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MEASURING STRUCTURE COMPLEXITY OF UML CLASS DIAGRAMS 被引量:6
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作者 Zhou Yuming Xu Baowen (Dept. of Computer Science & Eng., Southeast Univ., Nanjing 210096) (State Key Laboratory of Software Engineering, Wuhan University, Wuhan 430072) (Jiangsu Key Lab. of Computer Info. Proc. Tech., Soochow Univ., Suzhou 215006) 《Journal of Electronics(China)》 2003年第3期227-231,共5页
To provide system designer a valid measure to evaluate the structure complexityof class diagrams objectively, this letter first proposes a method to transform a class diagramsinto a weighted class dependence graph, th... To provide system designer a valid measure to evaluate the structure complexityof class diagrams objectively, this letter first proposes a method to transform a class diagramsinto a weighted class dependence graph, then presents a structure complexity measure for classdiagrams based on entropy distance. 展开更多
关键词 Class diagrams structure complexity MEASURE Entropy distance DEPENDENCE
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A Method for Measuring the Structure Complexity of Web Application
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作者 MAO Cheng-ying LU Yan-sheng 《Wuhan University Journal of Natural Sciences》 EI CAS 2006年第1期143-150,共8页
The precise and effective measure results of Web applications not only facilitate good comprehension of them, but also benefit to the macro-management of software activities, such as testing, reverse engineering, reus... The precise and effective measure results of Web applications not only facilitate good comprehension of them, but also benefit to the macro-management of software activities, such as testing, reverse engineering, reuse, etc. The paper exploits some researches on measuring the structure complexity of Web application. Through a deep analysis of the configuration and objects' interactions of Web system, two conclusions have been drawn:① A generic Web application consists of static web page, dynamic page, component and database object; ② The main interactions have only three styles, that is static link, dynamic link and call/return relation. Based on analysis and modeling of the content of a Web page (static or dynamic), complexity measure methods of both control logic of script and nesting of HTML code are further discussed. In addition, two methods for measuring the complexity of inte〉page navigation are also addressed by modeling the inte〉page navigation behaviors of Web application via WNG graph. 展开更多
关键词 structure complexity measure DD graph HTree tree WNG graph
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Tree species identity and interaction determine vertical forest structure in young planted forests measured by terrestrial laser scanning
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作者 Mengxi Wang Lander Baeten +7 位作者 Frieke Van Coillie Kim Calders Kris Verheyen Quentin Ponette Haben Blondeel Bart Muys John Armston Hans Verbeeck 《Forest Ecosystems》 SCIE CSCD 2024年第3期266-275,共10页
Vertical forest structure is closely linked to multiple ecosystem characteristics,such as biodiversity,habitat,and productivity.Mixing tree species in planted forests has the potential to create diverse vertical fores... Vertical forest structure is closely linked to multiple ecosystem characteristics,such as biodiversity,habitat,and productivity.Mixing tree species in planted forests has the potential to create diverse vertical forest structures due to the different physiological and morphological traits of the composing tree species.However,the relative importance of species richness,species identity and species interactions for the variation in vertical forest structure remains unclear,mainly because traditional forest inventories do not observe vertical stand structure in detail.Terrestrial laser scanning(TLS),however,allows to study vertical forest structure in an unprecedented way.Therefore,we used TLS single scan data from 126 plots across three experimental planted forests of a largescale tree diversity experiment in Belgium to study the drivers of vertical forest structure.These plots were 9–11years old young pure and mixed forests,characterized by four levels of tree species richness ranging from monocultures to four-species mixtures,across twenty composition levels.We generated vertical