Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely comme...Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,etc.In various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li PSs.Thus many novel array structured materials are applied to battery for tackling thorny problems mentioned above.In this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are summarized.Meanwhile,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery performances.Lastly,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are generalized.We hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.展开更多
Aqueous zinc ion batteries(AZIBs) demonstrate tremendous competitiveness and application prospects because of their abundant resources,low cost, high safety, and environmental friendliness. Although the advanced elect...Aqueous zinc ion batteries(AZIBs) demonstrate tremendous competitiveness and application prospects because of their abundant resources,low cost, high safety, and environmental friendliness. Although the advanced electrochemical energy storage systems based on zinc ion batteries have been greatly developed, many severe problems associated with Zn anode impede its practical application, such as the dendrite formation,hydrogen evolution, corrosion and passivation phenomenon. To address these drawbacks, electrolytes, separators, zinc alloys, interfacial modification and structural design of Zn anode have been employed at present by scientists. Among them, the structural design for zinc anode is relatively mature, which is generally believed to enhance the electroactive surface area of zinc anode, reduce local current density, and promote the uniform distribution of zinc ions on the surface of anode. In order to explore new research directions, it is crucial to systematically summarize the structural design of anode materials. Herein, this review focuses on the challenges in Zn anode, modification strategies and the three-dimensional(3D) structure design of substrate materials for Zn anode including carbon substrate materials, metal substrate materials and other substrate materials. Finally, future directions and perspectives about the Zn anode are presented for developing high-performance AZIBs.展开更多
Energetic structural materials(ESMs)are a new type of structural materials with bearing and damage characteristics.In this work the microstructure,mechanical properties and energy release characteristics of multi-elem...Energetic structural materials(ESMs)are a new type of structural materials with bearing and damage characteristics.In this work the microstructure,mechanical properties and energy release characteristics of multi-element Ti-Zr-Ta alloys with good casting performance were studied.The microstructure of the Ti_(x)ZrTa alloys gradually change from BCC+HCP to single BCC structure with the increase of Ti.While the Ti_(2)Zr_(y)Ta alloys was still uniform and single BCC structure with the increase of Zr.The evolution of microstructure and composition then greatly affect the mechanical properties and energy-release characteristics of Ti-Zr-Ta alloys.The synergistic effect of dual phase structure increases the fracture strain of Ti_(x)ZrTa(x=0.2,0.5)with the Ti content decreases,while the fracture strain of Ti_(x)ZrTa(x=2.0,3.0,4.0)gradually increase with the Ti content increases caused by the annihilation of the obstacles for dislocation movement.And as Zr content increases,the fracture strain of Ti_(2)Zr_(y)Ta alloys decrease,then the oxidation reaction rate and fragmentation degree gradually increase.The higher oxidation rate and the lager exposed oxidation area jointly leads the higher releasing energy efficiency of Ti_(x)ZrTa alloys with low Ti content and Ti_(2)Zr_(y)Ta alloys with high Zr content.展开更多
A new method is described to measure the dynamic shear modulus of underwater acoustic structure materials in a small anechoic water tank by using a broadband parametric source, a precise coordinate installation and te...A new method is described to measure the dynamic shear modulus of underwater acoustic structure materials in a small anechoic water tank by using a broadband parametric source, a precise coordinate installation and techniques of signal processing in the frequency range of 20 kHz - 100 kHz. The typical size of material samples is 500×500 mm2. Basic principles, experiment installation and measured results are also presented展开更多
The existence and its movement rule of crystalline structure defect are closely related to the diffusion, solid phase reaction, sintering, phase transformation as well as the physical and chemical properties of materi...The existence and its movement rule of crystalline structure defect are closely related to the diffusion, solid phase reaction, sintering, phase transformation as well as the physical and chemical properties of materials. Point defect theory has been widely applied in material mineralization research, unfavorable transformation controlling, material modification, the research and development of new materials and so on. Point defect theory is one of the important theories for new material research and development. Herein we mainly discuss the application of point defect theory in some structural material researches.展开更多
The thermal protection materials and structures are widely used in hypersonic vehicles for the purpose of thermal insulation, and their mechanical behavior is one of the key issues in design and manufacture of hyperso...The thermal protection materials and structures are widely used in hypersonic vehicles for the purpose of thermal insulation, and their mechanical behavior is one of the key issues in design and manufacture of hypersonic vehicles. It is our great pleasure to present the seven papers in this special subject of Theoretical & Applied Mechanics Letters (TAML) and introduce the recent progresses on the mechanical behavior of thermal protection materials and structures by the authors.展开更多
