Analysis of Emergy Structure,Function and Efficiency of Agro-ecosystem in Hunan Province

[Objective] The aim was to explore function and efficiency of emergy input/ output of Hunan agricultural ecosystem to reveal relationship of human being with natural resources and environment. [Method] Emergy structure, function and efficien- cy of Hunan agricultural ecosystem were analyzed based on input/output data in Hunan Province in 2009 as per emergy theory. [Result] The structure characters of agricultural ecosystem were as follows： Hunan is characterized with traditional agri- culture, depending greatly on both human and animal labor. For industrial accessory emergy, chemical fertilizers make most contribution to the system, and agricultural mechanization is not satisfied. Furthermore, renewable ratio of industrial accessory emergy is lower, and development and potential of green energy is promising. In addition, prices of the products are lower, without consideration of contribution made by natural resources and environment. It also suggested that Hunan agricultural chain is short and added value of products is not high. In general, emergy output of farming and animal husbandry dominates and the prices are lower than those of forestry and fishery. The function of the system was as follows： With lower environ- mental load ratio, the system is overloaded by population and the index of sustain- able development was 5.96, suggesting that the system enjoys vitality and potential, but the economy is undeveloped and the pressure from natural resources and envi- ronment is not high. The emergy output ratio was a little lower than national level in 2009, suggesting Hunan agricultural production is extensive. [Conclusion] The re- search indicated that rapid increase of population should be controlled; surplus labor should be transferred; agricultural structure and products structure should be further adjusted; agricultural technology should be further developed; agdcultural mechaniza- tion and modernization should be improved.

Review on the Fabrication of Surface Functional Structures for Enhancing Bioactivity of Titanium and Titanium Alloy Implants

Titanium and its alloys have been widely applied in many biomedical fields because of its excellent mechanical properties,corrosion resistance and good biocompatibility.However,problems such as rejection,shedding and infection will occur after titanium alloy implantation due to the low biological activity of titanium alloy surface.The structures with specific functions,which can enhance osseointegration and antibacterial properties,are fabricated on the surface of titanium implants to improve the biological activity between the titanium implants and human tissues.This paper presents a comprehensive review of recent developments and applications of surface functional structure in titanium and titanium alloy implants.The applications of surface functional structure on different titanium and titanium alloy implants are introduced,and their manufacturing technologies are summarized and compared.Furthermore,the fabrication of various surface functional structures used for titanium and titanium alloy implants is reviewed and analyzed in detail.Finally,the challenges affecting the development of surface functional structures applied in titanium and titanium alloy implants are outlined,and recommendations for future research are presented.

Design and additive manufacturing of bionic hybrid structure inspired by cuttlebone to achieve superior mechanical properties and shape memory function

Lightweight porous materials with high load-bearing,damage tolerance and energy absorption(EA)as well as intelligence of shape recovery after material deformation are beneficial and critical for many applications,e.g.aerospace,automobiles,electronics,etc.Cuttlebone produced in the cuttlefish has evolved vertical walls with the optimal corrugation gradient,enabling stress homogenization,significant load bearing,and damage tolerance to protect the organism from high external pressures in the deep sea.This work illustrated that the complex hybrid wave shape in cuttlebone walls,becoming more tortuous from bottom to top,creates a lightweight,load-bearing structure with progressive failure.By mimicking the cuttlebone,a novel bionic hybrid structure(BHS)was proposed,and as a comparison,a regular corrugated structure and a straight wall structure were designed.Three types of designed structures have been successfully manufactured by laser powder bed fusion(LPBF)with NiTi powder.The LPBF-processed BHS exhibited a total porosity of 0.042% and a good dimensional accuracy with a peak deviation of 17.4μm.Microstructural analysis indicated that the LPBF-processed BHS had a strong(001)crystallographic orientation and an average size of 9.85μm.Mechanical analysis revealed the LPBF-processed BHS could withstand over 25000 times its weight without significant deformation and had the highest specific EA value(5.32 J·g^(−1))due to the absence of stress concentration and progressive wall failure during compression.Cyclic compression testing showed that LPBF-processed BHS possessed superior viscoelastic and elasticity energy dissipation capacity.Importantly,the uniform reversible phase transition from martensite to austenite in the walls enables the structure to largely recover its pre-deformation shape when heated(over 99% recovery rate).These design strategies can serve as valuable references for the development of intelligent components that possess high mechanical efficiency and shape memory capabilities.

