Activated carbons calcined at 400˚C and 600˚C (AC-400 and AC-600), prepared using palm nuts, collected in the town of Franceville in Gabon, were used to study the dynamic adsorption of MnO<sub>4</sub>-<...Activated carbons calcined at 400˚C and 600˚C (AC-400 and AC-600), prepared using palm nuts, collected in the town of Franceville in Gabon, were used to study the dynamic adsorption of MnO<sub>4</sub>-</sup> ions in acidic media on fixed bed column and on the kinetic modeling of experimental data of breakthrough curves of MnO<sub>4</sub>-</sup> ions obtained. Results on the adsorption of MnO<sub>4</sub>-</sup> ions in fixed-bed dynamics obtained on AC-400 and AC-600 adsorbents beds indicated that the AC-400 bed appears to be the most efficient in removing MnO<sub>4</sub>-</sup> ions in acidic media. Indeed, the adsorbed amounts, the adsorbed capacities at saturation and the elimination percentage of MnO<sub>4</sub>-</sup> ions obtained with AC-400 (31.24 mg;52.06 mg·g<sup>-1</sup> and 41.65% respectively) were higher compared to those obtained with AC-600 (9.87 mg;16.45 mg·g<sup>-1</sup> and 17.79% respectively). The breakthrough curves kinetic modeling revealed that the Thomas model and the pseudo-first-order kinetic model were the most suitable models to describe the adsorption of MnO<sub>4</sub>-</sup> ions on adsorbents studied in our experimental conditions. The results of the intraparticle diffusion model showed that intraparticle diffusion was involved in the adsorption mechanism of MnO<sub>4</sub>-</sup> ions on investigated adsorbents and was not the limiting step and the only process controlling MnO<sub>4</sub>-</sup> ions adsorption. In contrast to AC-400, the intraparticle diffusion on AC-600 bed plays an important role in the adsorption mechanism of MnO<sub>4</sub>-</sup> ions.展开更多
On the basis of introducing the fundamental theory and the basic analysis steps of the sub model method, the strength of the new engine complex assembly structure was analyzed according to the properties of the engin...On the basis of introducing the fundamental theory and the basic analysis steps of the sub model method, the strength of the new engine complex assembly structure was analyzed according to the properties of the engine structures, some of the key parts of the engine were analyzed with refined mesh by sub model method and the error of the FEM solution was estimated by the extrapolation method. The example showed that the sub model can not only analyze the comlex structures without the restriction of the software and hardware of the computers, but get the more precise analysis result also. This method is more suitable for the strength analysis of the complex assembly structure.展开更多
The modified sub regular solution model was used for a calculation of the activity coefficient of immiscible binary alloy systems. The parameters needed for the calculation are the interaction parameters, λ 1 a...The modified sub regular solution model was used for a calculation of the activity coefficient of immiscible binary alloy systems. The parameters needed for the calculation are the interaction parameters, λ 1 and λ 2, which are represented as a linear function of temperature, T . The molar excess Gibbs free energy, G m E, can be written in the form G m E= x A x B[( λ 11 + λ 12 T )+( λ 21 + λ 22 T ) x B ] The calculation is carried out numerically for three immiscible binary alloy systems, Al Pb, Cu Tl and In V. The agreement between the calculated and experimentally determined values of activity coefficient is excellent.展开更多
This study aims to analyze seismic damage of reinforced outlet piers of arch dams by the nonlinear finite element (FE) sub-model method. First, the dam-foundation system is modeled and analyzed, in which the effects...This study aims to analyze seismic damage of reinforced outlet piers of arch dams by the nonlinear finite element (FE) sub-model method. First, the dam-foundation system is modeled and analyzed, in which the effects of infinite foundation, contraction joints, and nonlinear concrete are taken into account. The detailed structures of the outlet pier are then simulated with a refined FE model in the sub-model analysis. In this way the damage mechanism of the plain (unreinforced) outlet pier is analyzed, and the effects of two reinforcement measures (i.e., post-tensioned anchor cables and reinforcing bar) on the dynamic damage to the outlet pier are investigated comprehensively. Results show that the plain pier is damaged severely by strong earthquakes while implementation of post-tensioned anchor cables strengthens the pier effectively. In addition, radiation damping strongly alleviates seismic damage to the piers.展开更多