With the implementation of new-generation launch vehicles,space stations,lunar and deep space exploration,etc.,the development of spacecraft structures will face new challenges. In order to reduce the spacecraft weigh...With the implementation of new-generation launch vehicles,space stations,lunar and deep space exploration,etc.,the development of spacecraft structures will face new challenges. In order to reduce the spacecraft weight and increase the payload,composite material structures will be widely used. It is difficult to evaluate the strength and life of composite materials due to their complex mechanism and various phenomena in damage and failure.Meanwhile,the structures of composite materials used in spacecrafts will bear complex loads,including the coupling loads of tension,pressure,bending,shear,and torsion. Static loads,thermal loads,and vibration loads may occur at the same time,which asks for verification requirements to ensure the structure safety. Therefore,it is necessary to carry out a systematic multi-level experimental study. In this paper,the building block approach (BBA) is used to investigate the multilevel composite material structures for spacecrafts. The advanced measurement technology is adopted based on digital image correlation (DIC) and piezoelectric and optical fiber sensors to measure the composite material structure deformation. The virtual experiment technology is applied to provide sufficient and reliable data for the evaluation of the composite material structures of spacecrafts.展开更多
In this paper,the functional polymeric active materials were prepared by the grafting copolymerization and their structure and properties were studied.The results show that the structure and properties of these ac- ti...In this paper,the functional polymeric active materials were prepared by the grafting copolymerization and their structure and properties were studied.The results show that the structure and properties of these ac- tive materials have the relative large effects on the properties of gadolinium ion selective electrodes.展开更多
It is of great practical importance to analyze the shakedown of shell structures under cyclic loading, especially of those made of strain hardening materials.In this paper, same further understanding of the shakedown ...It is of great practical importance to analyze the shakedown of shell structures under cyclic loading, especially of those made of strain hardening materials.In this paper, same further understanding of the shakedown theorem for kinematic hardening materials has been made, and it is applied to analyze the shakedown of shell structures Though the residual stress of a real stale is related to plastic strain, the time-independent residual stress field as we will show in the theorem may be unrelated to the time-independent kinematically admissible plastic strain field For the engineering application, it will lie much more convenient to point this out clearly and definitely, otherwise it will be very difficult. Also, we have proposed a new method of proving this theorem.The above theorem is applied to the shakedown analysis of a cylindrical shell with hemispherical ends. According to the elastic solution, various possible residual sfcss and plastic strain Jlelds, the shakedown analysis of the structure can be reduced to a mathematical programming problem.The results of calculation show that the shakedown load oj strain hardening materials is about 30-40% higher than that of ideal plastic materials. So it is very important to consider the hardening of materials in the shakedown analysis,for it can greatly increase the structure design capacity, and meanwhile provide ascicntific basis to improve the design of shell structures.展开更多
Recently, intelligent or smart materials and structures have been received more and more attention due to their distinguished multi-field coupling properties and wide applications in aerospace, automobiles, civil stru...Recently, intelligent or smart materials and structures have been received more and more attention due to their distinguished multi-field coupling properties and wide applications in aerospace, automobiles, civil structures, medical devices, information storage, energy harvesting and so on. It is of academic challenge to fully understand the complex multi-field coupling behaviors of various smart materials and structures, and of engineering sig- nificance to enhance the performance and reliability of these materials and structures in industrial applications. The papers in the special topic of Mechanics of Intelligent Materials and Structures focus on the understanding of the electromechanical, magneto-elastic, and magneto-rheological coupling behav- iors and properties of smart materials and structures for applications in vibration control, resonators, and various functional devices.展开更多