plant profiles from the TLS data and derived six stand structural variables.Linear mixed models were used to test the effect of species richness on structural variables.Employing a hierarchical diversity interaction modelling framework,we further assessed species identity effect and various species interaction effects on the six stand structural variables.Our results showed that species richness did not significantly influence most of the stand structure variables,except for canopy height and foliage height diversity.Species identity on the other hand exhibited a significant impact on vertical forest structure across all sites.Species interaction effects were observed to be site-dependent due to varying site conditions and species pools,and rapidly growing tree species tend to dominate these interactions.Overall,our results highlighted the importance of considering both species identity and interaction effects in choosing suitable species combinations for forest management practices aimed at enhancing vertical forest structure. 展开更多
关键词 TreeDivNet FORBIO Stand structural complexity Terrestrial laser scanning Vertical forest structure Tree diversity Planted forests
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Discussion on the Complex Structure of Nilpotent Lie Groups Gk
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作者 Caiyu Du Yu Wang 《Open Journal of Applied Sciences》 2024年第6期1401-1411,共11页
Consider the real, simply-connected, connected, s-step nilpotent Lie group G endowed with a left-invariant, integrable almost complex structure J, which is nilpotent. Consider the simply-connected, connected nilpotent... Consider the real, simply-connected, connected, s-step nilpotent Lie group G endowed with a left-invariant, integrable almost complex structure J, which is nilpotent. Consider the simply-connected, connected nilpotent Lie group Gk, defined by the nilpotent Lie algebra g/ak, where g is the Lie algebra of G, and ak is an ideal of g. Then, J gives rise to an almost complex structure Jk on Gk. The main conclusion obtained is as follows: if the almost complex structure J of a nilpotent Lie group G is nilpotent, then J can give rise to a left-invariant integrable almost complex structure Jk on the nilpotent Lie group Gk, and Jk is also nilpotent. 展开更多
关键词 Almost Complex structure Nilpotent Lie Group Nilpotent Lie Algebra
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Analysis of complicated structure seismic wave fields 被引量:3
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作者 周辉 王尚旭 +1 位作者 李国发 沈金松 《Applied Geophysics》 SCIE CSCD 2010年第2期185-192,195,共9页
In western China seismic wave fields are very complicated and have low signal to noise ratio.In this paper,we focus on complex wave field research by forward modeling and indicate that density should not be ignored in... In western China seismic wave fields are very complicated and have low signal to noise ratio.In this paper,we focus on complex wave field research by forward modeling and indicate that density should not be ignored in wave field simulation if the subsurface physical properties are quite different.We use the acoustic wave equation with density in the staggered finite-difference method to simulate the wave fields.For this purpose a complicated geologic structural model with rugged surfaces,near-surface low-velocity layers,and high-velocity outcropping layers was designed.Based on the instantaneous wave field distribution,we analyzed the mechanism forming complex wave fields.The influence of low velocity layers on the wave field is very strong.A strong waveguide occurs between the top and base of a low velocity layer,producing multiples which penetrate into the earth and form strong complex wave fields in addition to reflections from subsurface interfaces.For verifying the correctness of the simulated wave fields,prestack depth migration was performed using different algorithms from the forward modeling.The structure revealed by the stacked migration profile is same as the known structure. 展开更多
关键词 Wave equation SIMULATION complex geological structure wave field analysis guided wave
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Structural Complexity Analysis of Information Systems Based on Petri Nets 被引量:3
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作者 王景光 甘仞初 《Journal of Beijing Institute of Technology》 EI CAS 1999年第4期416-423,共8页
