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Design and Engineering of Urban Interchange Ramp Bridge Structure
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作者 Yuxiao Zhang Maode Yang 《Journal of Architectural Research and Development》 2024年第2期62-67,共6页
This paper analyzes the structural design of an urban interchange ramp bridge from four aspects,which are the superstructure,pier structure,foundation structure,and deck structure design to summarize the structural de... This paper analyzes the structural design of an urban interchange ramp bridge from four aspects,which are the superstructure,pier structure,foundation structure,and deck structure design to summarize the structural design ideas of this urban interchange ramp bridge,which can be used as a reference for future construction of the same bridge. 展开更多
关键词 Interchange ramp bridge structure design Pier structure Foundation structure bridge deck structure
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Technical Analysis of Safety Monitoring and Evaluation of Existing Bridge Structures
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作者 Jiang Feng Qing Yang 《Journal of World Architecture》 2024年第2期17-24,共8页
Bridge structure safety monitoring and assessment has been a great concern for the government and the public,and bridge structure safety monitoring and assessment technology has also developed rapidly over the years.I... Bridge structure safety monitoring and assessment has been a great concern for the government and the public,and bridge structure safety monitoring and assessment technology has also developed rapidly over the years.Its goal is to equip relevant organizations and professionals with a deep understanding of the principles and practical applications of these technologies.By doing so,it seeks to facilitate the effective implementation of safety monitoring and assessment practices in bridge management.Ultimately,the aim is to foster the constructive development of road and bridge construction and operational management at a broader level. 展开更多
关键词 bridge structure Safety monitoring Defect diagnosis Theoretical modeling method
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Review and Prospect of Research on Structural Health Monitoring Technology for Bridges
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作者 Guoyi Liu 《Journal of Architectural Research and Development》 2024年第3期156-161,共6页
As a crucial infrastructure in the transport system,the safe operation of bridges is directly related to all aspects of people’s daily lives.The development of bridge structural health monitoring technology and its a... As a crucial infrastructure in the transport system,the safe operation of bridges is directly related to all aspects of people’s daily lives.The development of bridge structural health monitoring technology and its application play an important role in ensuring the safety and extending the service life of bridges.This paper carries out in-depth research and analysis on the related technology of bridge structural health monitoring.Firstly,the existing monitoring technologies at home and abroad are sorted out,and the advantages and problems of various methods are compared and analyzed,including nondestructive testing,stress measurement,vibration characteristic identification,and other commonly used monitoring technologies.Secondly,the key technologies and equipment in the bridge health monitoring system,such as sensor technology,data acquisition,and processing technology,are introduced in detail.Finally,the development trend in the field of bridge health monitoring is prospected from both theoretical research and technical application.In the future,with the development of emerging technologies such as big data,cloud computing,and the Internet of Things,it is expected that bridge health monitoring with intelligent and systematic features will be more widely applied to provide a stronger guarantee for the safe and efficient operation of bridges. 展开更多
关键词 bridge structural health monitoring Safe operation Monitoring technology
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ML and CFD Simulation of Flow Structure around Tandem Bridge Piers in Pressurized Flow
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作者 Aliasghar Azma Ramin Kiyanfar +4 位作者 Yakun Liu Masoumeh Azma Di Zhang Ze Cao Zhuoyue Li 《Computers, Materials & Continua》 SCIE EI 2023年第4期1711-1733,共23页