A facile microwave-assisted hydrothermal route has been developed for a synthesis of versatile carbon materials. The monosaccharide fructose aqueous solution was adopted as the starting material, and the p H of the so...A facile microwave-assisted hydrothermal route has been developed for a synthesis of versatile carbon materials. The monosaccharide fructose aqueous solution was adopted as the starting material, and the p H of the solution was adjusted to be in acidic(pH 4), neutral(pH 7) and basic(pH 10.5) conditions. The p H buffered fructose solutions were treated at different temperatures by a microwave-assisted hydrothermal technique. As-prepared carbon materials displayed p H and temperature dependent multi-morphologies(porous, spherical or core-shell), which were determined by transmission and scanning electron microscopic analyses(TEM and SEM). And the hypothesis of dehydration mechanism of hydrothermal synthesis was analyzed by ultraviolet extinction and Fourier transform infrared spectroscopy. It was found that as compared with normal hydrothermal synthesis, microwave assistance could efficiently increase the production yield and improve the spherical geometry of the carbon particles in neutral condition. By changing the p H of the system, acidic p H induces aggregation of the spheres, while basic p H produces more trends toward core-shell or sponge-like porous structure. The study opens a novel route to the production of polytropic carbon materials and suggests a potential niche market established from the green synthesis.展开更多
Dielectric laser accelerators(DLAs)are considered promising candidates for on-chip particle accelerators that can achieve high acceleration gradients.This study explores various combinations of dielectric materials an...Dielectric laser accelerators(DLAs)are considered promising candidates for on-chip particle accelerators that can achieve high acceleration gradients.This study explores various combinations of dielectric materials and accelerated structures based on the inverse Cherenkov effect.The designs utilize conventional processing methods and laser parameters currently in use.We optimize the structural model to enhance the gradient of acceleration and the electron energy gain.To achieve higher acceleration gradients and energy gains,the selection of materials and structures should be based on the initial electron energy.Furthermore,we observed that the variation of the acceleration gradient of the material is different at different initial electron energies.These findings suggest that on-chip accelerators are feasible with the help of these structures and materials.展开更多
Internal diffusion of molecules in porous materials plays an important role in many chemical processes.However, the pore diffusion capacity of porous materials cannot be measured by conventional catalyst characterizat...Internal diffusion of molecules in porous materials plays an important role in many chemical processes.However, the pore diffusion capacity of porous materials cannot be measured by conventional catalyst characterization methods. In the present paper, a pore diffusion factor, the ratio of the diffusionconstriction factor to the pore tortuosity of the porous materials, was proposed to measure the diffusion ability of pores inside solid materials, and a method was proposed for measuring the diffusion factor using a well-defined and uniform pore size material as a reference. The diffusion factor was calculated based on the effective diffusion coefficients and the diffusion-constriction factor and pore tortuosity of the reference porous materials. The pore diffusion factor measurement can be performed at room temperature and atmospheric pressure. The pore diffusion factor of conventional porous materials was found to be much smaller than 1, indicating that there is a lot of room for improving the diffusion ability of the conventional catalysts and adsorbents, and could be significantly increased through adding small number of fibers into the conventional porous materials as template.展开更多
Projectiles made of reactive structure materials(RSM)can damage the target with not only kinetic but also chemical energy,but the enhanced damage potential of RSM may become compromised if extreme loading condition di...Projectiles made of reactive structure materials(RSM)can damage the target with not only kinetic but also chemical energy,but the enhanced damage potential of RSM may become compromised if extreme loading condition disintegrates the projectile before the target is reached.In this work,a ductile coating of Ni was introduced to a tungsten-zirconium(W-Zr)alloy,a typical brittle RSM,to preserve the damage potential of the projectile.Detonation driving tests were carried out with X-ray photography and gunpowder deflagration driving tests were carried out with high-speed photography for the coated and uncoated RSM samples,respectively.The craters on the witness target were analyzed by scanning electron microscopy and X-ray diffraction.The Ni coating was found to effectively preserve the damage potential of the W-Zr alloy under extreme loading conditions,whereas the uncoated sample fractured and ignited before impacting the target in both detonation and deflagration driving.The crack propagation between the reactively brittle core and the ductile coating was analyzed based on the crack arrest theory to mechanistically demonstrate how the coating improves the structural integrity and preserves the damage potential of the projectile.Specifically,the Ni coating envelops theW-Zr core until the coated sphere penetrates the target,and the coating is then eroded and worn to release the reactive core for the projectile to damage the target more intensively.展开更多
