The modeling and self-excited vibration mechanism in the magnetic levitation-collision interface coupling system are investigated.The effects of the control and interface parameters on the system's stability are a...The modeling and self-excited vibration mechanism in the magnetic levitation-collision interface coupling system are investigated.The effects of the control and interface parameters on the system's stability are analyzed.The frequency range of self-excited vibrations is investigated from the energy point of view.The phenomenon of self-excited vibrations is elaborated with the phase trajectory.The corresponding control strategies are briefly analyzed with respect to the vibration mechanism.The results show that when the levitation objects collide with the mechanical interface,the system's vibration frequency becomes larger with the decrease in the collision gap;when the vibration frequency exceeds the critical frequency,the electromagnetic system continues to provide energy to the system,and the collision interface continuously dissipates energy so that the system enters the self-excited vibration state.展开更多
Polymer-based composite electrolytes composed of three-dimensional Li_(6.4)La_(3)Zr_(2)Al_(0.2)O_(12)(3D-LLZAO)have attracted increasing attention due to their continuous ion conduction and satisfactory mechanical pro...Polymer-based composite electrolytes composed of three-dimensional Li_(6.4)La_(3)Zr_(2)Al_(0.2)O_(12)(3D-LLZAO)have attracted increasing attention due to their continuous ion conduction and satisfactory mechanical properties.However,the organic/inorganic interface is incompatible,resulting in slow lithium-ion transport at the interface.Therefore,the compatibility of organic/inorganic interface is an urgent problem to be solved.Inspired by the concept of“gecko eaves”,polymer-based composite solid electrolytes with dense interface structures were designed.The bridging of organic/inorganic interfaces was established by introducing silane coupling agent(3-chloropropyl)trimethoxysilane(CTMS)into the PEO-3D-LLZAO(PL)electrolyte.The in-situ coupling reaction improves the interface affinity,strengthens the organic/inorganic interaction,reduces the interface resistance,and thus achieves an efficient interface ion transport network.The prepared PEO-3D-LLZAO-CTMS(PLC)electrolyte exhibits enhanced ionic conductivity of 6.04×10^(-4)S cm^(-1)and high ion migration number(0.61)at 60℃and broadens the electrochemical window(5.1 V).At the same time,the PLC electrolyte has good thermal stability and high mechanical properties.Moreover,the Li Fe PO_(4)|PLC|Li battery has excellent rate performance and cycling stability with a capacity decay rate of 2.2%after 100 cycles at 60℃and 0.1 C.These advantages of PLC membranes indicate that this design approach is indeed practical,and the in-situ coupling method provides a new approach to address interface compatibility issues.展开更多
The Laguerre polynomial method has been successfully used to investigate the dynamic responses of a half-space.However,it fails to obtain the correct stress at the interfaces in a layered half-space,especially when th...The Laguerre polynomial method has been successfully used to investigate the dynamic responses of a half-space.However,it fails to obtain the correct stress at the interfaces in a layered half-space,especially when there are significant differences in material properties.Therefore,a coupled Legendre-Laguerre polynomial method with analytical integration is proposed.The Rayleigh waves in a one-dimensional(1D)hexagonal quasicrystal(QC)layered half-space with an imperfect interface are investigated.The correctness is validated by comparison with available results.Its computation efficiency is analyzed.The dispersion curves of the phase velocity,displacement distributions,and stress distributions are illustrated.The effects of the phonon-phason coupling and imperfect interface coefficients on the wave characteristics are investigated.Some novel findings reveal that the proposed method is highly efficient for addressing the Rayleigh waves in a QC layered half-space.It can save over 99%of the computation time.This method can be expanded to investigate waves in various layered half-spaces,including earth-layered media and surface acoustic wave(SAW)devices.展开更多
The formation mechanism of calcium vanadate and manganese vanadate and the difference between calcium and manganese in the reaction with vanadium are basic issues in the calcification roasting and manganese roasting p...The formation mechanism of calcium vanadate and manganese vanadate and the difference between calcium and manganese in the reaction with vanadium are basic issues in the calcification roasting and manganese roasting process with vanadium slag.In this work,CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) diffusion couples were prepared and roasted for different time periods to illustrate and compare the diffusion reaction mechanisms.Then,the changes in the diffusion product and diffusion coefficient were investigated and calculated based on scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS) analysis.Results show that with the extension of the roasting time,the diffusion reaction gradually proceeds among the CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) diffusion couples.The regional boundaries of calcium and vanadium are easily identifiable for the CaO–V_(2)O_(5) diffusion couple.Meanwhile,for the MnO_(2)–V_(2)O_(5) diffusion couple,MnO_(2) gradually decomposes to form Mn_(2)O_(3),and vanadium diffuses into the interior of Mn_(2)O_(3).Only a part of vanadium combines with manganese to form the diffusion production layer.CaV_(2)O_(6) and MnV_(2)O_(6) are the interfacial reaction products of the CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) diffusion couples,respectively,whose thicknesses are 39.85 and 32.13μm when roasted for 16 h.After 16 h,both diffusion couples reach the reaction equilibrium due to the limitation of diffusion.The diffusion coefficient of the CaO–V_(2)O_(5) diffusion couple is higher than that of the MnO_(2)–V_(2)O_(5) diffusion couple for the same roasting time,and the diffusion reaction between vanadium and calcium is easier than that between vanadium and manganese.展开更多
