A diamond single crystal, which was synthesized at a high temperature of 1570 K and a high pressure of 5.5 GPa in a Fe-Ni-C system, was directly and systematically examined by transmission electron microscopy (TEM). I...A diamond single crystal, which was synthesized at a high temperature of 1570 K and a high pressure of 5.5 GPa in a Fe-Ni-C system, was directly and systematically examined by transmission electron microscopy (TEM). It is proposed that there exists a variety of imperfections such as dislocation loops, stacking faults, twins and stacking-fault tetrahedral in the diamond, which may be derived from the supersaturated vacancies generated during rapid cooling from high temperature. The formation process of the imperfections is discussed briefly.展开更多
We describe here a one-step method for the synthesis of Au/TiO2 nanosphere materials,which were formed by layered deposition of multiple anatase TiO2 nanosheets.The Au nanoparticles were stabilized by structural defec...We describe here a one-step method for the synthesis of Au/TiO2 nanosphere materials,which were formed by layered deposition of multiple anatase TiO2 nanosheets.The Au nanoparticles were stabilized by structural defects in each TiO2 nanosheet,including crystal steps and edges,thereby fixing the Au-TiO2 perimeter interface.Reactant transfer occurred along the gaps between these TiO2 nanosheet layers and in contact with catalytically active sites at the Au-TiO2 interface.The doped Au induced the formation of oxygen vacancies in the Au-TiO2 interface.Such vacancies are essential for generating active oxygen species（-＊O^-） on the TiO2 surface and Ti^3＋ ions in bulk TiO2.These ions can then form Ti^3＋-O^--Ti^4＋species,which are known to enhance the catalytic activity of formaldehyde（HCHO） oxidation.These studies on structural and oxygen vacancy defects in Au/TiO2 samples provide a theoretical foundation for the catalytic mechanism of HCHO oxidation on oxide-supported Au materials.展开更多
文摘A diamond single crystal, which was synthesized at a high temperature of 1570 K and a high pressure of 5.5 GPa in a Fe-Ni-C system, was directly and systematically examined by transmission electron microscopy (TEM). It is proposed that there exists a variety of imperfections such as dislocation loops, stacking faults, twins and stacking-fault tetrahedral in the diamond, which may be derived from the supersaturated vacancies generated during rapid cooling from high temperature. The formation process of the imperfections is discussed briefly.
基金supported by the National Natural Science Foundation of China (21107124, 21337003)the Youth Innovation Promotion Association (2011037)Science Promotion Program of Research Center for Eco-Environmental Sciences, Chinese Academic Sciences (No. 121311RCEES-QN-20130046F)
文摘We describe here a one-step method for the synthesis of Au/TiO2 nanosphere materials,which were formed by layered deposition of multiple anatase TiO2 nanosheets.The Au nanoparticles were stabilized by structural defects in each TiO2 nanosheet,including crystal steps and edges,thereby fixing the Au-TiO2 perimeter interface.Reactant transfer occurred along the gaps between these TiO2 nanosheet layers and in contact with catalytically active sites at the Au-TiO2 interface.The doped Au induced the formation of oxygen vacancies in the Au-TiO2 interface.Such vacancies are essential for generating active oxygen species（-＊O^-） on the TiO2 surface and Ti^3＋ ions in bulk TiO2.These ions can then form Ti^3＋-O^--Ti^4＋species,which are known to enhance the catalytic activity of formaldehyde（HCHO） oxidation.These studies on structural and oxygen vacancy defects in Au/TiO2 samples provide a theoretical foundation for the catalytic mechanism of HCHO oxidation on oxide-supported Au materials.