The traditional information hiding methods embed the secret information by modifying the carrier,which will inevitably leave traces of modification on the carrier.In this way,it is hard to resist the detection of steg...The traditional information hiding methods embed the secret information by modifying the carrier,which will inevitably leave traces of modification on the carrier.In this way,it is hard to resist the detection of steganalysis algorithm.To address this problem,the concept of coverless information hiding was proposed.Coverless information hiding can effectively resist steganalysis algorithm,since it uses unmodified natural stego-carriers to represent and convey confidential information.However,the state-of-the-arts method has a low hidden capacity,which makes it less appealing.Because the pixel values of different regions of the molecular structure images of material(MSIM)are usually different,this paper proposes a novel coverless information hiding method based on MSIM,which utilizes the average value of sub-image’s pixels to represent the secret information,according to the mapping between pixel value intervals and secret information.In addition,we employ a pseudo-random label sequence that is used to determine the position of sub-images to improve the security of the method.And the histogram of the Bag of words model(BOW)is used to determine the number of subimages in the image that convey secret information.Moreover,to improve the retrieval efficiency,we built a multi-level inverted index structure.Furthermore,the proposed method can also be used for other natural images.Compared with the state-of-the-arts,experimental results and analysis manifest that our method has better performance in anti-steganalysis,security and capacity.展开更多
The application of an external field is a promising method to control the microstructure of materials, leading to their improved performance. In the present paper, the strengthening and toughening behavior of some typ...The application of an external field is a promising method to control the microstructure of materials, leading to their improved performance. In the present paper, the strengthening and toughening behavior of some typical high-performance structural materials subjected to multifield coupling treatment, including electrostatic field, electro-pulse current, thermal field, and stress field, are reviewed in detail. In addition to the general observation that the plasticity of materials could be increased by multi-external fields, strength enhancement can be achieved by controlling atomic diffusion or phase transformations. The paper is not limited to the strengthening and toughening mechanisms of the multifield coupling effects on different types of structural materials but is intended to provide a generic method to improve both the strength and ductility of the materials. Finally, the prospects of the applications of multi-external fields have also been proposed based on current works.展开更多
The use of zirconia-based ceramic materials as smpport materidls for superconducting magnets and in cryopenic engineeriny generally has been considered. The relationship between compsition and mechanical properties at...The use of zirconia-based ceramic materials as smpport materidls for superconducting magnets and in cryopenic engineeriny generally has been considered. The relationship between compsition and mechanical properties at cryogenic temperature has also been investigated.展开更多
Activation analyses play a vital role in nuclear reactor design.Activation analyses,along with nuclear analyses,provide important information for nuclear safety and maintenance strategies.Activation analyses also help...Activation analyses play a vital role in nuclear reactor design.Activation analyses,along with nuclear analyses,provide important information for nuclear safety and maintenance strategies.Activation analyses also help in the selection of materials for a nuclear reactor,by providing the radioactivity and dose rate levels after irradiation.This information is important to help define maintenance activity for different parts of the reactor,and to plan decommissioning and radioactive waste disposal strategies.The study of activation analyses of candidate structural materials for near-term fusion reactors or ITER is equally essential,due to the presence of a highenergy neutron environment which makes decisive demands on material selection.This study comprises two parts; in the first part the activation characteristics,in a fusion radiation environment,of several elements which are widely present in structural materials,are studied.It reveals that the presence of a few specific elements in a material can diminish its feasibility for use in the nuclear environment.The second part of the study concentrates on activation analyses of candidate structural materials for near-term fusion reactors and their comparison in fusion radiation conditions.The structural materials selected for this study,i.e.India-specific Reduced Activation Ferritic-Martensitic steel(IN-RAFMS),P91-grade steel,stainless steel 316 LN ITER-grade(SS-316 LN-IG),stainless steel 316 L and stainless steel 304,are candidates for use in ITER either in vessel components or test blanket systems.Tungsten is also included in this study because of its use for ITER plasma-facing components.The study is carried out using the reference parameters of the ITER fusion reactor.The activation characteristics of the materials are assessed considering the irradiation at an ITER equatorial port.The presence of elements like Nb,Mo,Co and Ta in a structural material enhance the activity level as well as the dose level,which has an impact on design considerations.IN-RAFMS was shown to be a more effective low-activation material than SS-316 LN-IG.展开更多
基金This work was supported by the National Natural Science Foundation of China(52203066,51973157,61904123)the Tianjin Natural Science Foundation(18JCQNJC02900)+3 种基金the National innovation and entrepreneurship training program for college students(202310058007)the Tianjin Municipal college students’innovation and entrepreneurship training program(202310058088)the Science&Technology Development Fund of Tianjin Education Commission for Higher Education(Grant No.2018KJ196)the State Key Laboratory of Membrane and Membrane Separation,Tiangong University.
