There remain a number of unsolved problems about chemical reactions, and it is significant to explore new detection methods because they always offer some unique information about reactions from new points of view. Fo...There remain a number of unsolved problems about chemical reactions, and it is significant to explore new detection methods because they always offer some unique information about reactions from new points of view. For the first time, the solidification course of a modified two-component acrylic structural adhesive is measured by using reed-vibration mechanical spectroscopy for liquids (RMS-L) in this work, and results show that there are four sequential processes of mechanical spectra with time. The in-depth analyses indicate that RMS-L can detect in real-time the generation and disappearance of active free radicals, as well as the chemical cross-link processes in the adhesive. This kind of real-time detection will undoubtedly facilitate the study of the chemical reaction dynamics controlled by free radicals.展开更多
The computer aided engineering(CAE) analysis technique has become one of the most important means in modern automobile development due to its remarkably computing capability.With the development of CAE bussiness softw...The computer aided engineering(CAE) analysis technique has become one of the most important means in modern automobile development due to its remarkably computing capability.With the development of CAE bussiness software and intensive research on automotive development process,the CAE technique,which was only used as an auxiliary validation tool in the later product development in the past,is gradually used in each stage of product development now.Furthermore,accurate and fast analysis data can be supplied effectively.Especially in current CAE application, based on some optimization technologies such as sensitivity,feature and topology,the parametric design gradually enables a CAE engineer to be free from the condition which a convention analysis usually lags behind a design,and makes it be parallel to or even anterior to the design.Under the circumstance,the CAE resources can be maximized in each project development department,thereby promoting the project progress and quality,and creating a new philosophy of 'analysis-driven design'.展开更多
Different strategies can be used to perform reparations and reinforcements of ancient bolted and riveted metallic bridges. As the riveting process is not currently a common practice, it requires proper equipment and s...Different strategies can be used to perform reparations and reinforcements of ancient bolted and riveted metallic bridges. As the riveting process is not currently a common practice, it requires proper equipment and skilled workers. Another solution is the use of welding. However, the weldability of old steels is poor. Bolts are very attractive alternative solutions, and are most commonly used to repair old metallic bridges. Fitted bolts are expensive solutions; the alternative is the use of resin-injected bolts. The behavior of bolted joints with preloaded resin-injected bolts has been studied using quasi-static and creep tests; however, few studies on the slip and fatigue behavior of these joints can be found in the literature. This paper presents an overview of a few experimental programs that were carried out by several authors aiming at evaluating the fatigue behavior of single and double shear resin-injected bolted connections. A comparison between the experimental data of joints with preloaded standard bolts and preloaded resin- injected bolts shows a fatigue strength reduction in the latter. Since Eurocode 3 (EC3) suggests the same fatigue strength curve for joints made of resin-injected bolts and standard bolts, this may raise some con- cerns. Furthermore, research on the feasibility of using both bonded and bolted connections is shown. This last study was performed with high-strength low-alloy structural steel plates and an acrylic struc- tural adhesive for metal bonding. For both case studies, a statistical analysis is performed on fatigue experimental data using linearized boundaries and the Castillo and Fernandez-Canteli model. Fatigue design curves are proposed and compared with the design suggestions of several European and North American standards,展开更多
The propagation characteristics of laser-generated like-Rayleigh waves in viscoelastic adhesive coating/substrate structures were studied.Considering the viscoelasticity of the coating and substrate,we have establishe...The propagation characteristics of laser-generated like-Rayleigh waves in viscoelastic adhesive coating/substrate structures were studied.Considering the viscoelasticity of the coating and substrate,we have established the finite element models in frequency domain for the laser-generated like-Rayleigh waves in the epoxy coating/aluminum substrate,epoxy coating/brass substrate,and epoxy coating/foam substrate structures,respectively.In addition,we have investigated the waveform and propagation characteristics of the like-Rayleigh waves and studied the influences of the coating transparency,coating thickness,coating viscoelasticity,and substrate