Various regions are becoming increasingly vulnerable to the increased frequency of floods due to the recent changes in climate and precipitation patterns throughout the world.As a result,specific infrastructures,notab... Various regions are becoming increasingly vulnerable to the increased frequency of floods due to the recent changes in climate and precipitation patterns throughout the world.As a result,specific infrastructures,notably bridges,would experience significant flooding for which they were not intended and would be submerged.The flow field and shear stress distribution around tandem bridge piers under pressurized flow conditions for various bridge deck widths are examined using a series of three-dimensional(3D)simulations.It is indicated that scenarios with a deck width to pier diameter(Ld/p)ratio of 3 experience the highest levels of turbulent disturbance.In addition,maximum velocity and shear stresses occur in cases with Ld/p equal to 6.Results indicate that increasing the number of piers from 1 to 2 and 3 results in the increase of bed shear stress by 24%and 20%respectively.Finally,five machine learning algorithms,including Decision Trees(DT),Feed Forward Neural Networks(FFNN),and three Ensemble models,are implemented to estimate the flow field and the turbulent structure.Results indicated that the highest accuracy for estimation of U,and W,were obtained using AdaBoost ensemble with R2=0.946 and 0.951,respectively.Besides,the Random Forest algorithm outperformed AdaBoost slightly in the estimation of V and turbulent kinetic energy(TKE)with R2=0.894 and 0.951,respectively. 展开更多
关键词 bridge pier scour process deck width machine learning turbulent structure
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Structure Bearing Capacity Testing and Evaluation of Existing Bridges
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作者 Huigeng Liu Zonglin Zhou 《Journal of World Architecture》 2023年第1期30-34,共5页
The bearing capacity testing and evaluation of the existing bridge engineering structure is not only the key to clarify its structural quality and safety performance,but it also can lay a solid foundation for subseque... The bearing capacity testing and evaluation of the existing bridge engineering structure is not only the key to clarify its structural quality and safety performance,but it also can lay a solid foundation for subsequent repairs and maintenance work.To ensure the bearing capacity,durability and reliability of existing bridges,this paper analyzes the importance and methods of testing and evaluation of structural bearing capacity of a bridge.This analysis aims to provide scientific reference for the quality assessment and subsequent repair and maintenance of existing bridge engineering structures. 展开更多
关键词 Existing bridge bridge structure Bearing capacity detection Bearing capacity evaluation
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Deformation monitoring of long-span railway bridges based on SBAS-InSAR technology
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作者 Lv Zhou Xinyi Li +4 位作者 Yuanjin Pan Jun Ma Cheng Wang Anping Shi Yukai Chen 《Geodesy and Geodynamics》 EI CSCD 2024年第2期122-132,共11页
The deformation monitoring of long-span railway bridges is significant to ensure the safety of human life and property.The interferometric synthetic aperture radar(In SAR)technology has the advantage of high accuracy ... The deformation monitoring of long-span railway bridges is significant to ensure the safety of human life and property.The interferometric synthetic aperture radar(In SAR)technology has the advantage of high accuracy in bridge deformation monitoring.This study monitored the deformation of the Ganjiang Super Bridge based on the small baseline subsets(SBAS)In SAR technology and Sentinel-1A data.We analyzed the deformation results combined with bridge structure,temperature,and riverbed sediment scouring.The results are as follows:(1)The Ganjiang Super Bridge area is stable overall,with deformation rates ranging from-15.6 mm/yr to 10.7 mm/yr(2)The settlement of the Ganjiang Super Bridge deck gradually increases from the bridge tower toward the main span,which conforms to the typical deformation pattern of a cable-stayed bridge.(3)The sediment scouring from the riverbed cause the serious settlement on the bridge’s east side compared with that on the west side.(4)The bridge deformation negatively correlates with temperature,with a faster settlement at a higher temperature and a slow rebound trend at a lower temperature.The study findings can provide scientific data support for the health monitoring of long-span railway bridges. 展开更多
关键词 SBAS-InSAR Long-span railway bridge Deformation monitoring bridge structure Time series deformation
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Valley transport in Kekulé structures of graphene
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作者 王娟娟 汪军 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期44-53,共10页
Valleytronics is an emergent discipline in condensed matter physics and offers a new way to encode and manipulate information based on the valley degree of freedom in materials. Among the various materials being studi... Valleytronics is an emergent discipline in condensed matter physics and offers a new way to encode and manipulate information based on the valley degree of freedom in materials. Among the various materials being studied, Kekulé distorted graphene has emerged as a promising material for valleytronics applications. Graphene can be artificially distorted to form the Kekulé structures rendering the valley-related interaction. In this work, we review the recent progress of research on Kekulé structures of graphene and focus on the modified electronic bands due to different Kekulé distortions as well as their effects on the transport properties of electrons. We systematically discuss how the valley-related interaction in the Kekulé structures was used to control and affect the valley transport including the valley generation, manipulation, and detection. This article summarizes the current challenges and prospects for further research on Kekulé distorted graphene and its potential applications in valleytronics. 展开更多