文摘Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,etc.In various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li PSs.Thus many novel array structured materials are applied to battery for tackling thorny problems mentioned above.In this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are summarized.Meanwhile,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery performances.Lastly,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are generalized.We hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.
基金financially supported by the National Natural Science Foundation of China (Grants Nos. 52064013, 52064014, 52072323 and 52122211)the “Double-First Class” Foundation of Materials and Intelligent Manufacturing Discipline of Xiamen University。
文摘Aqueous zinc ion batteries(AZIBs) demonstrate tremendous competitiveness and application prospects because of their abundant resources,low cost, high safety, and environmental friendliness. Although the advanced electrochemical energy storage systems based on zinc ion batteries have been greatly developed, many severe problems associated with Zn anode impede its practical application, such as the dendrite formation,hydrogen evolution, corrosion and passivation phenomenon. To address these drawbacks, electrolytes, separators, zinc alloys, interfacial modification and structural design of Zn anode have been employed at present by scientists. Among them, the structural design for zinc anode is relatively mature, which is generally believed to enhance the electroactive surface area of zinc anode, reduce local current density, and promote the uniform distribution of zinc ions on the surface of anode. In order to explore new research directions, it is crucial to systematically summarize the structural design of anode materials. Herein, this review focuses on the challenges in Zn anode, modification strategies and the three-dimensional(3D) structure design of substrate materials for Zn anode including carbon substrate materials, metal substrate materials and other substrate materials. Finally, future directions and perspectives about the Zn anode are presented for developing high-performance AZIBs.
基金supported by the National Natural Science Foundation of China(Grant Nos.52171166,11972372 and U20A20231)supported by Sinoma Institute of Materials Research(Guang Zhou)Co.,Ltd。
文摘Energetic structural materials(ESMs)are a new type of structural materials with bearing and damage characteristics.In this work the microstructure,mechanical properties and energy release characteristics of multi-element Ti-Zr-Ta alloys with good casting performance were studied.The microstructure of the Ti_(x)ZrTa alloys gradually change from BCC+HCP to single BCC structure with the increase of Ti.While the Ti_(2)Zr_(y)Ta alloys was still uniform and single BCC structure with the increase of Zr.The evolution of microstructure and composition then greatly affect the mechanical properties and energy-release characteristics of Ti-Zr-Ta alloys.The synergistic effect of dual phase structure increases the fracture strain of Ti_(x)ZrTa(x=0.2,0.5)with the Ti content decreases,while the fracture strain of Ti_(x)ZrTa(x=2.0,3.0,4.0)gradually increase with the Ti content increases caused by the annihilation of the obstacles for dislocation movement.And as Zr content increases,the fracture strain of Ti_(2)Zr_(y)Ta alloys decrease,then the oxidation reaction rate and fragmentation degree gradually increase.The higher oxidation rate and the lager exposed oxidation area jointly leads the higher releasing energy efficiency of Ti_(x)ZrTa alloys with low Ti content and Ti_(2)Zr_(y)Ta alloys with high Zr content.