The purpose of this study is to investigate the effect of the concentration of silane coupling solution on the tensile strength of basalt fiber and the interfacial properties of basalt fiber reinforced polymer composi...The purpose of this study is to investigate the effect of the concentration of silane coupling solution on the tensile strength of basalt fiber and the interfacial properties of basalt fiber reinforced polymer composites.The surface treatment of basalt fibers was carried out using an aqueous alcohol solution method.Basalt fibers were subjected to surface treatment with 3-Methacryloxypropyl trimethoxy silane at 0.5 wt.%,1 wt.%,2 wt.%,4 wt.%and 10 wt.%.The basalt monofilament tensile tests were carried out to investigate the variation in strength with the concentration of the silane coupling agent.The microdroplet test was performed to examine the effect of the concentration of the silane coupling agent on interfacial strength of basalt reinforced polymer composites.The film was formed on the surface of the basalt fiber treated silane coupling agent solution.The tensile strength of basalt fiber increased because the damaged fiber surface was repaired by the firm of silane coupling agent.The firm was effective in not only the surface protection of basalt fiber but also the improvement on the interfacial strength of fiber-matrix interface.However,the surface treatment using the high concentration silane coupling agent solution has an adverse effect on the mechanical properties of the composite materials,because of causing the degradation of the interfacial strength of the composite materials.展开更多
The structural-acoustic coupling model for isotropic thin elastic plate was extended to honeycomb sandwich plate(HSP) by applying Green function method.Then an equivalent circuit model of the weakly-strongly coupled s...The structural-acoustic coupling model for isotropic thin elastic plate was extended to honeycomb sandwich plate(HSP) by applying Green function method.Then an equivalent circuit model of the weakly-strongly coupled system was proposed.Based on that,the estimation formulae of the coupled eigenfrequency were derived.The accuracy of the theoretical predictions was checked against experimental data,with good agreement achieved.Finally,the effects of HSP design parameters on the system coupling degree,the acoustic cavity eigenfrequency,and sound pressure response were analyzed.The results show that mechanical and acoustical characteristics of HSP can be improved by increasing the thickness of face sheet and reducing the mass density of material.展开更多
The surface modification of clay fines was carried out by using silanecoupling agent. By means of IR spectra etc, a study was made on the combined state ofcoupling agent and clay. A rubber--clay composite material wit...The surface modification of clay fines was carried out by using silanecoupling agent. By means of IR spectra etc, a study was made on the combined state ofcoupling agent and clay. A rubber--clay composite material with excellent performancehas been prepared.展开更多
A periodic pipe system composed of steel pipes and rubber hoses with the same inner radius is designed based on the theory of phononic crystals. Using the transfer matrix method, the band structure of the periodic pip...A periodic pipe system composed of steel pipes and rubber hoses with the same inner radius is designed based on the theory of phononic crystals. Using the transfer matrix method, the band structure of the periodic pipe is calculated considering the structural-acoustic coupling. The results show that longitudinal vibration band gaps and acoustic band gaps can coexist in the fluid-filled periodic pipe. The formation of the band gap mechanism is further analyzed. The band gaps are validated by the sound transmission loss and vibration-frequency response functions calculated using the finite element method. The effect of the damp on the band gap is analyzed by calculating the complex band structure. The periodic pipe system can be used not only in the field of vibration reduction but also for noise elimination.展开更多
The metal plastic flow, tribology performance and work roll vibration on the rolling interface were analyzed. Considering the effect of work roll vibration on the tribology behavior of rolling interface, the damping o...The metal plastic flow, tribology performance and work roll vibration on the rolling interface were analyzed. Considering the effect of work roll vibration on the tribology behavior of rolling interface, the damping of rolling interface was researched. It is found that the rolling interface, where the partial hydraulic lubricating film and dry friction area coexist, is of negative damping coefficient. The negative damping results from the dynamic variation of the thickness of lubricating film in the rolling interface, and is caused by the special coupling between dynamics and tribology of the rolling interface.展开更多
The coupling agents content and thickness on glass fiber (GF) surfaces which have been treated with silanes and titanates under different conditions are tested by means of XRF (X-Ray Fluorescent spectrometry). And the...The coupling agents content and thickness on glass fiber (GF) surfaces which have been treated with silanes and titanates under different conditions are tested by means of XRF (X-Ray Fluorescent spectrometry). And the rheological characteristics of the dispersed systems prepared from the above glass fibers combined with unsaturated polyester resin (UP) are discussed. The results show that the rigidity of the internal layers of silane coupling agent absorbed by glass surfaces is greater than the one of the external layers; while the effect of the titanate coupling agents on the rheolo- gical characteristics of the system is approximately the same in each structural layer, that is due to the fact that both the internal and external layers of titanates on glass surfaces have the similar flexible structures.展开更多
Electronic structure and spin-related state coupling at ferromagnetic material (FM)/MgO (FM = Fe, CoFe, CoFeB) interfaces under biaxial strain are evaluated using the first-principles calculations. The CoFeB/MgO i...Electronic structure and spin-related state coupling at ferromagnetic material (FM)/MgO (FM = Fe, CoFe, CoFeB) interfaces under biaxial strain are evaluated using the first-principles calculations. The CoFeB/MgO interface, which is su- perior to the Fe/MgO and CoFe/MgO interfaces, can markedly maintain stable and effective coupling channels for majority- spin A1 state under large biaxial strain. Bonding interactions between Fe, Co, and B atoms and the electron transfer between Bloch states are responsible for the redistribution of the majority-spin A1 state, directly influencing the coupling effect for the strained interfaces. Layer-projected wave function of the majority-spin Al state suggests slower decay rate and more stable transport property in the CoFeB/MgO interface, which is expected to maintain a higher tunneling magnetoresistance (TMR) value under large biaxial strain. This work reveals the internal mechanism for the state coupling al strained FM/MgO interfaces. This study may provide some references to the design and manufacturing of magnetic tunnel .junctions with high tunneling magnetoresistance effect.展开更多