关键词 GRAPHENE y-shaped Kekulé(Y-Kek)lattice distortion structure O-Kekulé(O-Kek)structure valley current
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Application Strategy of Composite Steel Composite Beams in Bridge Design
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作者 Shengtang Wang 《Journal of World Architecture》 2024年第2期31-36,共6页
The combined prefabricated steel-hybrid stacked girder structure is very common in modern bridge design.An actual bridge engineering design project is taken as an example in this paper to analyze the application strat... The combined prefabricated steel-hybrid stacked girder structure is very common in modern bridge design.An actual bridge engineering design project is taken as an example in this paper to analyze the application strategy of this structure,encompassing overall design strategy,structural design strategy,and structural calculation strategy.The aim is to offer insights that can enhance the quality of bridge design. 展开更多
关键词 PREFABRICATION Steel-hybrid stacked girder bridge design structural design and calculation
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Analysis of Bridge-Bearing Capacity Detection and Evaluation Technology
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作者 Wei Fu Bo Liu 《Journal of World Architecture》 2024年第2期129-133,共5页
A bridge project is taken as an example to analyze the application of bearing capacity detection and evaluation.This article provides a basic overview of the project,the application of bearing capacity detection techn... A bridge project is taken as an example to analyze the application of bearing capacity detection and evaluation.This article provides a basic overview of the project,the application of bearing capacity detection technology,and the bearing capacity assessment analysis.It is hoped that this analysis can provide a scientific reference for the load-bearing capacity detection and evaluation work in bridge engineering projects,thereby achieving a scientific assessment of the overall load-bearing capacity of the bridge engineering structure. 展开更多
关键词 bridge engineering structure Bearing capacity Calculation model Detection points Quantitative standards
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Structural Capacity Assessment of Cultural Bridges Key Study Dragoti Bridge
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作者 Arian Lako Shkelqim Gjevori +1 位作者 Xhorxhia Lako Edvin Paçi 《Journal of Civil Engineering and Architecture》 2023年第1期1-11,共11页
In this presentation,we have shown the methodology for the structural assessment of bridges that belong to the inventory of cultural heritage.Due to the significant number of“sub-standard”bridges,it is impossible fo... In this presentation,we have shown the methodology for the structural assessment of bridges that belong to the inventory of cultural heritage.Due to the significant number of“sub-standard”bridges,it is impossible for interventions in these bridges to be simultaneous and immediate,so certain criteria and priorities must be established in the ways of interventions for their rehabilitation.Bridges that are most at risk and need to be rehabilitated as soon as possible should be determined,and bridges that can be rehabilitated at a later stage should be identified.The prioritization scheme should include a number of aspects beyond the“pure engineering”ones.Main in this process are:seismicity of the area and the probability of the seismic event,vulnerability of the structure.Different structural systems may be considered to be more vulnerable in the event of an earthquake than others,and therefore may need attention as soon as possible.To make this preliminary assessment,we used the methodology of the US Highway Federation,then we proceed with the in-depth assessment of the carrying capacity using the well-known“time history”or“push over”methods,according to the specific case.As an example for the application of this methodology,we have taken the Dragoti Bridge,a category II cultural monument,the bridge with the largest span of light in Albania of 108 m. 展开更多
关键词 Dragoti bridge structural rehabilitation structural assessment
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Vector-intensity measure based seismic vulnerability analysis of bridge structures 被引量:8
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作者 Li Zhongxian Li Yang Li Ning 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2014年第4期695-705,共11页