Aim To present a quantitative method for structural complexity analysis and evaluation of information systems. Methods Based on Petri net modeling and analysis techniques and with the aid of mathematical tools in ge... Aim To present a quantitative method for structural complexity analysis and evaluation of information systems. Methods Based on Petri net modeling and analysis techniques and with the aid of mathematical tools in general net theory(GNT), a quantitative method for structure description and analysis of information systems was introduced. Results The structural complexity index and two related factors, i.e. element complexity factor and connection complexity factor were defined, and the relations between them and the parameters of the Petri net based model of the system were derived. Application example was presented. Conclusion The proposed method provides a theoretical basis for quantitative analysis and evaluation of the structural complexity and can be applied in the general planning and design processes of the information systems. 展开更多
关键词 information system Petri Nets structural complexity element complexity factor connection complexity factor
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Modularized and Parametric Modeling Technology for Finite Element Simulations of Underground Engineering under Complicated Geological Conditions
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作者 Jiaqi Wu Li Zhuo +4 位作者 Jianliang Pei Yao Li Hongqiang Xie Jiaming Wu Huaizhong Liu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第7期621-645,共25页
The surrounding geological conditions and supporting structures of underground engineering are often updated during construction,and these updates require repeated numerical modeling.To improve the numerical modeling ... The surrounding geological conditions and supporting structures of underground engineering are often updated during construction,and these updates require repeated numerical modeling.To improve the numerical modeling efficiency of underground engineering,a modularized and parametric modeling cloud server is developed by using Python codes.The basic framework of the cloud server is as follows:input the modeling parameters into the web platform,implement Rhino software and FLAC3D software to model and run simulations in the cloud server,and return the simulation results to the web platform.The modeling program can automatically generate instructions that can run the modeling process in Rhino based on the input modeling parameters.The main modules of the modeling program include modeling the 3D geological structures,the underground engineering structures,and the supporting structures as well as meshing the geometric models.In particular,various cross-sections of underground caverns are crafted as parametricmodules in themodeling program.Themodularized and parametric modeling program is used for a finite element simulation of the underground powerhouse of the Shuangjiangkou Hydropower Station.This complicatedmodel is rapidly generated for the simulation,and the simulation results are reasonable.Thus,this modularized and parametric modeling program is applicable for three-dimensional finite element simulations and analyses. 展开更多
关键词 Underground engineering modularized and parametric modeling finite element method complex geological structure cloud modeling
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在复二维仿射锥上的完备余齐性一Kahler度量
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作者 关庄丹 梁梦翔 《Chinese Quarterly Journal of Mathematics》 2024年第2期200-220,共21页
In this paper,we revisit the Kahler structures on the affine quadrics M1={z_(1)^(2)+z_(2)^(2)+z_(3)^(2)=1}in the paper by Bo Yang and Fang-Yang Zheng.We found that the Kahler structures on the complex surface are more... In this paper,we revisit the Kahler structures on the affine quadrics M1={z_(1)^(2)+z_(2)^(2)+z_(3)^(2)=1}in the paper by Bo Yang and Fang-Yang Zheng.We found that the Kahler structures on the complex surface are more complicated than what they have thought.We shall also give some detail calculations and found that our results fit quite well with earlier papers of the first author,one of them with X.X.Chen. 展开更多
关键词 Affine quadrics Complex structure Kahler metrics Cohomogeneity one action
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Numerical simulation and dimension reduction analysis of electromagnetic logging while drilling of horizontal wells in complex structures 被引量:7