文摘A new method is described to measure the dynamic shear modulus of underwater acoustic structure materials in a small anechoic water tank by using a broadband parametric source, a precise coordinate installation and techniques of signal processing in the frequency range of 20 kHz - 100 kHz. The typical size of material samples is 500×500 mm2. Basic principles, experiment installation and measured results are also presented
基金This work was supported by the "863" program (No. 2003AA322020)
文摘The existence and its movement rule of crystalline structure defect are closely related to the diffusion, solid phase reaction, sintering, phase transformation as well as the physical and chemical properties of materials. Point defect theory has been widely applied in material mineralization research, unfavorable transformation controlling, material modification, the research and development of new materials and so on. Point defect theory is one of the important theories for new material research and development. Herein we mainly discuss the application of point defect theory in some structural material researches.
基金support from the Natural Science Foundation of China(91016029,91216302,and 91216301)
文摘The thermal protection materials and structures are widely used in hypersonic vehicles for the purpose of thermal insulation, and their mechanical behavior is one of the key issues in design and manufacture of hypersonic vehicles. It is our great pleasure to present the seven papers in this special subject of Theoretical & Applied Mechanics Letters (TAML) and introduce the recent progresses on the mechanical behavior of thermal protection materials and structures by the authors.
文摘With the implementation of new-generation launch vehicles,space stations,lunar and deep space exploration,etc.,the development of spacecraft structures will face new challenges. In order to reduce the spacecraft weight and increase the payload,composite material structures will be widely used. It is difficult to evaluate the strength and life of composite materials due to their complex mechanism and various phenomena in damage and failure.Meanwhile,the structures of composite materials used in spacecrafts will bear complex loads,including the coupling loads of tension,pressure,bending,shear,and torsion. Static loads,thermal loads,and vibration loads may occur at the same time,which asks for verification requirements to ensure the structure safety. Therefore,it is necessary to carry out a systematic multi-level experimental study. In this paper,the building block approach (BBA) is used to investigate the multilevel composite material structures for spacecrafts. The advanced measurement technology is adopted based on digital image correlation (DIC) and piezoelectric and optical fiber sensors to measure the composite material structure deformation. The virtual experiment technology is applied to provide sufficient and reliable data for the evaluation of the composite material structures of spacecrafts.
文摘In this paper,the functional polymeric active materials were prepared by the grafting copolymerization and their structure and properties were studied.The results show that the structure and properties of these ac- tive materials have the relative large effects on the properties of gadolinium ion selective electrodes.
文摘It is of great practical importance to analyze the shakedown of shell structures under cyclic loading, especially of those made of strain hardening materials.In this paper, same further understanding of the shakedown theorem for kinematic hardening materials has been made, and it is applied to analyze the shakedown of shell structures Though the residual stress of a real stale is related to plastic strain, the time-independent residual stress field as we will show in the theorem may be unrelated to the time-independent kinematically admissible plastic strain field For the engineering application, it will lie much more convenient to point this out clearly and definitely, otherwise it will be very difficult. Also, we have proposed a new method of proving this theorem.The above theorem is applied to the shakedown analysis of a cylindrical shell with hemispherical ends. According to the elastic solution, various possible residual sfcss and plastic strain Jlelds, the shakedown analysis of the structure can be reduced to a mathematical programming problem.The results of calculation show that the shakedown load oj strain hardening materials is about 30-40% higher than that of ideal plastic materials. So it is very important to consider the hardening of materials in the shakedown analysis,for it can greatly increase the structure design capacity, and meanwhile provide ascicntific basis to improve the design of shell structures.
文摘Recently, intelligent or smart materials and structures have been received more and more attention due to their distinguished multi-field coupling properties and wide applications in aerospace, automobiles, civil structures, medical devices, information storage, energy harvesting and so on. It is of academic challenge to fully understand the complex multi-field coupling behaviors of various smart materials and structures, and of engineering sig- nificance to enhance the performance and reliability of these materials and structures in industrial applications. The papers in the special topic of Mechanics of Intelligent Materials and Structures focus on the understanding of the electromechanical, magneto-elastic, and magneto-rheological coupling behav- iors and properties of smart materials and structures for applications in vibration control, resonators, and various functional devices.
