from three kinds of electrolytes. The results show that the UV-Vis absorption edge of TNAs red-shifted with the increment of tube length and the short TNAs possess higher bandgap energy. The variation tendency of electrochemical window of TNAs is DMSO (5.5 V)〉Cit (3.2 V)〉HF (1.8 V). The long TNAs possess higher photocatalytic (PC) reactivity suggesting the surface roughness factor is the main determinant of PC efficiency, although, there is obvious recombination effects for the long TNAs. Evidenced by the positive correlation between tube length and photoelectrocatalytic (PEC) efficiency for TNAs from the same electrolyte, the enhancement of the tube length could lead to better PEC reactivity, but when the tube length is over a certain value, the PEC degradation rate no longer increases but decreases. The long TNAs with large surface roughness factor prepared from Cit and DMSO electrolytes exhibit comparative or even lower PEC performance compared with the short TNAs prepared from HF electrolyte, indicating that the PEC performance of TNAs was dominated by charge separation and photoelectron transfer properties rather than surface roughness coefficient and the tube length.展开更多
基金funded by the National Natural Science Foundation of China(51866012).
文摘To overcome the problems of natural decreases in power quality,and to eliminate wind speed fluctuation due to wind shear and tower shadow effect arising from wind turbine structural parameters,an improved prediction model accounting for the dual effect of wind shear and tower shadow is,in this paper,built.Compared to the conventional prediction model,the proposed model contains a new constraint condition,which makes the disturbance term caused by the tower shadow effect always negative so that the prediction result is closer to the actual situation.Furthermore,wind turbine structural parameters such as hub height,rotor diameter,the diameter of the tower top,and rotor overhang on wind shear and tower shadow effect are also explored in detail.The results show that the wind shear effect became weaker with the increase in hub height.The hub height is independent of the tower shadow effect.The rotor diameter is positively correlated with the wind shear and tower shadow effect.The tower shadow effect is positively correlated with the diameter of the tower top and negatively correlated with the rotor overhang.
基金supported by Important National Science & Technology Specific Projects of China (No.2) (Nos.2009ZX02001,2011ZX02403)
文摘The geometry of an inductively coupled plasma (ICP) etcher is usually considered to be an important factor for determining both plasma and process uniformity over a large wafer. During the past few decades, these parameters were determined by the "trial and error" method, resulting in wastes of time and funds. In this paper, a new approach of regression orthogonal design with plasma simulation experiments is proposed to investigate the sensitivity of the structural parameters on the uniformity of plasma characteristics. The tool for simulating plasma is CFD-ACE+, which is commercial multi-physical modeling software that has been proven to be accurate for plasma simulation. The simulated experimental results are analyzed to get a regression equation on three structural parameters. Through this equation, engineers can compute the uniformity of the electron number density rapidly without modeling by CFD-ACE+. An optimization performed at the end produces good results.
基金Project(51074180) supported by the National Natural Science Foundation of ChinaProject(2012AA041801) supported by the National High Technology Research and Development Program of China+2 种基金Project(2007CB714002) supported by the National Basic Research Program of ChinaProject(2013GK3003) supported by the Technology Support Plan of Hunan Province,ChinaProject(2010FJ1002) supported by Hunan Science and Technology Major Program,China
文摘In order to improve the strength and stiffness of shield cutterhead, the method of fuzzy mathematics theory in combination with the finite element analysis is adopted. An optimal design model of structural parameters for shield cutterhead is formulated,based on the complex engineering technical requirements. In the model, as the objective function of the model is a composite function of the strength and stiffness, the response surface method is applied to formulate the approximate function of objective function in order to reduce the solution scale of optimal problem. A multi-objective genetic algorithm is used to solve the cutterhead structure design problem and the change rule of the stress-strain with various structural parameters as well as their optimal values were researched under specific geological conditions. The results show that compared with original cutterhead structure scheme, the obtained optimal scheme of the cutterhead structure can greatly improve the strength and stiffness of the cutterhead, which can be seen from the reduction of its maximum equivalent stress by 21.2%, that of its maximum deformation by 0.75%, and that of its mass by 1.04%.