Preparation of Oat Bran Dietary Fiber by Steam Explosion and Its Functional Structure Characteristics

[Objectives]This study was conducted to investigate the process conditions,function and structural characteristics of oat bran dietary fiber prepared by steam explosion(SE).[Methods]With oat bran as the raw material,the technical parameters for preparing dietary fiber by steam explosion were studied,and the functional and structural characteristics of DF before and after modification were discussed.[Results]The optimum conditions for extracting DF from oat bran by SE modification were steam explosion pressure of 0.6 MPa and holding time of 4 min.The extraction rate of DF reached 33.9%.The solubility,water holding capacity,oil holding capacity and swelling force of Control-DF were 78.35%,2.25 g/g,1.55 g/g and 3.05 ml/g,respectively,and those of SE-DF were 95.69%,3.28 g/g,2.18 g/g and 5.98 ml/g,respectively.After SE treatment,the scavenging rates of oat bran DF on DPPH,ABTS,O-2·and·OH were significantly higher than those of untreated samples.The scavenging ability on free radicals was enhanced.The scavenging rates of Control-DF on DPPH,ABTS,O-2·and·OH were 43.72%,50.26%,31.02%and 39.25%,respectively,and those of SE-DF were 70.25%,73.21%and 63.69%59.32%,respectively.The surface of modified DF showed an obvious honeycomb structure.[Conclusions]This study can provide reference for functional modifications and utilization of dietary fiber from oat bran.

3D Printing of Tough Hydrogel Scaffolds with Functional Surface Structures for Tissue Regeneration

Hydrogel scaffolds have numerous potential applications in the tissue engineering field.However,tough hydrogel scaffolds implanted in vivo are seldom reported because it is difficult to balance biocompatibility and high mechanical properties.Inspired by Chinese ramen,we propose a universal fabricating method(printing-P,training-T,cross-linking-C,PTC&PCT)for tough hydrogel scaffolds to fill this gap.First,3D printing fabricates a hydrogel scaffold with desired structures(P).Then,the scaffold could have extraordinarily high mechanical properties and functional surface structure by cycle mechanical training with salting-out assistance(T).Finally,the training results are fixed by photo-cross-linking processing(C).The tough gelatin hydrogel scaffolds exhibit excellent tensile strength of 6.66 MPa(622-fold untreated)and have excellent biocompatibility.Furthermore,this scaffold possesses functional surface structures from nanometer to micron to millimeter,which can efficiently induce directional cell growth.Interestingly,this strategy can produce bionic human tissue with mechanical properties of 10 kPa-10 MPa by changing the type of salt,and many hydrogels,such as gelatin and silk,could be improved with PTC or PCT strategies.Animal experiments show that this scaffold can effectively promote the new generation of muscle fibers,blood vessels,and nerves within 4 weeks,prompting the rapid regeneration of large-volume muscle loss injuries.

Systematic analysis of corporate environmental responsibility:elements,structure,function,and principles

Corporate Environmental Responsibility(CER) is the subsystem of Corporate Social Responsibility(CSR),which continues to increase prominence in the global economy.Nowadays,CER becomes more important in corporate sustainable development.Based on Carroll's pyramid mode of CSR,this article explores the systematic feature of CER.From a systematic perspective,it sorts out its elements,structure,function,and principles of CER.And the four levels of economic,legal,ethical,and charitable structure are emphasized.With these considerations interpreted into practice,success will be achieved in potential cost savings,technological innovation,increased public acceptance,and better relations with governments.

Genetic Structure of Reaumuria soongorica Population in Fukang Desert, Xinjiang and Its Relationship with Ecological Factors

Genetic structure and differentiation of Reaumuria soongorica (Pall.) Maxim population from the desert of Fukang, Xinjiang, were assessed by means of random amplified polymorphic DNA (RAPD) markers. High genetic diversity and differentiation were revealed in the population of R soongorica by 15 random primers. One hundred and thirty-six individuals from seven subpopulations were sampled in the study. Seventy-one loci have been detected, and among them 69 were polymorphic. The mean proportion of polymorphic loci (PPB) was 97.18%. The analyses of Shannon information index (0.307 5), Nei's gene diversity (0.312 7) and G(ST)(0.312 0) indicated that there were more genetic variations within the subpopulations than those among the subpopulations. The results of AMOVA analysis showed that 61.58% of the genetic variations existed within subpopulations, and 38.02% among the subpopulations. The gene flow among the subpopulations of R soongorica (Nm = 1.102 8) was much less than that of the common anemophytes (Nm = 5.24), so genetic differentiation among the subpopulations occurred to some extent. Additionally, through the use of clustering and the correlation analyses, we found that the genetic structure of natural population of R soongorica was related to some ecological factors (soil factors mainly) of the oasis-desert transition zone. The genetic diversity level of R soongorica had negative correlation with the content of total soil P and Cl significantly (P < 0.05). On the contrary, it had significant positive correlation with CO32- (P < 0.05), showing that the distribution of the individuals of R soongorica in the sampled areas correlates with certain soluble salt. Furthermore, the genetic diversity of the natural population of R soongorica increased with the decreasing of the content of soil organic matters, water, total N and total P in soil. The paper concluded that the microenvironment ecological factors played an important role in the adaptive evolution of R soongorica population.