Based on the interpretations of three seismic profiles and one wide-angle seismic profile across the Northwest Sub-basin,South China Sea.stratigraphic sequences,deformation characteristics and an extension model for t...Based on the interpretations of three seismic profiles and one wide-angle seismic profile across the Northwest Sub-basin,South China Sea.stratigraphic sequences,deformation characteristics and an extension model for this sub-basin have been worked out.Three tectonic-stratigraphic units are determined.Detailed analyses of extension show that the event occurred mainly during the Paleogene and resulted in the formation of half-grabens or grabens distributed symmetrically around the spreading center.Sediments are characterized by chaotic and discontinuous reflectors,indicating clastic sediments. Farther to the southwest,the sub-basin features mainly continental rifting instead of sea-floor spreading. The rifting would have been controlled by the shape of the massif and developed just along the northern edge of the Zhongsha-Xisha Block,rather than joined the Xisha Trough.After 25 Ma.a southward ridge jump triggered the opening of the Southwest Sub-basin.The NW-directed stress caused by the sea-floor spreading of the Northwest Sub-basin may have prevented the continuous opening of the sub-basin.After that the Northwest Sub-basin experienced thermal cooling and exhibited broad subsidence.The deep crustal structure shown by the velocity model from a wide-angle seismic profile is also symmetrical around the spreading center,which indicates that the Northwest Sub-basin might have opened in a pure shear model.展开更多
The dense solid-phase governing equations for two-phase flows are obtained by using the kinetic theory of gas molecules.Assuming that the solid-phase velocity distributions obey the Maxwell equations,the collision ter...The dense solid-phase governing equations for two-phase flows are obtained by using the kinetic theory of gas molecules.Assuming that the solid-phase velocity distributions obey the Maxwell equations,the collision term for particles under dense two-phase flow conditions is also derived. In comparison with the governing equations of a dilute two-phase flow,the solid-particle's governing equations are developed for a dense turbulent solid-liquid flow by adopting some relevant terms from the dilute two-phase governing equations.Based on Cauchy-Helmholtz theorem and Smagorinsky model, a second-order dynamic sub-grid-scale(SGS)model,in which the sub-grid-scale stress is a function of both the strain-rate tensor and the rotation-rate tensor,is proposed to model the two-phase governing equations by applying dimension analyses.Applying the SIMPLEC algorithm and staggering grid system to the two-phase discretized governing equations and employing the slip boundary conditions on the walls,the velocity and pressure fields,and the volumetric concentration are calculated.The simulation results are in a fairly good agreement with experimental data in two operating cases in a conduit with a rectangular cross-section and these comparisons imply that these models are practical.展开更多
Geometric or sub-scale modeling techniques are used for the evaluation of large and complex dynamic structures to ensure accurate reproduction of load path and thus leading to true dynamic characteristics of such stru...Geometric or sub-scale modeling techniques are used for the evaluation of large and complex dynamic structures to ensure accurate reproduction of load path and thus leading to true dynamic characteristics of such structures. The sub-scale modeling technique is very effective in the prediction of vibration characteristics of original large structure when the experimental testing is not feasible due to the absence of a large testing facility. Previous researches were more focused on free and harmonic vibration case with little or no consideration for readily encountered random vibration. A sub-scale modeling technique is proposed for estimating the vibration characteristics of any large scale structure such as Launch vehicles, Mega structures, etc., under various vibration load cases by utilizing precise scaled-down model of that dynamic structure. In order to establish an analytical correlation between the original structure and its scaled models, different scale models of isotropic cantilever beam are selected and analyzed under various vibration conditions( i.e. free, harmonic and random) using finite element package ANSYS. The developed correlations are also validated through experimental testing The prediction made from the vibratory response of the scaled-down beam through the established sets of correlation are found similar to the response measured from the testing of original beam structure. The established correlations are equally applicable in the prediction of dynamic characteristics of any complex structure through its scaled-down models. This paper presents modified sub-scale modeling technique that enables accurate prediction of vibration characteristics of large and complex structure under not only sinusoidal but also for random vibrations.展开更多