基金financially supported by the National High-Tech Research and Development Program of China (No.2008AA05Z308)the National Natural Science Foundation of China (No.20776150)
文摘A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (SBEr), total pore volume (Vr) and average pore diameter (da) were measured and cal- culated as well as process parameters such as yield of char (CY) and burn-off (B). The relationship between the pore structural parameters of the GAC from coal blend (BC-GAC) and the ones of the GACs from corresponding single coals (SC-GACs) was analyzed, in which an index, the relative error (δ), was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with a less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.
基金This project is supported by National Defense Science and Technology Multi-vocation Foundation in Advance Research of China(No. 97J465JW0408).
文摘Some approaches to measure parallel 6-degree of freedom platform's posturestatically and to calibrate the platform's actual structural parameters by measuring a series of theplatform's varying postures are studied. In the case where high posture accuracy is requiredrelatively, to obtain the platform's actual structural parameters is very important. Threedimensions measurement with 2 theodolites are used to obtain the platform's postures statically andNewton iterative method is adopted to calibrate structural parameters. Some measures taken in themeasurement and the calibration are discussed in detail. And the experiment results of theplatform's posture control before and after the calibration are given. The results show that theplatform's posture control accuracy after the calibration is improved notably.
文摘Elemental analysis, Fourier transform infrared (FTIR), 1H-NMR, fluorescence spectroscopy, and surface tension methods have been used to characterize the molecular structure and the aggregation behaviors of two asphaltenic fractions derived, respectively, from an Alge- rian petroleum well and a corresponding storage tank deposit. Elemental analysis, FTIR, ~H-NMR, and fluores- cence spectroscopy were used to investigate the chemical composition and structural parameters of asphaltenes, while the surface tension method was used to measure the critical micelle concentration (CMC) in organic solvents with different solubility parameters and polarities in order to characterize the asphaltenes' aggregation behaviors. Results show that the unstable asphaltenes fraction extracted from the storage tank deposit possesses a higher polarity (higher heteroatoms content) and a lower aro- maticity than stable asphaltenes from the petroleum well. The CMC results indicate that asphaltenes with high polarity and low aromaticity have a high solubility in polar solvents such as nitrobenzene, whereas asphaltenes with low polarity and high aromaticity are more soluble in solvents with weak polarity, like toluene. It is concludedthat the difference of structure of asphaltene samples and polarity of solvents can lead to difference of aggregation behaviors.
文摘Superconductive properties for oxides were predicted by artificial neural network (ANN) method with structural and chemical parameters as inputs. The predicted properties include superconductivity for oxides, distributed ranges of the superconductive transition temperature (Tc) for complex oxides, and Tc values for cuprate superconductors. The calculated results indicated that the adjusted ANN can be used to predict superconductive properties for unknown oxides.
文摘The phase diagrams of microemulsion CTAB/butanol/cyclohexane/aqueous solution of nitrate (or aqueous solution of ammonium salt) were determined and the structural parameters and ΔG*o→i were obtained by means of dilution method and theoretical calculation. The effect of different w/s and salt concentration on the stability and structural parameters of microemulsion were investigated. The result shows that with the increase of w/s, the area of microemulsion and Nd decrease, Rw, l and n increase; with the increase of salt concentration, the area of microemulsion, l and Nd decrease, ΔG*o→I, Rw and n increase. Theoretical basis of preparing size-controlled long afterglow luminescence materials and study of the relationship between fluorescence properties and particle size are provided.
文摘Two body centered tetragonal (bet) crystal structures of α'-Fe_(16)N_2 with x=0.25, z=0.3125 (Jack-1) and x=0.222, z=0.306 (Jack-2) respectively, were analyzed theoretically with EMS software package. The simulation of diffraction patterns indicates that both diffraction patterns of the same axis in these two structures obey bcc extinction rule. The conclusion is also obtained from the analyses of the diffracted waves. α'-Fe_(16)N_2 precipitates in the diffusion layer of ion-nitrided α-iron have been studied with transmission electron microscope (TEM). We have distinctly observed the electron diffraction patterns of α'-Fe_(16)N_2 in [100], [111], [110], [011], [210], [021], [311], [113], [331] and [133] zone axes with perfect symmetry, which indicate the parallel orientation relationship with α matrix:<001>α'//<001>α'// {100}.α'// {100}tα. The analyses of diffraction patterns, which obey bcc extinction rule, verify the bct structure of α'-Fe_(16)N_2 discovered by X-ray diffraction.
