Objective In recent decades,China has implemented a series of policies to address air pollution.We aimed to assess the health effects of these policies on stroke burden attributable to ambient fine particulate matter(...Objective In recent decades,China has implemented a series of policies to address air pollution.We aimed to assess the health effects of these policies on stroke burden attributable to ambient fine particulate matter(PM_(2.5)).Methods Joinpoint regression was applied to explore the temporal tendency of stroke burden based on data from the Global Burden of Disease 2019 study.Results The age-standardized rates of disability-adjusted life year(DALY)for stroke attributable to ambient PM2.5 in China,increased dramatically during 1990-2012,subsequently decreased at an annual percentage change(APC)of-1.98[95% confidence interval(CI):-2.26,-1.71]during 2012-2019.For ischemic stroke(IS),the age-standardized DALY rates doubled from 1990 to 2014,and decreased at an APC of-0.83(95%CI:-1.33,-0.33)during 2014-2019.Intracerebral hemorrhage(ICH)showed a substantial increase in age-standardized DALY rates from 1990 to 2003,followed by declining trends,with APCs of-1.46(95%CI:-2.74,-0.16)during 2003-2007 and-3.33(95%CI:-3.61,-3.06)during 2011-2019,respectively.Conversely,the age-standardized DALY rates for subarachnoid hemorrhage(SAH)generally declined during 1990-2019.Conclusion Our results clarified the dynamic changes of the ambient PM_(2.5)-attributable stroke burden in China during 1990-2019,highlighting the health effects of air quality improvement policies.展开更多
Objective:To evaluate the effect of the ethyl acetate fraction derived from Sargassum pallidum extract against particulate matter(PM)-induced oxidative stress and inflammation in HaCaT cells and zebrafish.Methods:HaCa...Objective:To evaluate the effect of the ethyl acetate fraction derived from Sargassum pallidum extract against particulate matter(PM)-induced oxidative stress and inflammation in HaCaT cells and zebrafish.Methods:HaCaT cells and zebrafish were used to evaluate the protective effects of the ethyl acetate fraction of Sargassum pallidum extract against PM-induced oxidative stress and inflammation.The production of nitric oxide(NO),intracellular ROS,prostaglandin E_(2)(PGE_(2)),and pro-inflammatory cytokines,and the expression levels of COX-2,iNOS,and NF-κB were evaluated in PM-induced HaCaT cells.Furthermore,the levels of ROS,NO,and lipid peroxidation were assessed in the PM-exposed zebrafish model.Results:The ethyl acetate fraction of Sargassum pallidum extract significantly decreased the production of NO,intracellular ROS,and PGE_(2) in PM-induced HaCaT cells.In addition,the fraction markedly suppressed the levels of pro-inflammatory cytokines and inhibited the expression levels of COX-2,iNOS,and NF-κB.Furthermore,it displayed remarkable protective effects against PM-induced inflammatory response and oxidative stress,represented by the reduction of NO,ROS,and lipid peroxidation in zebrafish.Conclusions:The ethyl acetate fraction of Sargassum pallidum extract exhibits a protective effect against PM-induced oxidative stress and inflammation both in vitro and in vivo and has the potential as a candidate for the development of pharmaceutical and cosmeceutical products.展开更多
Oxy-combustion is a promising carbon-capture technology,but atmospheric-pressure oxy-combustion has a relatively low net efficiency,limiting its application in power plants.In pressurized oxycombustion(POC),the boiler...Oxy-combustion is a promising carbon-capture technology,but atmospheric-pressure oxy-combustion has a relatively low net efficiency,limiting its application in power plants.In pressurized oxycombustion(POC),the boiler,air separation unit,flue gas recirculation unit,and CO_(2)purification and compression unit are all operated at elevated pressure;this makes the process more efficient,with many advantages over atmospheric pressure,such as low NO_(x)emissions,a smaller boiler size,and more.POC is also more promising for industrial application and has attracted widespread research interest in recent years.It can produce high-pressure CO_(2)with a purity of approximately 95%,which can be used directly for enhanced oil recovery or geo-sequestration.However,the pollutant emissions must meet the standards for carbon capture,storage,and utilization.Because of the high oxygen and moisture concentrations in POC,the formation of acids via the oxidation and solution of SO_(x)and NO_(x)can be increased,causing the corrosion of pipelines and equipment.Furthermore,particulate matter(PM)and mercury emissions can harm the environment and human health.The main distinction between pressurized and atmospheric-pressure oxy-combustion is the former’s elevated pressure;thus,the effect of this pressure on the pollutants emitted from POC—including SO_(x),NO_(x),PM,and mercury—must be understood,and effective control methodologies must be incorporated to control the formation of these pollutants.This paper reviews recent advances in research on SO_(x),NO_(x),PM,and mercury formation and control in POC systems that can aid in pollutant control in such systems.展开更多
This research study explored the levels of base status metals in soil sediments and particulate matter in the wellington industrial estate location;the main objectives were to: 1) determine sodium and potassium, 2) de...This research study explored the levels of base status metals in soil sediments and particulate matter in the wellington industrial estate location;the main objectives were to: 1) determine sodium and potassium, 2) determine calcium and magnesium, 3) determine available iron. The following hypotheses were put forward;H<sub>0</sub><sub>a</sub>: there is no significant difference in the concentration levels between Ca and Mg in the study area, H<sub>1</sub><sub>a</sub>: there is significant difference in the concentration levels between Ca and Mg in the study area, H<sub>0</sub><sub>b</sub>: there is no significant difference in the concentration levels between Na and K in the study area, H<sub>1</sub><sub>b</sub>: there is significant difference in the concentration levels between Na and K in the study area. Six locations were used to collect samples with the aid of scoop and gravel free auger (at varying depths of 0 - 5 cm and 5 - 10 cm) which are Wellington Industrial Estate Area 1 (WIEL 1), (WIEL 2), (WIEL 3), (WIEL 4), (WIEL 5), (WIEL 6);the samples were given laboratory treatment. Flame photometer, EDTA, and Spectrophotometer were used in the determinations of sodium and potassium, calcium and magnesium, and available iron respectively. The results indicated that levels of potassium were in medium range (moderately high);sodium levels were generally low when compared to Brook’s classification table. Levels of calcium were generally low and those of magnesium were moderate based on Brook’s table of classification. Levels of available iron which fall within the range of Quijano-Guerta (2003) were high;this implies such levels can lead to toxicity. In all locations, there was decrease in the levels of each metal in the samples with (5 - 10 cm) depth.展开更多
Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ...Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ability of particulate matter allows EPFRs to migrate over long-distance transport,thereby impacting the quality of the local atmospheric environment.Additionally,EPFRs can also adhere to atmospheric particles and interact with typical gaseous pollutants to affect atmospheric chemical reactions.EPFRs can produce some reactive organic species,promoting oxidative stress in the human body,damaging biological macromolecules and ultimately affecting the organism health.EPFRs are considered as a novel type of pollutant that affects human health.Despite their significance,there are few literatures available on the characteristics and fate behaviors of EPFRs up to date.Therefore,supplemental reviews are crucial for providing comprehensive understanding of EPFRs.Materials and methods This review summarizes the characteristics of EPFRs in particulate matter,outlines the generation mechanism and influencing factors of EPFRs,and the impacts of EPFRs on environmental quality and organism health.Results The content of EPFRs in particulate matter ranges from 1017 to 1020 spins∙g−1.Due to the strong mobility of atmospheric particulate matter,the long-term exposure to high levels of EPFRs may aggravate the impact of particulate matter on human health.The interaction between EPFRs and typical gaseous pollutants can alter their fate and influence atmospheric chemical reactions.EPFRs are mainly produced by transition metal elements and substituted aromatic hydrocarbons through electron transfer.Additionally,the chemical bond rupture of organic substances through heat treatment or ultraviolet radiation can also produce EPFRs,and heterogeneous reactions are capable producing them as well.The production of EPFRs is not only influenced by transition metal elements and precursors,but also by various environmental factors such as oxygen,temperature,light radiation,and relative humidity.Discussion EPFRs in atmospheric particulates matters are usually rich in fine particulates with obvious seasonal and regional variations.They can easily enter the human respiratory tract and lungs with inhalable particulates,thereby increasing the risk of exposure.Additionally,EPFRs in atmospheric particulates can interact with some typical gaseous pollutants,impacting the life and fate of EPFRs in the atmosphere,and alter atmospheric chemical reactions.Traditionally,EPFRs are generated by transition metal elements and substituted aromatic hydrocarbons undergoing electron transfer in the post-flame and cool-zone regions of combustion systems and other thermal processes to remove HCl,H2O or CO groups,ultimately produce semiquinones,phenoxyls,and cyclopentadienyls.Recent studies have indicated that EPFRs can also be generated under the conditions of without transition metal elemental.Organics can also produce EPFRs through chemical bond rupture during heat treatment or light radiation conditions,as well as through some heterogeneous reactions and photochemical secondary generation of EPFRs.The presence or absence of oxygen has different effects on the type and yield of EPFRs.The concentration,type,and crystal type of transition metal elements will affect the type,content,and atmospheric lifetime of EPFRs.It is generally believed that the impact of transition metal element types on EPFRs is related to the oxidation-reduction potential.The combustion temperature or heat treatment process significantly affects the type and amount of EPFRs.Factors such as precursor loading content,pH conditions,light radiation and relative humidity also influence the generation of EPFRs.EPFRs can interact with pollutants in the environment during their migration and transformation process in environmental medium.This process accelerates the degradation of pollutants and plays a crucial role in the migration and transformation of organic pollutants in environmental media.The reaction process of EPFRs may lead to the production of reactive oxygen species(ROS)such as∙OH,which can induce oxidative stress,inflammation and immune response to biological lung cells and tissues,leading to chronic respiratory and cardiopulmonary dysfunction,cardiovascular damage and neurotoxic effects,ultimately impacting the health of organisms.Conclusions The interaction mechanism between EPFRs in particulate matter and gaseous pollutants remains unclear.Furthermore,research on the generation mechanism of EPFRs without the participation of transition metals is not comprehensive,and the detection of EPFRs is limited to simple qualitative categories and lack accurate qualitative analysis.Recommendations and perspectives Further research should be conducted on the generation mechanism,measurement techniques,migration pathways,and transformation process of EPFRs.It is also important to explore the interaction between EPFRs in atmospheric particulate matter and typical gaseous pollutants.展开更多
Air pollution is a result of multiple sources including both natural and anthropogenic activities. The rapid urbanization of the cities such as Bujumbura, economic capital of Burundi, is one of these factors. The very...Air pollution is a result of multiple sources including both natural and anthropogenic activities. The rapid urbanization of the cities such as Bujumbura, economic capital of Burundi, is one of these factors. The very first characterization of the spatio-temporal variability of PM<sub>2.5</sub> in Bujumbura and the forecasting of PM<sub>2.5</sub> concentration have been conducted in this paper using data collected during a year, from August 2022 to August 2023, by low-cost sensors installed in Bujumbura city. For each commune, an hourly, daily and seasonal analysis was carried out and the results showed that the mass concentrations of PM<sub>2.5</sub> in the three municipalities differ from one commune to another. The average hourly and annual PM<sub>2.5</sub> concentrations exceed the World Health Organization standards. The range is between 28.3 and 35.0 μg/m<sup>3</sup>. In order to make a prediction of PM<sub>2.5</sub> concentration, an investigation of Recurrent Neural Networks with Long Short-Term Memory has been undertaken.展开更多
In the present work, the different sample collection, pretreatment and analytical methods for polycyclic aromatic hydrocarbons (PAHs) in airborne particulates is systematacially reviewed, and the applications of the...In the present work, the different sample collection, pretreatment and analytical methods for polycyclic aromatic hydrocarbons (PAHs) in airborne particulates is systematacially reviewed, and the applications of these pretreatment and analytical methods for PAHs are compared in detail. Some comments on the future expectation are also presented.展开更多
This work mainly focuses on the mineralogical study of particulate matter(PM10) in Beijing. Samples were collected on polycarbonate filter from April, 2002 to March, 2003 in Beijing urban area. Scanning electronic m...This work mainly focuses on the mineralogical study of particulate matter(PM10) in Beijing. Samples were collected on polycarbonate filter from April, 2002 to March, 2003 in Beijing urban area. Scanning electronic microscopy coupled with energy dispersive X-ray(SEM/EDX) was used to investigate individual mineral particles in Beijing PM10. 1454 individual mineral particulates from 48 samples were analysed by SEM/EDX. The results revealed that mineral particulates were complex and heterogeneous. 38 kinds of minerals in PM10 were identified. The clay minerals, of annual average percentage of 30.1%, were the main composition among the identified minerals, and illite/smectite was the main composition in clay minerals, reaching up to 35%. Annual average percentage of quartz, calcite, compound particulates, carbonates were 13.5%, 10.9%, 11.95%, 10.31%, respectively. Annual average percentage less than 10% were gypsum, feldspar, dolomite, and so on. Fluorite, apatite, halite, barite and chloridize zinc(ZnCl2) were firstly identified in Beijing PM10. Sulfurization was found on surface of mineral particles, suggested extensive atmospheric reaction in air during summer.展开更多