A new gravity survey was carried out in the northern part of the onshore Kribi- Campo sub-basin in Cameroon. The data were incorporated to the existing ones and then analyzed and modeled in order to elucidate the subs...A new gravity survey was carried out in the northern part of the onshore Kribi- Campo sub-basin in Cameroon. The data were incorporated to the existing ones and then analyzed and modeled in order to elucidate the subsurface structure of the area. The area is characterized in its north-western part by considerably high positive anomalies indicative of the presence of a dense intrusive body. We find, 1) from the analysis of the gravity residual anomaly map, the high positive anomalies observed are the signature of a shallow dense structure;2) from the multi-scale analysis of the maxima of the horizontal gradient, the structure is confined between depths of 0.5 km and 5 km;3) from the quantitative interpretation of residual anomalies by spectral analysis, the depth to the upper surface of the intrusive body is not uniform, the average depth of the bottom is h1 = 3.6 km and the depths to particular sections of the roof of the intrusion are h2 = 1.6 km and h3 = 0.5 km;4) and the 3D modeling gives results that are suggestive of the presence of contacts between rocks of different densities at different depths and a dense intrusive igneous body in the upper crust of the Kribi zone. From the 3D model the dense intrusive igneous block is surrounded by sedimentary formations to the south-west and metamorphic formations to the north-east. Both formations have a density of about 2.74 g/cm3. The near surface portions of this igneous block lie at a depth range of 0.5 km to 1.5 km while its lower surface has a depth range of 3.6 km to 5.2 km. The shape of the edges and the bottom of the intrusive body are suggestive of the fact that it forms part of a broader structure underlying the Kribi-Campo sub-basin with a great influence on the sedimentary cover.展开更多
River flow in the Songwe sub-basin is predicted to alter due to climate change, which would have an impact on aquatic habitats, infrastructure, and people’s way of life. Therefore, the influence of climate change sho...River flow in the Songwe sub-basin is predicted to alter due to climate change, which would have an impact on aquatic habitats, infrastructure, and people’s way of life. Therefore, the influence of climate change should be taken into account when making decisions about the sustainable management of water resources in the sub-basin. This study looked into how river discharge would react to climate change in the future. By contrasting hydrological characteristics simulated under historical climate (1981-2010) with projected climate (2011-2040, 2041-2070, and 2071-2100) under two emission scenarios, the effects of climate change on river flow were evaluated (RCP 4.5 and RCP 8.5). The ensemble average of four CORDEX regional climate models was built to address the issue of uncertainty introduced by the climate models. The SWAT model was force-calibrated using the results from the generated ensemble average for the RCP 4.5 and RCP 8.5 emission scenarios in order to mimic the river flow during past (1981-2010) and future (2011-2100) events. The increase in river flows for the Songwe sub-basin is predicted to be largest during the rainy season by both the RCP 4.5 and RCP 8.5 scenarios. Under RCP 8.5, the abrupt decrease in river flow is anticipated to reach its maximum in March 2037, when the discharge will be 44.84 m<sup>3</sup>/sec, and in March 2027, when the discharge will be 48 m<sup>3</sup>/sec. The extreme surge in river flow will peak, according to the RCA4, in February 2023, in April 2083 under RCP 4.5, and, according to the CCLM4 and RCA4, in November 2027 and November 2046, respectively. The expected decrease and increase in river flow throughout both the dry and wet seasons may have an impact on the management of the sub-water basin’s resources, biodiversity, and hydraulic structures. The right adaptations and mitigation strategies should be adopted in order to lessen the negative consequences of climate change on precipitation, temperature, and river flow in the sub-basin.展开更多
It is still a challenging task to accurately and temperature-continuously express the thermodynamic properties and phase equilibrium behaviors of the salt-lake brine with multi-component,multitemperature and high conc...It is still a challenging task to accurately and temperature-continuously express the thermodynamic properties and phase equilibrium behaviors of the salt-lake brine with multi-component,multitemperature and high concentration.The essential subsystem of sulfate type brine,aqueous Li^(+)-Na^(+)-K^(+)-SO_(4)^(2-) and its subsystems across a temperature range from 250 K to 643 K are investigated with the improved comprehensive thermodynamic model.Liquid parameters(Δg_(IJ),Δh_(IJ),and ΔC_(p,IJ))associated with the contributions of Gibbs energy,enthalpy,and heat capacity to the binary interaction parameters,i.e.the temperature coefficients of eNRTL parameters formulated with a Gibbs Helmholtz expression,are determined via multi-objective optimization method.The solid constantsΔ_(f)G_(k)°^((298.15))andΔ_(f)H_(k)°^((298.15))of11 solid species occurred in the quaternary system are rebuilt from multi-temperature solubilities.The modeling results show the accurate representation of(1)solution properties and binary phase diagram at temperature ranges from eutectic points to 643 K;(2)isothermal phase diagrams for Li_(2)SO_(4)-Na_(2)SO_(4)-H_(2)O,Li_(2)SO_(4)-K_(2)SO_(4)-H_(2)O and Na_(2)SO_(4)-K_(2)SO_(4)-H_(2)O ternary systems.The predicted results of complete structure and polythermal phase diagram of ternary systems and the isothermal phase diagrams of quaternary system excellently match with the experimental data.展开更多