Analysis of the Protein Structure and Function of HpaG_(Xoo)

[Objective] The study was to analyze the structure and function of HpaGXoo and the relationship between the two.[Method] Some related bioinformatics analysis software on internet such as NPSA,Swiss-Model,SAPS and InterPro Scan were adopted to analyze the structure and predict its function.[Result] HpaGXoo consists of 139 amino acids,and has many alpha-helical and coiled structure,no signal peptide on N-terminal and no transmembrane structure.It locates in bacterial cytoplasm.[Conclusion] The study will lay ...

Structure and functions of Pinus sylvestris var. Sylvestriformis plantation ecosystem

Changbai pine (Pinus sylvestris var.Sylvestriformis) is an endemic and important tree species in Changbai Mountain. There were only 63 plant species in Changbai pine plantation, where hemicryptophyte was dominant(39.68%). Simpson diversity index was 0.87, Shannon-Wiener diversity index was 2.96, and evenness index was 0.82. Community structure were divided into three layers: tree layer, shrub layer and herb layer. The total biomass and net production were 111.982 t/hm2 and 8942.80 kg/(hm2 a) respectively. The total biomass for tree, shrub and herb layers were 106.150, 2.230, 2.264 t/hm2, accounting for 94.79%, 1.99%, and 2.02%, respectively, and net production for those were 7465, 223, and 1182 kg/(hm2 a), accounting for 83.47%, 2.49%, and 13.22% of the total respectively. The nutrient content in various organs is in the order of needle> branch> root> bark> trunk, For the assimilated organ, the nutrient content is in the order of N> K> Ca> P> Mg, and that in absorption organ is in the order of Ca> N> K> P> Mg. For the whole plantation ecosystem, nutrient content is in the order of soil> litter> herb layer> shrub layer> tree layer. Nutrient storage and its accumulation rate in tree layer take up 88.79% and 76.43% of the total, respectively.

Function and structure of the farmland shelterbelts in northern area of Shanxi Province

From the 1950s to 1960s, large area of Populus simonii shelterbelts system was established in northern area of Shanxi Province. For reconstructing the old shelterbelts, more attentions should be paid to selecting suitable tree species and design of logical shelterbelts structure. In order to provide a profound basis for the efficient establishment of shelterbelts, the study on function and structure of the farmland shelterbelts was conducted in Shuozhou and Datong areas, both are semi-arid areas in Northern Shanxi Province during 1996-2001. The wind-control effects of shelterbelts with different structures (close-spaced, wider-spaced, and widest-spaced) were investigated by portable wind vane and anemometer, wet and dry bulb thermometer, ground thermometer, glass service instrument. The results showed that the wind-control capacity of the shelterbelts during the leafing period should be thought as the criteria index in shelterbelts established. The wider-spaced shelterbelt that was made of 4-6 rows of trees, with a spacing of 2.0 m×3.0 m, had the best wind-control result.

Functional Equilibrium Between Photosynthetic and Above-ground Nonphotosynthetic Structures of Plants: Evidence from a Pruning Experiment with Three Subtropical Tree Species