Objective To investigate the antagonistic effects of different doses of Lianhua Qingwen on pulmonary injury induced by fine particulates PM2.5 in rats. Methods Fine particulates suspended in the environment were colle...Objective To investigate the antagonistic effects of different doses of Lianhua Qingwen on pulmonary injury induced by fine particulates PM2.5 in rats. Methods Fine particulates suspended in the environment were collected. Forty-eight healthy adult wistar rats were randomly divided into 6 groups with 8 rats in each group. Four groups of rats were exposed to PM2.5 by intratracheally dripping suspensions of fine particulates PM2.5(7.5 mg/kg) as dust-exposed model rats. Among them 24 rats in three groups received Lianhua Qingwen treatment(crude drug) at a dose of 2 g/kg, 4 g/kg, 8 g/kg per day for 3 days before dust exposure and were defined as low-dose, middle-dose and high-dose Lianhua Qingwen treatment groups respectively. The other dust-exposed model rats without treatment were assigned as PM2.5 control group. The un-exposed rats were set as saline control group(1.5 ml/kg saline) and blank control group. All rats were killed after 24 hours of the exposure. Lung tissue, serum and bronchoalveolar lavage fluid(BALF) were collected. The levels of malonaldehyde(MDA), lactate dehydrogenase(LDH), and glutathione peroxidase(GSH-PX) in blood serum and BALF, and superoxide dismutase(SOD) in blood surum were measured using fluorescent quantitation PCR; Expression of NF-E2-related factor 2(NRF-2), heme oxygenase 1(HO-1) and quinone oxidoreductase 1(NQO1) in lung tissues were measured using Western blot. Pathological changes of lung tissues in each group were also examined. Results Pathology revealed thickened alveolar septum, congestion of capillary, interstitial edema and infiltration of lymphocyte and neutrophil surrounding bronchiole in the PM2.5 control group, which weresignificantly relieved in the Lianhua Qingwen treatment groups. Compared to the blank and saline control groups, the PM2.5 control group had significantly higher levels of LDH and MDA(p<0.01) and lower level of GSH-PS(p<0.01) in BALF, significantly higher levels of LDH and MDA(p<0.05) and lower level of GSH-PS(p<0.05) in rat serum. The levels of MDA in blood serum and BALF were significantly lower in each treatment group than that in PM2.5 control group(all P<0.05). In both middle-dose and high-dose treatment group the measurements of LDH in serum and BALF as well as GSH-PX in serum were significant difference from those of PM2.5 control group(all P<0.05). Expressions of NRF-2, HO-1 and NQO1 in lung tissues were significantly different among middle-dose and high-dose treatment group compared with those in PM2.5 control group(all P<0.05). Conclusion Fine particulates PM2.5 in environment may induce pulmonary oxidative lesions in rats. Middle-dose and high-dose Lianhua Qingwen has antagonist effece on the injuries induced by fine particulates.展开更多
Aging behaviors of submicron Al2O3p/6061 composite were investigated by Vickers hardness (HV) measurement and transmission electron microscope (TEM) observation. The results showed that there was an idiographic micros...Aging behaviors of submicron Al2O3p/6061 composite were investigated by Vickers hardness (HV) measurement and transmission electron microscope (TEM) observation. The results showed that there was an idiographic microstructure and aging characteristic in the composite. Addition of fine Al2O3 particulates would strongly restrain the precipitation and reduce the thermal mismatch dislocation density due to the difference of coefficient of thermal expansion (CTE) between the matrix and the reinforcemertt.展开更多
Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent sus...Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent susceptibility (Xfd) showed the absence of superparamagnetic (SP) grains in the samples. The IRM20mT (isothermal remanent magnetization at 20 mT) being linearly proportional to SIRM (saturation isothermal remanent magnetization) (R^2=0.901), suggested that ferrimagnetic minerals were responsible for the magnetic properties of automobile emission particulates. The average contents of Cu, Cd, Pb and Fe in automobile emission particulates were 95.83, 22.14, 30.58 and 34727.31 mg/kg, respectively. Significant positive correlations exist between the magnetic parameters and the contents ofPb, Cu and Fe. The magnetic parameters of automobile emission particulates reflecting concentration of magnetic particles increased linearly with increase of Pb and Cu content, showed that the magnetic measurement could be used as a preliminary index for detection of Pb and Cu pollution.展开更多
A new dual-layer granular bed filter for hot gas cleanup was invented and studied experimentally. Fine sand,0.5-1 mm grain size and about 1350 kg/m3 bulk density,was used as the lower layer of the filter. Expanded per...A new dual-layer granular bed filter for hot gas cleanup was invented and studied experimentally. Fine sand,0.5-1 mm grain size and about 1350 kg/m3 bulk density,was used as the lower layer of the filter. Expanded perlite par-ticles,2-5 mm grain size and about 70 kg/m3 bulk density,was used for the upper layer of the filter in this study. It was confirmed that the sizes and densities of these two media matched well; the binary media remained in complete segre-gation during regeneration by fluidization. Test results show that the filtration of the expanded perlite particle layer was characterized as "deep bed filtration." Filtration of the fine sand layer was "surface cake filtration." The expanded per-lite particle layer contributed about 90% to the bed dust capacity,but only about 20% to the total bed pressure drop,which increased the bed dust capacity ten fold compared to a single-layer bed of the same sand and the same total bed pressure drop. The dust cake on the surface of the fine sand layer raised the collection efficiencies to over 99.99%.展开更多
The microstructure of laser welds of sub-micron particulate-reinforced aluminum matrix composite Al_2O_(3p)/6061Al and the weldability of the material were studied. Experimental results indicated that because of the h...The microstructure of laser welds of sub-micron particulate-reinforced aluminum matrix composite Al_2O_(3p)/6061Al and the weldability of the material were studied. Experimental results indicated that because of the huge specific surface area of the reinforcement, the interfacial reaction between the matrix and the reinforcement was re- strained intenslvely at elevated temperature and pulsed laser beam. The main factor affecting the weldability of the com- posite was the reinforcement segregation in the weld resulting from the push of the liquid/solid interface during the soli- dification of the molten pool. The laser pulse frequency directly affected the reinforcement segregation and the reinfor- cement distribution in the weld, so that the weldability of the composite could be improved by increasing the laser pulse frequency. On the basis of this, a satisfactory welded joint of sub-micron paniculate-reinforced aluminum matrix com- posite Al_2O_(3p)/6061Al was obtained by using appopriate welding parameters.展开更多
A study was made of influences of vacuum-baking treatment to SiC particulates on preparing cast Al-martix composite. By means of quadripole mass analyser(QMA), gases absorbed on the surface of SiC particulate have bee...A study was made of influences of vacuum-baking treatment to SiC particulates on preparing cast Al-martix composite. By means of quadripole mass analyser(QMA), gases absorbed on the surface of SiC particulate have been investigated, it is found that gases and pollutants absorbed on the surface prohibit SiC particulates from uniformly dispersing in the alloy melt.展开更多