Wind speed extremes in the sub-Arctic realm of the North-East Pacific region were investigated through extreme value analysis of wind speed obtained from wind simulations of the COSMO-CLM (Consortium for Small-scale M...Wind speed extremes in the sub-Arctic realm of the North-East Pacific region were investigated through extreme value analysis of wind speed obtained from wind simulations of the COSMO-CLM (Consortium for Small-scale Modelling, climate version) mesoscale model, as well as using observed data. The analysis showed that the set of wind speed extremes obtained from observations is a mixture of two different subsets each neatly described by the Weibull distribution. Using special metaphoric terminology, they are labelled as “Black Swans” and “Dragons”. The “Dragons” are responsible for strongest extremes. It has been shown that both reanalysis and GCM (general circulation model) data have no “Dragons”. This means that such models underestimate wind speed maxima, and the important circulation process generating the anomalies is not simulated. The COSMO-CLM data have both “Black Swans” and “Dragons”. This evidence provides a clue that an atmospheric model with a detailed spatial resolution (we used in this work the data from domain with 13.2 km spatial resolution) does reproduce the special mechanism responsible for the generation of the largest wind speed extremes. However, a more thorough analysis shows that the differences in the parameters of the cumulative distribution functions are still significant. The ratio between the modelled Dragons and Black Swans can reach up to only 10%. It is much less than 30%, which was the level established for observations.展开更多
In 1995, the Intergovernmental Panel on Climate Change (IPCC) released a thermodynamic model based on the Greenhouse Effect, aiming to forecast global temperatures. This study delves into the intricacies of that model...In 1995, the Intergovernmental Panel on Climate Change (IPCC) released a thermodynamic model based on the Greenhouse Effect, aiming to forecast global temperatures. This study delves into the intricacies of that model. Some interesting observations are revealed. The IPCC model equated average temperatures with average energy fluxes, which can cause significant errors. The model assumed that all energy fluxes remained constant, and the Earth emitted infrared radiation as if it were a blackbody. Neither of those conditions exists. The IPCC’s definition of Climate Change only includes events caused by human actions, excluding most causes. Satellite data aimed at the tops of clouds may have inferred a high Greenhouse Gas absorption flux. The model showed more energy coming from the atmosphere than absorbed from the sun, which may have caused a violation of the First and Second Laws of Thermodynamics. There were unexpectedly large gaps in the satellite data that aligned with various absorption bands of Greenhouse Gases, possibly caused by photon scattering associated with re-emissions. Based on science, we developed a cloud-based climate model that complied with the Radiation Laws and the First and Second Laws of Thermodynamics. The Cloud Model showed that 81.3% of the outgoing reflected and infrared radiation was applicable to the clouds and water vapor. In comparison, the involvement of CO<sub>2</sub> was only 0.04%, making it too minuscule to measure reliably.展开更多
Marine sediment velocity structural models have strong regional characteristics.Hamilton made two shallow continental shelf sediment velocity structure models,Lu Bo gave a model in accordance with the characteristics ...Marine sediment velocity structural models have strong regional characteristics.Hamilton made two shallow continental shelf sediment velocity structure models,Lu Bo gave a model in accordance with the characteristics of the continental shelf of China.However,no model can contain all geological situations.We got the in-situ velocity data at Zhapu and Jintang near the Hangzhou Bay by using the MFI GeoA(Multi-Frequency In-situ Geoacoustic Measurement),and used these data to make the velocity structure models.Finally,we got two different models.One is Zhapu velocity structural model that we can describe as Lower velocity-Higher velocity -Lower velocity-Higher velocity model simply。展开更多