Planar optical waveguides are the key elements in a modern, high-speed optical network. An important problem facing the optical fiber communication system, specifically planar optical waveguides, is coupling. The curr...Planar optical waveguides are the key elements in a modern, high-speed optical network. An important problem facing the optical fiber communication system, specifically planar optical waveguides, is coupling. The current study presents a coupling model for planar optical waveguides and optical fibers. The various effects of the optical properties of the coupling interface were analyzed by the scalar finite difference beam propagation method, including the thickness, with or without the matching refractive index of the interface adhesive. The findings can serve as a guide for planar optical waveguide packaging.展开更多
This paper analyzes the random response of structural-acoustic coupled systems. Most existing works on coupled structural-acoustic analysis are limited to systems under deterministic excitations due to high computatio...This paper analyzes the random response of structural-acoustic coupled systems. Most existing works on coupled structural-acoustic analysis are limited to systems under deterministic excitations due to high computational cost required by a random response analysis. To reduce the computational burden involved in the coupled random analysis, an iterative procedure based on the Pseudo excitation method has been developed. It is found that this algorithm has an overwhelming advantage in computing efficiency over traditional methods, as demonstrated by some numerical examples given in this paper.展开更多
Component-based software engineering is concerned with the develop-ment of software that can satisfy the customer prerequisites through reuse or inde-pendent development.Coupling and cohesion measurements are primaril...Component-based software engineering is concerned with the develop-ment of software that can satisfy the customer prerequisites through reuse or inde-pendent development.Coupling and cohesion measurements are primarily used to analyse the better software design quality,increase the reliability and reduced system software complexity.The complexity measurement of cohesion and coupling component to analyze the relationship between the component module.In this paper,proposed the component selection framework of Hexa-oval optimization algorithm for selecting the suitable components from the repository.It measures the interface density modules of coupling and cohesion in a modular software sys-tem.This cohesion measurement has been taken into two parameters for analyz-ing the result of complexity,with the help of low cohesion and high cohesion.In coupling measures between the component of inside parameters and outside parameters.Thefinal process of coupling and cohesion,the measured values were used for the average calculation of components parameter.This paper measures the complexity of direct and indirect interaction among the component as well as the proposed algorithm selecting the optimal component for the repository.The better result is observed for high cohesion and low coupling in compo-nent-based software engineering.展开更多
Herein,a bottom-down design is presented to successfully fabricate ZIF-derived Co3O4,grown in situ on a one-dimensional(1D)α-MnO2 material,denoted as α-MnO2@Co3O4.The synergistic effect derived from the coupled inte...Herein,a bottom-down design is presented to successfully fabricate ZIF-derived Co3O4,grown in situ on a one-dimensional(1D)α-MnO2 material,denoted as α-MnO2@Co3O4.The synergistic effect derived from the coupled interface constructed betweenα-MnO2 and Co3O4 is responsible for the enhanced catalytic activity.The resultantα-MnO2@Co3O4 catalyst exhibits excellent catalytic activity at a T90%(temperature required to achieve a toluene conversion of 90%)of approximately 229℃,which is 47 and 28℃ lower than those of the pureα-MnO2 nanowire and Co3O4-b obtained via pyrolysis of ZIF-67,respectively.This activity is attributed to the increase in the number of surface-adsorbed oxygen species,which accelerate the oxygen mobility and enhance the redox pairs of Mn^4+/Mn^3+ and Co^2+/Co^3+.Moreover,the result of in situ diffuse reflectance infrared Fourier transform spectroscopy suggests that the gaseous oxygen could be more easily activated to adsorbed oxygen species on the surface of α-MnO2@Co3O4 than on that of α-MnO2.The catalytic reaction route of toluene oxidation over theα-MnO2@Co3O4 catalyst is as follows:toluene→benzoate species→alkanes containing oxygen functional group→CO2 and H2O.In addition,the α-MnO2@Co3O4 catalyst shows excellent stability and good water resistance for toluene oxidation.Furthermore,the preparation method can be extended to other 1D MnO2 materials.A new strategy for the development of high-performance catalysts of practical significance is provided.展开更多
Constructing interfaces in heterostructures is effective for modulating the electronic properties of electrocatalysts.The hollow CoMoO_(4)-Co_(3)O_(4) heterostructure(HCMCH)was prepared as a bifunctional electrocataly...Constructing interfaces in heterostructures is effective for modulating the electronic properties of electrocatalysts.The hollow CoMoO_(4)-Co_(3)O_(4) heterostructure(HCMCH)was prepared as a bifunctional electrocatalyst for Li-O_(2) battery.The different components in CoMoO_(4)-Co_(3)O_(4) heterostructure presented the efficient coupling and enhanced the electrocatalytic activity for aprotic oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),in which it improved the obviously reduced overpotential of 300 mV(compared with the pure Ketjen black(KB)electrode),enhanced reversibility of 80%capacity retention after 6 full cycles and the superior cyclability of more than 200 cycles with an optimized strategy.The battery performance of the HCMCH was not only associated with the unique hollow structure and rich active sites but also with coupling interface constructions synergetic effects attaching to the improving conductivity and optimized the discharge conversion.These results suggested that this HCMCH electrocatalyst was a promising candidate for the Li-O_(2) battery and it gave a novel insight for high performance electrocatalyst designing.展开更多