文摘In this paper, the structural parameters, and density of the states of TaB2 compound have been calculated, and investigated in hexagonal phase with P6/mmm space group. The calculations have been performed with ultra-soft pseudo-potential in the frame work of Density Functional Theory (DFT) by using the Quantum Espresso package. With respect to high quantity of bulk modulus, and low quantity of the volume it is being understood that this compound has a very hard structure. The figure of density of states shows that this compound is a kind of metal. The obtained results from this research have good accord with experimental results, and with the same researches.
基金Projects(51708558,51878673,U1734208,52078485,U1934217,U1934209)supported by the National Natural Science Foundation of ChinaProject(2020JJ5740)supported by the Natural Science Foundation of Hunan Province,China+1 种基金Project(KF2020-03)supported by the Key Open Fund of State Key Laboratory of Mechanical Behavior and System Safety of Traffic Engineering Structures,ChinaProject(2020-Special-02)supported by the Science and Technology Research and Development Program of China Railway Group Limited。
文摘Random dynamic responses caused by the uncertainty of structural parameters of the coupled train-ballasted track-subgrade system under train loading can pose safety concerns to the train operation.This paper introduced a computational model for analyzing probabilistic dynamic responses of three-dimensional(3D)coupled train-ballasted track-subgrade system(TBTSS),where the coupling effects of uncertain rail irregularities,stiffness and damping properties of ballast and subgrade layers were simultaneously considered.The number theoretical method(NTM)was employed to design discrete points for the multi-dimensional stochastic parameters.The time-histories of stochastic dynamic vibrations of the TBSS with systematically uncertain structural parameters were calculated accurately and efficiently by employing the probability density evolution method(PDEM).The model-predicted results were consistent with those by the Monte Carlo simulation method.A sensitivity study was performed to assess the relative importance of those uncertain structural parameters,based on which a case study was presented to explore the stochastic probability evolution mechanism of such train-ballasted track-subgrade system.
基金supported by the National Key Basic Research and Development Programme of China(No.2005CB623703)the National Natural Science Foundation of China(No.50474051 and No.50374081).
文摘Inert anode has been a hot issue in the aluminum industry for many decades. With the help of FEA (finite element analysis) software ANSYS, a model was developed to simulate the thermal stress distribution working condition of an inert anode. To reduce its thermal stress, the effect of some parameters on the thermal stress distribution was investigated, including the anode height, the anode radius, the hole depth, the hole radius, and the radius of inner chamfer and outer chamfer. The results showed that in the actual working condition of an inert anode, there existed a large axial tensile stress near the tangent interface between the anode and bath, which was the major cause of anode breaking. Increasing the anode height and reducing the hole depth properly seemed to be beneficial for the stress distribution. With the increase of anode radius, the stress distribution became better first and then deteriorated, the reasonable value was between 0.045 to 0.06m. The hole radius had a significant effect on the stress and a smaller radius would reduce the thermal stress. The effect of the radius of the inner chamfer and the outer chamfer was less than other parameters.
基金Supported by the Natural Science Foundation of Shanxi Province Project(2012011023-2)
文摘The structure parameters in an actual industrial production have a great influence on the coefficient of supercharger floating bearing dynamic characteristics,but there has been little systematic study so far.In this paper,the influence of structural parameters of the turbocharger floating bearing on its dynamic characteristic coefficientsis systematically investigated based on the theories of hydrodynamic lubrication and tribology.The influence of clearance ratio on eccentricity and the influence of internal to external radius ratios,and Sommerfeld number were analyzed.A new formula of responding characteristics of the oil film force caused by the displacement or velocity disturbance was deduced near an equilibrium in the steady state.Applying the newly developed formula,the dynamic characteristic was studied for floating bearings.Regularity for change of oil film stiffness and damping was analyzed with the structural parameters of floating bearing such as radius ratios and eccentricity.It has been found that the clearance ratio increases with eccentricity when the radius ratio is unchanged.The eccentricity decreases with the internal to external radius ratio of floating rings when the clearance ratio is constant.The absolute value of total principal stiffness and total main damping decrease with the clearance ratio and radius ratio of floating rings when the total cross damping is stable.The results and findings in this paper can contribute to nonlinear dynamics designs of turbocharger rotor-bearing systems.