Voluminously epidemiological studies show that the relationships exist between the air pollution and human health and cancer. Aromatic hydrocarbons (AHs) in air form a large class of organic pollutants, which are wi...Voluminously epidemiological studies show that the relationships exist between the air pollution and human health and cancer. Aromatic hydrocarbons (AHs) in air form a large class of organic pollutants, which are widely in environment and many of them are known to be carcinogenic and/or mutagenic and contribute to ambient air pollution. In the past decades, bioassays mainly have been used to evaluate the toxicity of chemical mixtures in atmospheric particulates or aqueous environment. However, it is well known that the covalent complexes formed by carcinogens with DNA may be exert negative results in bioassay. So the main aim of this paper is to develop an evaluation method of toxicity effects of chemical mixtures in atmospheric particulates from chemical standpoint. In this study, the in vitro interaction of the AHs with DNA was investigated by absorption, fluorescence and resonance light scattering (RLS) spectroscopic techniques. The results showed that the AHs in the atmospheric particulates could combine with calf thymus DNA (ctDNA) and herring sperm DNA (hsDNA) without being activated or metabolized by organism, respectively. Intercalation may be present in the mechanism of interaction. The binding constants of the AHs with ctDNA and hsDNA were 2.5x102 and 2.0x103, respectively, which indicated that the interaction of the AHs with hsDNA is stronger than that with ctDNA. In addition, the relationships of dose-effect between the total mole concentration of chemical components and the ability of binding ctDNA and hsDNA were confirmed. This research made it possible to study the toxicity effects of chemical mixtures in atmospheric particulates by chemical method. It is believed that the composition and contents of unknown AHs and the interaction of DNA with AHs in atmospheric particulates of Xigu District of Lanzhou City, China are first reported in the past twenty years.展开更多
Seven polycyclic aromatic hydrocarbons (PAHs) in atmospheric particulates were determinated by high performance liquid chromatography (HPLC) with fluorescence detector using direction injection and an on-line enri...Seven polycyclic aromatic hydrocarbons (PAHs) in atmospheric particulates were determinated by high performance liquid chromatography (HPLC) with fluorescence detector using direction injection and an on-line enrichment trap column. The method simplified the sample pretreatment, saved time and increased the efficiency. With the on-line trap column, PAHs were separated availably even underground injecting 1.0 ml sample with relatively high column efficiency. The recoveries of the seven PAHs were from 85% to 120% for spiked atmospheric particulate sample. The limit of detection was 15.3-39.6 ng/L (S/N=3.3). There were good linear correlations between the peak areas and concentrations of the seven kinds of PAHs in the range of 1-50 ng/ml with the correlation coefficients over 0.9970. Furthermore, it also indicated that the method is available to determine PAHs in atmospheric particulates well.展开更多
Based on on-line single particle aerosol mass spectrometry (SPAMS) with high time resolution, the sources of atmospheric fine particu- late matter in Nan'ao County were analyzed. The results showed that during the ...Based on on-line single particle aerosol mass spectrometry (SPAMS) with high time resolution, the sources of atmospheric fine particu- late matter in Nan'ao County were analyzed. The results showed that during the monitoring period from March 24 to 27 in 2015, the primary source of fine particulate matter in Nao'ao County was motor vehicle exhaust, that is, 24.7% of fine particulates were from motor vehicle exhaust, followed by biomass burning (17.2%), fire coal (17.2%), and sea salt (13.3%). The proportions of fire coal and sea salt revealed the peculiarity of sources of atmospheric fine particulate matter in Nan'ao County. Therefore, it is suggested that some measures should be adopted to limit tourist traffic to reduce the adverse impact of motor vehicle exhaust on ambient air quality in Nan'ao County.展开更多
Objective This study aimed to use an air-liquid interface(ALI)exposure system to simulate the inhalation exposure of motorcycle exhaust particulates(MEPs)and then investigate the benchmark dose(BMD)of MEPs by evaluati...Objective This study aimed to use an air-liquid interface(ALI)exposure system to simulate the inhalation exposure of motorcycle exhaust particulates(MEPs)and then investigate the benchmark dose(BMD)of MEPs by evaluating cell relative viability(CRV)in lung epithelial BEAS-2B cells.Methods The MEPs dose was characterized by measuring the number concentration(NC),surface area concentration(SAC),and mass concentration(MC).BEAS-2B cells were exposed to MEPs at different concentrations via ALI and CRV was determined using Cell Counting Kit(CCK-8)assay.BMD software was applied to calculate BMD and the lower limit of benchmark dose(BMDL)according to Akaike Information Coefficient(AIC),with P-value based on Hill,Linear,Polynomial,and Power model.Results Our results reveal that BMD of NC and SAC were estimated by the best-fitting Hill model,while MC was estimated by Polynomial model.The BMDL for CRV following ALI exposure to MEPs were as follows:364.2#/cm^(3)for NC;0.662×10^(7)nm^(2)/cm^(3)for SAC;and 0.278μg/m^(3)for MC.Conclusion These results indicate that MEPs exposure via ALI system induces a dose-dependent decrease of CRV and provides the potential exposure threshold of MEPs in a lung cell model.展开更多
This study presents an investigation of the scattering and backscattering properties of the particulates in three Chinese inland lakes(the Taihu Lake, the Chaohu Lake and the Dianchi Lake) based on in situ measurement...This study presents an investigation of the scattering and backscattering properties of the particulates in three Chinese inland lakes(the Taihu Lake, the Chaohu Lake and the Dianchi Lake) based on in situ measurements taken at 119 sites. We modeled the particulate scattering spectra using a wavelength-dependent power-law function, finding that the power-law exponents in the Taihu Lake and the Chaohu Lake differ from those in the Dianchi Lake but are similar to the values in the U.S. coastal waters. In contrast to the open ocean, the backscattering properties in the three lakes can not be determined only from chlorophyll-a concentration. The backscattering ratio spectra exhibit a wavelength dependence feature in all three lakes, generally decreasing with the increasing wavelength. Analysis results of the correlations between the backscattering ratio and the individual water quality parameters clearly show that there are distinctive relations among the three lakes, attributed primarily to different compositions of optically active materials in the three lakes. Analysis of the mass-specific scattering and backscattering coefficients shows that the coefficients at wavelength 532 nm in the Taihu Lake and Chaohu Lake are similar, but they are apparently different from those in the Dianchi Lake. Lastly, Model I multiple linear regressions were adopted to partition the mass-specific cross-sections for scattering and backscattering into organic and inorganic cross-sections to further interpret the scattering and backscattering properties. The relative contribution of organic and inorganic particulates to scattering and backscattering is clearly different among the three lakes. The scattering and backscattering properties of the particulates in the three inland lakes vary significantly based on our collected data. The results indicated that the existing semi-analytical water quality retrieval models of the Taihu Lake can not be applied perfectly to the Chaohu Lake and the Dianchi Lake.展开更多