The interface properties in two-dimensional(2D)layered materials and their van der Waals(vdW)homo-/heterostructures are of importance in both uncovering novel physical phenomena and optimizing device performance.Despi...The interface properties in two-dimensional(2D)layered materials and their van der Waals(vdW)homo-/heterostructures are of importance in both uncovering novel physical phenomena and optimizing device performance.Despite considerable research interest and enthusiasm direct toward the interlayer coupling in 2D homo-and heterostructures,there is limited research on the coupling at the 2D layered material-substrate interface.This limitation is due to the challenges in achieving direct detection.Currently,the coupling mechanisms at the 2D layered material-substrate interface is ambiguous,which needs greater attention.In this study,we have systematically investigated the interface coupling between monolayer WS_(2)and its supported substrates using high-temperature and high-vacuum in-situ Raman spectroscopy through monitoring the low-frequency Raman mode of monolayer WS_(2).Our findings reveal that both interfacial spacing and strain can significantly affect the coupling strength between the monolayer WS_(2)and the supported substrate.More notably,we found that the strategic introduction of appropriate interfacial strain can effectively enhance the interface coupling.Consequently,we have succeeded in achieving effective regulation of the sample-substrate coupling via a convenient way of controlling the cooling process during annealing.Our findings contribute to a deeper understanding of the coupling correlation between 2D layered materials and substrates,which is of great significance for the design and optimization of high-performance devices based on 2D layered semiconductors.展开更多
Investigated in this paper are the effects of strain gradients onthe stress distribution near an interface. The quasi-axis-symmetryinterface problem is solved by using the couple stress theory and theper- turbation me...Investigated in this paper are the effects of strain gradients onthe stress distribution near an interface. The quasi-axis-symmetryinterface problem is solved by using the couple stress theory and theper- turbation method. The results show that a boundary layer existsnear an interface or a fixed boundary, where the shear stressperpendicular to the interface is significantly different from thatobtained from the classical elasticity theory.展开更多
The field of environmental sciences is abundant with various interfaces and is the right place for the application of new fundamental approaches leading towards a better understanding of environmental phenomena. Follo...The field of environmental sciences is abundant with various interfaces and is the right place for the application of new fundamental approaches leading towards a better understanding of environmental phenomena. Following the definition of environmental interface by Mihailovic and Bala? [1], such interface can be, for example, placed between: human or animal bodies and surrounding air, aquatic species and water and air around them, and natural or artificially built surfaces (vegetation, ice, snow, barren soil, water, urban communities) and the atmosphere, cells and surrounding environment, etc. Complex environmental interface systems are (i) open and hierarchically organised (ii) interactions between their constituent parts are nonlinear, and (iii) their interaction with the surrounding environment is noisy. These systems are therefore very sensitive to initial conditions, deterministic external perturbations and random fluctuations always present in nature. The study of noisy non-equilibrium processes is fundamental for modelling the dynamics of environmental interface regarded as biophysical complex system and for understanding the mechanisms of spatio-temporal pattern formation in contemporary environmental sciences. In this paper we will investigate an aspect of dynamics of energy flow based on the energy balance equation. The energy exchange between interacting environmen- tal interfaces regarded as biophysical complex systems can be represented by coupled maps. Therefore, we will numerically investigate coupled maps representing that exchange. In ana- lysis of behaviour of these maps we applied Lyapunov exponent and cross sample entropy.展开更多
We have defined the environmental interface through the exchange processes between media forming this interface. Considering the environmental interface as a complex system we elaborated the advanced mathematical tool...We have defined the environmental interface through the exchange processes between media forming this interface. Considering the environmental interface as a complex system we elaborated the advanced mathematical tools for its modelling. We have suggested two coupled maps serving the exchange processes on the environmental interfaces spatially ranged from cellular to planetary level, i.e. 1) the map with diffusive coupling for energy exchange simulation and 2) the map with affinity, which is suitable for matter exchange processes at the cellular level. We have performed the dynamical analysis of the coupled maps using the Lyapunov exponent, cross sample as well as the permutation entropy in dependence on different map parameters. Finally, we discussed the map with affinity, which shows some features making it a promising toll in simulation of exchange processes on the environmental interface at the cellular level.展开更多
基金Project supported by the National Natural Science Foundation of China(No.12372005)。
文摘The modeling and self-excited vibration mechanism in the magnetic levitation-collision interface coupling system are investigated.The effects of the control and interface parameters on the system's stability are analyzed.The frequency range of self-excited vibrations is investigated from the energy point of view.The phenomenon of self-excited vibrations is elaborated with the phase trajectory.The corresponding control strategies are briefly analyzed with respect to the vibration mechanism.The results show that when the levitation objects collide with the mechanical interface,the system's vibration frequency becomes larger with the decrease in the collision gap;when the vibration frequency exceeds the critical frequency,the electromagnetic system continues to provide energy to the system,and the collision interface continuously dissipates energy so that the system enters the self-excited vibration state.