This paper presents a method for seismic vulnerability analysis of bridge structures based on vector-valued intensity measure (viM), which predicts the limit-state capacities efficiently with multi-intensity measure... This paper presents a method for seismic vulnerability analysis of bridge structures based on vector-valued intensity measure (viM), which predicts the limit-state capacities efficiently with multi-intensity measures of seismic event. Accounting for the uncertainties of the bridge model, ten single-bent overpass bridge structures are taken as samples statistically using Latin hypercube sampling approach. 200 earthquake records are chosen randomly for the uncertainties of ground motions according to the site condition of the bridges. The uncertainties of structural capacity and seismic demand are evaluated with the ratios of demand to capacity in different damage state. By comparing the relative importance of different intensity measures, Sa(T1) and Sa(T2) are chosen as viM. Then, the vector-valued fragility functions of different bridge components are developed. Finally, the system-level vulnerability of the bridge based on viM is studied with Duunett- Sobel class correlation matrix which can consider the correlation effects of different bridge components. The study indicates that an increment IMs from a scalar IM to viM results in a significant reduction in the dispersion of fragility functions and in the uncertainties in evaluating earthquake risk. The feasibility and validity of the proposed vulnerability analysis method is validated and the bridge is more vulnerable than any components. 展开更多
关键词 bridge structure seismic vulnerability analysis vector-valued intensity measure components' correlation system vulnerability
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Finite Element Model Updating of Bridge Structures Based on Sensitivity Analysis and Optimization Algorithm 被引量:6
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作者 HUANG Minshui ZHU Hongping 《Wuhan University Journal of Natural Sciences》 CAS 2008年第1期87-92,共6页
The dynamic characteristics of bridge structures, such as the natural frequencies, mode shapes and model damping ratio, are the basis of structural dynamic computation, seismic analysis, vibration control and structur... The dynamic characteristics of bridge structures, such as the natural frequencies, mode shapes and model damping ratio, are the basis of structural dynamic computation, seismic analysis, vibration control and structural health condition monitoring. In this paper, a three-dimensional finite-element model is established for a highway bridge over a railway on No.312 National Highway and the ambient test is carried out in site, the dynamic characteristics of the bridge are studied using the finite-element analysis and ambient vibration measurements. Comparison between the theoretical and experimental results shows that the frequency differences of the modes range between 0.44% and 8.77%. If the measurement is more reliable, the finite element model updating is necessary. Thus, a set of design variables is selected based on sensitivity analysis, then the finite element model of the bridge is updated based on optimization algorithm. The results of model updating show that the proposed updating method in this paper is more simple and effective, the updated finite element model can reflect the dynamic characteristics of the bridge better, the analytical results can provide the theoretical basis for damage identification and health condition monitoring of the bridge. 展开更多
关键词 sensitivity analysis optimization algorithm model updating bridge structure
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Effect of Crosslink Structure of Bridge Polycarboxylate Superplasticizers on Dispersion Ability 被引量:5
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作者 毕耀 雷家珩 +1 位作者 DU Xiaodi ZHANG Anfu 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2013年第2期339-342,共4页
Bridge polycarboxylate superplasticizers(PCs) with crosslink structure were synthesized by using polyethyleneglycol di-acrylate(PEGdA), replacing partial polyethyleneglycol mono-acrylate (PEGmA) as crosslinking ... Bridge polycarboxylate superplasticizers(PCs) with crosslink structure were synthesized by using polyethyleneglycol di-acrylate(PEGdA), replacing partial polyethyleneglycol mono-acrylate (PEGmA) as crosslinking agent. Structures of bridge PCs were analyzed by gel permeation chromatography, and dispersion ability was evaluated by cement paste dispersity variation on time and rheology test. The experimental results showed that, molecular weight(MW) of bridge PCs increased with increase of PEGdA proportion, and MW distribution curve changed from Gaussian to fiat like, which meant notable increase of highly crosslinked copolymer. Bridge PCs led to decreased initial cement paste dispersity and better dispersity retention due to slow releasing. Further research showed that, PEGdA proportion had slight effect on polymerization degree of backbone, MW distribution of backbone deviated from Gaussian distribution and shoulder peaks appeared on distribution curve when PEGdA increased. 展开更多
关键词 bridge polycarboxylate superplasticizers cement paste dispersity crosslink structure polyethyleneglycol di-acrylate
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Synthesis and Crystal Structure of the Ladder-like Organotin Complex: μ-pentaoxygen bridged penta(bis-benzyltin) bis-salicylate 被引量:7