viscoelasticity on the propagation characteristics of the like-Rayleigh waves.Moreover,we have verified the results by the theoretical phase velocity and attenuation curves.The results show that the coating viscoelasticity induces the attenuation characteristics of the higher frequencies of the like-Rayleigh waves,but has little effect on the lower frequencies,and the substrate viscoelasticity has the influences on both the higher and lower frequencies of the like-Rayleigh waves,especially the lower frequencies.Furthermore,the mode and dispersive characteristics of the like-Rayleigh waves are closely related to the substrates.This study provides a useful theoretical basis for inverting mechanical parameters and evaluating the adhesive quality of the viscoelastic adhesive coating/substrate structures.展开更多
One of the critical issues in gram-negative bacterial adhesion is how wettability regulates adhesion as the surface wettability varies from superhydrophilic to superhydrophobic,and what is the relevant/contributing ro...One of the critical issues in gram-negative bacterial adhesion is how wettability regulates adhesion as the surface wettability varies from superhydrophilic to superhydrophobic,and what is the relevant/contributing role of the lipopolysaccharide(LPS) outer layer of the gram-negative shell during this procedure.Herein,by avoiding the unexpected influence induced by the varied topographies,control over gram-negative bacteria adhesion by wettability is achieved on biomimetic hierarchical surfaces,which is mainly mediated by LPS layer.The study provides a methodology to have a good control over bacteria cell adhesion by properly designing wettable surface structures.This design concept is helpful for developing new generations of biomaterials in order to control a variety of diseases induced by gramnegative bacteria,which still continue to be very important and necessary in the fields of biomedicine.展开更多
In order to understand how cells respond to concave and convex subcellular surface structures,colloidal crystal array and honeycomb-structured surfaces composed of highly ordered hexagonal units with completely invers...In order to understand how cells respond to concave and convex subcellular surface structures,colloidal crystal array and honeycomb-structured surfaces composed of highly ordered hexagonal units with completely inverse curvature were fabricated via facile self-assembly and breath figure approaches,respectively.The influence of hexagonal surface curvature on cell fate was subsequently investigated.Cells underwent more extensive spreading on the convex colloidal crystal array surface,while adhesive forces were higher on the concave honeycomb surface.The behaviors of cells on the different surfaces were investigated by comparing cell morphology,cellular adhesive force and cytoskeleton structure.The results revealed comprehensive differences in cell behavior between those on concave honeycomb surfaces and convex colloidal crystal arrays.展开更多
基金supported by the Natural Science Foundations of Xinjiang Automatic Region, China (Grant Nos. 200821104, 2009211B16, and 2010211B16)the Support Program of Science and Technology of Xinjiang Automatic Region, China (Grant No. 201091112)the West-Light Foundation of the Chinese Academy of Sciences (Grant No. RCPY200906)
文摘There remain a number of unsolved problems about chemical reactions, and it is significant to explore new detection methods because they always offer some unique information about reactions from new points of view. For the first time, the solidification course of a modified two-component acrylic structural adhesive is measured by using reed-vibration mechanical spectroscopy for liquids (RMS-L) in this work, and results show that there are four sequential processes of mechanical spectra with time. The in-depth analyses indicate that RMS-L can detect in real-time the generation and disappearance of active free radicals, as well as the chemical cross-link processes in the adhesive. This kind of real-time detection will undoubtedly facilitate the study of the chemical reaction dynamics controlled by free radicals.
文摘The computer aided engineering(CAE) analysis technique has become one of the most important means in modern automobile development due to its remarkably computing capability.With the development of CAE bussiness software and intensive research on automotive development process,the CAE technique,which was only used as an auxiliary validation tool in the later product development in the past,is gradually used in each stage of product development now.Furthermore,accurate and fast analysis data can be supplied effectively.Especially in current CAE application, based on some optimization technologies such as sensitivity,feature and topology,the parametric design gradually enables a CAE engineer to be free from the condition which a convention analysis usually lags behind a design,and makes it be parallel to or even anterior to the design.Under the circumstance,the CAE resources can be maximized in each project development department,thereby promoting the project progress and quality,and creating a new philosophy of 'analysis-driven design'.