A method was developed for the determination of trace arsenic by spectrophotometry. The proposed method is rapid, simple, and inexpensive. This method can be used for sensitive determination of trace arsenic in enviro...A method was developed for the determination of trace arsenic by spectrophotometry. The proposed method is rapid, simple, and inexpensive. This method can be used for sensitive determination of trace arsenic in environmental samples and especially in air particulates. The results obtained by this method as a proposed method were compared with those obtained by hydride generation atomic absorption spectrometry as a popular reported method for the determination of arsenic and an excellent agreement was found between them. The method was also used for determination of arsenic associated with airborne particulate matter and diesel exhaust particulates. The results showed that considerable amount of arsenic are associated with diesel engine particulates. The variation in concentration of arsenic was also investigated. The atmospheric concentration of arsenic was different in different sampling stations was dependent to the traffic density.展开更多
基金supported by National Key Research and Development Program of China(2018YFE0115300,2022YFC3600800,2017YFC0211706)Chinese Academy of Medical Sciences(CAMS)Innovation Fund for Medical Sciences(2021-I2M-1-010)+3 种基金National Natural Science Foundation of China(82073658,82070473)National High Level Hospital Clinical Research Funding(2022-GSP-GG-1,2022-GSP-GG-2)Research Unit of Prospective Cohort of Cardiovascular Diseases and Cancers,CAMS(2019RU038)National Clinical Research Center for Cardiovascular Diseases,Fuwai Hospital,CAMS(NCRC2020006)。
文摘Objective In recent decades,China has implemented a series of policies to address air pollution.We aimed to assess the health effects of these policies on stroke burden attributable to ambient fine particulate matter(PM_(2.5)).Methods Joinpoint regression was applied to explore the temporal tendency of stroke burden based on data from the Global Burden of Disease 2019 study.Results The age-standardized rates of disability-adjusted life year(DALY)for stroke attributable to ambient PM2.5 in China,increased dramatically during 1990-2012,subsequently decreased at an annual percentage change(APC)of-1.98[95% confidence interval(CI):-2.26,-1.71]during 2012-2019.For ischemic stroke(IS),the age-standardized DALY rates doubled from 1990 to 2014,and decreased at an APC of-0.83(95%CI:-1.33,-0.33)during 2014-2019.Intracerebral hemorrhage(ICH)showed a substantial increase in age-standardized DALY rates from 1990 to 2003,followed by declining trends,with APCs of-1.46(95%CI:-2.74,-0.16)during 2003-2007 and-3.33(95%CI:-3.61,-3.06)during 2011-2019,respectively.Conversely,the age-standardized DALY rates for subarachnoid hemorrhage(SAH)generally declined during 1990-2019.Conclusion Our results clarified the dynamic changes of the ambient PM_(2.5)-attributable stroke burden in China during 1990-2019,highlighting the health effects of air quality improvement policies.
基金This work was supported financially by Korea Environment Industry&Technology Institute through Project to make multi-ministerial national biological research resources more advanced program,funded by Korea Ministry of Environment(grant number RS-2023-00230403).
文摘Objective:To evaluate the effect of the ethyl acetate fraction derived from Sargassum pallidum extract against particulate matter(PM)-induced oxidative stress and inflammation in HaCaT cells and zebrafish.Methods:HaCaT cells and zebrafish were used to evaluate the protective effects of the ethyl acetate fraction of Sargassum pallidum extract against PM-induced oxidative stress and inflammation.The production of nitric oxide(NO),intracellular ROS,prostaglandin E_(2)(PGE_(2)),and pro-inflammatory cytokines,and the expression levels of COX-2,iNOS,and NF-κB were evaluated in PM-induced HaCaT cells.Furthermore,the levels of ROS,NO,and lipid peroxidation were assessed in the PM-exposed zebrafish model.Results:The ethyl acetate fraction of Sargassum pallidum extract significantly decreased the production of NO,intracellular ROS,and PGE_(2) in PM-induced HaCaT cells.In addition,the fraction markedly suppressed the levels of pro-inflammatory cytokines and inhibited the expression levels of COX-2,iNOS,and NF-κB.Furthermore,it displayed remarkable protective effects against PM-induced inflammatory response and oxidative stress,represented by the reduction of NO,ROS,and lipid peroxidation in zebrafish.Conclusions:The ethyl acetate fraction of Sargassum pallidum extract exhibits a protective effect against PM-induced oxidative stress and inflammation both in vitro and in vivo and has the potential as a candidate for the development of pharmaceutical and cosmeceutical products.
基金support of the National Key Research and Development Program of China(2022YFE0206600)the National Natural Science Foundation of China(52376125)Fundamental Research Funds for the Central Universities.
文摘Oxy-combustion is a promising carbon-capture technology,but atmospheric-pressure oxy-combustion has a relatively low net efficiency,limiting its application in power plants.In pressurized oxycombustion(POC),the boiler,air separation unit,flue gas recirculation unit,and CO_(2)purification and compression unit are all operated at elevated pressure;this makes the process more efficient,with many advantages over atmospheric pressure,such as low NO_(x)emissions,a smaller boiler size,and more.POC is also more promising for industrial application and has attracted widespread research interest in recent years.It can produce high-pressure CO_(2)with a purity of approximately 95%,which can be used directly for enhanced oil recovery or geo-sequestration.However,the pollutant emissions must meet the standards for carbon capture,storage,and utilization.Because of the high oxygen and moisture concentrations in POC,the formation of acids via the oxidation and solution of SO_(x)and NO_(x)can be increased,causing the corrosion of pipelines and equipment.Furthermore,particulate matter(PM)and mercury emissions can harm the environment and human health.The main distinction between pressurized and atmospheric-pressure oxy-combustion is the former’s elevated pressure;thus,the effect of this pressure on the pollutants emitted from POC—including SO_(x),NO_(x),PM,and mercury—must be understood,and effective control methodologies must be incorporated to control the formation of these pollutants.This paper reviews recent advances in research on SO_(x),NO_(x),PM,and mercury formation and control in POC systems that can aid in pollutant control in such systems.
文摘This research study explored the levels of base status metals in soil sediments and particulate matter in the wellington industrial estate location;the main objectives were to: 1) determine sodium and potassium, 2) determine calcium and magnesium, 3) determine available iron. The following hypotheses were put forward;H<sub>0</sub><sub>a</sub>: there is no significant difference in the concentration levels between Ca and Mg in the study area, H<sub>1</sub><sub>a</sub>: there is significant difference in the concentration levels between Ca and Mg in the study area, H<sub>0</sub><sub>b</sub>: there is no significant difference in the concentration levels between Na and K in the study area, H<sub>1</sub><sub>b</sub>: there is significant difference in the concentration levels between Na and K in the study area. Six locations were used to collect samples with the aid of scoop and gravel free auger (at varying depths of 0 - 5 cm and 5 - 10 cm) which are Wellington Industrial Estate Area 1 (WIEL 1), (WIEL 2), (WIEL 3), (WIEL 4), (WIEL 5), (WIEL 6);the samples were given laboratory treatment. Flame photometer, EDTA, and Spectrophotometer were used in the determinations of sodium and potassium, calcium and magnesium, and available iron respectively. The results indicated that levels of potassium were in medium range (moderately high);sodium levels were generally low when compared to Brook’s classification table. Levels of calcium were generally low and those of magnesium were moderate based on Brook’s table of classification. Levels of available iron which fall within the range of Quijano-Guerta (2003) were high;this implies such levels can lead to toxicity. In all locations, there was decrease in the levels of each metal in the samples with (5 - 10 cm) depth.