It is well known that plants have functional equilibrium between their above-ground parts (shoots) and below-ground parts (roots), but whether the above-ground parts of plants have functional equilibrium between their photosynthetic structures (leaves) and non-photosynthetic structures (branches and stem) is unknown. The purpose of this study is to test the hypotheses that: (1) the above-ground parts of plants have functional equilibriums between their photosynthetic structures and non-photosynthetic structures; (2) the maintenance of the equilibriums is guaranteed by the alteration of biomass partitioning to photosynthetic and non-photosynthetic structures. To test these hypotheses, a pruning experiment with four pruning intensities (0%, 20%, 50%, and 70%) were carried out with three subtropical Chinese tree species ( Ficus microcarpa, Ficus virens, Cinnamomum camphora). Pruning treatments were conducted in two successive years. The results were in conformity with the hypothesis, i.e. above-ground parts of trees had functional equilibriums between photosynthetic and non-photosynthetic structures. Pruning decreased instantaneously the mass ratios of photosynthetic structures to non-photosynthetic structures (P/NP) of all three tree species, the reduction in P/NP was strengthened with pruning intensity. However, one year after pruning, the P/NP of all pruned trees increased and were not smaller than those of unpruned trees. In agreement with the expectation, the biomass partitioning of pruned trees was altered, more newly produced above-ground biomass was partitioned to leaf growth and less to branch and stem growth, thus enabled the damaged trees to restore their functional equilibrium between photosynthetic and non-photosynthetic structures. It is clear that the maintenance of functional equilibrium between photosynthetic and non-photosynthetic structures guaranteed by the alteration of biomass partitioning provides plants a good strategy to resist external disturbance and damage.

Structural and functional connectivity of the whole brain and subnetworks in individuals with mild traumatic brain injury:predictors of patient prognosis

Patients with mild traumatic brain injury have a diverse clinical presentation,and the underlying pathophysiology remains poorly understood.Magnetic resonance imaging is a non-invasive technique that has been widely utilized to investigate neuro biological markers after mild traumatic brain injury.This approach has emerged as a promising tool for investigating the pathogenesis of mild traumatic brain injury.G raph theory is a quantitative method of analyzing complex networks that has been widely used to study changes in brain structure and function.However,most previous mild traumatic brain injury studies using graph theory have focused on specific populations,with limited exploration of simultaneous abnormalities in structural and functional connectivity.Given that mild traumatic brain injury is the most common type of traumatic brain injury encounte red in clinical practice,further investigation of the patient characteristics and evolution of structural and functional connectivity is critical.In the present study,we explored whether abnormal structural and functional connectivity in the acute phase could serve as indicators of longitudinal changes in imaging data and cognitive function in patients with mild traumatic brain injury.In this longitudinal study,we enrolled 46 patients with mild traumatic brain injury who were assessed within 2 wee ks of injury,as well as 36 healthy controls.Resting-state functional magnetic resonance imaging and diffusion-weighted imaging data were acquired for graph theoretical network analysis.In the acute phase,patients with mild traumatic brain injury demonstrated reduced structural connectivity in the dorsal attention network.More than 3 months of followup data revealed signs of recovery in structural and functional connectivity,as well as cognitive function,in 22 out of the 46 patients.Furthermore,better cognitive function was associated with more efficient networks.Finally,our data indicated that small-worldness in the acute stage could serve as a predictor of longitudinal changes in connectivity in patients with mild traumatic brain injury.These findings highlight the importance of integrating structural and functional connectivity in unde rstanding the occurrence and evolution of mild traumatic brain injury.Additionally,exploratory analysis based on subnetworks could serve a predictive function in the prognosis of patients with mild traumatic brain injury.

Studies on structure and function of digestive system of Cymatium pileare

The digestive system of Cymatium pileare consists of buccal cavity, oesophagus, stom- ach, intestine, anus, salivary glands and liver. There is a contractible 'Argobuccinum' form proboscis in the anterior extremity of its body, and the buccal cavity lies in the anterior part of the proboscis, with a pair of jaws and a piece of radular ribbon. The jaws have many neatly arraned sickle- shaped sharpen denticles. Its dentition formula of radula is 2- (7) 1' (5-6) I (5-6) .1 (7) .2. In the middle of oesophagus, there is an expanded crop, which has the function of temporary food stor- age and preliminarily digesting food. The stomach is U-shaped and there are 2 entrances for liver ducts in its ventral side. The intestine is short and can be divided into 2 parts based on the structure of epithelia of their inner walls. The inner wall of foreintestine is stratified columnar epithelium, but the inner wall of hindintestine is pesudostratified columnar epithelium. The salivary gland of C. pileare is toxic gland and the toxin extracted from it plays a great role on its predation. The liver of C. pileare is compound tubuloacinar gland with mitochondrion, rough endoplasmic reticulum, Golgi comples and lysosome in its glandular cells.