基金the financial support of the Portuguese Foundation for Science and Technology (FCT) through the postdoctoral grant (SFRH/BPD/107825/2015)the funding of Pro-Life-Prolonging the Lifetime of Old Steel and Steel-Concrete Bridges (RFSR-CT-2015-00025) by the Research Fund for Coal and Steel (RFCS)
文摘Different strategies can be used to perform reparations and reinforcements of ancient bolted and riveted metallic bridges. As the riveting process is not currently a common practice, it requires proper equipment and skilled workers. Another solution is the use of welding. However, the weldability of old steels is poor. Bolts are very attractive alternative solutions, and are most commonly used to repair old metallic bridges. Fitted bolts are expensive solutions; the alternative is the use of resin-injected bolts. The behavior of bolted joints with preloaded resin-injected bolts has been studied using quasi-static and creep tests; however, few studies on the slip and fatigue behavior of these joints can be found in the literature. This paper presents an overview of a few experimental programs that were carried out by several authors aiming at evaluating the fatigue behavior of single and double shear resin-injected bolted connections. A comparison between the experimental data of joints with preloaded standard bolts and preloaded resin- injected bolts shows a fatigue strength reduction in the latter. Since Eurocode 3 (EC3) suggests the same fatigue strength curve for joints made of resin-injected bolts and standard bolts, this may raise some con- cerns. Furthermore, research on the feasibility of using both bonded and bolted connections is shown. This last study was performed with high-strength low-alloy structural steel plates and an acrylic struc- tural adhesive for metal bonding. For both case studies, a statistical analysis is performed on fatigue experimental data using linearized boundaries and the Castillo and Fernandez-Canteli model. Fatigue design curves are proposed and compared with the design suggestions of several European and North American standards,
基金supported by National Basic Research Program of China(2012CB921504)Major Program of National Natural Science Foundation of China(51239005)+4 种基金National Natural Science Foundation of China(11404147,11174142)Natural Science Foundation of Jiangsu Province(BK20140519)China Postdoctoral Science Foundation(2015M571672)Research Fund for Advanced Talents of Jiangsu University(11JDG118)Training Project of Young Backbone Teachers of Jiangsu University
文摘The propagation characteristics of laser-generated like-Rayleigh waves in viscoelastic adhesive coating/substrate structures were studied.Considering the viscoelasticity of the coating and substrate,we have established the finite element models in frequency domain for the laser-generated like-Rayleigh waves in the epoxy coating/aluminum substrate,epoxy coating/brass substrate,and epoxy coating/foam substrate structures,respectively.In addition,we have investigated the waveform and propagation characteristics of the like-Rayleigh waves and studied the influences of the coating transparency,coating thickness,coating viscoelasticity,and substrate viscoelasticity on the propagation characteristics of the like-Rayleigh waves.Moreover,we have verified the results by the theoretical phase velocity and attenuation curves.The results show that the coating viscoelasticity induces the attenuation characteristics of the higher frequencies of the like-Rayleigh waves,but has little effect on the lower frequencies,and the substrate viscoelasticity has the influences on both the higher and lower frequencies of the like-Rayleigh waves,especially the lower frequencies.Furthermore,the mode and dispersive characteristics of the like-Rayleigh waves are closely related to the substrates.This study provides a useful theoretical basis for inverting mechanical parameters and evaluating the adhesive quality of the viscoelastic adhesive coating/substrate structures.
基金the NSFC(Nos.51273111,51173105,51573092)the National Basic Research Program of China(973 Program,No.2012CB933803)SJTU-UM Collaborative Research Program,the Program for Professor of Special Appointment(Eastern Scholar)at the Shanghai Institutions of Higher Learning
文摘One of the critical issues in gram-negative bacterial adhesion is how wettability regulates adhesion as the surface wettability varies from superhydrophilic to superhydrophobic,and what is the relevant/contributing role of the lipopolysaccharide(LPS) outer layer of the gram-negative shell during this procedure.Herein,by avoiding the unexpected influence induced by the varied topographies,control over gram-negative bacteria adhesion by wettability is achieved on biomimetic hierarchical surfaces,which is mainly mediated by LPS layer.The study provides a methodology to have a good control over bacteria cell adhesion by properly designing wettable surface structures.This design concept is helpful for developing new generations of biomaterials in order to control a variety of diseases induced by gramnegative bacteria,which still continue to be very important and necessary in the fields of biomedicine.
基金supported by the Major Program of Chinese National Programs for Fundamental Research and Development(973 Project,No.2012CB933803)the National Science Foundation of China(No.21574081)
文摘In order to understand how cells respond to concave and convex subcellular surface structures,colloidal crystal array and honeycomb-structured surfaces composed of highly ordered hexagonal units with completely inverse curvature were fabricated via facile self-assembly and breath figure approaches,respectively.The influence of hexagonal surface curvature on cell fate was subsequently investigated.Cells underwent more extensive spreading on the convex colloidal crystal array surface,while adhesive forces were higher on the concave honeycomb surface.The behaviors of cells on the different surfaces were investigated by comparing cell morphology,cellular adhesive force and cytoskeleton structure.The results revealed comprehensive differences in cell behavior between those on concave honeycomb surfaces and convex colloidal crystal arrays.