基金supported by the Key Program(U20A20235)funded by the National Natural Science Foundation of Chinathe National Natural Science Foundation of China(52171127,51974242)+3 种基金the Natural Science Basic Research Program of Shaanxi(2023-JC-QN-0595)the Regional Innovation Capability Guidance Program of Shaanxi(2022QFY10-06)the Key R&D Program of Xianyang Science and Technology Bureau(2021ZDYF-GY-0029)the Program of Xi’an Science and Technology Bureau(23GXFW0066)。
文摘Polymer-based composite electrolytes composed of three-dimensional Li_(6.4)La_(3)Zr_(2)Al_(0.2)O_(12)(3D-LLZAO)have attracted increasing attention due to their continuous ion conduction and satisfactory mechanical properties.However,the organic/inorganic interface is incompatible,resulting in slow lithium-ion transport at the interface.Therefore,the compatibility of organic/inorganic interface is an urgent problem to be solved.Inspired by the concept of“gecko eaves”,polymer-based composite solid electrolytes with dense interface structures were designed.The bridging of organic/inorganic interfaces was established by introducing silane coupling agent(3-chloropropyl)trimethoxysilane(CTMS)into the PEO-3D-LLZAO(PL)electrolyte.The in-situ coupling reaction improves the interface affinity,strengthens the organic/inorganic interaction,reduces the interface resistance,and thus achieves an efficient interface ion transport network.The prepared PEO-3D-LLZAO-CTMS(PLC)electrolyte exhibits enhanced ionic conductivity of 6.04×10^(-4)S cm^(-1)and high ion migration number(0.61)at 60℃and broadens the electrochemical window(5.1 V).At the same time,the PLC electrolyte has good thermal stability and high mechanical properties.Moreover,the Li Fe PO_(4)|PLC|Li battery has excellent rate performance and cycling stability with a capacity decay rate of 2.2%after 100 cycles at 60℃and 0.1 C.These advantages of PLC membranes indicate that this design approach is indeed practical,and the in-situ coupling method provides a new approach to address interface compatibility issues.
基金Project supported by the National Natural Science Foundation of China(No.12102131)the Natural Science Foundation of Henan Province of China(No.242300420248)the International Science and Technology Cooperation Project of Henan Province of China(No.242102521010)。
文摘The Laguerre polynomial method has been successfully used to investigate the dynamic responses of a half-space.However,it fails to obtain the correct stress at the interfaces in a layered half-space,especially when there are significant differences in material properties.Therefore,a coupled Legendre-Laguerre polynomial method with analytical integration is proposed.The Rayleigh waves in a one-dimensional(1D)hexagonal quasicrystal(QC)layered half-space with an imperfect interface are investigated.The correctness is validated by comparison with available results.Its computation efficiency is analyzed.The dispersion curves of the phase velocity,displacement distributions,and stress distributions are illustrated.The effects of the phonon-phason coupling and imperfect interface coefficients on the wave characteristics are investigated.Some novel findings reveal that the proposed method is highly efficient for addressing the Rayleigh waves in a QC layered half-space.It can save over 99%of the computation time.This method can be expanded to investigate waves in various layered half-spaces,including earth-layered media and surface acoustic wave(SAW)devices.