文摘Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ability of particulate matter allows EPFRs to migrate over long-distance transport,thereby impacting the quality of the local atmospheric environment.Additionally,EPFRs can also adhere to atmospheric particles and interact with typical gaseous pollutants to affect atmospheric chemical reactions.EPFRs can produce some reactive organic species,promoting oxidative stress in the human body,damaging biological macromolecules and ultimately affecting the organism health.EPFRs are considered as a novel type of pollutant that affects human health.Despite their significance,there are few literatures available on the characteristics and fate behaviors of EPFRs up to date.Therefore,supplemental reviews are crucial for providing comprehensive understanding of EPFRs.Materials and methods This review summarizes the characteristics of EPFRs in particulate matter,outlines the generation mechanism and influencing factors of EPFRs,and the impacts of EPFRs on environmental quality and organism health.Results The content of EPFRs in particulate matter ranges from 1017 to 1020 spins∙g−1.Due to the strong mobility of atmospheric particulate matter,the long-term exposure to high levels of EPFRs may aggravate the impact of particulate matter on human health.The interaction between EPFRs and typical gaseous pollutants can alter their fate and influence atmospheric chemical reactions.EPFRs are mainly produced by transition metal elements and substituted aromatic hydrocarbons through electron transfer.Additionally,the chemical bond rupture of organic substances through heat treatment or ultraviolet radiation can also produce EPFRs,and heterogeneous reactions are capable producing them as well.The production of EPFRs is not only influenced by transition metal elements and precursors,but also by various environmental factors such as oxygen,temperature,light radiation,and relative humidity.Discussion EPFRs in atmospheric particulates matters are usually rich in fine particulates with obvious seasonal and regional variations.They can easily enter the human respiratory tract and lungs with inhalable particulates,thereby increasing the risk of exposure.Additionally,EPFRs in atmospheric particulates can interact with some typical gaseous pollutants,impacting the life and fate of EPFRs in the atmosphere,and alter atmospheric chemical reactions.Traditionally,EPFRs are generated by transition metal elements and substituted aromatic hydrocarbons undergoing electron transfer in the post-flame and cool-zone regions of combustion systems and other thermal processes to remove HCl,H2O or CO groups,ultimately produce semiquinones,phenoxyls,and cyclopentadienyls.Recent studies have indicated that EPFRs can also be generated under the conditions of without transition metal elemental.Organics can also produce EPFRs through chemical bond rupture during heat treatment or light radiation conditions,as well as through some heterogeneous reactions and photochemical secondary generation of EPFRs.The presence or absence of oxygen has different effects on the type and yield of EPFRs.The concentration,type,and crystal type of transition metal elements will affect the type,content,and atmospheric lifetime of EPFRs.It is generally believed that the impact of transition metal element types on EPFRs is related to the oxidation-reduction potential.The combustion temperature or heat treatment process significantly affects the type and amount of EPFRs.Factors such as precursor loading content,pH conditions,light radiation and relative humidity also influence the generation of EPFRs.EPFRs can interact with pollutants in the environment during their migration and transformation process in environmental medium.This process accelerates the degradation of pollutants and plays a crucial role in the migration and transformation of organic pollutants in environmental media.The reaction process of EPFRs may lead to the production of reactive oxygen species(ROS)such as∙OH,which can induce oxidative stress,inflammation and immune response to biological lung cells and tissues,leading to chronic respiratory and cardiopulmonary dysfunction,cardiovascular damage and neurotoxic effects,ultimately impacting the health of organisms.Conclusions The interaction mechanism between EPFRs in particulate matter and gaseous pollutants remains unclear.Furthermore,research on the generation mechanism of EPFRs without the participation of transition metals is not comprehensive,and the detection of EPFRs is limited to simple qualitative categories and lack accurate qualitative analysis.Recommendations and perspectives Further research should be conducted on the generation mechanism,measurement techniques,migration pathways,and transformation process of EPFRs.It is also important to explore the interaction between EPFRs in atmospheric particulate matter and typical gaseous pollutants.
文摘Air pollution is a result of multiple sources including both natural and anthropogenic activities. The rapid urbanization of the cities such as Bujumbura, economic capital of Burundi, is one of these factors. The very first characterization of the spatio-temporal variability of PM<sub>2.5</sub> in Bujumbura and the forecasting of PM<sub>2.5</sub> concentration have been conducted in this paper using data collected during a year, from August 2022 to August 2023, by low-cost sensors installed in Bujumbura city. For each commune, an hourly, daily and seasonal analysis was carried out and the results showed that the mass concentrations of PM<sub>2.5</sub> in the three municipalities differ from one commune to another. The average hourly and annual PM<sub>2.5</sub> concentrations exceed the World Health Organization standards. The range is between 28.3 and 35.0 μg/m<sup>3</sup>. In order to make a prediction of PM<sub>2.5</sub> concentration, an investigation of Recurrent Neural Networks with Long Short-Term Memory has been undertaken.
基金Project supported by the National Natural Science Foundation of China (No. 20437020 20575073) NSFC-JSPS Joint Research Project (No. 20511140134) the Major Research Program of Chinese Academy of Sciences (KZCX3-SW-432)
文摘In the present work, the different sample collection, pretreatment and analytical methods for polycyclic aromatic hydrocarbons (PAHs) in airborne particulates is systematacially reviewed, and the applications of these pretreatment and analytical methods for PAHs are compared in detail. Some comments on the future expectation are also presented.
基金The National Natural Science Foundation of China(No.40275040) and the Shanghai Leading Academic Disciplines(No. T0105)
文摘This work mainly focuses on the mineralogical study of particulate matter(PM10) in Beijing. Samples were collected on polycarbonate filter from April, 2002 to March, 2003 in Beijing urban area. Scanning electronic microscopy coupled with energy dispersive X-ray(SEM/EDX) was used to investigate individual mineral particles in Beijing PM10. 1454 individual mineral particulates from 48 samples were analysed by SEM/EDX. The results revealed that mineral particulates were complex and heterogeneous. 38 kinds of minerals in PM10 were identified. The clay minerals, of annual average percentage of 30.1%, were the main composition among the identified minerals, and illite/smectite was the main composition in clay minerals, reaching up to 35%. Annual average percentage of quartz, calcite, compound particulates, carbonates were 13.5%, 10.9%, 11.95%, 10.31%, respectively. Annual average percentage less than 10% were gypsum, feldspar, dolomite, and so on. Fluorite, apatite, halite, barite and chloridize zinc(ZnCl2) were firstly identified in Beijing PM10. Sulfurization was found on surface of mineral particles, suggested extensive atmospheric reaction in air during summer.