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作者 WANG Jian-Qiu CHEN Zhi-Min ZENG Rong-Ying KUANG Dai-Zhi FENG Yong-Lan ZHANG Fu-Xing 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第12期1387-1392,共6页
A novel organotin complex of μ-pentaoxygen bridged penta(bis-benzyltin) bissalicylate has been synthesized by the reaction of bis-benzyltin oxide and salicylic acid and its structure has been determined by X-ray di... A novel organotin complex of μ-pentaoxygen bridged penta(bis-benzyltin) bissalicylate has been synthesized by the reaction of bis-benzyltin oxide and salicylic acid and its structure has been determined by X-ray diffraction. The crystal belongs to monoclinic, space group P21/n with a = 1.7206(5), b = 2.1401(6), c = 2.1488(6)nm, β= 93.325(5)°, V = 7.899(4) nm^3, Z = 4, Dc = 1.564 g/cm^3,μ(MoKα) = 16.17cm^-1, Mr = 1859.94, F(000) = 3692, R1= 0.0755 and wR2= 0.1557. According to structural analysis, the coordination geometry of tin is a distorted trigonal bipyramid, and the ladder-like structure is shaped by four Sn2O2 planar four-membered rings. 展开更多
关键词 μ-pentaoxygen bridged penta(bis-benzyltin) bis-salicylate synthesis crystal structure
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Internal Force Distribution in Steel-Concrete Composite Structure for Pylon of Cable-Stayed Bridge 被引量:5
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作者 蒲黔辉 白光亮 《Journal of Southwest Jiaotong University(English Edition)》 2009年第2期95-101,共7页
Adopting a steel-anchor beam and steel corbel composite structure in the anchor zone on pylon is one of the key techniques for the design of Jintang bridge, a cable-stayed bridge in Zhoushan, China. In order to ensure... Adopting a steel-anchor beam and steel corbel composite structure in the anchor zone on pylon is one of the key techniques for the design of Jintang bridge, a cable-stayed bridge in Zhoushan, China. In order to ensure the safety of the steel-concrete composite structure, a stud connector model for the joint section was put forward. Experiments were conducted to obtain the relation between load and slip of specimen, the failure pattern of stud connector, the yield bearing capacity and ultimate bearing capacity of a single stud, etc. The whole process of the structural behavior of the specimen was comprehensively analyzed. The features of the internal force distribution in the steel-concrete composite structure and the strain distribution of stud connector under different loads were emphatically studied. The test results show that the stud connector is applicable for the steel-concrete composite structure for pylon of Jintang bridge. The stud has a good ductility performance and a obvious yield process before its destruction. The stud connector basically works in a state of elasticity under a load less than the yield load. 展开更多
关键词 Stud connector Experimental research Steel-concrete composite structure Cable-stayed bridge Internal force distribution
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Synthesis and Crystal Structure of 1D Chloride Bridged Cadmium(Ⅱ) Chain
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作者 欧光川 《湖南科技学院学报》 2005年第5期113-115,共3页
Hydrothermal reaction of 1,10-phenanthroline with CdCl2·2.5H2O in aqueous solution leads to the complex of [Cd(μ-Cl)2(phen)]n (phen = 1-10-phenanthroline). The crystal structure has been determined by X-ray anal... Hydrothermal reaction of 1,10-phenanthroline with CdCl2·2.5H2O in aqueous solution leads to the complex of [Cd(μ-Cl)2(phen)]n (phen = 1-10-phenanthroline). The crystal structure has been determined by X-ray analysis. It crystallizes in monoclinic with space group C2/c, a = 16.947(3), b = 10.529(2), c = 7.235(1) , β = 110.795(3)°, V = 1208.8(3) 3, Z = 4, Dc = 1.997 g.cm-3, μ= 2.22 mm-1, F(000) = 704, R = 0.0231, Rw = 0.0626 for 1194 reflections with I > 2σ (I). In the crystal structure, the [Cd(phen)]2+ units are bridged by chloride ions to form 1D chain. The 1D chains combine through π……π interactions of phen groups to form 2D infinite molecular zipper. 展开更多
关键词 合成反应 晶体结构 氯化镉 钱恩
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Synthesis and Crystal Structure of an Azide Bridged Binuclear Zinc(Ⅱ) Dimer Containing Taurine Schiff Base [Zn_2(C_8H_9N_2O_3S)_2·(N_3)_2·(H_2O)_2]_2·_2H_2O 被引量:3
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作者 JIANG Yi-Min LI Jia-Ming +1 位作者 XIE Fu-Qing WANG Yan-Fei 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第7期767-770,共4页
The title complex [Zn2L2(N3)2(H2O)2]·2H2O (L = N-(2-pyridylmethylidene) taurine) has been synthesized in a methanol-water solution. The crystal belongs to monoclinic, space group P2 1/C with a = 15.8064... The title complex [Zn2L2(N3)2(H2O)2]·2H2O (L = N-(2-pyridylmethylidene) taurine) has been synthesized in a methanol-water solution. The crystal belongs to monoclinic, space group P2 1/C with a = 15.8064(10), b = 10.5015(5), c = 17.3193(11) ,A, β= 111.314(2)°, V = 2678.2 (3) ,A ^3 C16H26N10O10S2Zn2, Mr = 713.33, Z = 4, DC = 1.769 g/cm^3, μ = 2.017 mm^-1 and F(000) = 1456. The asymmetric unit consists of two half-molecules of the complex and two water molecules. Four N and two O atoms form the coordination environment of each Zn atom, resulting in a distorted octahedral configuration. The two halves of each independent dimer are related by a crystallographic inversion centre, which lies at the centre of the ring formed by two Zn atoms and the coordinating atoms of the two azide anions. The average separation of Zn(Ⅱ)...Zn(Ⅱ) is 3.322 A. The molecules are linked by O-H...O hydrogen bonds, generating an interesting zigzag infinite chain structure in the ac plane. 展开更多