基金supported by the National Natural Science Foundation of China(Nos.52174277 and 51874077)the Fundamental Funds for the Central Universities,China(No.N2225032)+1 种基金the China Postdoctoral Science Foundation(No.2022M720683)the Postdoctoral Fund of Northeastern University,China。
文摘The formation mechanism of calcium vanadate and manganese vanadate and the difference between calcium and manganese in the reaction with vanadium are basic issues in the calcification roasting and manganese roasting process with vanadium slag.In this work,CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) diffusion couples were prepared and roasted for different time periods to illustrate and compare the diffusion reaction mechanisms.Then,the changes in the diffusion product and diffusion coefficient were investigated and calculated based on scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS) analysis.Results show that with the extension of the roasting time,the diffusion reaction gradually proceeds among the CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) diffusion couples.The regional boundaries of calcium and vanadium are easily identifiable for the CaO–V_(2)O_(5) diffusion couple.Meanwhile,for the MnO_(2)–V_(2)O_(5) diffusion couple,MnO_(2) gradually decomposes to form Mn_(2)O_(3),and vanadium diffuses into the interior of Mn_(2)O_(3).Only a part of vanadium combines with manganese to form the diffusion production layer.CaV_(2)O_(6) and MnV_(2)O_(6) are the interfacial reaction products of the CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) diffusion couples,respectively,whose thicknesses are 39.85 and 32.13μm when roasted for 16 h.After 16 h,both diffusion couples reach the reaction equilibrium due to the limitation of diffusion.The diffusion coefficient of the CaO–V_(2)O_(5) diffusion couple is higher than that of the MnO_(2)–V_(2)O_(5) diffusion couple for the same roasting time,and the diffusion reaction between vanadium and calcium is easier than that between vanadium and manganese.
文摘The purpose of this study is to investigate the effect of the concentration of silane coupling solution on the tensile strength of basalt fiber and the interfacial properties of basalt fiber reinforced polymer composites.The surface treatment of basalt fibers was carried out using an aqueous alcohol solution method.Basalt fibers were subjected to surface treatment with 3-Methacryloxypropyl trimethoxy silane at 0.5 wt.%,1 wt.%,2 wt.%,4 wt.%and 10 wt.%.The basalt monofilament tensile tests were carried out to investigate the variation in strength with the concentration of the silane coupling agent.The microdroplet test was performed to examine the effect of the concentration of the silane coupling agent on interfacial strength of basalt reinforced polymer composites.The film was formed on the surface of the basalt fiber treated silane coupling agent solution.The tensile strength of basalt fiber increased because the damaged fiber surface was repaired by the firm of silane coupling agent.The firm was effective in not only the surface protection of basalt fiber but also the improvement on the interfacial strength of fiber-matrix interface.However,the surface treatment using the high concentration silane coupling agent solution has an adverse effect on the mechanical properties of the composite materials,because of causing the degradation of the interfacial strength of the composite materials.
基金Project(51105375)supported by the National Natural Science Foundation of ChinaProject(CSTC2010BB8204)supported by Chongqing Natural Science Foundation,China
文摘The structural-acoustic coupling model for isotropic thin elastic plate was extended to honeycomb sandwich plate(HSP) by applying Green function method.Then an equivalent circuit model of the weakly-strongly coupled system was proposed.Based on that,the estimation formulae of the coupled eigenfrequency were derived.The accuracy of the theoretical predictions was checked against experimental data,with good agreement achieved.Finally,the effects of HSP design parameters on the system coupling degree,the acoustic cavity eigenfrequency,and sound pressure response were analyzed.The results show that mechanical and acoustical characteristics of HSP can be improved by increasing the thickness of face sheet and reducing the mass density of material.
文摘The surface modification of clay fines was carried out by using silanecoupling agent. By means of IR spectra etc, a study was made on the combined state ofcoupling agent and clay. A rubber--clay composite material with excellent performancehas been prepared.
基金Supported by the National Natural Science Foundation of China under Grant No 11372346
文摘A periodic pipe system composed of steel pipes and rubber hoses with the same inner radius is designed based on the theory of phononic crystals. Using the transfer matrix method, the band structure of the periodic pipe is calculated considering the structural-acoustic coupling. The results show that longitudinal vibration band gaps and acoustic band gaps can coexist in the fluid-filled periodic pipe. The formation of the band gap mechanism is further analyzed. The band gaps are validated by the sound transmission loss and vibration-frequency response functions calculated using the finite element method. The effect of the damp on the band gap is analyzed by calculating the complex band structure. The periodic pipe system can be used not only in the field of vibration reduction but also for noise elimination.
文摘The metal plastic flow, tribology performance and work roll vibration on the rolling interface were analyzed. Considering the effect of work roll vibration on the tribology behavior of rolling interface, the damping of rolling interface was researched. It is found that the rolling interface, where the partial hydraulic lubricating film and dry friction area coexist, is of negative damping coefficient. The negative damping results from the dynamic variation of the thickness of lubricating film in the rolling interface, and is caused by the special coupling between dynamics and tribology of the rolling interface.
文摘The coupling agents content and thickness on glass fiber (GF) surfaces which have been treated with silanes and titanates under different conditions are tested by means of XRF (X-Ray Fluorescent spectrometry). And the rheological characteristics of the dispersed systems prepared from the above glass fibers combined with unsaturated polyester resin (UP) are discussed. The results show that the rigidity of the internal layers of silane coupling agent absorbed by glass surfaces is greater than the one of the external layers; while the effect of the titanate coupling agents on the rheolo- gical characteristics of the system is approximately the same in each structural layer, that is due to the fact that both the internal and external layers of titanates on glass surfaces have the similar flexible structures.