Crystal structure,phase transitions,and thermodynamic properties of magnesium metavanadate(MgV_(2)O_(6))

As a promising anode material for magnesium ion rechargeable batteries,magnesium metavanadate(MgV_(2)O_(6))has attracted considerable research interest in recent years.A MgV_(2)O_(6)sample was synthesized via a facile solid-state reaction by multistep-firing stoichiometric mixtures of MgO and V2O5 powder under an air atmosphere.The solid-state phase transition fromα-MgV_(2)O_(6)toβ-MgV_(2)O_(6)occurred at 841 K and the enthalpy change was 4.37±0.04 kJ/mol.The endothermic effect at 1014 K and the enthalpy change was 26.54±0.26 kJ/mol,which is related to the incongruent melting ofβ-MgV_(2)O_(6).In situ XRD was performed to investigate phase transition of the as-prepared MgV_(2)O_(6)at high temperatures.The cell parameters obtained by Rietveld refinement indicated that it crystallizes in a monoclinic system with the C2/m space group,and the lattice parameters of a=9.280 A°,b=3.501 A°,c=6.731 A°,β=111.76°.The solid-state phase transition fromα-MgV_(2)O_(6)toβ-MgV_(2)O_(6)was further studied by thermal kinetics,indicating that this process is controlled first by a fibril-like mechanism and then by a spherulitic-type mechanism with an increasing heating rate.Additionally,the enthalpy change of MgV_(2)O_(6)at high temperatures was measured utilizing the drop calorimetry,heat capacity was calculated and given as:Cp=208.3+0.03583T-4809000T^(−2)(298-923 K)(J mol^(−1)K^(−1)),the high-temperature heat capacity can be used to calculate Gibbs free energy of MgV_(2)O_(6)at high temperatures.

Comparing Ecological Functions of Eastern and Southern Slopes of a Rangeland Ecosystem in Chaharbagh Region, Golestan Province, Iran

Getting aware of one kind of soil surface attributs is very important. Assessment of important attributes of soil and vegetation can help us to be aware of rangeland potential and help us to determine its situation. The goal of this research is to determine some plant and soil indicators of hilly winter rangelands of Eastern and Southern slopes of Chaharbagh region in Golestan province. By considering plant cover and soil surface attributes, it used the SSCC （soil surface classification） method to assess soil surface attributes. The length and width of ecological patches were measured in the forms of lichen, lichen-Grass, forbs, shrub and bare soil inter patches with litter. Also in this research, it measured the 11 soil surface parameters. These parameters are belonging to three main soil attributes stability, infiltration and nutrient cycles. These three indicators were measured in east and west of Eastern and Southern slopes of this ecosystem and showed significance differences （p 〈 0.05） in shrub, forbs and lichen-grass. In southern and especially in west aspect, these indicators in shrub were more than Eastern. But, in lossy hill of Eastern, lichen-grass patch is more significant. The most important ecological indicators of east landscapes of this region are forbs and lichen-grass.

Discussion on Structure Evolution and Function Expansion of Agriculture in China

According to the characteristics of agricultural development during different periods, agricultural development was basically divided into traditional period, planning system period and household contracting pedod to discuss the related laws of agricultural development in China. The agricultural function expansion during different periods was analyzed in terms of agricultural structure evolution, while structural optimization and function expansion of modem agriculture in China were also studied. The results indicated that during the traditional period, agricultural structure emphasized feeding people and grain production while agricultural function reflected the economic function beyond surviving standard. During the planning system period, a unitary structural mode of agriculture was formed in China, which showed that agriculture was dominated by planting industry and planting industry was dominated by grain, while agriculture executed the mixed economic function beyond surviving and liv- ing standard. During the household contracting period, the industrial structure of agriculture in China gradually became diversification and optimi- zation, but as the economic function of industrial standard, agricultural development was still greatly inhibited. The structural evolution of modem agriculture in China must step forward towards collectivization and scale merit, while ecological function and social function of agriculture increas- ingly become important and the function of agricultural production becomes mere and more diverse.