In this work, the possibility of enhanced activity during the hydrodesulfurization of dibenzothiophene over certain nano-MoS<sub>2</sub> catalyst due to the presence of H<sub>2</sub>S was exami...In this work, the possibility of enhanced activity during the hydrodesulfurization of dibenzothiophene over certain nano-MoS<sub>2</sub> catalyst due to the presence of H<sub>2</sub>S was examined by focusing on the reaction kinetics. With H<sub>2</sub>S generated <i>in situ</i>, the overall reaction followed the autocatalytic rate law;while in the absence of H<sub>2</sub>S the kinetics indicated a pseudo-first-order reaction. H<sub>2</sub>S appears to modify the relative contributions of parallel hydrogenation and desulfurization reactions by drastically increasing the hydrogenation rate. Kinetic models were developed that describe the hydrodesulfurization reaction at various H<sub>2</sub>S concentrations, and the kinetic parameters and adsorption equilibrium constants associated with this process were estimated by fitting the experimental data. The results suggest that the promotion and/or inhibition of hydrodesulfurization by H<sub>2</sub>S likely result from the same overall reaction mechanism.展开更多
文摘Activated carbons calcined at 400˚C and 600˚C (AC-400 and AC-600), prepared using palm nuts, collected in the town of Franceville in Gabon, were used to study the dynamic adsorption of MnO<sub>4</sub>-</sup> ions in acidic media on fixed bed column and on the kinetic modeling of experimental data of breakthrough curves of MnO<sub>4</sub>-</sup> ions obtained. Results on the adsorption of MnO<sub>4</sub>-</sup> ions in fixed-bed dynamics obtained on AC-400 and AC-600 adsorbents beds indicated that the AC-400 bed appears to be the most efficient in removing MnO<sub>4</sub>-</sup> ions in acidic media. Indeed, the adsorbed amounts, the adsorbed capacities at saturation and the elimination percentage of MnO<sub>4</sub>-</sup> ions obtained with AC-400 (31.24 mg;52.06 mg·g<sup>-1</sup> and 41.65% respectively) were higher compared to those obtained with AC-600 (9.87 mg;16.45 mg·g<sup>-1</sup> and 17.79% respectively). The breakthrough curves kinetic modeling revealed that the Thomas model and the pseudo-first-order kinetic model were the most suitable models to describe the adsorption of MnO<sub>4</sub>-</sup> ions on adsorbents studied in our experimental conditions. The results of the intraparticle diffusion model showed that intraparticle diffusion was involved in the adsorption mechanism of MnO<sub>4</sub>-</sup> ions on investigated adsorbents and was not the limiting step and the only process controlling MnO<sub>4</sub>-</sup> ions adsorption. In contrast to AC-400, the intraparticle diffusion on AC-600 bed plays an important role in the adsorption mechanism of MnO<sub>4</sub>-</sup> ions.
文摘On the basis of introducing the fundamental theory and the basic analysis steps of the sub model method, the strength of the new engine complex assembly structure was analyzed according to the properties of the engine structures, some of the key parts of the engine were analyzed with refined mesh by sub model method and the error of the FEM solution was estimated by the extrapolation method. The example showed that the sub model can not only analyze the comlex structures without the restriction of the software and hardware of the computers, but get the more precise analysis result also. This method is more suitable for the strength analysis of the complex assembly structure.
文摘The modified sub regular solution model was used for a calculation of the activity coefficient of immiscible binary alloy systems. The parameters needed for the calculation are the interaction parameters, λ 1 and λ 2, which are represented as a linear function of temperature, T . The molar excess Gibbs free energy, G m E, can be written in the form G m E= x A x B[( λ 11 + λ 12 T )+( λ 21 + λ 22 T ) x B ] The calculation is carried out numerically for three immiscible binary alloy systems, Al Pb, Cu Tl and In V. The agreement between the calculated and experimentally determined values of activity coefficient is excellent.
基金National Natural Science Foundation of China under Grant Nos.51179093 and 91215301Specialized Research Fund for the Doctoral Program of Higher Education under Grant No.20130002110032
文摘This study aims to analyze seismic damage of reinforced outlet piers of arch dams by the nonlinear finite element (FE) sub-model method. First, the dam-foundation system is modeled and analyzed, in which the effects of infinite foundation, contraction joints, and nonlinear concrete are taken into account. The detailed structures of the outlet pier are then simulated with a refined FE model in the sub-model analysis. In this way the damage mechanism of the plain (unreinforced) outlet pier is analyzed, and the effects of two reinforcement measures (i.e., post-tensioned anchor cables and reinforcing bar) on the dynamic damage to the outlet pier are investigated comprehensively. Results show that the plain pier is damaged severely by strong earthquakes while implementation of post-tensioned anchor cables strengthens the pier effectively. In addition, radiation damping strongly alleviates seismic damage to the piers.