基金Project supported by the National Key Research and Development Program of China(Grant No.2016YFB0400801)the National Natural Science Foundation of China(Grant Nos.61774128,61674124,11604275,11304257,and 61227009)+1 种基金the Natural Science Foundation of Fujian Province of China(Grant Nos.2017J01012,2014J01026,2016J01037,and 2015J01028)the Fundamental Research Funds for the Central Universities,China(Grant Nos.20720150027,20720160044,20720160122,20720170085,20720170012,and 20720150033)
文摘Electronic structure and spin-related state coupling at ferromagnetic material (FM)/MgO (FM = Fe, CoFe, CoFeB) interfaces under biaxial strain are evaluated using the first-principles calculations. The CoFeB/MgO interface, which is su- perior to the Fe/MgO and CoFe/MgO interfaces, can markedly maintain stable and effective coupling channels for majority- spin A1 state under large biaxial strain. Bonding interactions between Fe, Co, and B atoms and the electron transfer between Bloch states are responsible for the redistribution of the majority-spin A1 state, directly influencing the coupling effect for the strained interfaces. Layer-projected wave function of the majority-spin Al state suggests slower decay rate and more stable transport property in the CoFeB/MgO interface, which is expected to maintain a higher tunneling magnetoresistance (TMR) value under large biaxial strain. This work reveals the internal mechanism for the state coupling al strained FM/MgO interfaces. This study may provide some references to the design and manufacturing of magnetic tunnel .junctions with high tunneling magnetoresistance effect.
文摘Planar optical waveguides are the key elements in a modern, high-speed optical network. An important problem facing the optical fiber communication system, specifically planar optical waveguides, is coupling. The current study presents a coupling model for planar optical waveguides and optical fibers. The various effects of the optical properties of the coupling interface were analyzed by the scalar finite difference beam propagation method, including the thickness, with or without the matching refractive index of the interface adhesive. The findings can serve as a guide for planar optical waveguide packaging.
基金supported by the National Natural Science Foundation of China (11072049,10772038)the Key Project of Chinese National Programs for Fundamental Research and Development (2010CB832703)+1 种基金the National Key Technology Support Program (2009BAG12A04)the Program for New Century Excellent Talents in University
文摘This paper analyzes the random response of structural-acoustic coupled systems. Most existing works on coupled structural-acoustic analysis are limited to systems under deterministic excitations due to high computational cost required by a random response analysis. To reduce the computational burden involved in the coupled random analysis, an iterative procedure based on the Pseudo excitation method has been developed. It is found that this algorithm has an overwhelming advantage in computing efficiency over traditional methods, as demonstrated by some numerical examples given in this paper.
基金We deeply acknowledge Taif University for Supporting this research through Taif University Researchers Supporting Project number(TURSP-2020/231),Taif University,Taif,Saudi Arabia.
文摘Component-based software engineering is concerned with the develop-ment of software that can satisfy the customer prerequisites through reuse or inde-pendent development.Coupling and cohesion measurements are primarily used to analyse the better software design quality,increase the reliability and reduced system software complexity.The complexity measurement of cohesion and coupling component to analyze the relationship between the component module.In this paper,proposed the component selection framework of Hexa-oval optimization algorithm for selecting the suitable components from the repository.It measures the interface density modules of coupling and cohesion in a modular software sys-tem.This cohesion measurement has been taken into two parameters for analyz-ing the result of complexity,with the help of low cohesion and high cohesion.In coupling measures between the component of inside parameters and outside parameters.Thefinal process of coupling and cohesion,the measured values were used for the average calculation of components parameter.This paper measures the complexity of direct and indirect interaction among the component as well as the proposed algorithm selecting the optimal component for the repository.The better result is observed for high cohesion and low coupling in compo-nent-based software engineering.
文摘Herein,a bottom-down design is presented to successfully fabricate ZIF-derived Co3O4,grown in situ on a one-dimensional(1D)α-MnO2 material,denoted as α-MnO2@Co3O4.The synergistic effect derived from the coupled interface constructed betweenα-MnO2 and Co3O4 is responsible for the enhanced catalytic activity.The resultantα-MnO2@Co3O4 catalyst exhibits excellent catalytic activity at a T90%(temperature required to achieve a toluene conversion of 90%)of approximately 229℃,which is 47 and 28℃ lower than those of the pureα-MnO2 nanowire and Co3O4-b obtained via pyrolysis of ZIF-67,respectively.This activity is attributed to the increase in the number of surface-adsorbed oxygen species,which accelerate the oxygen mobility and enhance the redox pairs of Mn^4+/Mn^3+ and Co^2+/Co^3+.Moreover,the result of in situ diffuse reflectance infrared Fourier transform spectroscopy suggests that the gaseous oxygen could be more easily activated to adsorbed oxygen species on the surface of α-MnO2@Co3O4 than on that of α-MnO2.The catalytic reaction route of toluene oxidation over theα-MnO2@Co3O4 catalyst is as follows:toluene→benzoate species→alkanes containing oxygen functional group→CO2 and H2O.In addition,the α-MnO2@Co3O4 catalyst shows excellent stability and good water resistance for toluene oxidation.Furthermore,the preparation method can be extended to other 1D MnO2 materials.A new strategy for the development of high-performance catalysts of practical significance is provided.
基金supported by the National Natural Science Foundation of China(Nos.22271018,12304037)Talent introduction and scientific research funds of Beijing Normal University(No.310432107)Interdisciplinary Research Foundation for Doctoral Candidates of Beijing Normal University(No.BNUXKJC2216).