文摘The atomic structural parameter P-i = (Z(i)*/n(i)*) (1 + n(i)*/n(i)) (1 + m(i)/Z) and the molecular structural parameter [GRAPHICS] are defined. The standard formation enthalpies (Delta(f)H(m)(phi)) of 74 species of rare earth compounds were studied with P, and the correlation coefficient is R > 0.94. The structural factors and the properties of rare earth compounds are influenced by the Z(i)*, n(i)*, n(i), m(i), Z. This study has special referential value to predict the properties of rare earth compounds.
文摘In order to improve the performance of vehicle radiators, a two-dimensional heat transfer steady-state model of the radiator was set up. The influence of the structural parameters (axial ratio) of the heat exchange tube on the windward side on the heat transfer performance of the radiator was studied. With the increase of the axial ratio of the heat exchange tube on the windward side, the heat exchange capacity of the heat exchange tube surface slightly decreases. The heat exchange area increases significantly, which increases the total heat exchange of the radiator and improves the heat transfer performance of the radiator. When the axial ratio increases from 1.0 to 2.0, the average surface heat transfer capacity decreases from 5664.16</span><span style="font-family:""> </span><span style="font-family:Verdana;">W/m<sup>2</sup> to 5623.57</span><span style="font-family:""> </span><span style="font-family:Verdana;">W/m<sup>2</sup>.
基金supported by the National Natural Science Foundation of China(Grant No.31972845)the Open Fund of National Ocean Fisheries Engineering and Technology Research Center(Grant No.A1-2006-21-200208).
文摘In order to study the influence mechanism of structural type and size on the hydrodynamic performance of vertical curved V-type otter board,this paper based on the computational fluid dynamics method,a three-dimensional numerical model of vertical curved V-type otter board is established to calculate and analyze its hydrodynamic performance,and the validity of the numerical simulation results is verified by designing and constructing a scaled model for dynamic flume experiments.On this basis,the effects of different structural parameters,such as the deflector angle,camber,and spacing,on the hydrodynamic performance of the vertical curved V-Type otter board are investigated and the optimal structural design scheme is determined.The results demonstrate that single or synchronous changes of the angle,camber,and spacing of the two deflectors have varying degrees of impact on the hydrodynamic performance of the vertical curved V-Type otter board.To improve the expansion effect of the otter board,setting the angle of the deflector A to 40◦and that of the deflector B to 30◦,or setting the camber of deflectors A and B to 18%,or setting the spacing between deflectors A and B to 380 mm and that between the deflector and the main panel to 670 mm can increase the lift coefficient of the vertical curved V-Type otter board to its maximum value.Considering the overall performance of the otter board,when the angle of the deflector A is set to 25◦and that of the deflector B is set to 30◦,or the camber of the deflector A is set to 6% and that of the deflector B is set to 9%,or the spacing between deflectors A and B is set to 340 mm and that between the deflector and the main panel is set to 610 mm,the lift-to-drag ratio of the otter board can be increased to its maximum value.
基金supported by National Key R&D Program of China(Grant numbers 2022YFB2405202)。
文摘For combined sensible-latent heat storage system(CSLHS)(termed as the hybrid configuration),macro encapsulation can effectively solve the leakage problem of PCMs.However,due to the poor thermal conductivity of PCMs,the charging performance of the hybrid configuration slightly increases compared to the solid structure(with only sensible materials).Meanwhile,the natural convection in the PCMs zone could improve the charging performance.So,how to improve natural convection intensity is a key issue for the CSLHS by macro encapsulating.It is found that adding fins can significantly enhance natural convection and accelerate the melting of PCM.In this paper,we proposed the hybrid configuration with fins built-in by macro encapsulation,and analyzed its charging performance with different fin structural parameters in the PCM zone by CFD simulation.In the case,the sensible heat storage material is high-temperature concrete and the PCM is a low-melting-point mixed molten salt.We analyzed the effects of fin number,fin length and fin thickness on the charging performance of the hybrid configuration respectively.From the result,the charging performance increases with the fin number,but the increase rate gradually decreases.When the fin number is 6,the charging performance increases by 20.18%compared to the situation without fin.The charging performance increases gradually with the fin length.Compared with the hybrid configuration without fin,for each 10 mm increase in fin length,its charging performances increase by 4.09%,5.26%,7.02%,8.77%,11.70%,and 15.79%,respectively.Different from number and length of fins,the effect of thickness on the charging performance is very small.When the fin thickness increased from 1 mm to 4 mm,the charging performance only increased by 2.3%.It indicates that the main reason for the improving the charging performance is to increase the natural convection intensity by dividing the PCM zone through fins.These results show that the charging performance of the CSLHS with macro encapsulation can be improved by optimizing fin structural parameters.