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作者 Zhen-Guan Wu Shao-Gui Deng +5 位作者 Xu-Quan He Runren Zhang Yi-Ren Fan Xi-Yong Yuan Yi-Zhi Wu Qing Huo Liu 《Petroleum Science》 SCIE CAS CSCD 2020年第3期645-657,共13页
Electromagnetic logging while drilling(LWD)is one of the key technologies of the geosteering and formation evaluation for high-angle and horizontal wells.In this paper,we solve the dipole source-generated magnetic/ele... Electromagnetic logging while drilling(LWD)is one of the key technologies of the geosteering and formation evaluation for high-angle and horizontal wells.In this paper,we solve the dipole source-generated magnetic/electric fields in 2D formations efficiently by the 2.5D finite diff erence method.Particularly,by leveraging the field’s rapid attenuation in spectral domain,we propose truncated Gauss–Hermite quadrature,which is several tens of times faster than traditional inverse fast Fourier transform.By applying the algorithm to the LWD modeling under complex formations,e.g.,folds,fault and sandstone pinch-outs,we analyze the feasibility of the dimension reduction from 2D to 1D.For the formations with smooth lateral changes,like folds,the simplified 1D model’s results agree well with the true responses,which indicate that the 1D simplification with sliding window is feasible.However,for the formation structures with drastic rock properties changes and sharp boundaries,for instance,faults and sandstone pinch-outs,the simplified 1D model will lead to large errors and,therefore,2.5D algorithms should be applied to ensure the accuracy. 展开更多
关键词 Complex formation structures Horizontal wells Electromagnetic logging while drilling 2.5D algorithm-Model simplification
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Study on the Structure of Supramolecular Inclusion Complex of β-Cyclodextrin with Retinoic Acid 被引量:3
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作者 Yan Ling ZHANG Wei Sheng LIU +2 位作者 Yang LI Xue Yi MA Yao Zu CHEN 《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第4期317-320,共4页
Inclusion compound of retinoic acid with (-cyclodextrin was prepared by coprecipitating method, the structure of resulting product was studied by elemental analysis, differential scanning caloriemetry(DSC) analysis, F... Inclusion compound of retinoic acid with (-cyclodextrin was prepared by coprecipitating method, the structure of resulting product was studied by elemental analysis, differential scanning caloriemetry(DSC) analysis, FT-IR spectroscopy and X-ray diffractometry, and the formed supramolecule self-assembles in aqueous solution according to molar ratio 2:1 of host-guest. 展开更多
关键词 Retinoic acid Β-CYCLODEXTRIN Inclusion complex structure
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Image segmentation of small defects in precision weldments with complex structure 被引量:3
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作者 石端虎 刚铁 +1 位作者 袁媛 杨双羊 《China Welding》 EI CAS 2007年第1期52-56,共5页
In this paper, the X-ray nondestructive test method of small defects in precision weldments with complex structure was presented. To resolve the difficulty of defect segmentation in variable grey image, the image proc... In this paper, the X-ray nondestructive test method of small defects in precision weldments with complex structure was presented. To resolve the difficulty of defect segmentation in variable grey image, the image processing based on Visual Basic programming method was adopted. The methods of automatic contrast and partial grey stretch were used to enhance the X-ray detection image which has relatively low contrast, then automatic threshold method was carried out to segment the two high intensity zones, and weld zones which contain the small defects was extracted. Smoothing and sharpen processing were proceeded on the extracted weld zones, and small defects in X-ray detection image of weldments with complex structure were segmented by using the method of background subtraction in the end. The effects of raster were eliminated, and because of that the image processing was only proceeded on the extracted weld zones, the calculated speed using the above provided algorithm was improved. 展开更多
关键词 X-ray testing complex structure Visual Basic program small defects image segmentation