基金supported by the National Basic Research Program(973) of China (No.2007CB41170403)the National Natural Science Foundation of China(No.40806023)the Scientific Research Fund of the SIO,SOA(No.1404-10)
文摘Based on the interpretations of three seismic profiles and one wide-angle seismic profile across the Northwest Sub-basin,South China Sea.stratigraphic sequences,deformation characteristics and an extension model for this sub-basin have been worked out.Three tectonic-stratigraphic units are determined.Detailed analyses of extension show that the event occurred mainly during the Paleogene and resulted in the formation of half-grabens or grabens distributed symmetrically around the spreading center.Sediments are characterized by chaotic and discontinuous reflectors,indicating clastic sediments. Farther to the southwest,the sub-basin features mainly continental rifting instead of sea-floor spreading. The rifting would have been controlled by the shape of the massif and developed just along the northern edge of the Zhongsha-Xisha Block,rather than joined the Xisha Trough.After 25 Ma.a southward ridge jump triggered the opening of the Southwest Sub-basin.The NW-directed stress caused by the sea-floor spreading of the Northwest Sub-basin may have prevented the continuous opening of the sub-basin.After that the Northwest Sub-basin experienced thermal cooling and exhibited broad subsidence.The deep crustal structure shown by the velocity model from a wide-angle seismic profile is also symmetrical around the spreading center,which indicates that the Northwest Sub-basin might have opened in a pure shear model.
基金The project supported by the National Natural Science Foundation of China (50176022)
文摘The dense solid-phase governing equations for two-phase flows are obtained by using the kinetic theory of gas molecules.Assuming that the solid-phase velocity distributions obey the Maxwell equations,the collision term for particles under dense two-phase flow conditions is also derived. In comparison with the governing equations of a dilute two-phase flow,the solid-particle's governing equations are developed for a dense turbulent solid-liquid flow by adopting some relevant terms from the dilute two-phase governing equations.Based on Cauchy-Helmholtz theorem and Smagorinsky model, a second-order dynamic sub-grid-scale(SGS)model,in which the sub-grid-scale stress is a function of both the strain-rate tensor and the rotation-rate tensor,is proposed to model the two-phase governing equations by applying dimension analyses.Applying the SIMPLEC algorithm and staggering grid system to the two-phase discretized governing equations and employing the slip boundary conditions on the walls,the velocity and pressure fields,and the volumetric concentration are calculated.The simulation results are in a fairly good agreement with experimental data in two operating cases in a conduit with a rectangular cross-section and these comparisons imply that these models are practical.
文摘Geometric or sub-scale modeling techniques are used for the evaluation of large and complex dynamic structures to ensure accurate reproduction of load path and thus leading to true dynamic characteristics of such structures. The sub-scale modeling technique is very effective in the prediction of vibration characteristics of original large structure when the experimental testing is not feasible due to the absence of a large testing facility. Previous researches were more focused on free and harmonic vibration case with little or no consideration for readily encountered random vibration. A sub-scale modeling technique is proposed for estimating the vibration characteristics of any large scale structure such as Launch vehicles, Mega structures, etc., under various vibration load cases by utilizing precise scaled-down model of that dynamic structure. In order to establish an analytical correlation between the original structure and its scaled models, different scale models of isotropic cantilever beam are selected and analyzed under various vibration conditions( i.e. free, harmonic and random) using finite element package ANSYS. The developed correlations are also validated through experimental testing The prediction made from the vibratory response of the scaled-down beam through the established sets of correlation are found similar to the response measured from the testing of original beam structure. The established correlations are equally applicable in the prediction of dynamic characteristics of any complex structure through its scaled-down models. This paper presents modified sub-scale modeling technique that enables accurate prediction of vibration characteristics of large and complex structure under not only sinusoidal but also for random vibrations.