文摘Constructing interfaces in heterostructures is effective for modulating the electronic properties of electrocatalysts.The hollow CoMoO_(4)-Co_(3)O_(4) heterostructure(HCMCH)was prepared as a bifunctional electrocatalyst for Li-O_(2) battery.The different components in CoMoO_(4)-Co_(3)O_(4) heterostructure presented the efficient coupling and enhanced the electrocatalytic activity for aprotic oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),in which it improved the obviously reduced overpotential of 300 mV(compared with the pure Ketjen black(KB)electrode),enhanced reversibility of 80%capacity retention after 6 full cycles and the superior cyclability of more than 200 cycles with an optimized strategy.The battery performance of the HCMCH was not only associated with the unique hollow structure and rich active sites but also with coupling interface constructions synergetic effects attaching to the improving conductivity and optimized the discharge conversion.These results suggested that this HCMCH electrocatalyst was a promising candidate for the Li-O_(2) battery and it gave a novel insight for high performance electrocatalyst designing.
基金supported by the National Key R&D Program of China(2018YFA0703700)the National Natural Science Foundation of China(62374037)+1 种基金Shanghai Municipal Natural Science Foundation(20ZR1403200)the National Young 1000 Talent Plan of China。
文摘The interface properties in two-dimensional(2D)layered materials and their van der Waals(vdW)homo-/heterostructures are of importance in both uncovering novel physical phenomena and optimizing device performance.Despite considerable research interest and enthusiasm direct toward the interlayer coupling in 2D homo-and heterostructures,there is limited research on the coupling at the 2D layered material-substrate interface.This limitation is due to the challenges in achieving direct detection.Currently,the coupling mechanisms at the 2D layered material-substrate interface is ambiguous,which needs greater attention.In this study,we have systematically investigated the interface coupling between monolayer WS_(2)and its supported substrates using high-temperature and high-vacuum in-situ Raman spectroscopy through monitoring the low-frequency Raman mode of monolayer WS_(2).Our findings reveal that both interfacial spacing and strain can significantly affect the coupling strength between the monolayer WS_(2)and the supported substrate.More notably,we found that the strategic introduction of appropriate interfacial strain can effectively enhance the interface coupling.Consequently,we have succeeded in achieving effective regulation of the sample-substrate coupling via a convenient way of controlling the cooling process during annealing.Our findings contribute to a deeper understanding of the coupling correlation between 2D layered materials and substrates,which is of great significance for the design and optimization of high-performance devices based on 2D layered semiconductors.
基金the National Natural Science Foundation of China (No.19891180).
文摘Investigated in this paper are the effects of strain gradients onthe stress distribution near an interface. The quasi-axis-symmetryinterface problem is solved by using the couple stress theory and theper- turbation method. The results show that a boundary layer existsnear an interface or a fixed boundary, where the shear stressperpendicular to the interface is significantly different from thatobtained from the classical elasticity theory.
基金funded by the Serbian Ministry of Science and Technology under the project No.III 43007“Research of climate changes and their impact on environment.Monitoring of the impact,adaptation and moderation”for 2011-2014.
文摘The field of environmental sciences is abundant with various interfaces and is the right place for the application of new fundamental approaches leading towards a better understanding of environmental phenomena. Following the definition of environmental interface by Mihailovic and Bala? [1], such interface can be, for example, placed between: human or animal bodies and surrounding air, aquatic species and water and air around them, and natural or artificially built surfaces (vegetation, ice, snow, barren soil, water, urban communities) and the atmosphere, cells and surrounding environment, etc. Complex environmental interface systems are (i) open and hierarchically organised (ii) interactions between their constituent parts are nonlinear, and (iii) their interaction with the surrounding environment is noisy. These systems are therefore very sensitive to initial conditions, deterministic external perturbations and random fluctuations always present in nature. The study of noisy non-equilibrium processes is fundamental for modelling the dynamics of environmental interface regarded as biophysical complex system and for understanding the mechanisms of spatio-temporal pattern formation in contemporary environmental sciences. In this paper we will investigate an aspect of dynamics of energy flow based on the energy balance equation. The energy exchange between interacting environmen- tal interfaces regarded as biophysical complex systems can be represented by coupled maps. Therefore, we will numerically investigate coupled maps representing that exchange. In ana- lysis of behaviour of these maps we applied Lyapunov exponent and cross sample entropy.
文摘We have defined the environmental interface through the exchange processes between media forming this interface. Considering the environmental interface as a complex system we elaborated the advanced mathematical tools for its modelling. We have suggested two coupled maps serving the exchange processes on the environmental interfaces spatially ranged from cellular to planetary level, i.e. 1) the map with diffusive coupling for energy exchange simulation and 2) the map with affinity, which is suitable for matter exchange processes at the cellular level. We have performed the dynamical analysis of the coupled maps using the Lyapunov exponent, cross sample as well as the permutation entropy in dependence on different map parameters. Finally, we discussed the map with affinity, which shows some features making it a promising toll in simulation of exchange processes on the environmental interface at the cellular level.