文摘Objective To investigate the antagonistic effects of different doses of Lianhua Qingwen on pulmonary injury induced by fine particulates PM2.5 in rats. Methods Fine particulates suspended in the environment were collected. Forty-eight healthy adult wistar rats were randomly divided into 6 groups with 8 rats in each group. Four groups of rats were exposed to PM2.5 by intratracheally dripping suspensions of fine particulates PM2.5(7.5 mg/kg) as dust-exposed model rats. Among them 24 rats in three groups received Lianhua Qingwen treatment(crude drug) at a dose of 2 g/kg, 4 g/kg, 8 g/kg per day for 3 days before dust exposure and were defined as low-dose, middle-dose and high-dose Lianhua Qingwen treatment groups respectively. The other dust-exposed model rats without treatment were assigned as PM2.5 control group. The un-exposed rats were set as saline control group(1.5 ml/kg saline) and blank control group. All rats were killed after 24 hours of the exposure. Lung tissue, serum and bronchoalveolar lavage fluid(BALF) were collected. The levels of malonaldehyde(MDA), lactate dehydrogenase(LDH), and glutathione peroxidase(GSH-PX) in blood serum and BALF, and superoxide dismutase(SOD) in blood surum were measured using fluorescent quantitation PCR; Expression of NF-E2-related factor 2(NRF-2), heme oxygenase 1(HO-1) and quinone oxidoreductase 1(NQO1) in lung tissues were measured using Western blot. Pathological changes of lung tissues in each group were also examined. Results Pathology revealed thickened alveolar septum, congestion of capillary, interstitial edema and infiltration of lymphocyte and neutrophil surrounding bronchiole in the PM2.5 control group, which weresignificantly relieved in the Lianhua Qingwen treatment groups. Compared to the blank and saline control groups, the PM2.5 control group had significantly higher levels of LDH and MDA(p<0.01) and lower level of GSH-PS(p<0.01) in BALF, significantly higher levels of LDH and MDA(p<0.05) and lower level of GSH-PS(p<0.05) in rat serum. The levels of MDA in blood serum and BALF were significantly lower in each treatment group than that in PM2.5 control group(all P<0.05). In both middle-dose and high-dose treatment group the measurements of LDH in serum and BALF as well as GSH-PX in serum were significant difference from those of PM2.5 control group(all P<0.05). Expressions of NRF-2, HO-1 and NQO1 in lung tissues were significantly different among middle-dose and high-dose treatment group compared with those in PM2.5 control group(all P<0.05). Conclusion Fine particulates PM2.5 in environment may induce pulmonary oxidative lesions in rats. Middle-dose and high-dose Lianhua Qingwen has antagonist effece on the injuries induced by fine particulates.
文摘Aging behaviors of submicron Al2O3p/6061 composite were investigated by Vickers hardness (HV) measurement and transmission electron microscope (TEM) observation. The results showed that there was an idiographic microstructure and aging characteristic in the composite. Addition of fine Al2O3 particulates would strongly restrain the precipitation and reduce the thermal mismatch dislocation density due to the difference of coefficient of thermal expansion (CTE) between the matrix and the reinforcemertt.
基金Project supported by the National Natural Science Foundation of China (No. 40371056)the Foundation for the Author of NationalExcellent Doctoral Dissertation of China (No. 200149)
文摘Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent susceptibility (Xfd) showed the absence of superparamagnetic (SP) grains in the samples. The IRM20mT (isothermal remanent magnetization at 20 mT) being linearly proportional to SIRM (saturation isothermal remanent magnetization) (R^2=0.901), suggested that ferrimagnetic minerals were responsible for the magnetic properties of automobile emission particulates. The average contents of Cu, Cd, Pb and Fe in automobile emission particulates were 95.83, 22.14, 30.58 and 34727.31 mg/kg, respectively. Significant positive correlations exist between the magnetic parameters and the contents ofPb, Cu and Fe. The magnetic parameters of automobile emission particulates reflecting concentration of magnetic particles increased linearly with increase of Pb and Cu content, showed that the magnetic measurement could be used as a preliminary index for detection of Pb and Cu pollution.
基金Projects 2006C23075 supported by the Key Research Project of Zhejiang Province02J20101-19 by the Science Foundation of Ningbo City
文摘A new dual-layer granular bed filter for hot gas cleanup was invented and studied experimentally. Fine sand,0.5-1 mm grain size and about 1350 kg/m3 bulk density,was used as the lower layer of the filter. Expanded perlite par-ticles,2-5 mm grain size and about 70 kg/m3 bulk density,was used for the upper layer of the filter in this study. It was confirmed that the sizes and densities of these two media matched well; the binary media remained in complete segre-gation during regeneration by fluidization. Test results show that the filtration of the expanded perlite particle layer was characterized as "deep bed filtration." Filtration of the fine sand layer was "surface cake filtration." The expanded per-lite particle layer contributed about 90% to the bed dust capacity,but only about 20% to the total bed pressure drop,which increased the bed dust capacity ten fold compared to a single-layer bed of the same sand and the same total bed pressure drop. The dust cake on the surface of the fine sand layer raised the collection efficiencies to over 99.99%.
基金This project is financially supported by the National Nature Science Fund (59785016) and the Opening Fund ([2000]002) of the N
文摘The microstructure of laser welds of sub-micron particulate-reinforced aluminum matrix composite Al_2O_(3p)/6061Al and the weldability of the material were studied. Experimental results indicated that because of the huge specific surface area of the reinforcement, the interfacial reaction between the matrix and the reinforcement was re- strained intenslvely at elevated temperature and pulsed laser beam. The main factor affecting the weldability of the com- posite was the reinforcement segregation in the weld resulting from the push of the liquid/solid interface during the soli- dification of the molten pool. The laser pulse frequency directly affected the reinforcement segregation and the reinfor- cement distribution in the weld, so that the weldability of the composite could be improved by increasing the laser pulse frequency. On the basis of this, a satisfactory welded joint of sub-micron paniculate-reinforced aluminum matrix com- posite Al_2O_(3p)/6061Al was obtained by using appopriate welding parameters.
文摘A study was made of influences of vacuum-baking treatment to SiC particulates on preparing cast Al-martix composite. By means of quadripole mass analyser(QMA), gases absorbed on the surface of SiC particulate have been investigated, it is found that gases and pollutants absorbed on the surface prohibit SiC particulates from uniformly dispersing in the alloy melt.
基金Project supported by the Excellent Doctor Foundation of Lanzhou University.