文摘A new gravity survey was carried out in the northern part of the onshore Kribi- Campo sub-basin in Cameroon. The data were incorporated to the existing ones and then analyzed and modeled in order to elucidate the subsurface structure of the area. The area is characterized in its north-western part by considerably high positive anomalies indicative of the presence of a dense intrusive body. We find, 1) from the analysis of the gravity residual anomaly map, the high positive anomalies observed are the signature of a shallow dense structure;2) from the multi-scale analysis of the maxima of the horizontal gradient, the structure is confined between depths of 0.5 km and 5 km;3) from the quantitative interpretation of residual anomalies by spectral analysis, the depth to the upper surface of the intrusive body is not uniform, the average depth of the bottom is h1 = 3.6 km and the depths to particular sections of the roof of the intrusion are h2 = 1.6 km and h3 = 0.5 km;4) and the 3D modeling gives results that are suggestive of the presence of contacts between rocks of different densities at different depths and a dense intrusive igneous body in the upper crust of the Kribi zone. From the 3D model the dense intrusive igneous block is surrounded by sedimentary formations to the south-west and metamorphic formations to the north-east. Both formations have a density of about 2.74 g/cm3. The near surface portions of this igneous block lie at a depth range of 0.5 km to 1.5 km while its lower surface has a depth range of 3.6 km to 5.2 km. The shape of the edges and the bottom of the intrusive body are suggestive of the fact that it forms part of a broader structure underlying the Kribi-Campo sub-basin with a great influence on the sedimentary cover.
文摘River flow in the Songwe sub-basin is predicted to alter due to climate change, which would have an impact on aquatic habitats, infrastructure, and people’s way of life. Therefore, the influence of climate change should be taken into account when making decisions about the sustainable management of water resources in the sub-basin. This study looked into how river discharge would react to climate change in the future. By contrasting hydrological characteristics simulated under historical climate (1981-2010) with projected climate (2011-2040, 2041-2070, and 2071-2100) under two emission scenarios, the effects of climate change on river flow were evaluated (RCP 4.5 and RCP 8.5). The ensemble average of four CORDEX regional climate models was built to address the issue of uncertainty introduced by the climate models. The SWAT model was force-calibrated using the results from the generated ensemble average for the RCP 4.5 and RCP 8.5 emission scenarios in order to mimic the river flow during past (1981-2010) and future (2011-2100) events. The increase in river flows for the Songwe sub-basin is predicted to be largest during the rainy season by both the RCP 4.5 and RCP 8.5 scenarios. Under RCP 8.5, the abrupt decrease in river flow is anticipated to reach its maximum in March 2037, when the discharge will be 44.84 m<sup>3</sup>/sec, and in March 2027, when the discharge will be 48 m<sup>3</sup>/sec. The extreme surge in river flow will peak, according to the RCA4, in February 2023, in April 2083 under RCP 4.5, and, according to the CCLM4 and RCA4, in November 2027 and November 2046, respectively. The expected decrease and increase in river flow throughout both the dry and wet seasons may have an impact on the management of the sub-water basin’s resources, biodiversity, and hydraulic structures. The right adaptations and mitigation strategies should be adopted in order to lessen the negative consequences of climate change on precipitation, temperature, and river flow in the sub-basin.
基金financial support of the National Natural Science Foundation of China(U1707602,U1407204)Yangtze Scholars and Innovative Research Team in University of Education of China,the Innovative Research Team of Tianjin Municipal Education Commission(TD125004)。
文摘It is still a challenging task to accurately and temperature-continuously express the thermodynamic properties and phase equilibrium behaviors of the salt-lake brine with multi-component,multitemperature and high concentration.The essential subsystem of sulfate type brine,aqueous Li^(+)-Na^(+)-K^(+)-SO_(4)^(2-) and its subsystems across a temperature range from 250 K to 643 K are investigated with the improved comprehensive thermodynamic model.Liquid parameters(Δg_(IJ),Δh_(IJ),and ΔC_(p,IJ))associated with the contributions of Gibbs energy,enthalpy,and heat capacity to the binary interaction parameters,i.e.the temperature coefficients of eNRTL parameters formulated with a Gibbs Helmholtz expression,are determined via multi-objective optimization method.The solid constantsΔ_(f)G_(k)°^((298.15))andΔ_(f)H_(k)°^((298.15))of11 solid species occurred in the quaternary system are rebuilt from multi-temperature solubilities.The modeling results show the accurate representation of(1)solution properties and binary phase diagram at temperature ranges from eutectic points to 643 K;(2)isothermal phase diagrams for Li_(2)SO_(4)-Na_(2)SO_(4)-H_(2)O,Li_(2)SO_(4)-K_(2)SO_(4)-H_(2)O and Na_(2)SO_(4)-K_(2)SO_(4)-H_(2)O ternary systems.The predicted results of complete structure and polythermal phase diagram of ternary systems and the isothermal phase diagrams of quaternary system excellently match with the experimental data.