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Structure and Magnetic Properties of a Manganese Complex with 1-Carboxymethylpyridinium-3-carboxylate 被引量:3
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作者 WANG Yan-Qin LIU Zhi-Liang GAO En-Qing 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第12期1761-1766,共6页
One complex with a zwitterionic dicarboxylate ligand, [Mn(L)(N3)]n 1 (L = 1-car- boxymethylpyridinium-3-carboxylate), was synthesized and structurally characterized. Complex 1 crystallizes in triclinic, space gr... One complex with a zwitterionic dicarboxylate ligand, [Mn(L)(N3)]n 1 (L = 1-car- boxymethylpyridinium-3-carboxylate), was synthesized and structurally characterized. Complex 1 crystallizes in triclinic, space group P1 with a = 7.570(2), b = 7.808(2), c = 9.232(3) A, β= 94.450(19)°, V= 489.0(3) A3, Z = 2, Mr = 277.11, Dc = 1.882 g/cm3, F(000) = 278,μ = 1.359 mm-1, S = 1.021, the final R = 0.0509 and wR = 0.1149 for 2236 observed reflections with 1 〉 2σ(I). Complex 1 consists of two-dimensional coordination layers in which the anionic uniform chains with mixed triple bridges (one end-on (EO) azide and two syn-syn carboxylates) are cross-linked by the flexible cationic N-methylpyridinium spacers. Magnetic studies demonstrated that the triple bridge in 1 transmits antiferromagnetic coupling between the Mn(Ⅱ) ions. 展开更多
关键词 zwitterionic ligand manganese complex structure mixed bridges magnetic properties
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ISOPARAMETRIC HYPERSURFACES AND COMPLEX STRUCTURES 被引量:1
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作者 Zizhou TANG Wenjiao YAN 《Acta Mathematica Scientia》 SCIE CSCD 2022年第6期2223-2229,共7页
The main purpose of this note is to construct almost complex or complex structures on certain isoparametric hypersurfaces in unit spheres.As a consequence,complex structures on S^(1)×S^(7)×S^(6),and on S^(10... The main purpose of this note is to construct almost complex or complex structures on certain isoparametric hypersurfaces in unit spheres.As a consequence,complex structures on S^(1)×S^(7)×S^(6),and on S^(10)×S^(3)×S(2)with vanishing first Chern class,are built. 展开更多
关键词 almost complex structure INTEGRABLE Hermitian structure isoparametric hypersurface
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Complex structure of human Hsp90~N and a novel small inhibitor FS5 被引量:1
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作者 Rui Liu Xiao-Lu Lu +4 位作者 Xian-Hua Huang Wei He Jing-Jing Duan Jin Zhang Jian Li 《Nuclear Science and Techniques》 SCIE CAS CSCD 2020年第3期74-84,共11页
Heat shock proteins(Hsps)are a family of abundantly expressed ATP-dependent chaperone proteins.Hsp90 is an eminent member of Hsp family.Thus far,two primary functions have been described for Hsp90:first,as a regulator... Heat shock proteins(Hsps)are a family of abundantly expressed ATP-dependent chaperone proteins.Hsp90 is an eminent member of Hsp family.Thus far,two primary functions have been described for Hsp90:first,as a regulator of conformational change of some protein kinases and nuclear hormone receptors,and the other as an indispensable factor in cellular stress response.Hsp90 has an essential number of interaction proteins since it participates in almost every biological process and its importance is self-evident.Hsp90 has an inextricable relationship in the pathogenesis of cancer,especially in the proliferation and irradiation of cancer cells,thus being a notable cancer target.Since the discovery of geldanamycin,the first inhibitor of Hsp90,from the bacterial species Streptomyces hygroscopicus,even more attention has been focused toward Hsp90.Many structure-based inhibitors of Hsp90 have been designed to develop an innovative method to defeat cancer.However,already designed inhibitors have various deficiencies,such as hepatotoxicity,poor aqueous solubility,instability,and non-ideal oral bioavailability.Based on the aforementioned reasons and to achieve an optimal performance and fewer side effects,we designed a novel inhibitor of Hsp90,called FS5,and resolved the crystal structure of the Hsp90^N-FS5 complex(1.65 A°,PDB code 5XRB).Furthermore,we compared the complexes Hsp90^N,Hsp90^N-GDM,and Hsp90^N-ATP and suggest that the inhibitor FS5 may compete with ATP for binding to Hsp90,which can be regarded as a potential strategy for the development of novel cancer drugs in the future. 展开更多
关键词 Heat shock protein 90 Complex crystal structure Interactions Anti-tumor drugs X-ray diffraction