文摘Nitrogen-rich heterocyclic energetic compounds(NRHECs)and their salts have witnessed widespread synthesis in recent years.The substantial energy-density content within these compounds can lead to potentially dangerous explosive reactions when subjected to external stimuli such as electrical discharge.Therefore,developing a reliable model for predicting their electrostatic discharge sensitivity(ESD)becomes imperative.This study proposes a novel and straightforward model based on the presence of specific groups(-NH_(2) or-NH-,-N=N^(+)-O^(-)and-NNO_(2),-ONO_(2) or-NO_(2))under certain conditions to assess the ESD of NRHECs and their salts,employing interpretable structural parameters.Utilizing a comprehensive dataset comprising 54 ESD measurements of NRHECs and their salts,divided into 49/5 training/test sets,the model achieves promising results.The Root Mean Square Error(RMSE),Mean Absolute Error(MAE),and Maximum Error for the training set are reported as 0.16 J,0.12 J,and 0.5 J,respectively.Notably,the ratios RMSE(training)/RMSE(test),MAE(training)/MAE(test),and Max Error(training)/Max Error(test)are all greater than 1.0,indicating the robust predictive capabilities of the model.The presented model demonstrates its efficacy in providing a reliable assessment of ESD for the targeted NRHECs and their salts,without the need for intricate computer codes or expert involvement.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.50874101 and 51104142)
文摘The effects of double shielded TIG (tungsten inert gas) torch's structural parameters, including the flow rate ratio between the inner and outer layers of gas and the extended length of the electrode (abbreviated as ELE in this work), on the fusion zone profile have been investigated for OCrl3NiSMo martensitic stainless steel. Results show that the double shielded TIG process yields relatively high penetration of the weld pool in a broad range of the structural parameters. ELE over 3 mm is too large and causes adverse reactions on the protection of electrode. The outer gas with relatively high flow rate or the outer layer with high oxygen content is conducive to the oxygen dissolved into the arc, which results in the oxidation of the weld pool surface and the electrode tip. The double shielded TIG welded metal was tested and presented good impact property.
基金Project supported by the National High Technology Research and Development Program of China (No. 2009AA063003), the State Key Development Program for Basic Research of China (No. 2009CB220004), the National Natural Science Foundation of China (No. 21177085) and the Research & Development Foundation of Shanghai Jiao Tong University.
文摘The effect of structural parameters of TiO2 nanotube arrays (TNAs) upon their photocatalytic/photoelectro- catalytic performance is studied by comparing the morphological characteristics and physicochemical properties with different tube lengths prepared from three kinds of electrolytes. The results show that the UV-Vis absorption edge of TNAs red-shifted with the increment of tube length and the short TNAs possess higher bandgap energy. The variation tendency of electrochemical window of TNAs is DMSO (5.5 V)〉Cit (3.2 V)〉HF (1.8 V). The long TNAs possess higher photocatalytic (PC) reactivity suggesting the surface roughness factor is the main determinant of PC efficiency, although, there is obvious recombination effects for the long TNAs. Evidenced by the positive correlation between tube length and photoelectrocatalytic (PEC) efficiency for TNAs from the same electrolyte, the enhancement of the tube length could lead to better PEC reactivity, but when the tube length is over a certain value, the PEC degradation rate no longer increases but decreases. The long TNAs with large surface roughness factor prepared from Cit and DMSO electrolytes exhibit comparative or even lower PEC performance compared with the short TNAs prepared from HF electrolyte, indicating that the PEC performance of TNAs was dominated by charge separation and photoelectron transfer properties rather than surface roughness coefficient and the tube length.