文摘Wind speed extremes in the sub-Arctic realm of the North-East Pacific region were investigated through extreme value analysis of wind speed obtained from wind simulations of the COSMO-CLM (Consortium for Small-scale Modelling, climate version) mesoscale model, as well as using observed data. The analysis showed that the set of wind speed extremes obtained from observations is a mixture of two different subsets each neatly described by the Weibull distribution. Using special metaphoric terminology, they are labelled as “Black Swans” and “Dragons”. The “Dragons” are responsible for strongest extremes. It has been shown that both reanalysis and GCM (general circulation model) data have no “Dragons”. This means that such models underestimate wind speed maxima, and the important circulation process generating the anomalies is not simulated. The COSMO-CLM data have both “Black Swans” and “Dragons”. This evidence provides a clue that an atmospheric model with a detailed spatial resolution (we used in this work the data from domain with 13.2 km spatial resolution) does reproduce the special mechanism responsible for the generation of the largest wind speed extremes. However, a more thorough analysis shows that the differences in the parameters of the cumulative distribution functions are still significant. The ratio between the modelled Dragons and Black Swans can reach up to only 10%. It is much less than 30%, which was the level established for observations.
文摘In 1995, the Intergovernmental Panel on Climate Change (IPCC) released a thermodynamic model based on the Greenhouse Effect, aiming to forecast global temperatures. This study delves into the intricacies of that model. Some interesting observations are revealed. The IPCC model equated average temperatures with average energy fluxes, which can cause significant errors. The model assumed that all energy fluxes remained constant, and the Earth emitted infrared radiation as if it were a blackbody. Neither of those conditions exists. The IPCC’s definition of Climate Change only includes events caused by human actions, excluding most causes. Satellite data aimed at the tops of clouds may have inferred a high Greenhouse Gas absorption flux. The model showed more energy coming from the atmosphere than absorbed from the sun, which may have caused a violation of the First and Second Laws of Thermodynamics. There were unexpectedly large gaps in the satellite data that aligned with various absorption bands of Greenhouse Gases, possibly caused by photon scattering associated with re-emissions. Based on science, we developed a cloud-based climate model that complied with the Radiation Laws and the First and Second Laws of Thermodynamics. The Cloud Model showed that 81.3% of the outgoing reflected and infrared radiation was applicable to the clouds and water vapor. In comparison, the involvement of CO<sub>2</sub> was only 0.04%, making it too minuscule to measure reliably.
文摘Marine sediment velocity structural models have strong regional characteristics.Hamilton made two shallow continental shelf sediment velocity structure models,Lu Bo gave a model in accordance with the characteristics of the continental shelf of China.However,no model can contain all geological situations.We got the in-situ velocity data at Zhapu and Jintang near the Hangzhou Bay by using the MFI GeoA(Multi-Frequency In-situ Geoacoustic Measurement),and used these data to make the velocity structure models.Finally,we got two different models.One is Zhapu velocity structural model that we can describe as Lower velocity-Higher velocity -Lower velocity-Higher velocity model simply。
文摘In this work, the possibility of enhanced activity during the hydrodesulfurization of dibenzothiophene over certain nano-MoS<sub>2</sub> catalyst due to the presence of H<sub>2</sub>S was examined by focusing on the reaction kinetics. With H<sub>2</sub>S generated <i>in situ</i>, the overall reaction followed the autocatalytic rate law;while in the absence of H<sub>2</sub>S the kinetics indicated a pseudo-first-order reaction. H<sub>2</sub>S appears to modify the relative contributions of parallel hydrogenation and desulfurization reactions by drastically increasing the hydrogenation rate. Kinetic models were developed that describe the hydrodesulfurization reaction at various H<sub>2</sub>S concentrations, and the kinetic parameters and adsorption equilibrium constants associated with this process were estimated by fitting the experimental data. The results suggest that the promotion and/or inhibition of hydrodesulfurization by H<sub>2</sub>S likely result from the same overall reaction mechanism.