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The complex band structure for armchair graphene nanoribbons 被引量:1
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作者 张留军 夏同生 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第11期548-554,共7页
Using a tight binding transfer matrix method, we calculate the complex band structure of armchair graphene nanoribbons. The real part of the complex band structure calculated by the transfer matrix method fits well wi... Using a tight binding transfer matrix method, we calculate the complex band structure of armchair graphene nanoribbons. The real part of the complex band structure calculated by the transfer matrix method fits well with the bulk band structure calculated by a Hermitian matrix. The complex band structure gives extra information on carrier's decay behaviour. The imaginary loop connects the conduction and valence band, and can profoundly affect the characteristics of nanoscale electronic device made with graphene nanoribbons. In this work, the complex band structure calculation includes not only the first nearest neighbour interaction, but also the effects of edge bond relaxation and the third nearest neighbour interaction. The band gap is classified into three classes. Due to the edge bond relaxation and the third nearest neighbour interaction term, it opens a band gap for N = 3M- 1. The band gap is almost unchanged for N =3M + 1, but decreased for N = 3M. The maximum imaginary wave vector length provides additional information about the electrical characteristics of graphene nanoribbons, and is also classified into three classes. 展开更多
关键词 armchair graphene nanoribbons complex band structure edge bond relaxation third nearest neighbour interaction
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Synthesis, Crystal Structure and Luminescent Property of [Zn(C_(12)H_9O_3)_2(C_(10)H_8N_2)]_n·nH_2O 被引量:2
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作者 李伟琦 封霞 +1 位作者 冯云龙 温一航 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第6期701-706,共6页
Under hydrothermal condition, the reaction of 2-naphthoxyacetic acid with ZnCl2 and 4,4′-bipyridine (4,4′-bipy) has afforded a new Zn(Ⅱ) compound, [Zn(C12H9O3)2(C10H8N2)]n·nH2O1, which was structurally... Under hydrothermal condition, the reaction of 2-naphthoxyacetic acid with ZnCl2 and 4,4′-bipyridine (4,4′-bipy) has afforded a new Zn(Ⅱ) compound, [Zn(C12H9O3)2(C10H8N2)]n·nH2O1, which was structurally characterized by single-crystal X-ray diffraction analysis. The crystal is of monoclinic, space group P21/c with a = 7.7335(2), b = 19.3834(4), c = 20.1707(4) A, β = 104.9830(10)°, V = 2920.82(11) A^3, C34H28ZnN2O7, Mr = 641.95, Z = 4, Dc = 1.460 g/cm^3,μ = 0.895 mm^-1, F(000) = 1328, R = 0.0406 and wR = 0.0876 for 4417 observed reflections (I〉 2σ(I)) Complex 1 consists of one-dimensional zigzag chains deriving from Zn(C12H9O3)2 units linked by 4,4′-bipy ligands, and lattice water molecules decorate between the chains. Non-covalent interactions, such as hydrogen-bonding and aromatic π-π interactions, lead to the formation of a 3D network structure. The thermogravimetric analysis (TGA) and luminescent property for 1 have also been studied in this paper. 展开更多
关键词 hydrothermal synthesis 4 4′-bipy 2-naphthoxyacetic acid Zn(Ⅱ) complex crystal structure supramolecular interaction luminescent property
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A review of the design methods of complex topology structures for 3D printing 被引量:1
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作者 Jiawei Feng Jianzhong Fu +2 位作者 Zhiwei Lin Ce Shang Bin Li 《Visual Computing for Industry,Biomedicine,and Art》 2018年第1期34-49,共16页
As a matter of fact,most natural structures are complex topology structures with intricate holes or irregular surface morphology.These structures can be used as lightweight infill,porous scaffold,energy absorber or mi... As a matter of fact,most natural structures are complex topology structures with intricate holes or irregular surface morphology.These structures can be used as lightweight infill,porous scaffold,energy absorber or micro-reactor.With the rapid advancement of 3D printing,the complex topology structures can now be efficiently and accurately fabricated by stacking layered materials.The novel manufacturing technology and application background put forward new demands and challenges to the current design methodologies of complex topology structures.In this paper,a brief review on the development of recent complex topology structure design methods was provided;meanwhile,the limitations of existing methods and future work are also discussed in the end. 展开更多