关键词 binuclear zinc complex N-(2-pyridylmethylidene)-taurine schiff base bridging azide crystal structure
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Synthesis and Crystal Structure of a Dinuclear Cu(II) Complex with Tridentate Schiff Base and Azido Bridge 被引量:1
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作者 LINHong FENGYunLong GAOShan 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第4期375-378,共4页
A new dinuclear copper(II) complex ([Cu(C12H17N2O)(N3)]2, C24H34Cu2N10O2) has been synthesized and characterized by X-ray structure determination. It crystallizes in the monoclinic system, space group P21/c with a =... A new dinuclear copper(II) complex ([Cu(C12H17N2O)(N3)]2, C24H34Cu2N10O2) has been synthesized and characterized by X-ray structure determination. It crystallizes in the monoclinic system, space group P21/c with a = 18.529(4), b = 10.933(2), c = 14.534(3) ?, β = 111.07(3)°, V = 2748(1) ?3, Z = 4, Mr = 621.69, F(000) = 1288, Dc = 1.503 g/cm3 and μ(MoKα) = 1.590 mm?1. The structure was refined to R = 0.0647 and wR = 0.1846 for 4406 observed reflections (I > 2σ(I)). The asymmetric unit comprises two halfmolecules. The complex is a centrosymmetric dimmer in which the copper atoms are penta-coordinated by three coordination atoms from the corresponding tridentate Schiff base ligand and two bridging azide anions. The Cu(II)…Cu(II) average distance is 3.350(1) ?. 展开更多
关键词 dimethylamino-1-propylamine SALICYLALDEHYDE Schiff base Cu(II) complex crystal structure bridging azide
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Soil Structure Interaction Effects on Pushover Analysis of Short Span RC Bridges 被引量:1
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作者 Islam M. Ezz El-Arab 《Open Journal of Civil Engineering》 2017年第3期348-361,共14页
A three dimensional finite element of nonlinear pushover analysis for short span Reinforced Concrete (RC) bridge with circular piers cross section is modeling to present effects of soil structural interaction (SSI). S... A three dimensional finite element of nonlinear pushover analysis for short span Reinforced Concrete (RC) bridge with circular piers cross section is modeling to present effects of soil structural interaction (SSI). Structural elements models are including linear foundation springs modeling, and nonlinear RC piers modeling. The paper succeeded to present the SSI effects of nonlinear pushover analysis of short spans RC bridges to determine the significant effects on dynamic characteristics and displacement capacity of short span RC bridges performance;that is increasing within range 11% to 20% compared to baseline pushover analysis of bridge without SSI effects. Results show the bridge stiffness decreases due to SSI effects on the bridge support for more flexible soils types that generates large displacement, with corresponding less base shear in bridge piers and footings by average percentage 12% and 18%, which is important for structural evaluation for new bridge construction and also, for strengthening and repair works evaluation of existing bridges. 展开更多
关键词 SOIL structure INTERACTION PUSHOVER Analysis RC bridge Nonlinear
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Synthesis and Crystal Structure of a Three-dimensional Mn(Ⅱ) Coordination Polymer with 3-(Pyrazin-2-yloxy)-pyridine and Azide Anion as Mixed Bridge Ligand 被引量:1
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作者 李红 赵红艳 +1 位作者 张士国 石敬民 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第12期1511-1513,共3页
A three-dimensional coordination polymer [Mn2(μ1.3-N3)4(μ-PP)2]n (PP = 3-(pyrazin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand, and its c... A three-dimensional coordination polymer [Mn2(μ1.3-N3)4(μ-PP)2]n (PP = 3-(pyrazin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand, and its crystal structure was determined by X-ray crystallography. The crystal data: triclinic system, space group P1, with a = 6.794(4), b = 9.885(6), c = 9.947(6) A, α = 64.170(6), β= 84.190(8), γ= 85.319(8)°, V = 597.7(6)A^3, Z = 1, C18H14Mn2N18O2, Mr = 624.35, Dc = 1.735 g/cm^3, F(000) = 314 and μ = 1.117 mm^-1. In the crystal, the azide anion acts as a bridge ligand and makes adjacent Mn(Ⅱ) ions connect into a two-dimensional sheet on the ab plane, then 3-(pyrazin-2-yloxy)-pyridine serves as a bidentate bridge ligand to connect neighboring sheets along 展开更多
关键词 II Synthesis and Crystal structure of a Three-dimensional Mn Coordination Polymer with 3 Pyrazin-2-yloxy pyridine and Azide Anion as Mixed bridge Ligand
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