文摘Voluminously epidemiological studies show that the relationships exist between the air pollution and human health and cancer. Aromatic hydrocarbons (AHs) in air form a large class of organic pollutants, which are widely in environment and many of them are known to be carcinogenic and/or mutagenic and contribute to ambient air pollution. In the past decades, bioassays mainly have been used to evaluate the toxicity of chemical mixtures in atmospheric particulates or aqueous environment. However, it is well known that the covalent complexes formed by carcinogens with DNA may be exert negative results in bioassay. So the main aim of this paper is to develop an evaluation method of toxicity effects of chemical mixtures in atmospheric particulates from chemical standpoint. In this study, the in vitro interaction of the AHs with DNA was investigated by absorption, fluorescence and resonance light scattering (RLS) spectroscopic techniques. The results showed that the AHs in the atmospheric particulates could combine with calf thymus DNA (ctDNA) and herring sperm DNA (hsDNA) without being activated or metabolized by organism, respectively. Intercalation may be present in the mechanism of interaction. The binding constants of the AHs with ctDNA and hsDNA were 2.5x102 and 2.0x103, respectively, which indicated that the interaction of the AHs with hsDNA is stronger than that with ctDNA. In addition, the relationships of dose-effect between the total mole concentration of chemical components and the ability of binding ctDNA and hsDNA were confirmed. This research made it possible to study the toxicity effects of chemical mixtures in atmospheric particulates by chemical method. It is believed that the composition and contents of unknown AHs and the interaction of DNA with AHs in atmospheric particulates of Xigu District of Lanzhou City, China are first reported in the past twenty years.
基金Project supported by the National Natural Science Foundation of China (No.20437020)Major Research Program of Chinese Academy of Sciences (No.KZCX3-SW-432).
文摘Seven polycyclic aromatic hydrocarbons (PAHs) in atmospheric particulates were determinated by high performance liquid chromatography (HPLC) with fluorescence detector using direction injection and an on-line enrichment trap column. The method simplified the sample pretreatment, saved time and increased the efficiency. With the on-line trap column, PAHs were separated availably even underground injecting 1.0 ml sample with relatively high column efficiency. The recoveries of the seven PAHs were from 85% to 120% for spiked atmospheric particulate sample. The limit of detection was 15.3-39.6 ng/L (S/N=3.3). There were good linear correlations between the peak areas and concentrations of the seven kinds of PAHs in the range of 1-50 ng/ml with the correlation coefficients over 0.9970. Furthermore, it also indicated that the method is available to determine PAHs in atmospheric particulates well.
基金Supported by the Science and Technology Funding Project of Shantou City,China([2015]106)
文摘Based on on-line single particle aerosol mass spectrometry (SPAMS) with high time resolution, the sources of atmospheric fine particu- late matter in Nan'ao County were analyzed. The results showed that during the monitoring period from March 24 to 27 in 2015, the primary source of fine particulate matter in Nao'ao County was motor vehicle exhaust, that is, 24.7% of fine particulates were from motor vehicle exhaust, followed by biomass burning (17.2%), fire coal (17.2%), and sea salt (13.3%). The proportions of fire coal and sea salt revealed the peculiarity of sources of atmospheric fine particulate matter in Nan'ao County. Therefore, it is suggested that some measures should be adopted to limit tourist traffic to reduce the adverse impact of motor vehicle exhaust on ambient air quality in Nan'ao County.
基金supported by the funding from the National Natural Science Foundation of China[No.81472955,82073596 and 91643203]。
文摘Objective This study aimed to use an air-liquid interface(ALI)exposure system to simulate the inhalation exposure of motorcycle exhaust particulates(MEPs)and then investigate the benchmark dose(BMD)of MEPs by evaluating cell relative viability(CRV)in lung epithelial BEAS-2B cells.Methods The MEPs dose was characterized by measuring the number concentration(NC),surface area concentration(SAC),and mass concentration(MC).BEAS-2B cells were exposed to MEPs at different concentrations via ALI and CRV was determined using Cell Counting Kit(CCK-8)assay.BMD software was applied to calculate BMD and the lower limit of benchmark dose(BMDL)according to Akaike Information Coefficient(AIC),with P-value based on Hill,Linear,Polynomial,and Power model.Results Our results reveal that BMD of NC and SAC were estimated by the best-fitting Hill model,while MC was estimated by Polynomial model.The BMDL for CRV following ALI exposure to MEPs were as follows:364.2#/cm^(3)for NC;0.662×10^(7)nm^(2)/cm^(3)for SAC;and 0.278μg/m^(3)for MC.Conclusion These results indicate that MEPs exposure via ALI system induces a dose-dependent decrease of CRV and provides the potential exposure threshold of MEPs in a lung cell model.
基金Under the auspices of National Natural Science Foundation of China(No.41171269,41101378)
文摘This study presents an investigation of the scattering and backscattering properties of the particulates in three Chinese inland lakes(the Taihu Lake, the Chaohu Lake and the Dianchi Lake) based on in situ measurements taken at 119 sites. We modeled the particulate scattering spectra using a wavelength-dependent power-law function, finding that the power-law exponents in the Taihu Lake and the Chaohu Lake differ from those in the Dianchi Lake but are similar to the values in the U.S. coastal waters. In contrast to the open ocean, the backscattering properties in the three lakes can not be determined only from chlorophyll-a concentration. The backscattering ratio spectra exhibit a wavelength dependence feature in all three lakes, generally decreasing with the increasing wavelength. Analysis results of the correlations between the backscattering ratio and the individual water quality parameters clearly show that there are distinctive relations among the three lakes, attributed primarily to different compositions of optically active materials in the three lakes. Analysis of the mass-specific scattering and backscattering coefficients shows that the coefficients at wavelength 532 nm in the Taihu Lake and Chaohu Lake are similar, but they are apparently different from those in the Dianchi Lake. Lastly, Model I multiple linear regressions were adopted to partition the mass-specific cross-sections for scattering and backscattering into organic and inorganic cross-sections to further interpret the scattering and backscattering properties. The relative contribution of organic and inorganic particulates to scattering and backscattering is clearly different among the three lakes. The scattering and backscattering properties of the particulates in the three inland lakes vary significantly based on our collected data. The results indicated that the existing semi-analytical water quality retrieval models of the Taihu Lake can not be applied perfectly to the Chaohu Lake and the Dianchi Lake.
文摘A method was developed for the determination of trace arsenic by spectrophotometry. The proposed method is rapid, simple, and inexpensive. This method can be used for sensitive determination of trace arsenic in environmental samples and especially in air particulates. The results obtained by this method as a proposed method were compared with those obtained by hydride generation atomic absorption spectrometry as a popular reported method for the determination of arsenic and an excellent agreement was found between them. The method was also used for determination of arsenic associated with airborne particulate matter and diesel exhaust particulates. The results showed that considerable amount of arsenic are associated with diesel engine particulates. The variation in concentration of arsenic was also investigated. The atmospheric concentration of arsenic was different in different sampling stations was dependent to the traffic density.