Influence of ecological function protection zone on the water conservation in Gansu-Qinghai Contiguous Region of the upper Yellow River

The implementation of Ecological Function Protection Zone(EFPZ)policy is significant for the ecological restoration and conservation of soil and water in the territory space.This manuscript analyzed and quantified the impact of EFPZ on the regional water conservation function,based on land use data from 2005,2008,2010,2015 and 2020,by conducting a counterfactual simulation along with the GeoSOS-FLUS model and the InVEST model.The results demonstrate that the delineation of EFPZ can significantly influence the water conservation.(1)From 2010 to 2020,as the EFPZ was implemented,the water conservation in the study area was increasing year by year,with a growth rate of 0.03×10^(8) m^(3)∙a^(-1).On the other hand,the simulated water conservation capacity without the implementation of EFPZ decreased year by year,with a decrease rate of 0.01×10^(8) m^(3)∙a^(-1).(2)The EFPZ accounts for only 23%of the total area,but the contribution rate of water conservation reaches 80%.The actual values of water conservation and average water yield per unit pixel in the EFPZ show an increasing trend both internally and externally,while the counterfactual simulation values exhibit a decreasing trend.(3)The water conservation is much higher within the EFPZ than without EFPZ.The implementation of EFPZ has a significant effect on the improvement of the water conservation capacity in Maqu EFPZ and Yellow River Source EFPZ.The protection effectiveness should be enhanced in Qilian Mountain EFPZ and afforestation activities need to be carefully considered in Loess Plateau EFPZ.

Strain concentration factor of heterogeneous materials and analytical influence functions based on Eshelby tensor

In this manuscript,Eshelby tensor is employed to assess the strain concentration that arises in the matrix phase at the interface,offering precise values and locations of maximum strain under specific loading conditions for both spherical and cylindrical inclusions.When compared to numerical simulation results,the analytical predictions grounded in the Eshelby tensor exhibit satisfactory accuracy.Then an analytical calculation method based on Eshelby tensor for the elastic strain influence functions of reduced-order homogenization(ROH)method is developed and adopted on particle-reinforced and fibrous composites,presenting its feasibility and advantage on off-line stage calculation of ROH method.The error analyses between analytical and numerical results are conducted.The numerical results also exhibit the necessity of finer interface partitioning to obtain the response on micro-scale with higher resolution.

Tree structure and diversity shape the biomass of primary temperate mountain forests

Primary forests are spatially diverse terrestrial ecosystems with unique characteristics,being naturally regenerative and heterogeneous,which supports the stability of their carbon storage through the accumulation of live and dead biomass.Yet,little is known about the interactions between biomass stocks,tree genus diversity and structure across a temperate montane primary forest.Here,we investigated the relationship between tree structure(variability in basal area and tree size),genus-level diversity(abundance,tree diversity)and biomass stocks in temperate primary mountain forests across Central and Eastern Europe.We used inventory data from726 permanent sample plots from mixed beech and spruce across the Carpathian Mountains.We used nonlinear regression to analyse the spatial variability in forest biomass,structure,and genus-level diversity and how they interact with plot-level tree age,disturbances,temperature and altitude.We found that the combined effects of genus and structural indices were important for addressing the variability in biomass across different spatial scales.Local processes in disturbance regimes and uneven tree age support forest hete rogeneity and the accumulation of live and dead biomass through the natural regeneration,growth and decay of the forest ecosystem.Structural complexities in basal area index,supporte d by genus-level abundance,positively influence total biomass stocks,which was modulated by tree age and disturbances.Spruce forests showed higher tree density and basal area than mixed beech forests,though mixed beech still contributes significantly to biomass across landscapes.Forest heterogeneity was strongly influenced by complexities in forest composition(tree genus diversity,structure).We addressed the importance of primary forests as stable carbon stores,achieved through structure and diversity.Safeguarding such ecosystems is critical for ensuring the stability of the primary forest,carbon store and biodiversity into the future.

Structure,electronic,and nonlinear optical properties of superalkaline M_(3)O(M=Li,Na)doped cyclo[18]carbon

Cyclo[18]carbon has received considerable attention thanks to its novel geometric configuration and special electronic structure.Superalkalis have low ionization energy.Doping a superalkali in cyclo[18]carbon is an effective method to improve the optical properties of the system because considerable electron transfer occurs.In this paper,the geometry,bonding properties,electronic structure,absorption spectrum,and nonlinear optical(NLO)properties of superalkaline M_(3)O(M=Li,Na)-doped cyclo[18]carbon were studied by using density functional theory.M_(3)O and the C_(18) rings are not coplanar.The C_(18) ring still exhibits alternating long and short bonds.The charge transfer between M_(3)O and C_(18) forms stable[M_(3)O]+[C_(18)]-ionic complexes.C_(18)M_(3)O(M=Li,Na)shows striking optical nonlinearity,i.e.,their first-and second-order hyperpolarizability(βvec andγ||)increase considerably atλ=1907 nm and 1460 nm.