基金Funded by the National Natural Science Foundation of China(NSFC)(Nos.51408073,51678080 and 51678081)
文摘A facile microwave-assisted hydrothermal route has been developed for a synthesis of versatile carbon materials. The monosaccharide fructose aqueous solution was adopted as the starting material, and the p H of the solution was adjusted to be in acidic(pH 4), neutral(pH 7) and basic(pH 10.5) conditions. The p H buffered fructose solutions were treated at different temperatures by a microwave-assisted hydrothermal technique. As-prepared carbon materials displayed p H and temperature dependent multi-morphologies(porous, spherical or core-shell), which were determined by transmission and scanning electron microscopic analyses(TEM and SEM). And the hypothesis of dehydration mechanism of hydrothermal synthesis was analyzed by ultraviolet extinction and Fourier transform infrared spectroscopy. It was found that as compared with normal hydrothermal synthesis, microwave assistance could efficiently increase the production yield and improve the spherical geometry of the carbon particles in neutral condition. By changing the p H of the system, acidic p H induces aggregation of the spheres, while basic p H produces more trends toward core-shell or sponge-like porous structure. The study opens a novel route to the production of polytropic carbon materials and suggests a potential niche market established from the green synthesis.
基金the National Natural Science Foundation of China(Grant No.11975214)。
文摘Dielectric laser accelerators(DLAs)are considered promising candidates for on-chip particle accelerators that can achieve high acceleration gradients.This study explores various combinations of dielectric materials and accelerated structures based on the inverse Cherenkov effect.The designs utilize conventional processing methods and laser parameters currently in use.We optimize the structural model to enhance the gradient of acceleration and the electron energy gain.To achieve higher acceleration gradients and energy gains,the selection of materials and structures should be based on the initial electron energy.Furthermore,we observed that the variation of the acceleration gradient of the material is different at different initial electron energies.These findings suggest that on-chip accelerators are feasible with the help of these structures and materials.
基金supported by the National Nature Science Foundation of China (Grant No:91534120)。
文摘Internal diffusion of molecules in porous materials plays an important role in many chemical processes.However, the pore diffusion capacity of porous materials cannot be measured by conventional catalyst characterization methods. In the present paper, a pore diffusion factor, the ratio of the diffusionconstriction factor to the pore tortuosity of the porous materials, was proposed to measure the diffusion ability of pores inside solid materials, and a method was proposed for measuring the diffusion factor using a well-defined and uniform pore size material as a reference. The diffusion factor was calculated based on the effective diffusion coefficients and the diffusion-constriction factor and pore tortuosity of the reference porous materials. The pore diffusion factor measurement can be performed at room temperature and atmospheric pressure. The pore diffusion factor of conventional porous materials was found to be much smaller than 1, indicating that there is a lot of room for improving the diffusion ability of the conventional catalysts and adsorbents, and could be significantly increased through adding small number of fibers into the conventional porous materials as template.
基金National Natural Science Foundation of China.Grant ID:11872123.
文摘Projectiles made of reactive structure materials(RSM)can damage the target with not only kinetic but also chemical energy,but the enhanced damage potential of RSM may become compromised if extreme loading condition disintegrates the projectile before the target is reached.In this work,a ductile coating of Ni was introduced to a tungsten-zirconium(W-Zr)alloy,a typical brittle RSM,to preserve the damage potential of the projectile.Detonation driving tests were carried out with X-ray photography and gunpowder deflagration driving tests were carried out with high-speed photography for the coated and uncoated RSM samples,respectively.The craters on the witness target were analyzed by scanning electron microscopy and X-ray diffraction.The Ni coating was found to effectively preserve the damage potential of the W-Zr alloy under extreme loading conditions,whereas the uncoated sample fractured and ignited before impacting the target in both detonation and deflagration driving.The crack propagation between the reactively brittle core and the ductile coating was analyzed based on the crack arrest theory to mechanistically demonstrate how the coating improves the structural integrity and preserves the damage potential of the projectile.Specifically,the Ni coating envelops theW-Zr core until the coated sphere penetrates the target,and the coating is then eroded and worn to release the reactive core for the projectile to damage the target more intensively.