关键词 Complex topology structure Computer-aided design 3D printing Optimization design
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One Novel Mn(Ⅱ)Complex with 1-Substituted-1H-1,2,3-triazole-4-carboxylic Acid:Crystal Structure,Fluorescence and Hirshfeld Surface Analysis 被引量:3
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作者 赵红 朱毓卿 冯超 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2017年第1期66-72,共7页
The crystal structure of one novel Mn(II) complex, [Mn(pmta)_3]_2[Mn(H_2O)_6]·4H_2O(1), is reported(Hpmta = 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid). In the title compound, the asymmetric ... The crystal structure of one novel Mn(II) complex, [Mn(pmta)_3]_2[Mn(H_2O)_6]·4H_2O(1), is reported(Hpmta = 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid). In the title compound, the asymmetric unit consists of a [Mn(pmta_)3]ˉ anion, half [Mn(H_2O)_6]^(2+) counter cation and two lattice H_2O molecules, and the intra- and intermolecular hydrogen bonds connect the complex into a supramolecular structure. The liquid-state fluorescence spectra of complex 1 have been determined. Hirshfeld surface analysis was also studied. The main intermolecular interactions in the complex are O···H and H···H contacts. 展开更多
关键词 Mn(Ⅱ) complex crystal structure supramolecular structure Hirshfeld surface
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Synthesis,Crystal Structure and Heterogeneous Catalysis of a New Chiral Manganese Coordination Polymer Based on the Schiff-base Ligand 被引量:3
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作者 夏庆春 李子建 +2 位作者 刘燕 刘百战 崔勇 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2018年第1期161-167,共7页
A homochrial manganese(Ⅲ) complex(1) derived from chiral salen ligand(1 R,2 R)-(-)-1,2-diphenylethane-1,2-diamine-N,N?-bicarboxyl-salicylidene) has been synthesized through solvothermal procedure and charac... A homochrial manganese(Ⅲ) complex(1) derived from chiral salen ligand(1 R,2 R)-(-)-1,2-diphenylethane-1,2-diamine-N,N?-bicarboxyl-salicylidene) has been synthesized through solvothermal procedure and characterized by IR,elemental analysis,TGA,circular dichroism(CD),powder and single-crystal X-ray crystallography.It crystallizes in orthorhombic,space group P212121 with a = 9.108(3),b = 16.431(5),c = 26.531(6) A,V = 3970.4(19) A^3,Z = 4,Dc = 1.248 g/cm^3,F(000) = 1568,Mr = 745.73,μ = 0.383 mm^-1,the final GOOF = 0.957,R = 0.0631 and wR = 0.1079 for 13250 observed reflections with I 〉 2σ(I).The coordination polymer 1 possesses a 1 D infinite zigzag chain architecture constructed by the dicarboxyl-functionalized metallosalen ligand(Mn-salen),and the polymeric chains are further assembled into a 3D supramolecular network structure via strong intermolecular hydrogen bonding interactions between adjacent zigzag chains.As a heterogeneous catalyst,1 was used as an efficient heterogeneous catalyst for the asymmetric olefin epoxidation. 展开更多
关键词 manganese(Ⅲ) complex crystal structure salen asymmetric catalysis
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Syntheses and Crystal Structures of Hg(Ⅱ)and Ag(Ⅰ)Complexes Containing 2-Acetylpyridine-paminobenzoylhydrazone Ligand 被引量:2
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作者 黄超 陈冬梅 朱必学 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2017年第3期471-477,共7页
The two complexes [HgI_2L](DMF)(1) and [AgL_2](ClO_4)(CH_3CN)(2) were synthesized from the reaction of Schiff base ligand(2-acetylpyridine-p-aminobenzoylhydrazone)(L) with HgI_2 or AgClO_4 respectively. ... The two complexes [HgI_2L](DMF)(1) and [AgL_2](ClO_4)(CH_3CN)(2) were synthesized from the reaction of Schiff base ligand(2-acetylpyridine-p-aminobenzoylhydrazone)(L) with HgI_2 or AgClO_4 respectively. The compounds are characterized by ^1H NMR,FTIR and elemental analysis. The structures of the ligand and two complexes are measured via single-crystal X-ray diffraction. In these two complexes,the structures are both distorted triangular bipyramids with five-coordinated centers. 展开更多
关键词 Schiff base acylhydrazone complex crystal structure
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