基金This work is supported,in part,by the National Natural Science Foundation of China under grant numbers U1536206,U1405254,61772283,61602253,61672294,61502242in part,by the Jiangsu Basic Research Programs-Natural Science Foundation under grant numbers BK20150925 and BK20151530+1 种基金in part,by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)fundin part,by the Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET)fund,China.
文摘The traditional information hiding methods embed the secret information by modifying the carrier,which will inevitably leave traces of modification on the carrier.In this way,it is hard to resist the detection of steganalysis algorithm.To address this problem,the concept of coverless information hiding was proposed.Coverless information hiding can effectively resist steganalysis algorithm,since it uses unmodified natural stego-carriers to represent and convey confidential information.However,the state-of-the-arts method has a low hidden capacity,which makes it less appealing.Because the pixel values of different regions of the molecular structure images of material(MSIM)are usually different,this paper proposes a novel coverless information hiding method based on MSIM,which utilizes the average value of sub-image’s pixels to represent the secret information,according to the mapping between pixel value intervals and secret information.In addition,we employ a pseudo-random label sequence that is used to determine the position of sub-images to improve the security of the method.And the histogram of the Bag of words model(BOW)is used to determine the number of subimages in the image that convey secret information.Moreover,to improve the retrieval efficiency,we built a multi-level inverted index structure.Furthermore,the proposed method can also be used for other natural images.Compared with the state-of-the-arts,experimental results and analysis manifest that our method has better performance in anti-steganalysis,security and capacity.
基金financially supported by the National Natural Science Foundation of China (Nos. U1708253 and 51571052)the Major Technology Projects of Liaoning Province, China (No. 2019JH1/10100004)the Natural Science Foundation of Liaoning Province, China (No. 2019MS-122)。
文摘The application of an external field is a promising method to control the microstructure of materials, leading to their improved performance. In the present paper, the strengthening and toughening behavior of some typical high-performance structural materials subjected to multifield coupling treatment, including electrostatic field, electro-pulse current, thermal field, and stress field, are reviewed in detail. In addition to the general observation that the plasticity of materials could be increased by multi-external fields, strength enhancement can be achieved by controlling atomic diffusion or phase transformations. The paper is not limited to the strengthening and toughening mechanisms of the multifield coupling effects on different types of structural materials but is intended to provide a generic method to improve both the strength and ductility of the materials. Finally, the prospects of the applications of multi-external fields have also been proposed based on current works.
文摘The use of zirconia-based ceramic materials as smpport materidls for superconducting magnets and in cryopenic engineeriny generally has been considered. The relationship between compsition and mechanical properties at cryogenic temperature has also been investigated.
文摘Activation analyses play a vital role in nuclear reactor design.Activation analyses,along with nuclear analyses,provide important information for nuclear safety and maintenance strategies.Activation analyses also help in the selection of materials for a nuclear reactor,by providing the radioactivity and dose rate levels after irradiation.This information is important to help define maintenance activity for different parts of the reactor,and to plan decommissioning and radioactive waste disposal strategies.The study of activation analyses of candidate structural materials for near-term fusion reactors or ITER is equally essential,due to the presence of a highenergy neutron environment which makes decisive demands on material selection.This study comprises two parts; in the first part the activation characteristics,in a fusion radiation environment,of several elements which are widely present in structural materials,are studied.It reveals that the presence of a few specific elements in a material can diminish its feasibility for use in the nuclear environment.The second part of the study concentrates on activation analyses of candidate structural materials for near-term fusion reactors and their comparison in fusion radiation conditions.The structural materials selected for this study,i.e.India-specific Reduced Activation Ferritic-Martensitic steel(IN-RAFMS),P91-grade steel,stainless steel 316 LN ITER-grade(SS-316 LN-IG),stainless steel 316 L and stainless steel 304,are candidates for use in ITER either in vessel components or test blanket systems.Tungsten is also included in this study because of its use for ITER plasma-facing components.The study is carried out using the reference parameters of the ITER fusion reactor.The activation characteristics of the materials are assessed considering the irradiation at an ITER equatorial port.The presence of elements like Nb,Mo,Co and Ta in a structural material enhance the activity level as well as the dose level,which has an impact on design considerations.IN-RAFMS was shown to be a more effective low-activation material than SS-316 LN-IG.